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5th International Conference on Chemical and Bioprocess engineering, ICCBPE 2015

作者： Wisessirikul, W. Loykulnant, S. Montha, S. Fhulua, T. Prapainainar, P. Interdisciplinary Graduate Program in Advanced and Sustainable Environmental Engineering Thailand Advanced Institute of Science and Technology Tokyo Institute of Technology Kasetsart University Bangkok10900 Thailand Natural Rubber Focus Unit National Metal and Materials Technology Center NSTDA 111 Paholyothin Rd. Klong 1 Klong Luang Pathumthani12120 Thailand Environment Research Unit National Metal and Materials Technology Center NSTDA 111 Paholyothin Rd. Klong 1 Klong Luang Pathumthani12120 Thailand National Center of Excellence for Petroleum Petrochemicals and Advance Materials Department of Chemical Engineering Faculty of Engineering Kasetsart University Thailand Center of Excellence of Nanotechnology Kasetsart University Thailand

This research studied the quantity of free formaldehyde released from 2- [(hydroxymethyl)amino]ethanol (HAE) in DI water and natural rubber latex mixture using high-performance liquid chromatography (HPLC) technique. The quantity of formaldehyde retained in the solution was cross-checked by using titration technique. The investigated factors were the concentration of preservative (HAE), pH, and temperature. Taguchi's method was used to design the experiments. The number of experiments was reduced to 16 experiments from all possible experiments by orthogonal arrays (3 factors and 4 levels in each factor). Minitab program was used as a tool for statistical calculation and for finding the suitable condition for the preservative system. HPLC studies showed that higher temperature and higher concentration of the preservative influence the amount of formaldehyde released. It was found that conditions at which formaldehyde was released in the lowest amount were 1.6%w/v HAE, 4 to 40 °C, and the original pH. Nevertheless, the pH value of NR latex should be more than 10 (the suitable pH value was found to be 13). This preservative can be used to replace current preservative systems and can maintain the quality of latex for long-term storage. Use of the proposed preservative system was also shown to have reduced impact on the toxicity of the environment. © Published under licence by IOP Publishing Ltd.

关键词： Formaldehyde

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2-[(Hydroxymethyl)amino]ethanol in water as a preservative: Study of formaldehyde released by Taguchi's method

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IOP Conference Series: Earth and Environmental Science 2016年第1期36卷

作者： W Wisessirikul S Loykulnant S Montha T Fhulua P Prapainainar Interdisciplinary Graduate Program in Advanced and Sustainable Environmental Engineering Thailand Advanced Institute of Science and Technology and Tokyo Institute of Technology Kasetsart University Bangkok 10900 Thailand Natural Rubber Focus Unit National Metal and Materials Technology Center NSTDA 111 Paholyothin Rd. Klong 1 Klong Luang Pathumthani 12120 Thailand Environment Research Unit National Metal and Materials Technology Center NSTDA 111 Paholyothin Rd. Klong 1 Klong Luang Pathumthani 12120 Thailand National Center of Excellence for Petroleum Petrochemicals and Advance Materials Department of Chemical Engineering Faculty of Engineering Kasetsart University Thailand Center of Excellence of Nanotechnology Kasetsart University Thailand

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Effect of Vegetable Oils as Processing Aids in SBR Compounds

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Macromolecular Symposia 2015年第1期354卷

作者： Worawan Pechurai Warunee Chiangta Pariya Tharuen Program in Rubber and Polymer Technology Faculty of Engineering and Agro-Industry Maejo University Chiangmai 50290 Thailand

This research was studied on the cure characteristics and mechanical properties of rubber compounds using vegetable oil as the processing aid in styrene butadiene rubber compound such as castor oil and jatropha oil in comparison with petroleum based aromatic oil. The quantities of the oils varied from 0 to 9 phr. The study showed that the cure characteristics in terms of maximum torque and torque difference tended to decrease with increasing concentrations of oils, while scorch time and cure rate index increased. Moreover, hardness and 100% modulus tended to decrease as increasing loading levels of the oils in the SBR vulcanizates while elongation at break increased. However, tensile strength was not significantly affected. For using the vegetable oils, we found that abrasion resistance and rebound resilience were better than those of aromatic oil, and also displayed high hardness. It could be concluded that the vegetable oils were better alternative processing aids compared to aromatic oil, which has been reported as carcinogenic.

