Hydrogen peroxide(H_(2)O_(2))in situ electrosynthesis by O_(2)reduction reaction is a promising alternative to the conventional Fenton treatment of refractory ***,O_(2)mass transfer limitation,cathodic catalyst select...
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Hydrogen peroxide(H_(2)O_(2))in situ electrosynthesis by O_(2)reduction reaction is a promising alternative to the conventional Fenton treatment of refractory ***,O_(2)mass transfer limitation,cathodic catalyst selectivity,and electron transfer in O_(2)reduction remain major engineering ***,we have proposed a systematic solution for efficient H_(2)O_(2)generation and its electro-Fenton(EF)application for refractory organic degradation based on the fabrication of a novel ZrO_(2)/CMK-3/PTFE cathode,in which polytetrafluoroethylene(PTFE)acted as a hydrophobic modifier to strengthen the O_(2)mass transfer,ZrO_(2)was adopted as a hydrophilic modifier to enhance the electron transfer of O_(2)reduction,and mesoporous carbon CMK-3 was utilized as a catalyst substrate to provide catalytic active ***,feasible mass transfer of O_(2)from the hydrophobic to the hydrophilic layer was designed to increase the contact between O_(2)and the reaction *** H_(2)O_(2)yield of the ZrO_(2)/CMK-3/PTFE cathode was significantly improved by approximately 7.56 times compared to that of the co nventional gas diffusion cathode under the same *** H_(2)O_(2)generation rate and Faraday efficiency reached125.98 mg·cm^(-2)·h^(-1)(normalized to 5674.04 mmol·g^(-1)·h^(-1)by catalyst loading)and 78.24%at-1.3 V versus standard hydrogen electrode(current density of-252 mA·cm^(-2)),*** high H_(2)O_(2)yield ensured that sufficient OH was produced for excellent EF performance,resulting in a degradation efficiency of over 96%for refractory *** study offers a novel engineering solution for the efficient treatment of refractory wastewater using EF technology based on in situ high-yield H_(2)O_(2)electrosynthesis.
With the popularity of online courses and e-learning, a large amount of data on online learning behaviour has been accumulated. How to use these data to predict early students' performance so as to improve teachin...
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Fluorinated gases(F-gases)play a vital role in the chemical industry and in the fields of air conditioning,refrigeration,health care,and organic ***,the direct emission of waste gases containing F-gases into the atmos...
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Fluorinated gases(F-gases)play a vital role in the chemical industry and in the fields of air conditioning,refrigeration,health care,and organic ***,the direct emission of waste gases containing F-gases into the atmosphere contributes to greenhouse effects and generates toxic *** porous materials for the energy-efficient capture,separation,and recovery of F-gases is highly ***,as a highly designable porous adsorbents,metal–organic frameworks(MOFs)exhibit excellent selective sorption performance toward F-gases,especially for the recognition and separation of different F-gases with highly similar properties,showing their great potential in F-gases control and *** this review,we discuss the capture and separation of F-gases and their azeotropic,near-azeotropic,and isomeric mixtures in various application scenarios by MOFs,specifically classify and analyze molecular interaction between F-gases and MOFs,and interpret the mechanisms underlying their high performance regarding both adsorption capacity and selectivity,providing a repertoire for future materials *** faced in the transformation research roadmap of MOFs adsorbent separation technologies toward F-gases are also discussed,and areas for future research endeavors are highlighted.
Learning the parameters of Bayesian networks(BNs) is a key challenge in real-world decision support applications,especially when there are small data *** A Posteriori(MAP) estimation is alternate way to compute the **...
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ISBN:
(数字)9789887581536
ISBN:
(纸本)9781665482561
Learning the parameters of Bayesian networks(BNs) is a key challenge in real-world decision support applications,especially when there are small data *** A Posteriori(MAP) estimation is alternate way to compute the *** the hyper parameters in MAP are difficult to determine when the samples are small.A conventional way to address this challenge is to introduce domain knowledge/expert judgments that are encoded as qualitative parameter *** paper proposed a Sorting Constraint Auxiliary Model(SCAM) algorithm for learning BN *** firstly translate informative range constraints into mathematics inequality formulation with regards to the relationships among BN parameters by *** we recruit conjugate distribution fitting using equivalence uniform distribution to generate virtual samplings in parameter *** sampling counts,combined with small data statistics,help to reconstruct the BN parameter in MAP *** experimental results show that the SCAM algorithm can obtain more accurate parameters than the existing parameter learning ***,we demonstrate successful application to real threat assessment case studies in case of scarce data.
Due to the increasing need of science and technology, more and more spacecraft are in space. Once the spacecraft reaches its useful life, it will become floating junk in space. Active space debris removal technology i...
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Defect inspection based on computer vision has gradually replaced the traditional detection method, which is widely used in industry and greatly improving the efficiency of industrial production. Most defect inspectio...
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For Hammerstein system with fractional linear state space model, it is very difficult to build its model by identification method. The difficulty lies in that the nonlinear state space equation model describing the sy...
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This paper introduces a quadratic programming-based stable motion control method for humanoid robots. This method is based on the virtual model and the optimal force distribution. We added a six-dimensional mixed cons...
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With the rapid development of global industry, photovoltaic (PV) power generation has become a research hotspot for new energy applications. Due to the limitations of the environment, the output power of PV power gene...
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Classification of imbalanced data is a problem to be solved in practical applications,and sampling algorithm is a more effective *** SMOTE algorithm is a classical oversampling algorithm that provides a strong guideli...
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ISBN:
(数字)9789887581536
ISBN:
(纸本)9781665482561
Classification of imbalanced data is a problem to be solved in practical applications,and sampling algorithm is a more effective *** SMOTE algorithm is a classical oversampling algorithm that provides a strong guideline for dealing with imbalanced datasets,but there are still some limitations,such as blurring the boundary between positive class samples and negative class *** alleviate the limitations,in this study,a new oversampling method called KB-SMOTE(K-means++Borderline-SMOTE) is *** new algorithm first clusters the minority class,next synthesizes new samples between cluster center and borderline points in minority samples,which solves the problem of blurred class boundary of imbalanced datasets,avoids the interference of noisy samples and reduces the impact on the original ***,this paper uses KB-SMOTE as a data preprocessing algorithm,combined with a hypersphere information granular classifier to classify the imbalanced *** the experimental part,the combined classifier of this paper is compared with other classification algorithms on several imbalanced datasets,and the effectiveness of the algorithm is verified.
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