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Self-assembly of a new 3D platelike ternary-oxo-cluster:An efficient catalyst for the synthesis of pyrazoles

Chinese Chemical Letters 2022年第1期33卷 354-357页

作者： Guoping Yang Yufeng Liu Xiaoling Lin Bangming Ming Ke Li Changwen Hu Jiangxi Province Key Laboratory of Synthetic Chemistry Jiangxi Key Laboratory for Mass Spectrometry and InstrumentationEast China University of TechnologyNanchang 330013China Jiangxi Engineering Technology Research Center of Nuclear Geoscience Data Science and System East China University of TechnologyNanchang 330013China Key Laboratory of Cluster Science of Ministry of Education School of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 100081China

A new metal-oxo-clusters-based inorganic framework[NaCo_(2)Mo_(2)O_(7)(OH)_(3)]_(n)(NaCoMo),named as 3D platelike ternary-oxo-cluster,has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction structure analysis,FT-IR spectroscopy,powder X-ray diffraction(PXRD),scanning electron microscope(SEM),energy-dispersive X-ray spectroscopy(EDS)analyses,X-ray photoelectron spectroscopy(XPS)and thermogravimetric analysis(TGA).Structure analysis reveals that there are no classical building units in NaCoMo,and the asymmetric units of NaCoMo are directly extended into a new platelike 3D *** functional theory calculations(DFT)indicates that the crystal formation process is exothermic and the structure is extremely *** addition,the compound presents excellent catalytic activity in the condensation and cyclization reaction of sulfonyl hydrazides and 1,3-diketones to synthesize pyrazoles,and the yield of the desired product is up to 99%.The successful synthesis of NaCoMo represents the discovery of a new kind of non-classical polyoxometalates.

关键词： Polyoxometalates Oxo clusters 3D inorganic framework Condensation reaction Pyrazoles

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Discriminative latent semantics-preserving similarity embedding hashing for cross-modal retrieval

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Neural Computing and Applications 2024年第18期36卷 10655-10680页

作者： Chen, Yongfeng Tan, Junpeng Yang, Zhijing Cheng, Yongqiang Chen, Ruihan School of Information Engineering Guangdong University of Technology Guangdong Guangzhou510006 China School of Electronic and Information Engineering South China University of Technology Guangdong Guangzhou510641 China Guangdong Provincial Key Laboratory of Intellectual Property and Big Data Guangdong Guangzhou510665 China Department of Computer Science and Technology University of Hull HullHU6 7RX United Kingdom

Recently, there has been a significant increase in interest in cross-modal hashing technology. For hash code learning, most previous supervision methods use label information to create a similarity matrix in a straightforward manner. However, there are still the following challenges: (1) The asymmetric similarity matrix method only considers the similarity of labels, and the discriminant constraint in Hamming space is ignored;(2) there are optimization errors between the cross-modal semantic correlation of the Hamming space and the nonlinearity of the feature space;and (3) the cross-modal hash matrix is in a dynamic state during the optimization process, and the hash code is easily disturbed and there is bit uncertainty. To this end, we propose the Discriminative Latent Semantics-preserving Similarity Embedding Cross-modal Hashing (DLSSECH) method. Specifically, to reduce the quantization error, we introduce a non-asymmetric similarity decomposition based on orthogonal rotation bias. It can decompose the bitwise correlation of the learned hash code to capture more discriminative semantic information and compact hash code. In addition, to capture the cross-modal semantic correlation of nonlinear feature transformation and reduce quantization error, we propose the latent correlation error matrices based on orthogonal rotation decomposition. The model maintains the maximum difference in semantic dependencies between the projected data and its semantic representation. Finally, we use a sparse common hash matrix and non-asymmetric similarity decomposition factors to solve the uncertainty of the dynamic changes of the hash code. The effectiveness of DLSSECH has demonstrated through experiments on four cross-modal retrieval datasets, where it outperformed some state-of-the-art methods. © The Author(s), under exclusive licence to Springer-Verlag London Ltd., part of Springer Nature 2024.