关键词： castor oil jatropha oil processing aid styrene butadiene rubber vegetable oil

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Evaluation of biodegradable plastics for rubber seedling applications

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AIP Conference Proceedings 2015年第1期1674卷

作者： Mohd Khairulniza Mansor Dayang Habibah A. I. H. Mazlina Mustafa Kamal aHigh Value-Added Rubber Products and Nanostructured Materials Program Technology and Engineering Division Rubber Research Institute of Malaysia Malaysian Rubber Board 47000 Sg. Buloh Selangor Darul Ehsan Malaysia

The main negative consequence of conventional plastics in agriculture is related to handling the wastes plasticand the associated environmental impact. Hence, a study of different types of potentially biodegradable plastics used for nursery applications have been evaluated on its mechanical,water absorption propertiesand Fourier transform infra-red (FTIR) spectroscopy. Supplied samples from different companies were designated as SF, CF and CO. Most of the polybags exhibited mechanical properties quite similar to the conventional plastics (polybag LDPE). CO polybag which is based on PVA however had extensively higher tensile strength and water absorption properties. FTIR study revealed a characteristics absorbance of conventional plastic, SF, CF and CO biodegradable polybag are associated with polyethylene, poly(butylene adipate-co-terephthalate) (PBAT), polyethylene and polyvinyl alcohol (PVA) structures respectively.

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The Potential of Perlite as an Odour-Adsorbing Fillers in Natural rubber Vulcanizates

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Macromolecular Symposia 2015年第1期354卷

作者： Tithinun Rattanaplome Philaiwan Pornprasit Napat Chantaramee Rubber and Polymer Technology Program Faculty of Engineering and Agro-Industry Maejo University Chiang Mai 50290 Thailand Materials Science Program Faculty of Science Maejo University Chiang Mai 50290 Thailand

The objective of this research was to reduce an offensive odour by using perlite as an odour-adsorbing filler. Perlite was mixed with highly odorous STR20 and RSS5. Perlite content was varied at 0, 10, 20 and 30 phr. The ability to reduce odour by sensory method and GC-MS were examined. Cure characteristics and mechanical properties, such as tensile strength, hardness and abrasion resistance, were also determined. From the sensory method, the odour reduction efficiency increased with increasing perlite *** an addition of perlite, the reduction of some components from an offensive odour, such as thiourea and benzothiazole, was also observed using GC-MS technique. Furthermore, the addition of perlite showed an increase in torque difference, a slight change in scorch time and a decrease in cure time, an increase in hardness and abrasion resistance but a decrease in tensile strength. Perlite was shown to be comparable to clay with respect to mechanical properties and potentially be used as low-cost and odour-adsorbing filler.

关键词： clay mechanical properties natural rubber odour-adsorbing filler perlite

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Grafting of maleic anhydride onto deproteinized natural rubber via differential microemulsion polymerization

Grafting of maleic anhydride onto deproteinized natural rubb...

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CAN 2012 11th International Conference on Advances and Trends in engineering Materials and Their Applications, AES-ATEMA 2012

作者： Wongthong, Pinyo Nakason, Charoen Pan, Qinmin Rempel, Garry L. Kiatkamjornwong, Suda Program in Petrochemistry Chulalongkorn University Bangkok 10330 Thailand Dept. of Rubber Technology and Polymer Science Prince of Songkla University Pattani 94000 Thailand Dept. of Chemical Engineering Soochow University Suzhou 215123 Jiangsu China Dept. of Chemical Engineering University of Waterloo Waterloo ON N2L3G1 Canada Dept. of Imaging and Printing Technology Chulalongkorn University Bangkok 10330 Thailand Division of Science Royal Institute of Thailand Sanam Suepa Dusit Bangkok 10300 Thailand

ISBN: (纸本)9780987994523

The graft copolymerization of maleic anhydride (MA) onto deproteinized natural rubber (DPNR) was performed by differential microemulsion polymerization. The chemical structure of the graft copolymer was characterized by Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) spectroscopies. The influences of the monomer and initiator concentrations, reaction temperature, and reaction time on the grafting efficiency and gel fraction were elucidated. It was found that the grafting efficiency increases with increasing the amount of the initiator. High grafting efficiency at high reaction temperature was observed. The grafting efficiency was found to be more than 90% under the best condition for the graft copolymerization at 10 phr of MA and 7 phr of benzoyl peroxide at 80 °C for 8 h. However, low gel fraction was found at low reaction temperature (60 °C). Thermal properties of the grafted natural rubber were also investigated. The graft copolymer in this work shall be used as a blend compatibilizer for blending of natural rubber and thermoplastic to produce thermoplastic elastomers in our future work. © 2012, Advanced engineering Solutions.

