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Modeling the impact of temperature-dependent thermal conductivity on hydrogen desorption from magnesium hydride

International Journal of Hydrogen Energy 2025年 138卷 491-508页

作者： Abdi Lanbaran, Davoud Wang, Chao Wen, Chuang Wu, Zhen Li, Bo School of Engineering University of Kent United Kingdom School of Construction Management and Engineering University of Reading United Kingdom Department of Process Equipment and Control Engineering Xi'an Jiaotong University China School of Electrical Electronic and Mechanical Engineering University of Bristol United Kingdom

Hydrogen desorption from metal hydrides, especially magnesium hydrides, presents a major challenge in hydrogen storage applications due to their low thermal conductivity and high hydrogen release temperature. Efficient hydrogen release is crucial for operation, as thermal conductivity is key in heat transfer and desorption kinetics. Previous studies have largely assumed a constant thermal conductivity, but considering its temperature dependence is essential for accurate modeling and optimization of the process. In this study, a numerical evaluation of temperature-dependent thermal conductivity in hydrogen desorption from magnesium hydride was conducted using COMSOL Multiphysics and the finite element method (FEM). Two distinct methods, thermochemical storage systems (TCSS) and radial heat flux were investigated under slow and fast hydrogen release conditions. The results show that accounting for temperature-dependent thermal conductivity significantly reduces desorption time, shortening it by approximately 9 min in slow desorption processes and 0.6 min in fast desorption compared to constant thermal conductivity models. Furthermore, the temperature-dependent model enhanced heat distribution, leading to a lower equilibrium pressure of 1.96 MPa (MPa) compared to 2.09 MPa in constant models, and accelerated hydrogen release, as demonstrated by an increase in Darcy's velocity. The findings suggest that incorporating temperature-dependent thermal conductivity in hydrogen storage models is essential for improving heat transfer efficiency, optimizing desorption kinetics, and enhancing overall system performance. These insights will aid in the development of hydrogen storage in metal hydrides and contribute to more accurate predictions of hydrogen storage system performance. © 2025 The Authors

关键词： Temperature distribution

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High concentration of Ti^(3+)in C-TiO_(x)nanosheets boosting efficient photodegradation

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Science China(Technological Sciences) 2025年第3期68卷 156-166页

作者： Chongbei WU Xuan LI Haibin WANG Jiaxin TANG Shuai WEI Yuanyuan WU Aobing WANG Jizhou JIANG Hebei Key Laboratory of Man-machine Environmental Thermal Control Technology and Equipment Hebei Vocational University of Technology and EngineeringXingtai054000China School of Materials Science and Engineering Key Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationWuhan Institute of TechnologyWuhan430205China

Semiconductor photocatalysis holds significant promise for addressing dye-pollution in ***,the efficiency of photocatalytic water purification is constrained by the weak light absorption capacity and low active site distribution of *** a bottom-up approach,carbon-doped TiO_(x)(C-TiO_(x))nanosheets with high concentrations of Ti^(3+)active sites were fabricated by etching the Al element in Ti_(3)Ai C_(2)with H_(2)O_(2).Experimental evidence demonstrates that the optimal C-TiO_(x)nanosheets exhibit high activity for the photocatalytic degradation of methylene blue,achieving a degradation rate of 100%within 50 *** introduction of carbon into the C-TiO_(x)nanosheets induces a red shift in the absorption edge,boosting the migration of photo-generated charge ***,there is a significant correlation between the concentration of Ti^(3+)active sites and the density of oxygen vacancies in the C-TiO_(x)nanosheets,which synergistically influence the photocatalytic degradation performance of MB dye wastewater.

