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Sub- and Supercritical Water Flooding for Enhanced Oil Recovery in High Water Cut Heavy Oil Reservoirs: An Experimental Study

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SSRN 2024年

作者： Miao, Yan Zhao, Qiuyang Huang, Zujie Zhao, keyu Zhao, Hao Guo, Liejin Wang, Yechun State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Xinjin Weihua Institute of Clean Energy Research Foshan528216 China

High water cut poses a formidable challenge for heavy oil reservoirs, necessitating a strategy to enhance oil recovery. This study introduces a green-efficient approach - Supercritical Water Flooding (SCWF), suitable for sandstone heavy oil reservoirs with high water cut, compared to conventional subcritical water flooding and steam flooding. A novel experimental system (450°C,30MPa) was established to conduct SCWF experiments for heavy oil from Shengli Oilfield. The results showed that SCWF at 400°C and 25MPa had the recovery factor of 96.27% and the viscosity reduction rate of 61.6% for GD heavy oil. The dynamic process of SCWF is divided into three stages: pressure rising drainage stage, heating and depressurization stage, and miscible flooding stage. Analysis indicates that the high diffusivity, solubility and reactivity of supercritical water make thermal fluid breakthrough, miscible flooding and aquathermolysis reactions become the key mechanisms for high oil recovery and in situ upgrading of SCWF for high water cut heavy oil reservoirs. © 2024, The Authors. All rights reserved.

关键词： Crude oil

Comparison of Gelatinous and Calcined Magnesia Supported Ni or/And Co-Based Catalysts for Aqueous Bioglycerol Phase Reforming

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SSRN 2021年

作者： Liu, Dashuai Dou, Binlin Zhang, Hua Wu, Kai Zhao, Longfei Zeng, Pingchao Chen, Haisheng Xu, Yujie School of Energy and Power Engineering Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering University of Shanghai for Science and Technology Shanghai200093 China Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing100190 China

In this study, glycerol aqueous phase reforming was carried out in a batch reactor. The gases produced were H2, CO, CH4, and CO2 during the experiment. The catalysts used included Ni or/and Co catalysts supported by MgO. Meanwhile, two different MgO supporters were prepared by the sol-gel method and calcining method, and the active metal was added by an initial wet impregnation (IWI) method. The catalysts were characterized by BET, BJH, TEM, and XRD. In order to achieve the purpose of comparison, the activity of different types of catalysts was tested under similar conditions. It was found that the amount of hydrogen produced by the catalyst containing gelatinous MgO supporter is more than 1.5 times that of other catalysts, and the Ni-Co-MgO had the best catalytic effect among the same types of catalysts. The activity of the Ni-Co-MgO catalyst was tested under different temperatures, concentrations, and CaO conditions. We found that Ni-Co bimetallic catalyst supported on gelatinous MgO has the best highest gas production, while the catalyst containing calcined MgO support usually has a better hydrogen selectivity. Through the stability study of the Ni-Co-MgO catalyst, we found that the bimetallic catalyst supported by gelatinous MgO support has better catalytic stability. © 2021, The Authors. All rights reserved.

关键词： Sol-gel process

RECENT ADVANCES OF SURFACE WETTABILITY EFFECT ON flow BOILING HEAT TRANSFER PERFORMANCE

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Frontiers in Heat and Mass Transfer 2021年 17卷

作者： Cao, Shuang Yang, Hui Zhao, Luxing Wang, Tao Xie, Jian School of Energy and Power Engineering Zhengzhou University of Light Industry Zhengzhou450002 China Beijing Key Laboratory of Multiphase Flow and Heat Transfer for Low Grade Energy Utilization North China Electric Power University Beijing102206 China

flow boiling heat transfer is an effective way to fulfill the energy transfer. The wettability of boiling surface influences the liquid spreading ability and the growth, departure, and release frequency of bubbles, which determines the heat transfer performance. According to the wettability and combination forms, boiling surface are classified into weak wetting surface, strong wetting surface, and heterogeneous wetting surface. Fabricating by physical, chemical method or coating the original surface with a layer of low surface energy, the weak wetting surface has more effective activation point and nucleation center density to improve heat transfer performance at low heat flux. The strong wetting surface always formed by physical or chemical treatment to enhance the rapid rewetting of the wall surface. It has a smaller bubble separation diameter, higher separation frequency and higher CHF. The heterogeneous wetting surface, having the synthetic effects of the strong and weak surface wettabilities, is a hot issue of recent study. But its composition and heat transfer enhancement mechanism are very complicated which need to study thoroughly. Furthermore, the intelligent wetting surface, having the dynamics wettability function, is also briefly analyzed in this paper. Despite the advances in this aspect, the boiling surfaces can be further optimized by fabricate effective wettability to achieve a strong stability, high heat transfer performance and realize the synergistic effect of flow pattern and heat transfer. © 2021, Global Digital Central. All rights reserved.