关键词： Semantics

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On the parameterized complexity of minimum/maximum degree vertex deletion on several special graphs

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Frontiers of Computer Science 2023年第4期17卷 97-107页

作者： Jia LI Wenjun LI Yongjie YANG Xueying YANG School of Information Engineering Hunan Industry PolytechnicChangsha 410036China Hunan Provincial Key Laboratory of Intelligent Processing of Big Data on Transportation School of Computer and Communication EngineeringChangsha University of Science and TechnologyChangsha 410015China Chair of Economic Theory Saarland UniversitySaarbrücken 66123Germany

In the minimum degree vertex deletion problem,we are given a graph,a distinguished vertex in the graph,and an integer κ,and the question is whether we can delete at most κ vertices from the graph so that the distinguished vertex has the unique minimum *** maximum degree vertex deletion problem is defined analogously but here we want the distinguished vertex to have the unique maximum *** is known that both problems areΨ-hard and fixed-parameter intractable with respect to some natural *** this paper,we study the(parameterized)complexity of these two problems restricted to split graphs,p-degenerate graphs,and planar *** study provides a comprehensive complexity landscape of the two problems restricted to these special graphs.

关键词： minimum degree maximum degree vertex deletion split graphs planar graphs parameterized complexity

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A novel hybrid butterfly optimization algorithm for feature selection with sine cosine velocity in the high-dimensional classification data

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Journal of Intelligent and Fuzzy Systems 2024年第5-6期47卷 369-391页

作者： Zhang, Li Chen, Xiaobo Key Laboratory of Data Science and Intelligence Education Hainan Normal University Ministry of Education Haikou Hainan China School of Computer Engineering Jiangsu University of Technology Changzhou Jiangsu China Changzhou City Center Branch People's Bank of China Changzhou Jiangsu China Key Laboratory of Symbolic Computation and Knowledge Engineering Ministry of Education Jilin University Changchun China

Aiming at the shortcomings of the traditional butterfly optimization algorithm in solving the high-dimensional classification feature selection problem, which has low convergence and is prone to fall into local optimal solutions, a new hybrid butterfly optimization algorithm is proposed, i.e., HBOA-SCV (A novel hybrid butterfly optimization algorithm with sine cosine velocity). The algorithm is applied to solve a high-dimensional classification feature selection problem. Firstly, the algorithm's global exploration and local exploitation ability can be dynamically balanced by introducing inertia weight coefficients w based on multiple learning strategies. Secondly, using the updated speed position formula of the sine-cosine acceleration strategy, individual butterflies' autonomous search ability and convergence speed can be further improved. Finally, according to the fitness value of each butterfly individual, the moving step length and direction of the butterfly individual are automatically adjusted better to fit the actual search process of the butterfly individual, increase the search ability in the global range, and avoid the algorithm from falling into the local optimum. To verify the algorithm's effectiveness, 18 high-dimensional classification numbers are selected to carry out simulation and comparison experiments between HBOA-SCV and traditional BOA algorithm, five improved BOA algorithms and other comparative algorithms for high-dimensional classification data successively. The experimental results show that the average fitness value and classification accuracy of the HBOA-SCV algorithm are better than the comparison algorithm, thus verifying the superiority of the HBOA-SCV algorithm. © 2024 - IOS Press. All rights reserved.

关键词： Optimization algorithms

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Federated Incremental Named Entity Recognition 31

Federated Incremental Named Entity Recognition

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31st International Conference on Computational Linguistics, COLING 2025

作者： Liu, Zesheng Zhu, Qiannan Li, Cuiping Chen, Hong School of Information Renmin University of China Beijing China Key Laboratory of Data Engineering and Knowledge Engineering MOE China Engineering Research Center of Database and Business Intelligence MOE China School of Artificial Intelligence Beijing Normal University Beijing China Engineering Research Center of Intelligent Technology and Educational Application MOE China

ISBN: (纸本)9798891761964

Federated learning-based Named Entity Recognition (FNER) has attracted widespread attention through decentralized training on local clients. However, most FNER models assume that entity types are pre-fixed, so in practical applications, local clients constantly receive new entity types without enough storage to access old entity types, resulting in severe forgetting on previously learned knowledge. In addition, new clients collecting only new entity types may join the global training of FNER irregularly, further exacerbating catastrophic forgetting. To overcome the above challenges, we propose a Forgetting-Subdued Learning (FSL) model which solves the forgetting problem on old entity types from both intra-client and inter-client two aspects. Specifically, for intra-client aspect, we propose a prototype-guided adaptive pseudo labeling and a prototypical relation distillation loss to surmount catastrophic forgetting of old entity types with semantic shift. Furthermore, for inter-client aspect, we propose a task transfer detector. It can identify the arrival of new entity types that are protected by privacy and store the latest old global model for relation distillation. Qualitative experiments have shown that our model has made significant improvements compared to several baseline methods. © 2025 Association for Computational Linguistics.

