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Atomically Dispersed Co Sites on BiOCl Nanosheets for Efficient CO 2 Photoreduction

Green Energy & Environment 2025年

作者： Ting Peng Yiduo Wang Ke Wang Kaini Zhang Yiqing Wang Yufei Xu Qingqing Guan Guofu Wang Wenjie Zhang Binglan Wu Shaohua Shen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an 710049 China College of Chemical and Biological Engineering Zhejiang University Hangzhou 310058 China Institute of Zhejiang University-Quzhou Quzhou 324000 China

Efficient CO 2 photoreduction to produce fuel remains a great challenge, due to the fast recombination of photogenerated charge carriers and the lack of effective reactive sites in the developed photocatalysts. Herein, single Co atoms (Co SA ) were highly dispersed on hydrothermally synthesized BiOCl nanosheets (BOC) by a facile two-step electrostatic self-assembly and pyrolysis method. The obtained Co SA -BOC could be performed for efficient CO 2 photoreduction to stoichiometrically produce CO and O 2 at the ratio of 2:1, with the CO evolution rate reaching 45.93 μmol g –1 h –1 , ∼4 times that of the pristine BOC. This distinctly improved photocatalytic performance for Co SA -BOC should be benefited from the introduction of atomically dispersed Co-O 4 coordination structures, which could accelerate the migration of photogenerated charge carriers to surface by creating an impurity energy level in the forbidden band, and act as the reactive sites to deliver the photogenerated electrons to activate CO 2 molecules for CO production. This work provides a facile and reliable strategy to highly disperse single atoms on low-dimensional semiconductors for efficient CO 2 photoreduction to selectively produce CO.

关键词： photocatalysis CO 2 reduction BiOCl nanosheets single Co atoms

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Multi-physics analysis of the galvanic corrosion of Mg-steel couple under the influence of time-dependent anisotropic deposition film

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Journal of Magnesium and Alloys 2021年第3期9卷 866-882页

作者： Kai Wang Chenpei Li Yanhui Li Jinling Lu Yueshe Wang Xingqi Luo State Key Laboratory of Eco-hydraulics in Northwest Arid Region Xi'an University of TechnologyNo.5 Jinhua South RoadXi'an 710048China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityNo.28 Xianning West RoadXi'an 710049China

The anisotropic deposit film formed during the galvanic corrosion can impede the mass transfer of the involved species,thereby affecting the electro-chemical behavior and the evolution of galvanic *** limitations of experimental studies in the spatial-temporal scales restrict a deeper understanding of the corrosion mechanism,which can be complemented by numerical simulation.A multi-physics coupled model is proposed in this work to systematically investigate the temporal and spatial evolution of galvanic corrosion of the Mg-steel couple with the growing anisotropic deposition *** utilizing the multi-physics field coupled technique,various coupled physical-chemical processes underlying the corrosion behavior are built into the model,including chemical reactions,ionic mass transfer in the bulk solution and the deposition layer,interfacial reaction,deposition of corrosion products as well as the morphological transitions caused by metal dissolution and *** particular,the anisotropic deposit film is considered to be a porous layer with a porosity varying in time and space as the corrosion *** predicted corrosion morphology by this model is better than the previous *** coupled relationship between the electrochemical behavior(e.g.,electrode reaction kinetics,current density,surface potential)and the physical processes(e.g.,ionic transport,geometric evolution of metal surface and film interface)is *** results indicate that a porous deposition layer with a denser inner layer and a loose outer layer is generated,leading to more significant inhibition of mass transfer in the inner layer than the outer *** anisotropism of the deposition layer results in a non-uniform conductivity distribution and a discontinuous current density distribution in the *** current density on the electrode surface is inhibited by the deposition layer and the variation in the cathode/anode area ratio during the corrosion *** c

关键词： Galvanic corrosion Corrosion product film Modeling Mass transport Porosity

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Lattice Boltzmann method and its applications in engineering thermophysics

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Chinese Science Bulletin 2009年第18期54卷 4117-4134页