关键词： Chemical modification

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Abstracts of papers presented at the 14th conference of the Weed Science Society of Israel Abstracts of papers presented at the international conference on controlled atmosphere and fumigation (CAF) in stored products Abstracts of papers presented at the joint international conference of FAOPMA — CEPA on pest control in the 21st century Abstracts of papers presented at the 2nd international Agro-Ecology Symposium on integrated pest management: from the drawing board to the market

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Phytoparasitica 1996年第3期24卷 199-265页

作者： E. Yogev M. Berson Y. Benyamini Y. Sheinboim T. Lev-Ran A. Bahat Y. Barkai Y. Gatti M. Zaidan O. Barazani Y. Boshvize S. Graph U. Luchinsky T. Blumenfeld Y. Kleifeld G. Herzlinger H. Bucsbaum S. Golan T. Chilf R. Aly Y. Ohali A. Ovadia Y. Chachlon H. Yovel Y. Tesler G. Colodney A. Nir S. Zarka A. Tal B. Rubin T. Yaacoby Y. Alon Y. Kedar Orit Ben-Zvi Assaraf O. Shainberg H. D. Rabinowitch E. Tel-Or Y. Goldwasser D. M. Joel D. Plakhine V. Portnoy G. Tzuri N. Katzir Dalia Losner-Goshen A. M. Mayer R. Jacobsohn Z. Tanaami H. Eisenberg Ziva Amsellem Z. Kernyi L. Hornok J. Gressel Adiva Shomer-Ilan Ela Nir Daphna Michaeli V. Kampel A. Warshawsky M. Yogev M. Negbi J. Hershenhorn Y. Lavan T. Hilf M. Horowitz M. Cohen I. Hirsch A. Veneziani S. T. Conyers C. H. Bell Ana C. Sá-Fischer C. S. Adler Ch. Reichmuth P. W. Flinn D. W. Hagstrum G. N. Mbata R. G. Winks Elisabeth A. Hyne M. Q. Chaudhry A. D. MacNicoll N. R. Price M. Schöller J. -F. Dugast R. Plarre S. Navarro E. J. Donahaye R. Diaz Miriam Rindner A. Azrieli P. Trematerra F. Fontana M. Mancini Ailsa D. Hocking Marta H. Taniwaki J. Lacey A. Hamer N. Magan N. Paster F. M. Caliboso D. G. Alvindia G. C. Sabio M. T. dela Cruz Okky Setyawati Dharmaputra A. S. R. Putri M. Sidik Eleni Papademetriou A. Varnava C. Mouskos M. A. Malek B. Parveen K. A. Dzisi W. O. Ellis Ana Maria Estevez Ljubica Galletti T. Fichet E. Oteiza L. A. Lizana M. X. Gonzalez B. Yakobson Y. Slavezky H. Ephrati El-H. Bartaly R. K. Kashyap M. Gupta W. L. Kashyap B. S. Dahiya A. K. Dash J. R. Rangaswamy R. D. Shroff D. S. Jayas W. E. Muir N. D. G. White L Gaye Weller J. E. van S. Graver Wu-Kang Peng M. Bengston E. Alip C. Reed J. G. Leesch G. F. Knapp G. F. Russell L. B. Llewellin Ch. Ulrichs H. J. Banks P. C. Annis R. Allanson R. Tauscher K. Westphal S. Mohan M. Gopalan P. C. Sumdarababu V. V. Sree Narayanan Sabine Prozell G. Ziegleder B. Schartmann R. Matissek J. Kraus D. Gerard S. Rogg W. Raemann R. F. Ryan Ya-Nan Wang R. T. Noyes P. Kenkel J. T. Criswell G. W. Cuperus C. J. Waterford C. P. Whittle L. Be Luxembourg Chemicals and Agriculture Ltd. Tel Aviv Israel Agrochemicals Dept. Milchan Bros. Ltd. Ramat Gan Israel Extension Service Ministry of Agriculture Zefat Mevo Hamma Ramat HaGolan Israel Dept. of Weed Science ARO Newe Ya’ar Research Center Haifa Israel Agrochemicals Department Milchan Bros. Ltd. Ramat Gan Israel Tarsis-Agrichem Tel Aviv Israel Weed Control Co. Ltd. Bet Dagan Israel Dept. of Field Crops Vegetables and Genetics The Hebrew University of Jerusalem Faculty of Agriculture Rehovot Israel Plant Protection and Inspection Services Ministry of Agriculture Bet Dagan 50250 Agan Chemical Manufacturers Ltd. Ashdod Israel Dept. of Field Crops Vegetables and Genetics Rehovot Dept. of Agricultural Botany The Hebrew University of Jerusalem Faculty of Agriculture Rehovot Israel Dept. of Weed Science ARO Newe Ya’ar Research Center Haifa Dept. of Botany The Hebrew University of Jerusalem Jerusalem Israel Dept. of Vegetable Crops ARO The Volcani Center Bet Dagan Israel Dept. of Plant Genetics Weizmann Institute of Science Rehovot Israel Inst. for Plant Science Agricultural Biotechnology Center Gödöllö Hungary Dept. of Botany Tel-Aviv University Tel Aviv Israel Dept. of Plant Genetics The Weizmann Institute of Science Rehovot Israel Dept. of Organic Chemistry The Weizmann Institute of Science Rehovot Israel Dept. of Ornamental Horticulture ARO The Volcani Center Bet Dagan Israel Weed Control Co. Ltd. Bet Dagan Chem-Nir Ltd. Kefar Shemaryahu Tiveon-Chem Co. Haifa Israel Central Science Laboratory Ministry of Agriculture Fisheries and Food Slough Berks UK Federal Biological Research Centre for Agriculture and Forestry Inst. for Stored Product Protection Berlin Germany USDA-ARS Grain Marketing and Production Research Center Manhattan USA School of Biological Sciences Abia State University Uturu Nigeria CSIRO Division of Entomology SCMC Nambour CSIRO Division of Entomology Canberra Australia DowElanco Europe Letcombe Laboratory L