关键词： Wetting

Under-Deposit Corrosion Behavior and Dynamic Deliquescence Properties of Ammonium Salts Covered on Pipelines and Components in a Crude Oil Distillation Column: Experimental and Theoretical Studies

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SSRN 2022年

作者： Li, Ruidong Chen, Jukai Wang, Yueshe State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi'An710049 China School of Chemical Engineering & Technology China University of Mining and Technology Xuzhou221116 China

Electrochemical experiments based on the interdigital electrodes of SAE 1020 steel and atomic simulation were performed to investigate the under-deposit corrosion behavior and dynamic deliquescence properties of ammonium salts. In-situ electrochemical measurements demonstrate that the deliquescence of ammonium salts affects the evolution of the interface, and the surface characterization results proved that the critical state of moisture absorption leads to the most severe corrosion. Additional ab initio molecular dynamics simulations suggest that the H transport chain impacted by the hydrolysis of NH4+ leads to a variation in the charge state of the system, which may triggering corrosion. © 2022, The Authors. All rights reserved.

关键词： Steel corrosion

Simulation Study on the Dynamic Characteristics of Natural Circulation Coupled Phase Change Material for Equal Height Difference Passive Containment Cooling System

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SSRN 2024年

作者： Chen, Weixiong Huang, Yufan Wang, Han Yang, Xiaohu Li, Shaodan Zhao, Quanbin Chong, Daotong State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Wuhan Second Ship Design and Research Institute Wuhan430205 China

The passive containment cooling system (PCCS) plays a significant role in ensuring the safety of nuclear power plants. To further reduce peak pressure in the containment during a loss of coolant accident (LOCA), phase change materials (PCMs) are utilized to improve the system’s cooling effectiveness. The dynamic simulation model of PCCS has been developed using Apros software. This article focuses on examining the system’s dynamic characteristics related to various tube startup methods and comparatively analyzing the impact of different PCM thicknesses on heat transfer capacity. The results indicate that post-accident, PCM significantly suppresses peak pressure in the containment. Under the full tube startup method with 4 mm PCM, the peak pressure decreases to 1.75 MPa, whereas under the empty tube startup method, it is reduced to 1.69 MPa. With natural circulation empty tube startup method, PCM can reduce pressure change intensity in the containment but negatively affects natural circulation heat transfer. Although the full tube startup method underperforms the empty tube startup method on suppressing peak pressure, PCM can positively affect natural circulation heat transfer in the early stages of the accident. Empty tube startup offers the advantages of higher heat transfer capacity and lighter weight, making it the optimal choice for ocean nuclear platforms. Additionally, the higher peak power of PCM heat transfer under the empty tube startup method indicates that system can withstand larger thermal shocks. © 2024, The Authors. All rights reserved.

关键词： Thermoelectric equipment

A High-Performance VS2-Modifed Separator for Lithium–Sulfur Batteries

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A High-Performance VS2-Modifed Separator for Lithium–Sulfur...

中国化学会第三届中国能源材料化学研讨会

作者： Jianan Wang Guorui Yang Shanshan Yi Ling Wang Silan Wang Wei Yan Shujiang Ding Department of Environmental Science and Engineering State Key Laboratory of Multiphase Flow in Power EngineeringXi'an Jiaotong University Department of Applied Chemistry School of ScienceState Key Laboratory for Electrical Insulation and Power EquipmentXi'an Jiaotong Univrsity School of Electronic and Information Engineering Xi'an Jiaotong University

Lithium–sulfur（Li-S） batteries are a promising candidate to couple renewable energy sources for green transportation and large-scale energy storage because of their relatively low cost and high theoretical specific capacity(1,675 mA h g).However,a major problem preventing the practical applications of Li-S batteries is the rapid capacity fading,predominantly due to the "shuttle effect" of polysulphides（LiPSs）.

