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聚丙烯酸酯修饰铜电极用于电化学二氧化碳还原选择性生成多碳产物（英文）

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Science Bulletin 2024年第15期 2395-2404页

作者：石玉川张凯妮董崇礼 Ta Thi Thuy Nga 汪淼魏代星王佳琳王亦清沈少华 International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Department of Physics Tamkang University

Highly selective production of value-added multicarbon(C2+) products via electrochemical CO2reduction reaction（eCO2RR） on polycrystalline copper（Cu） remains ***,the facile surface modification using poly（α-ethyl cyanoacrylate）(PECA) is presented to greatly enhance the C2+selectivity for eCO2RR over polycrystalline Cu,with Faradaic efficiency（FE） towards C2+products increased from30.1% for the Cu electrode to 72.6% for the obtained Cu-PECA electrode at -1.1 V *** hydrogen electrode（RHE）.Given the well-determined FEs towards C2+products,the partial current densities for C2+production could be estimated to be-145.4 mA cm-2for the Cu-PECA electrode at -0.9 V *** in a homemade flow ***-situ spectral characterizations and theoretical calculations reveal that PECA featured with electron-accepting-C≡N and-COOR groups decorated onto the Cu electrode could inhibit the adsorption of *H intermediates and stabilize the *CO intermediates,given the redistributed interfacial electron density and the raised energy level of d-band center（Ed） of Cu active sites,thus facilitating the C-C coupling and then the C2+selective *** study is believed to be guidable to the modification of electrocatalysts and electrodes with polymers to steer the surface adsorption behaviors of reaction intermediates to realize practical eCO2RR towards value-added C2+products with high activity and selectivity.

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Enhanced Hydrogen Production of Acidified La2nio4 in Water and Seawater by Coupled Piezo-Photocatalysis

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SSRN 2022年

作者： Ma, Xinyu Gao, Yangfei Yang, Bian Lou, Xiaojie Huang, Jianbing Ma, Lijing Jing, Dengwei International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Frontier Institute of Science and Technology State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong University Xi’an710049 China School of Materials Science and Engineering Xi’an University of Technology Xi’an710048 China

Photocatalytic water splitting for hydrogen production is more sustainable than traditional desalination and electrocatalysis, because of avoiding electrode corrosion and other problems. Two-dimensional perovskite oxide materials have multiple characteristics such as ferroelectric, piezoelectric and pyroelectric properties, demonstrating good light response and chemical stability, which provides a broad prospect in photo-chemical conversion. In this study, acidified La2NiO4 can greatly improve the amount of hydrogen evolution by coupling its piezocatalysis and photocatalysis. Under the full-spectrum illumination assisted with ultrasonic vibration in seawater, a recordable hydrogen production activity of 1315.44 μmol·g-1·h-1 was obtained in acidified La2NiO4 by 0.006 mol/L HCl, which more than 200 times higher than that of pure La2NiO4 (6.89 μmol·g-1·h-1) in methanol solution. It is found that the significant hydrogen production of La2NiO4 samples treated with acidification lies in the fast separation of charge carriers in comparison with those without acidification. © 2022, The Authors. All rights reserved.

关键词： Hydrogen production

Enhanced Hydrogen Production of Acidified Ruddlesden-Popper Type Perovskite Oxides in Water and Seawater by Coupled Piezo-Photocatalysis

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SSRN 2022年

作者： Ma, Xinyu Gao, Yangfei Yang, Bian Lou, Xiaojie Huang, Jianbing Ma, Lijing Jing, Dengwei International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi'An710049 China Frontier Institute of Science and Technology State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong University Xi'An710049 China School of Materials Science and Engineering Xi’an University of Technology Xi’an Xi'An710048 China

关键词： Hydrogen production

Coupling Effect of Heat Transfer and flow Resistance in the Rifled Tube Water Wall of a Ultra-Supercritical CFB Boiler

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Journal of Thermal Science 2019年第5期28卷 1078-1088页

作者： LI Yaode YANG Dong OUYANG Shijie LIU Dan WANG Wenyu State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China North China Electric Power Test and Research Institute Co. Ltd Tianjing 300000 China

The coupling factor is used in this study to characterise the combined effect of the heat transfer and resistance characteristics of a rifled tube. Boundary layer theory is utilised to investigate the relationship between the comprehensive coefficient and Reynolds number in two regions, namely, higher and lower than pseudo-critical enthalpy. Results indicate that mass flux exerts a decisive negative influence on the coupling effect, and the impacts of pressure and heat flux are weak. The overall effect decreases rapidly as the mass flux increases, but it increases in the area behind the quasi-critical enthalpy. The coupling effect is also affected by specific heat ratio, thermal acceleration and buoyancy. The correlations of heat transfer and friction resistance are deduced with high precision according to experimental data.