关键词： bottom-up strategies C-TiO_(x)nanosheets high-concentrations Ti^(3+) photocatalytic degradation

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Modulated Degradation Rates of Bone Mineral-Like Calcium Phosphate Glass to Support the Proliferation and Osteogenic Differentiation of Bone Marrow-Derived Stem Cells

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Journal of Bionic engineering 2024年第4期21卷 1960-1974页

作者： Lizhe He Yuye Huang Jiafei Gu Xiaoling Liu Jun Yin Xiang Gao Department of Neurosurgery The First Affiliated Hospital of Ningbo UniversityNingbo315010China Center for Medical and Engineering Innovation The First Affiliated Hospital of Ningbo UniversityNingbo315010China The State Key Laboratory of Fluid Power Transmission and Control Systems Key Laboratory of 3D Printing Process and Equipment of Zhejiang ProvinceSchool of Mechanical EngineeringZhejiang UniversityHangzhou310028China Faculty of Science and Engineering University of Nottingham Ningbo ChinaNingbo315100China

With an elemental composition similar to bone mineral,and the ability to release phosphorus and calcium that benefit bone regeneration,Calcium Phosphate Glass(CPG)serves as a promising component of bone tissue engineering ***,the degradation of CPG composites typically results in increased acidity,and its impact on bone-forming activity is less *** this work,we prepared 3D-printed composite scaffolds comprising CPG,Poly-ε-caprolactone(PCL),and various Magnesium Oxide(MgO)*** the MgO content effectively suppressed the degradation of CPG,maintaining a physiological pH of the degradation *** the degradation of CPG/PCL scaffolds resulted in upregulated apoptosis of Rat Bone Marrow-derived Stem Cells(rBMSC),scaffolds containing MgO were free from these negative impacts,and an optimal MgO content of 1 wt%led to the most pronounced osteogenic differentiation of *** work demonstrated that the rapid degradation of CPG impaired the renewability of stem cells through the increased acidity of the surrounding media,and MgO effectively modulated the degradation rate of CPG,thus preventing the negative effects of rapid degradation and supporting the proliferation and osteogenic differentiation of the stem cells.

关键词： Phosphate glass Polymer composites 3D printing Bone tissue engineering Scaffolds

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NO reduction by carbon-based gases based on coal gasification fractions:NO reduction intermediate identification and kinetic analysis

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Frontiers of Environmental Science & engineering 2025年第3期19卷 175-189页

作者： Xiang Zhang Jian Tian Tanghui Hu Guangyong Yue Xianlong Liu Wen Zhou Xiaohong Liu Xinye Wang Ministry-of-Education Key Laboratory for the Green Preparation and Application of Functional Materials Hubei Engineering Research Center for Green Industrialization Technology of Industrial WasteSchool of Materials Science and EngineeringHubei UniversityWuhan 430062China Hubei Huda Tianshu New Energy Materials Industrial Research and Design Institute Co. Ltd.Wuhan 430062China Wuhan Tianshu Dust Removal Equipment Co. Ltd.Wuhan 430062China Engineering Laboratory for Energy System Process Conversion&Emission Control Technology of Jiangsu Province School of Energy and Mechanical EngineeringNanjing Normal UniversityNanjing 210042China

Combining pulverized coal gasifiers with cement kiln production is promising for application in low-cost and efficient NO *** paper presents a pulverized coal gasifier catalytic denitration technique and investigates the homogeneous reduction(by CO and CH_(4))and heterogeneous catalytic reduction(by coke,CaO,MgO,and Fe_(2)O_(3))of NO.A combination of Chemkin simulations and fixed-bed experiments is used to elucidate the reaction pathways and key intermediates of NO reduction by carbon-based *** addition,the activation energies for different catalyst combinations were analyzed via reaction *** results demonstrate that the presence of small amounts of O_(2) inhibits NO reduction by CO but promotes NO reduction by CH_(4).The NCO·radical is essential for the NO reduction process,and the generation of this radical depends on the CH_(4) cleavage intermediate and O·*** and Fe_(2)O_(3) exhibit more significant catalytic effects on NO reduction by carbon-based gases than the other catalysts *** presence of a small amount of O_(2) in the reacting gas mixtures facilitates the NO reduction *** activation energy is reduced to 1.02 kJ/mol,and the NO conversion reaches 99.80%when the catalyst is C+CaO+MgO+Fe_(2)O_(3) and the gas composition is CO+CH_(4)+O_(2).This work provides theoretical support and data recommendations for the use of pulverized coal gasifiers for the denitrification of cement kilns.