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FLAMMABILITY AND TOXICITY OF COMPOSITE-MATERIALS FOR MARINE VEHICLES

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NAVAL ENGINEERS JOURNAL 1990年第5期102卷 45-54页

作者： SEVART, JL GRIFFIN, OH GURDAL, Z WARNER, GA Jeffrey L. Sevart:is a native of Kansas and a 1985 graduate of Kansas State University with a B.S. in mechanical engineering (magna cum laude). After working as a stress analysis engineer at Boeing Military Airplane Company in Wichita Kans. he attended Virginia Polytechnic Institute and State University and received an M.S. in engineering mechanics in February 1988. He currently resides in Akron Ohio working as a research engineer in tire composites research at The Goodyear Tire and Rubber Company. O. Hayden Griffin Jr.:received his B.S. and M.S. in mechanical engineering from Texas Tech University in 1970 and 1971 respectively. He received his Ph.D. in engineering mechanics from Virginia Polytechnic Institute and State University in 1980. Prior to joining the faculty of Virginia Polytechnic Institute and State University as associate professor of engineering science and mechanics in September 1985 he was employed at the U.S. Naval Surface Warfare Center (Dahlgren Virginia) BF Goodrich Tire Group (Akron Ohio) the Bendix Advanced Technology Center (Columbia Maryland) and the Johns Hopkins University Applied Physics Laboratory (Laurel Maryland). He is currently an associate director of the Virginia Institute for Material Systems. He is a registered professional engineer in Virginia and is a member of the American Society of Mechanical Engineers and the American Society for Composites. Zafer Gürdal:received his M.S. in mechanical and aerospace engineering from Illinois Institute of Technology in 1981 and his Ph.D. in aerospace engineering from Virginia Polytechnic Institute and State University in 1985. He worked as a research associate in the Aerospace and Ocean Engineering Department at Virginia Tech before joining the Engineering Science and Mechanics Department as an assistant professor in September 1985. Professor Gürdal's research interests include: composite structures failure mechanics of composites structural optimization and damage tolerant design. He is a member of the American Institute

Characteristics of both thermoplastic and thermoset composite materials as they pertain to marine vehicle applications are discussed. Comparison of various material selection factors such as strength, damage and moisture resistance, and flammability and toxicity as well as cost and availability of thermoset and thermoplastic composite materials are presented. Methods for testing and reducing the flammability and toxicity are discussed. Many commercially available composite systems are reported to provide favorable characteristics for marine applications. Although there seems to be a need for improved production technology for thermoplastics, they present potential advantages in physical properties over thermoset composites.

关键词： Composite Materials

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