关键词： supercritical pressure heat transfer frictional resistance coupling effect

Expression of SALL4 in the synovial tissue of refractory rheumatoid arthritis patients

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Rheumatology & Autoimmunity 2024年第1期4卷 59-61页

作者： Ru Fan Zeqiong Liang Yujie Bu Fen Zhang Xing Cen Yuqing Liu Fenping Lian Fengwu Chen Shengxiao Zhang Junwei Chen Department of Rheumatology The Second Hospital of Shanxi Medical UniversityTaiyuanChina State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'anShaanxiChina Key Laboratory of Cellular Physiology at Shanxi Medical University Ministry of EducationTaiyuanChina Shanxi Provincial Key Laboratory of Rheumatism Immune Microecology The Second Hospital of Shanxi Medical UniversityTaiyuanChina

To the Editor,Rheumatoid arthritis(RA)synovitis is characterized by synovial inflammation,characterized by synovial proliferation,neovascularization,and leukocyte infiltration into the joint space,1 leading to irreversible cartilage and bone damage.2 This synovial inflammation stimulates the formation of pannus,which is an invasive tumor-like mass,ultimately contributing to the pathogenesis of *** shares several similarities with cancer,including joint pain,swelling,and stiffness,which are accompanied by hypoxia in the synovial tissue and tumor environment.3 Spalt-like transcription factor 4(SALL4)plays an essential role in the occurrence and development of tumors.4 However,SALL4 expression in synovial tissue of RA is yet to be *** study aimed to investigate SALL4 expression in synovial tissue derived from patients with RA,using immunohistochemical techniques.

关键词： SALL4 patients inflammation

Capacitance probe for water holdup measurement in crude oil-water flows

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Measurement: Sensors 2020年 10-12卷

作者： Zheng, Xuebo Yang, Bo Bai, Bofeng State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

Water holdup in crude oil-water flows is a crucial parameter to identify flow patterns or monitor the flow process in oil production. It has been increasingly important to accurately predict water holdup. Due to the simple structure and robust performance, capacitance probes have been widely used in experimental research and industrial application. In this paper, we proposed a water holdup measurement device based on a capacitance probe for crude oil-water flows. The measurement principle lies in the fact that the output capacitance is proportional to the part of the probe immersed in water. It was found that when inserted into crude oil, the surface of the probes will absorb hydrocarbons and form an oil film covering the probes. The formed oil film will reduce the sensitivity of the output capacitance to the water layer height. The thicker the film the lower the sensitivity. We examined the parameters that affect the thickness of the formed oil film and found that the thickness is mainly dependent on temperature and water holdup. The higher the temperature the thinner the formed oil film. The reason is that an increase of temperature leads to a decrease of viscosity. In addition, as the temperature approached about 50 °C, the thickness is nearly unchanged. As for the water holdup, at low temperatures the effect is considerable. At relatively high temperatures, the effect is minor and can be neglected. The experimental results showed that the capacitance probes have the highest sensitivity at about 50 °C. We designed and manufactured a prototype of the measurement device. The probes were inserted with heating wires to heat the crude oil near the probes and the current was controlled by an integrated circuit to maintain the temperature at about 50 °C. The field test showed that the natural gas entrained in the production fluids caused the device to under-predict the water holdup. After gas-liquid separation, the prediction errors were within ±6%. © 2020 The Author

关键词： Crude oil

A New Reduced Reaction Mechanism of the Surrogate Fuel for RP-3 Kerosene

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SSRN 2022年

作者： Liu, Jing Hu, Erjiang Zheng, Weilin Zeng, Wen Chang, Yachao State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Shangxi Xi’an710049 China Liaoning Key Lab of Advanced Test Technology for Aerospace Propulsion System Shenyang Aerospace University Liaoning Shenyang110136 China Key Laboratory of Ocean Energy Utilization and Energy Conservation Ministry of Education Dalian University of Technology Dalian116024 China