作者： HE YaLing LI Qing WANG Yong TANG GuiHua School of Energy and Power Engineering State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049 China

The lattice Boltzmann method (LBM), a mesoscopic method between the molecular dynamics method and the conventional numerical methods, has been developed into a very efficient numerical alternative in the past two decades. Unlike conventional numerical methods, the kinetic theory based LBM simulates fluid flows by tracking the evolution of the particle distribution function, and then accumulates the distribution to obtain macroscopic averaged properties. In this article we review some work on LBM applications in engineering thermophysics: (1) brief introduction to the development of the LBM; (2) fundamental theory of LBM including the Boltzmann equation, Maxwell distribution function, Boltzmann-BGK equation, and the lattice Boltzmann-BGK equation; (3) lattice Boltzmann models for compressible flows and non-equilibrium gas flows, bounce back-specular-reflection boundary scheme for microscale gaseous flows, the mass modified outlet boundary scheme for fully developed flows, and an implicit-explicit finite-difference-based LBM; and (4) applications of the LBM to oscillating flow, compressible flow, porous media flow, non-equilibrium flow, and gas resonant oscillating flow.

关键词：格子玻尔兹曼方法工程热物理格子Boltzmann 麦克斯韦分布函数分子动力学方法可压缩流动应用数值方法

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A novel mid-temperature chemical looping system with near-zero carbon emissions for hydrogen and power coproduction

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Energy 2025年 329卷

作者： Yang Li Yu Fang Mingkai Liu Kai Liu Zhongrui Gai Yuanhui Shen Ruqi Zhang Ying Pan Hongguang Jin Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing 100190 China University of Chinese Academy of Sciences Beijing 100049 China International Research Center for Renewable Energy & State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

Designing an efficient system for conversion of fossil fuel to hydrogen with lower environmental impact represents a promising strategy to meet the demands of a low-carbon future society. This study introduces an integrated chemical looping system combining hydrogen production and combustion for low-carbon fossil fuel conversion. The system achieves hydrogen production at 600 °C, significantly lower than conventional steam methane reforming (850 °C). Moreover, chemical looping combustion is employed to enable efficient CO 2 capture. The proposed system is investigated from key reactions, system performance, and economic feasibility aspects. Experimental results show 80 % methane conversion, a hydrogen yield of 2.6 in the hydrogen production process, and nearly 100 % CO 2 purity from purge gas combustion. Thermodynamic analysis reveals the energy and exergy efficiencies of 74.3 % and 68.9 %, surpassing the reference system by 3.6 % and 4.1 %, respectively. Economic assessment indicates a 10 % reduction in the levelized cost of hydrogen compared to the reference system. 1000 consecutive cycles confirm the outstanding stability of the oxygen carrier particles for the system. This study demonstrates the system's feasibility, cost-effectiveness, and potential for sustainable hydrogen production with minimal environmental impact, introducing a promising method for the efficient utilization of fossil fuels.

关键词： Differential thermal analysis

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Evaporation and drying characteristics of the sessile ferrofluid droplet under a horizontal magnetic field

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Fundamental Research 2022年第2期2卷 222-229页

作者： Zhaonan Liu Jiandong Zhou Yang Li Xin Zhuo Xiujuan Shi Dengwei Jing State Key Laboratory of Multiphase Flow in Power Engineering and International Research Center for Renewable Energy X^an Jiaotong UniversityXi'an 710049China

In this study,the evaporation characteristics and drying patterns of various sessile ferrofluid droplets on certain substrate under horizontal magnetic fields of controlled intensities are *** effects of droplet concentration and magnetic field intensity on the duration of each evaporation stage and drying patterns of droplets have been systematically *** turned out that a plateau appears at the initial stage of evaporation in the absence of magnetic field and it was found that the plateau value is positively correlated with the concentration of ferrofluid *** the external magnetic field,the evaporation time of droplets decreases,the stage of contact line retreat extends,the stage of late pinning mode shortens,and the deposition area of ferrofluid droplet decreases compared to that of without magnetics *** deposition area increases gradually and becomes more uniform with the increase of magnetic *** decrease of friction force which is due to the decrease of the number of nanoparticles at the contact line under external magnetic field is the main reason for the observed *** found that the coffee ring and the uniform deposition inside the droplet will be destroyed when the magnetic field intensity is higher than a critical *** work has a significant reference value for the evaporation of sessile magnetic fluid droplets under the applied magnetic field,especially when the drying pattern needs to be precisely controlled,such as in spray or biomedicine.