关键词： Federated learning

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Differentially Private Federated Stochastic Primal-Dual Learning for Internet of Vehicles

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IEEE Internet of Things Journal 2025年第11期12卷 17034-17050页

作者： Li, Yiwei Wang, Shuai Chang, Tsung-Hui Xiamen University of Technology Fujian Key Laboratory of Communication Network and Information Processing Xiamen361024 China University of Electronic Science and Technology of China National Key Laboratory of Wireless Communications Chengdu611731 China Chinese University of Hon g Kong School of Science and Engineering Shenzhen518172 China Shenzhen Research Institute of Big Data Shenzhen518172 China

Federated learning (FL) has the potential to empower Internet of Vehicles (IoV) networks by enabling smart vehicles (SVs) to participate in the learning process under the orchestration of a vehicular service provider while keeping data locally. In this article, we propose a novel federated stochastic primal-dual algorithm with differential privacy (FedSPD-DP) to ensure robust privacy protection for FL based IoV (FL-IoV) systems. The FedSPD-DP algorithm leverages multiple steps of local stochastic gradient descent (SGD) and partial client participation (PCP) to improve communication efficiency while incorporating differential privacy (DP) to ensure privacy protection. Our theoretical analysis explores the impact of these strategies on learning performance. Specifically, we demonstrate that the data sampling strategy and PCP enhance data privacy, while a larger number of local SGD steps may increase privacy leakage, revealing a nontrivial tradeoff between communication efficiency and privacy protection. Extensive experiments on real-world data validate the effectiveness of the proposed algorithm, showing superior performance compared to state-of-the-art FL algorithms, and confirming the analytical results and properties. © 2014 IEEE.

关键词： Federated learning

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Advances in anode interfacial materials for organic solar cells

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Aggregate 2024年第4期5卷 74-95页

作者： Menglan Lv Junhua Huang Xuanyan Luo Shan Yu Xu Wang Zhuo Wang Fei Pan Bin Zhang Liming Ding Engineering Research Center for Energy Conversion and Storage Technology of Guizhou School of Chemistry and Chemical EngineeringGuizhou UniversityGuiyangChina College of Big Data and Information Engineering Guizhou UniversityGuiyangChina School of Chemical Engineering Guizhou Institute of TechnologyGuiyangChina Center for Excellence in Nanoscience(CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication(CAS)National Center for Nanoscience and TechnologyBeijingChina

Organic solar cells(OSCs)have attracted much interest in the past few decades because of their advantages,such as being lightweight,low cost,simple preparation process,and environmental *** researchers have made significant progress on the active layer materials of OSCs,the interface engineering is another entry point for upgrading the photovoltaic performance of ***,the interface modification materials,including anode interfacial materials and cathode interfacial materials,are two essential parts of interfacial layers for OSCs,in which the excellent interfacial materials can realize the very high-performance photovoltaic *** these interfacial materials,the anode interfacial layers(AILs)play a crucial role in improving photovoltaic *** review expresses a detailed conclusion of the development of anode interfacial materials and an outlook on future trends for OSCs.

关键词： anode interfacial materials organic solar cells power conversion efficiency

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Measurement of Absorption Spectroscopy Based on a Dispersion-Managed Dual-Comb Laser

Measurement of Absorption Spectroscopy Based on a Dispersion...

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2024 IEEE International Conference on Imaging Systems and Techniques, IST 2024

作者： Jing, Xiuhan Zhang, Chenghong Zhang, He Lyu, Wenhao Fu, Bo Xu, Lijun School of Instrumentation and Optoelectronic Engineering Beihang University Key Laboratory of Precision Opto-Mechatronics Technology of Education Ministry Beijing China School of Engineering Medicine Beihang University Key Laboratory of Big Data-Based Precision Medicine Ministry of Industry and Information Technology Beijing China

