检索结果-内蒙古大学图书馆

Understanding of Spinel Phases in Lithium-Rich Cathode for High-Energy-Density Lithium-Ion Batteries:A Review

Energy Material Advances 2024年第1期5卷 212-235页

作者： Youyou Fang Jiayu Zhao Yuefeng Su Jinyang Dong Yun Lu Ning Li Haoyu Wang Feng Wu Lai Chen School of Materials Science and Engineering Beijing Key Laboratory of Environmental Science and EngineeringBeijing Institute of TechnologyBeijing 100081P.R.China Chongqing Innovation Center Beijing Institute of TechnologyChongqing 401120P.R.China

Layered Li-rich oxides have attracted much attention because of higher capacity than that of traditional layered oxides(more than 250 mAh g^(−1)).However,the intrinsic issues of Li-rich cathode materials suffer from lattice oxygen loss,poor rate capability,voltage fade,and limited cycle *** tackle these problems,the Li-rich cathode containing intergrown layer and spinel phases was proposed,and this heterostructure material meets the requirements of high energy and stable surface with a fast Li^(+)diffusion ***,we review the recent progress and in-depth understanding about heterostructure including microstructure and morphology,performance of advancement and degradation mechanisms,and modification *** attention is given to the high-performance energy mechanism as follows:(a)spinel phase and oxygen vacancy jointly enhance the lattice structure and prevent the irreversible oxygen release,(b)higher capacity is achieved by promotion of activation of Li_(2)MnO_(3) phase and control of the activation rate to realize stable long-term cyclability,and(c)spinel phase provides the 3D interconnected Li^(+)diffusion channels and protects the surface region from side *** other issue that aroused interest is the undesirable changes of phase transition and degradation mechanisms as follows:(a)the key reconstruction process is to produce a“good”spinel to maintain the surface and interior structure stability.(b)It is significant to figure out the structure degradation and phase transition mechanism in the cycled *** review aims to provide inspiration and opportunities for the design of high-energy-density cathode materials,thereby bridging the gap between laboratory research and practical battery applications.

关键词： lattice oxygen losspoor spinel phases heterostructure material high energy density lithium ion batteries layered oxides more high energy stable surface microstructure lithium rich cathode

来源：评论

学校读者我要写书评

暂无评论

Low temperature thermal strain of the IRFPA and the creep lifetime evaluation of solder joints

Low temperature thermal strain of the IRFPA and the creep li...

引用

2022 Applied Optics and Photonics China: Optoelectronics and Nanophotonics, AOPC 2022

作者： Liu, Yue Bo Yan, Jia Hui Liao, Wen Yuan Niu, Hao Chen, Xi Yu Li, Shu Wang Lai, Can Xiong Yang, Shao Hua Science and Technology on Reliability Physics and Application of Electronic Component Laboratory China Electronic Product Reliability and Environmental Testing Research Institute Guangzhou511370 China

ISBN: (纸本)9781510662261

Cryogenic Infrared Rays Focal Plane Array (IRFPA) detectors have been widely used in industry, transportation, security monitoring, meteorology and medicine because of the high sensitivity and temperature resolution. For HgCdTe IRFPA detectors, the typical working temperature is about 80 K. To make the IRFPA detector works at low temperatures, the detector should be integrated on a Dewar cold platform, whose refrigeration power would be higher than the heat load of the IRFPA. In general, the IRFPA detector and the Dewar cold platform would be integrated together to form a Dewar assembly at room temperature. In addition, the materials in IRFPA have different thermal expand coefficients, it means the thermal mismatch in the IRFPA would be an unavoidable issue in work. The thermal strain has a significant effect on the solder joints in switching cycle, which could lead to the creep strain and thermal fatigue crack. With the increase of the switch cyclic number, the creep strain and thermal fatigue crack under the thermal stress would lead to the failure of solder joints. Therefore, the low temperature thermal strain in switching cycle can affect the reliability of IRFPA detectors. So, the low temperature thermal strain and the creep lifetime of solder joints has been researched. © 2023 SPIE.

关键词： Dewars

来源：评论

学校读者我要写书评

暂无评论

Building Better Batteries:Solid-State Batteries with Li-Rich Oxide Cathodes

引用

Energy Material Advances 2023年第1期4卷 402-425页

作者： Lifeng Xu Shi Chen Yuefeng Su Jizhuang He Lian Wang Xing Shen Lai Chen Duanyun Cao Yun Lu Meng Wang Liying Bao Ning Li Feng Wu Beijing Key Laboratory of Environmental Science and Engineering School of Material Science and EngineeringBeijing Institute of TechnologyBeijing 100081China Beijing Institute of Technology Chongqing Innovation Center Chongqing 401120China

High-capacity Li-rich oxide materials have received extensive attention due to their unique anion-cation charge compensation ***,the high operating voltage,poor cycling performance,unsafe oxygen evolution,and voltage decay limit their industrial *** emergence and development of solid-state batteries offer a great opportunity to solve these issues by replacing flammable and unstable liquid electrolytes with solid ***,utilization of high-capacity Li-rich oxide cathodes enables to establish high-energy-density solid-state batteries with wide voltage ranges,light weight,and high mechanical *** review summarizes the recent progress of Li-rich oxide materials and solid electrolytes,emphasizing their major advantages,interface challenges,and modification approaches in the development of Li-rich solid-state *** also propose possible characterization strategies for effective interfacial observation and *** is hoped that this review should inspire the rational design and development of better solid-state batteries for application in portable devices,electric vehicles,as well as power grids.