关键词： A High-Performance VS2-Modifed Separator for Lithium Sulfur Batteries

Research of Cooling Tower Filler Based on Radial Basic Function Artificial Neural Network (Rbf Ann)

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SSRN 2022年

作者： Chen, Jie Zhang, Lixin Zhao, Shunan Chen, Yongbao Song, Huijuan Liu, Jingnan Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering School of Energy and Power Engineering University of Shanghai for Science and Technology Shanghai200093 China China Institute of Water Resources and Hydropower Beijing100038 China

The filler is the core component of a cooling tower for heat dissipation. The empirical formulas of N, β xv , and ΔP are constitute the performance of filler. In certain conditions, the formulas are obtained by experiments. Performance equations for identical countercurrent fillers are different at varying heights or seawater concentrations. The conventional method is linear interpolation to obtain the filler performance under different conditions. But its uncertainty limits the application of the performance equation to some extent. Therefore, the RBF ANN is adopted to analyze the filler performance based on the existing performance equations in this paper. The dataset is generated by the filler performance equations. The results show that RBF ANN has a preferable prediction effect of filler performance with high correlation (R>0.99) and prediction accuracy (N 10 >90%). In addition, the trend of the predicted results and the experimental results of the filler performance is consistent. Therefore, RBF ANN can accurately predict the filler performance at different heights and different seawater concentrations, which provides the basis for the design of cooling towers. © 2022, The Authors. All rights reserved.

关键词： Cooling towers

Spray, ignition and combustion characteristics of biodiesel and diesel fuels injected by micro-hole nozzle under ultra-high injection pressure

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Spray, ignition and combustion characteristics of biodiesel ...

8th International Conference on Modeling and Diagnostics for Advanced Engine Systems, COMODIA 2012

作者： Kuti, Olawole Abiola Zhu, Jingyu Nishida, Keiya Wang, Xiangang Huang, Zuohua Department of Mechanical Engineering Federal University of Technology PMB 704 Akure Ondo State Nigeria Department of Mechanical System Engineering University of Hiroshima 1-4-1 Kagamiyama Higashi-Hiroshima 739-8527 Japan Changan Automobile Corporation No. 199 Wuhong Road Yubei District Chonqing China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

The spray and combustion characteristics of biodiesel (BDF) and diesel fuels injected by a micro-hole nozzle of 0.08 mm diameter under increasing injection pressure up to ultra-high value of 300 MPa were investigated in this research. The LIF-PIV (Laser Induced Fluorescence- Particle Image Velocimetry) technique was used to investigate the spray and entrained gas characteristics of the fuels while the OH chemiluminescence and two color techniques were utilized to study the ignition and combustion characteristics of the spray flames. From the research it was observed that at all injection pressures, due to inferior atomization processes, the normal velocity and total mass of the entrained gas by BDF was less compared to diesel. As a result of higher cetane number the BDF's flame ignition delay was shorter compared to diesel. The ratio of the mass flow rate of gas entrained to mass flow rate of injected fuel by BDF was less compared to diesel. Oxygen content in the BDF played a greater role in soot reduction as against the gas entrained. Copyright © 2012 by the Japan Society of Mechanical Engineers.

关键词： Biodiesel

Efficient Charge Transfer at the Donor-Bridge-Acceptor Interface for Excellent Supercapacitors

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SSRN 2023年

作者： Yin, Baoyi Hao, Liang Li, Xiaogan Yang, Qi-Guo Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering School of Energy and Power Engineering University of Shanghai for Science and Technology Shanghai200093 China School of Microelectronics Dalian University of Technology Dalian116024 China

The intrinsic electrochemical activity and active sites of the battery-like electrode in supercapacitors originate from efficient charge transfer at the interface. A seamless all-carbon graphdiyne layer on CoNi2S4 yolk-shell spheres (CoNi2S4/GDY YSSs) provides a unique structure of a flawless "donor–bridge–acceptor" interface, where Ni atoms and Co atoms serve as electron donors and acceptors, respectively, connected by the sp-C–Ni and sp-C–Co bonds as bridges. Importantly, this particular can facilitate effective electron transfer from the Ni atoms to the Co atoms, resulting in more interfacial Co2+ active sites. Additionally, the seamless all-carbon graphdiyne layer greatly enhances the structural and interfacial stabilities of CoNi2S4 yolk-shell spheres, effectively avoiding structural deterioration. Profiting from its structural merits, the CoNi2S4/GDY YSSs electrode delivers a considerable capacitance of 856 C/g at 1 A/g, along with exceptional rate capability (61.9% for 50-fold current density increase). Furthermore, an asymmetric supercapacitor with the CoNi2S4/GDY YSSs electrode cathode achieves a remarkable maximum energy density of 91.7 Wh/kg at a power density of 793 W/kg. Furthermore, the strategy proposed in this study has the potential to open up new pathways for the battery-like electrode design with realistic supercapacitor applications. © 2023, The Authors. All rights reserved.

关键词： Charge transfer