ISBN: (纸本)9798350378214

Dual-comb spectroscopy is a competitive means of laser absorption spectroscopy owing to broad spectral range and high spectral resolution. Single-cavity dual-comb systems based on mode-locked lasers hold promising potential for further simplifying dual-comb spectroscopy. Two combs possess natural coherence because of common mode noise suppression. Herein, we proposed an all-fiber dispersion-managed dual-comb laser to broaden the spectra of dual combs. The output laser with a 3-dB bandwidth as broad as 9 nm at 1.5 μm was experimentally obtained. Dual combs were realized by the walk-off of orthogonal polarization modes and directly employed to absorption spec-troscopy due to their overlapped spectra. In order to improve the signal-to-noise ratio of dual-comb measurement, interferogram averaging was conducted, where the signal-to-noise ratio was generally proportional to the square root of averaging times. Besides, phase and frequency jitter was corrected by cross-correlation method. High resolution absorption lines of hydrogen cyanide from P18 to P26 were measured. Positions of measured absorption lines were in line with ones in HITRAN database, with an average error of approximate 1 pm. To the best of our knowledge, the 9-line result was the broadest bandwidth of polarization-multiplexed single-cavity dual combs without additional spectral spreading operation. The results demonstrate that the compact dual-comb spectrometer can be considered a potential candidate for quantitative measurements in practical applications. © 2024 IEEE.

关键词： Spectral resolution

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Surface-enhanced Raman scattering on nanomaterials for cancer and pathogens diagnosis

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Nano Research 2025年第2期18卷 650-674页

作者： Jingjing Wu Baohong Zhang Lei Xu Yanyu Zhao Tao Chen Jie Lin Anran Li School of Engineering Medicine Beihang UniversityBeijing 100191China Key Laboratory of Big Data-Based Precision Medicine Ministry of Industry and Information Technology of the People’s Republic of ChinaBeihang UniversityBeijing 100191China School of Optics and Photonics Beijing Institute of TechnologyBeijing 100089China Shanxi Lu'an Taihang Lubricant Technology Co. Ltd.Changzhi 046204China Cixi Institute of Biomedical Engineering Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China

Surface-enhanced Raman scattering(SERS)is a non-invasive spectroscopic technique that provides specific chemical fingerprint information for biomarkers in cancer and pathogen ***,the SERS strategies are limited by the non-specific interactions between substrates and co-existing substances in biological matrices and the challenges of obtaining molecular fingerprint information from the complex vibrational *** recent years,the rapid development of novel substrates with high SERS activity has opened up new opportunities for their applications in cancer and pathogen *** aim of this review is to present the recent progress and perspectives of novel SERS-based substrates for cancer and pathogen diagnostic ***,we will introduce recently developed SERS-active nanomaterials and discuss the influencing factors of the SERS ***,the advantages of SERS in the diagnosis of cancer and pathogens will be ***,we will review the latest breakthroughs in cancer and pathogen detection research with SERS technology,as well as the new opportunities for SERS applications brought about by artificial intelligence(Al)*** addition,the novel microfluidic-SERS platforms for cancer and pathogens diagnosis will also be ***,we will summarize the challenges and future perspectives of SERS technology in the field of early cancer diagnosis and rapid pathogen *** is highly expected that this review could benefit a comprehensive understanding of the research status of the SERS-active nanomaterials and arouse the research enthusiasm for them,leading to accelerated clinical translation of SERS technology in cancer and pathogen diagnosis.

关键词： surface-enhanced Raman scattering(SERS) SERS-active nanomaterials cancer and pathogen diagnosis artificial intelligence(Al)technology

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Pattern-Moving-Based Parameter Identification of Output Error Models with Multi-Threshold Quantized Observations

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Computer Modeling in engineering & Sciences 2022年第3期130卷 1807-1825页

作者： Xiangquan Li Zhengguang Xu Cheng Han Ning Li School of Automation and Electrical Engineering University of Science and Technology BeijingKey Laboratory of Knowledge Automation for Industrial ProcessesMinistry of EducationBeijing100083China School of Information Engineering Jingdezhen UniversityJingdezhen333000China

This paper addresses a modified auxiliary model stochastic gradient recursive parameter identification algorithm(M-AM-SGRPIA)for a class of single input single output(SISO)linear output error models with multi-threshold quantized *** proves the convergence of the designed algorithm.A pattern-moving-based system dynamics description method with hybrid metrics is proposed for a kind of practical single input multiple output(SIMO)or SISO nonlinear systems,and a SISO linear output error model with multi-threshold quantized observations is adopted to approximate the unknown *** system input design is accomplished using the measurement technology of random repeatability test,and the probabilistic characteristic of the explicit metric value is employed to estimate the implicit metric value of the pattern class variable.A modified auxiliary model stochastic gradient recursive algorithm(M-AM-SGRA)is designed to identify the model parameters,and the contraction mapping principle proves its *** numerical examples are given to demonstrate the feasibility and effectiveness of the achieved identification algorithm.

关键词： Pattern moving multi-threshold quantized observations output error model auxiliary model parameter identification

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