By combining the reaction class-based global sensitivity analysis (RC-GSA) methodology, species sensitivity analysis (SSA) methodology, decoupling method and genetic algorithm (GA), a reduced reaction mechanism of the surrogate fuel (10% n-dodecane/14% n-decane/30% iso-hexadecane/36% methylcyclohexane/10% toluene, in mole fraction) for RP-3 kerosene was constructed. As an example, the detailed construction process of skeleton mechanism of methylcyclohexane (MCH) was presented, and the skeleton mechanism constructions of other components in the surrogate fuel were similar to that of MCH. First, the dominant reaction classes in the fuel-relevant mechanism of MCH were recognized by the RC-GSA, the representative species in each retained reaction classes were selected by the SSA, and the skeleton fuel-relevant mechanism of MCH was developed. Second, through combining the skeleton fuel-relevant mechanism of MCH with the reduced reaction mechanism of C 0 -C 3 by the decoupling method, the initial skeleton mechanism of MCH was obtained. Third, based on the GA, the rate constants of fuel-relevant reactions in the initial skeleton mechanism of MCH were optimized to enhance the prediction performance. Finally, by coupling the skeleton reaction mechanisms of n-dodecane, n-decane, toluene, iso-hexadecane, MCH, and the reduced reaction mechanism of C 0 -C 3 , a reduced mechanism (containing 121 species and 469 reactions) of the surrogate fuel for RP-3 kerosene was formed. The predicted main species concentrations during the oxidation process in the jet-stirred reactor, the ignition delay times in the shock tube and laminar flame speeds in the constant volume bomb by this reduced mechanism are in good agreement with the corresponding experimental data of RP-3 kerosene. © 2022, The Authors. All rights reserved.

关键词： Sensitivity analysis

Influence of Different Equations of State on Simulation Results of Supercritical CO_(2) Centrifugal Compressor

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Mechanical engineering Science 2021年第2期3卷 25-33页

作者： Yueming YANG Bingkun MA Yongqing XIAO Jianhui QI Shandong Engineering Laboratory for High-efficiency Energy Conservation and Energy Storage Technology&Equipment School of Energy and Power EngineeringShandong UniversityJinanChina Beijing Key Laboratory of Multiphase Flow and Heat Transfer for Low Grade Energy Utilization North China Electric Power UniversityBeijingChina

Supercritical CO_(2)(SCO_(2))Brayton cycle has received more and more attention in the field of power generation due to its high cycle efficiency and compact ***_(2) compressor is the core component of the cycle,and the improvement of its performance is the key to improving the efficiency of the entire ***,the operation of the SCO_(2) compressor near the critical point has brought many design and operation *** on the Reynolds Averaged Navier-Stokes(RANS)model,the performance and flow field of SCO_(2) centrifugal compressors based on different CO_(2) working fluid models are numerically investigated in this *** stability and convergence of the compressor steady-state simulation are also *** results show that the fluid based on the Span-Wanger(SW)equation can obtain a more ideal compressor performance curve and capture a more accurate flow field structure,while the CO_(2) ideal gas is not suitable for the calculation of SCO_(2) centrifugal *** its flow field can be used as the initial flow field for numerical calculation of centrifugal compressor based on CO_(2) real gas.

关键词： Supercritical CO_(2) Centrifugal compressor Near the critical point Compressor performance Real gas equation of state

Phosphorus Flame Retardant Modified Aramid Nanofiber Separator for Advanced Safety Lithium-Sulfur Batteries

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SSRN 2024年

作者： Liu, Jianwei Zhu, Lei Wang, Jianan Chai, Qinqin Sun, Shiyi Chen, Xin Wang, Xue Zhang, Yating Yan, Wei College of Chemistry and Chemical Engineering Xi’an University of Science and Technology Shaanxi Xi’an710054 China Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiao tong University Shaanxi Xi’an710049 China Xianggui Manganese Industry Co. Ltd. Shaanxi Province Ziyang County725300 China School of Physics and Electrical Engineering Weinan Normal University Shaanxi Weinan714099 China Xi'an Hantang Analysis & Test Co. Ltd Xi’an710201 China

Safety concerns have perennially impeded the large-scale implementation of high-energy-density storage systems. Nevertheless, because the intrinsic drawbacks of the commercial polyolefin separator are poor thermal stability and low flammability with a large thermal contribution, the development of an advanced separator that solves the above questions is imminent. In this work, gradient flame-retardant aramid nanofiber separators (T-PMIA) were synthesized by a single-step electrospinning method. The T-PMIA separator demonstrates excellent Li-ion diffusion and proficiently suppresses the "shuttle effect" through its plentiful multilevel beaded structure and robust anchoring of soluble polysulfides (Li2Sx), achieved by optimizing the functional groups P and -P-O. Moreover, the enhanced separator exhibits a rapid self-extinguishing feature (self-extinguishing time: 0.20 s) and impressive mechanical properties (tensile strength of up to 12.58 MPa and puncture force of 0.94 N). Accordingly, the T-PMIA separator still showed a stable cycling performance (maintain 901.7 mAg-1 after 100 cycles) even at high temperature (80 ℃). This simple separator strategy offers a highly competitive option for the large-scale production of high-safety lithium-sulfur (Li-S) batteries. This uncomplicated separator strategy presents a compelling solution for the large-scale production of high-safety lithium-sulfur (Li-S) batteries © 2024, The Authors. All rights reserved.

关键词： Separators