关键词： Carbon-based gas Catalytic denitration Coke Kinetic analysis Reaction mechanism

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Numerical Investigation of Boundary Grid Effect on Heat Transfer Computation of RP-3 at Supercritical Temperature of Helical Tube Wall

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Journal of Thermal Science 2021年第2期30卷 504-516页

作者： LIU Shaobei BAO Zewei HUANG Weixing ZENG Tao QIAO Min MENG Jiancheng School of Chemical Engineering Sichuan UniversityChengdu 610065China School of Mechanical Engineering Sichuan University of Science&EngineeringZigong 643000China Sichuan Provincial Key Lab of Process Equipment and Control Zigong 643000China

To get reliable computational results,the RNG k-ε turbulence model with enhanced wall treatment was validated to solve the heat transfer of supercritical RP-3 in a helically coiled tube,and models of the thermo-physical properties of RP-3 were optimally *** significantly,the grid independence was validated by two-step procedure,and the effect of boundary grids of the supercritical-temperature wall on the computational accuracy was well *** adjusting boundary-layer girds' size,four regions (increased,pseudo-convergence,decreased and convergence) of the outlet temperature Tout were obtained and *** results showed that the maximum computation errors of Tout and the pressure differential between the inlet and outlet ΔP reached 20.65% and 98.15%,respectively,indicating that boundary grids have a significant influence on computation of flow and heat *** on this,a dimensionless distance from the wall-adjacent cell to the wall y+=Prw-1/1.78 (Prw denotes Wall Prandtl number) was recommended as a convergence *** variation laws of viscous length scale y* were discussed under different structural parameters,operation parameters,and helical *** explicit model of y* was proposed to calculate the height (y) of the first boundary layer grids and refine boundary grids efficiently.A modified model for coefficient of fiiction factor Cf was proposed based on Rogers's,and Nusselt number Nu was proposed based on an analogy of momentum and heat *** above models about y*,Cf and Nu could apply to both the entrance region and the whole tube length,and showed good performance when Reynolds number was extended to above 70 000,or whenever the outlet temperature is below or above the critical point.

关键词： supercritical heat transfer helically coiled tube aviation kerosene dimensionless wall distance viscous length scale

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Boron promoted Fe^(3+)/peracetic acid process for sulfamethazine degradation:Efficiency,role of boron,and identification of the reactive species

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Journal of Environmental Sciences 2024年第1期135卷 72-85页

作者： Yanhong Zhang Guangbing Liu Yuzhu Xue Lichun Fu Yawei Qian Minhui Hou Xiang Li Chen Ling Ying Zhang Yuwei Pan Jiangsu Provincial Key Laboratory of Environmental Engineering Jiangsu Provincial Academy of Environmental ScienceNanjing 210036China College of Biology and the Environment Nanjing Forestry UniversityNanjing 210037China School of Iron and Steel Soochow UniversitySuzhou 215000China School of the Environment Nanjing UniversityNanjing 210023China SUMEC Complete Equipment&Engineering Co. LTD.Nanjing 211500China Key Laboratory of Pollution Process and Environmental Criteria Ministry of EducationCollege of Environmental Science and EngineeringNankai UniversityTianjin 300350China School of Environment Key Laboratory for Yellow River and Huai River Water Environmental and Pollution ControlMinistry of EducationHenan Key Laboratory for Environmental Pollution ControlHenan Normal UniversityXinxiang 453007China