关键词： Ferrofluid Droplet Drying pattern Evaporation characteristics Magnetic field

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Development and technical progress in large-scale circulating fluidized bed boiler in China

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Frontiers in Energy 2020年第4期14卷 699-714页

作者： Zhong HUANG Lei DENG Defu CHE State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi'an Jiaotong UniversityXi'an 710049China

Circulating fluidized bed(CFB)boilers has realized the clean and efficient utilization of inferior coal like gangue and coal slime,high sulfur coal,anthracite,petroleum coke,oil shale and other *** a country with the largest amount of CFB boilers and the largest installed capacity in the world,China has 440100-600 MWe CFB boilers with a total capacity of 82.29 GWe,including 227 units of 135 MWe,95 units of300 MWe,and 24 supercritical *** statistics of typical 100-300 MWe CFB boilers showed that the average number of unplanned shut-down was only 0.37 times per year,among which the 135 MWe was 0.26 times per year and 300 MWe was 0.46 times per ycai*.The auxiliary power ratio of some 300 MWe CFB boilers based on flow-pattern reconstruction can be reduced to about 4%,which is closed to the same level of pulverized coal(PC)*** paper summarizes the development process and application status of China's large-scale CFB boilers,analyzes the characteristics and technical performance of the iconic units,and introduces solutions to the problems such as water wall wear and bottom ash cooling.

关键词： CFB boiler installed capacity reliability economics ultra-low emission China

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Solar receiver/reactor for hydrogen production with biomass gasification in supercritical water

Solar receiver/reactor for hydrogen production with biomass ...

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作者： Liao, Bo Guo, Liejin Lu, Youjun Zhang, Ximin State Key Laboratory of Multiphase Flow in Power Engineering Xi'An Jiaotong University Xi'an Shaanxi Province 710049 China

A novel receiver/reactor driven by concentrating solar energy for hydrogen production by supercritical water gasification (SCWG) of biomass was designed, constructed and tested. Model compound (glucose) and real biomass (corncob) were successfully gasified under SCW conditions to generate hydrogen-rich fuel gas in the apparatus. It is found that the receiver/reactor temperature increased with the increment of the direct normal solar irradiation (DNI). Effects of the DNI, the flow rates and concentration of the feedstocks as well as alkali catalysts addition were investigated. The results showed that DNI and flow rates of reactants have prominent effects on the temperature of reactor wall and gasification results. Higher DNI and lower feed concentrations favor the biomass gasification for hydrogen production. The encouraging results indicate a promising approach for hydrogen production with biomass gasification in supercritical water using concentrated solar energy. © 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

关键词： Hydrogen production

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Function-reversible facets enabling SrTiO_(3)nanocrystals for improved photocatalytic hydrogen evolution

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Frontiers in Energy 2024年第1期18卷 101-109页

作者： Bin WANG Bei AN Xiaoqian LI Shaohua SHEN School of Physics Key Laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter(Ministry of Education)Key Laboratory of Shaanxi for Advanced Materials and Mesoscopic PhysicsXi’an Jiaotong UniversityXi’an 710049China International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049China

It has been widely reported that,for faceted nanocrystals,the two adjacent facets with different band levels contribute to promoted charge separation,and provide active sites for photocatalytic reduction and oxidation reaction,*** such cases,only one family of facets can be used for photocatalytic hydrogen ***,by using SrTiO_(3)nanocrystals enclosed by{023}and{001}facets as a model photocatalyst,this paper proposed a strategy to achieve the full-facets-utilization of the nanocrystals for photocatalytic hydrogen via chemically depositing Pt nanoparticles on all *** photo-deposition experiment of CdS provided direct evidence to demonstrate that the{023}facets which were responsible for photooxidation reaction can be function-reversed for photocatalytic hydrogen evolution after depositing Pt nanoparticles,together with the{001}***,the full-facets-utilization led to a much-improved activity for photocatalytic hydrogen,in contrast to those SrTiO_(3)nanocrystals with only{001}facets deposited by Pt nanoparticles via a photo-deposition method.