In this work,boron(B)was used to promote Fe^(3+)/peracetic acid(Fe^(3+)/PAA)for the degradation of sulfamethazine(SMT).An SMT degradation efficiency of 9.1%was observed in the Fe^(3+)/PAA system over 60 min,which was significantly increased to 99.3%in the B/Fe^(3+)/PAA system over 10 *** B/Fe^(3+)/PAA process also exhibited superior resistance to natural substances,excellent adaptability to different harmful substances,and good removal of antibiotics in natural fresh water *** mechanism of action of boron for Fe^(3+)reduction was determined using scanning electron microscopy(SEM),X-ray photoelectron spectroscopy(XPS),Fourier transform infrared(FT-IR)spectroscopy,density functional theory(DFT)calculations,and electrochemical *** dominant role of^(·)OH was confirmed using quenching experiments,electron spin resonance(EPR)spectroscopy,and quantitative *** radicals(R-O^(·))and Fe(IV)also significantly contribute to the removal of *** calculations on the reaction between Fe^(2+)and the PAA were conducted to further determine the contribution from ^(·)OH,R-O^(·),and Fe(IV)from the perspective of thermodynamics and the reaction *** boron dosages,Fe^(3+)dosages,and initial pH values were also investigated in the B/Fe^(3+)/PAA system to study their effect of SMT removal and the production of the reactive ***(IV)production determined the k_(R-O·+Fe(IV))value suggesting that Fe(IV)may play a more important role than R-O^(·).A comparison of the results with other processes has also proved that the procedure described in this study(B/Fe^(3+)/PAA)is an effective method for the degradation of antibiotics.

关键词： Boron Peracetic acid Sulfamethazine DFT Reactive species

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Experimental and Internal Flow Investigation on the Performance of a Hydraulic Retarder with Different Liquid-Filled Amount and Blade Inclination Angles

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Journal of Thermal Science 2022年第3期31卷 923-933页

作者： DAI Cui DONG Liang ZHANG Xing ZHU Jiancheng LIN Haibo School of Energy and Power Engineering Jiangsu UniversityZhenjiang212013China Sichuan Provincial Key Lab of Process Equipment and Control Sichuan University of Science&EngineeringZigong643000China Research Center of Fluid Machinery Engineering and Technology Jiangsu UniversityZhenjiang212013China Pipeline Research Design Center PipeChina North Pipeline CompanyLangfang065000China

In order to study the variation of brake torque,vibration,pressure fluctuation,exterior noise and internal flow for a hydraulic retarder with different inclination angles and liquid-filled amount,a bench-scale hydraulic retarder was *** INV3020 data collection system was used for the synchronous acquisition of brake torque,vibration,pressure fluctuation and exterior noise *** were performed with different inclination angles(90°and 75°)and six liquid-filled amount(50 vol%,60 vol%,70 vol%,80 vol%,90vol%and 100 vol%).The torque-volume ratio was proposed to accurately analyze the influence of inclination angle on the liquid volume in stator and rotor and the brake *** multiphase flow model was employed to capture the volume and velocity *** research shows that the brake performance improves and the vibration increases with the decrease of inclination angle and the increase of liquid-filled *** pressure fluctuation increases as the liquid-filled amount increases,while the lower inclination angle effectively lowers the pressure fluctuation *** sound pressure level trends upward with increasing liquid-filled amount,and the lower inclination angle can effectively reduce the *** volume distribution of the liquid phase under different liquid-filled amount is basically *** lower inclination angle can induce more vortexes.

关键词： hydraulic retarder blade inclination angle liquid-filled amount brake torque vibration pressure fluctuation noise numerical calculation

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Discussion on the Teaching of "engineering Materials" with Philosophy Thoughts 8

Discussion on the Teaching of "engineering Materials" with P...

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8th Annual International Conference on Material Science and Environmental engineering, MSEE 2020

作者： Liu, Yan Qu, Yanpeng Song, Qinghua Chen, Songying Department of Process Equipment and Control Engineering School of Mechanical Engineering Shandong University Jinan250061 China

The college students in engineering can improve their professional level and comprehensive ability through learning the knowledge with philosophical ideas. In the teaching practice on the course of engineering materials, the authors constructed the contents including the ideological and political factors, and linked the philosophy thoughts with the professional education. The main results are as follows. We understand the similarities of engineering materials and life connotation, and clarify the internal relation and interaction mechanism between materials and objective environment through explaining the environmental theory;We know that we should find out the the principal contradiction during the engineering materials selection and life path selection through the contradiction theory;We understand the influence of various factors on the change of material performances and the influence of creative tools on the development of disciplines through the things correlation theory;We recognize that we need to sum up the historical experiences and learn the failure analysis methods to reduce the probability of disaster accidents through the philosophy methodology. Some relevant teaching cases are introduced in this paper. © 2021 Published under licence by IOP Publishing Ltd.