关键词： SrTiO_(3)nanocrystals crystal facets photocatalysis hydrogen evolution

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Remote open-path laser-induced breakdown spectroscopy for the analysis of manganese in steel samples at high temperature

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Plasma Science and Technology 2019年第3期21卷 52-59页

作者： Minchao CUI Yoshihiro DEGUCHI Zhenzhen WANG Seiya TANAKA Min-Gyu JEON Yuki FUJITA Shengdun ZHAO School of Mechanical Engineering Xi'an Jiaotong University Graduate School of Advanced Technology and Science University of Tokushima State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Division of Mechanical Engineering Korea Maritime and Ocean University School of Mechanical Engineering Xi’an Jiaotong University

A remote open-path laser-induced breakdown spectroscopy(LIBS) system was designed and studied in the present work for the purpose of combining the LIBS technique with the steel production line. In this system, the relatively simple configuration and optics were employed to measure the steel samples at a remote distance and a hot sample temperature. The system has obtained a robustness for the deviation of the sample position because of the open-path and alloptical structure. The measurement was carried out at different sample temperatures by placing the samples in a muffle furnace with a window in the front door. The results show that the intensity of the spectral lines increased as the sample temperature increased. The influence of the sample temperature on the quantitative analysis of manganese in the steel samples was investigated by measuring ten standard steel samples at different temperatures. Three samples were selected as the test sample for the simulation measurement. The results show that, at the sample temperature of 500 ℃, the average relative error of prediction is 3.1% and the average relative standard deviation is 7.7%, respectively.

关键词： remote open-path LIBS steel manganese sample temperature quantitative analysis

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No new physics in single-phase fluid flow and heat transfer in mini-and micro-channels-is it a conclusion?

No new physics in single-phase fluid flow and heat transfer ...

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1st ASME Micro/Nanoscale Heat Transfer International Conference, MNHT08

作者： Wen-Quan, Tao Gui-Hua, Tang Ya-Ling, He Zhuo, Li State Key Laboratory of Multiphase Flow School of Energy and Power Engineering Xi'an Jiaotong University Xi'an 710049 China

ISBN: (纸本)0791842924

First the flow friction characteristics of nitrogen and helium in stainless steel microtubes, glass microtubes, square glass microchannels, and rectangular silicon microchannels are tested. The data in glass microtubes with diameters from 50 to 201 microns and in square glass channels with characteristic diameters from 52 to 100 microns show that the friction factors are in good agreement with the conventional predictions. The friction factors in stainless-steel tubes with diameters from 119 to 300 microns are much higher than the conventional ones. The results for two of the four silicon microchannels with characteristic diameters from 26-60 microns are in good agreement while those of the other two channels are larger. This discrepancy is resulted from the large relative surface roughness. Smaller friction factors in glass microtubes with diameters from 10 to 20 microns are obtained due to the rarefaction effect. Second the flow friction experimental data for deionized water flow in glass microtubes with diameters from 50 to 530 microns show that friction factors and transition Reynolds numbers are in good agreement with the conventional predictions. However, the friction factors in stainless steel microtubes with diameters from 50-1570 microns are much higher than the conventional predictions. This discrepancy is attributed to the large surface relative roughness or denser roughness distribution. Numerical simulations considering electroviscous effect are carried out. The simulation results show that the electroviscous effect does not play a significant role in the friction factor for channel dimensions of the order of microns though it does affect the velocity profile and hence it could be neglected in engineering applications for channel dimensions of the order of microns. Third the measured local Nusselt number distribution of deionized water along the axial direction of the stainless steel tubes of 373-1570 microns with uniform heat flux do not accord with th

关键词： Glass

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