关键词： Students

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Numerical modeling of droplets injection in the secondary flow of the wet steam ejector in the refrigeration cycle

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INTERNATIONAL JOURNAL OF REFRIGERATION 2022年 136卷 103-113页

作者： Dadpour, Daryoush Lakzian, Esmail Gholizadeh, Mohammad Ding, Hongbing Han, Xu [a]Center of Computational Energy Department of Mechanical Engineering Hakim Sabzevari University Sabzevar Iran [b]Tianjin Key Laboratory of Process Measurement and Control School of Electrical and Information Engineering Tianjin University Tianjin 300072 China [c]Key Lab of Condition Monitoring and Control for Power Plant Equipment North China Electric Power University Ministry of Education Baoding 071003 China

Steam ejector plays a key role in the refrigeration system. The water has been used as a working fluid because water is more economical and non-toxic. The operating fluid often enters the evaporator as a water liquid and droplets evaporate by absorbing heat. Cooling load changing causes the vapor in the outlet of the evaporator to be accompanied by droplets. Therefore, there are droplets at the inlet of secondary nozzle and flow should be simulated as a wet steam flow with injection droplets at the secondary flow. In this paper, the effects of droplets injection at secondary flow have been investigated on the performance of the refrigeration cycle. For this purpose, the Eulerian-Eulerian method has been used and the results have been validated with experimental data. Six cases are considered with different wetness and number of droplets in the secondary flow. The results of case 6 show COP, T-outlet, and ER decrease about 22.93%, 15.66%, and 22.93%, respectively. In addition, the steam accompanies by droplets at the outlet of ejector. Therefore, it is essential for designers and operators to model and consider the effects of the droplets on the wall erosion to optimize the wet steam ejector and refrigeration cycle performance.

关键词： Wet steam ejector Refrigeration cycle Droplets injection COP ER

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Role of NO and SO_(2)in mercury oxidation over a La_(2)O_(3)/Fe_(2)O_(3)catalyst with high thermal stability

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Journal of Environmental Sciences 2021年第11期33卷 36-44页

作者： Ruihui Liu Yang Yang Tingyu Zhu Wenqing Xu School of Resources and Ciuil Engineering Northeastern UniversityShenyang 110819China Research Center for Process Pollution Control National Engineering Laboratory for Hydrometallurgical Cleaner Production TechnologyInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Resources and Materials Northeastern University at QinhuangdaoQinhuangdao 066004China National Engineering Laboratory for Flue Gas Pollutants Control Technology and Equipment Tsinghua UniversityBeijing 100084China

In this study,the thermal stability of a ferric oxide catalyst for mercury oxidation was found to be considerably promoted by doping with La_(2)O_(3).The catalysts doped with La_(2)O_(3)maintained a higher surface area when subjected to high-temperature calcination,with lower average pore size and a narrower pore size distribution.X-ray diffraction(XRD)results revealed that La_(2)O_(3)doping hinders the growth of catalyst particles and crystallization of the material at high *** NO and SO_(2)inhibited Hg^(0)oxidation over the La_(2)O_(3)/Fe_(2)O_(3)*** transform infrared(FTIR)spectra revealed that SO_(2)reacts with O_(2)over the catalysts to form several species that are inert for mercury oxidation,such as S042^(-),HS04^(-),or other related species;these inert species cover the catalyst surface and consequently decrease Hg^(0)oxidation *** addition,NO or SO_(2)competed with Hg^(0)for active sites on the La_(2)O_(3)/Fe_(2)O_(3)catalyst and hindered the adsorption of mercury,thereby inhibiting subsequent Hg^(0)***^(0)oxidation on the La_(2)O_(3)/Fe_(2)O_(3)catalyst mainly followed the Eley-Rideal ***,the inhibition effects of NO and SO_(2)were at least partially reversible,and the catalytic activity was temporarily restored after eliminating NO or S0_(2).

关键词： Mercury Flue gas Fe_(2)O_(3) La_(2)O_(3) Thermal stability

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