关键词： Solid rational cycling

来源：评论

学校读者我要写书评

暂无评论

Efficient extraction of phenol from wastewater by ionic micro-emulsion method:Anionic and cationic

引用

Chinese Journal of Chemical engineering 2023年第6期58卷 137-145页

作者： Chaobo Zhang Xiaoyong Yang Jian Dai Wenxia Liu Hang Yang Zhishan Bai State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process School of Mechanical and Power EngineeringEast China University of Science and TechnologyShanghai 200237China

Phenolic wastewater is one of the priorities in the field of wastewater treatment,which poses a serious threat to the human health and nature *** this paper,cationic cetyltrimethylammonium bromide(CTAB)and anionic sodium oleate(Na OL)microemulsions were utilized to extract phenol from the *** optimal extraction factors were investigated by exploring the effects of microemulsion composition ratio and extraction conditions on the phenol extraction ***,the enhanced extraction mechanism of phenol by cations microemulsions is illustrated by studying the extraction process of cationic and anionic microemulsions in the extraction of *** optimum components were obtained:surfactant concentration of 0.2 mol·L^(-1),isoamyl alcohol volume of 30%,internal aqueous phase concentration of CTAB microemulsion of 0.05 mol·L^(-1),and internal aqueous phase concentration of Na OL microemulsion of 0.09 mol·L^(-1).The extraction efficiencies were 96.44%and 82.0%when using CTAB and Na OL microemulsions under optimal conditions(water-emulsion ratio of 5,contact time of 9 min,extraction temperature of 298.15 K,and p H of 9),confirming the enhanced extraction of phenol by CTAB cationic *** was analyzed that the enhanced extraction of CTAB microemulsion was due to the electrostatic adsorption of cations with phenol root ions.

关键词： Phenol-containing wastewater Phenol recovery Microemulsion extraction Ionic microemulsion Mechanism analysis

来源：评论

学校读者我要写书评

暂无评论

Estimation of unfrozen water content of saturated sandstones using nuclear magnetic resonance, mercury intrusion porosimetry, and ultrasonic tests

引用

Journal of Rock Mechanics and Geotechnical engineering 2024年第9期16卷 3465-3484页

作者： Fei Liu Shibing Huang Gang Liu Shilin Yu School of Resources and Environmental Engineering Wuhan University of Science and TechnologyWuhan430081China Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources Wuhan University of Science and TechnologyWuhan430081China

The unfrozenwater content(UWC)is a crucial parameter that affects the strength and thermal properties of rocks in relation to engineering construction and geological disasters in cold *** this study,three different methods were employed to test and estimate the UWC of saturated sandstones,including nuclear magnetic resonance(NMR),mercury intrusion porosimetry(MIP),and ultrasonic *** NMR method enabled the direct measurement of the UWC of sandstones using the free induction decay(FID).The MIP method was used to analyze the pore structures of sandstones,with the UWC subsequently calculated based on pore ice ***,the MIP test constituted an indirect measurement ***,a correlation was established between the P-wave velocity and the UWC of these sandstones based on the mixture theory,which could be employed to estimate the UWC as an empirical *** methods demonstrated that the UWC initially exhibited a rapid decrease from 0C to5C and then generally became constant beyond20***,these test methods had different *** NMR method was used to directly and accurately calculate the UWC in the ***,the cost and complexity of NMR equipment have precluded its use in the *** UWC can be effectively estimated by the MIP test,but the estimation accuracy is influenced by the ice crystallization process and the pore size *** P-wave velocity has been demonstrated to be a straightforward and practical empirical parameter and was utilized to estimate the UWC based on the mixture *** method may be more suitable in the *** methods confirmed the existence of a hysteresis phenomenon in the freezing-thawing *** average hysteresis coefficient was approximately 0.538,thus validating the GibbseThomson *** study not only presents alternative methodologies for estimating the UWC of saturated sandstones but also contribute to our understanding of the freezin

关键词： Unfrozen water content(UWC) Nuclear magnetic resonance(NMR) Mercury intrusion porosimetry(MIP) Pore structures P-wave velocity Sandstone

来源：评论

学校读者我要写书评

暂无评论

Nano silica aerogel-induced formation of an organic/alloy biphasic interfacial layer enables construction of stable high-energy lithium metal batteries

引用

Green Energy & Environment 2023年第4期8卷 1071-1080页

作者： Chengwei Ma Xinyu Zhang Chengcai Liu Yuanxing Zhang Yuanshen Wang Ling Liu Zhikun Zhao Borong Wu Daobin Mu Beijing Key Laboratory of Environmental Science and Engineering School of Materials Science and EngineeringBeijing Institute of TechnologyBeijing100081China Collaborative Innovation Center of Electric Vehicles in Beijing Beijing100081China

Lithium metal batteries represent promising candidates for high-energy-density batteries, however, many challenges must still be overcome,e.g., interface instability and dendrite growth. In this work, nano silica aerogel was employed to generate a hybrid film with high lithium ion conductivity(0.6 mS cm^(-1)at room temperature) via an in situ crosslinking reaction. TOF-SIMS profile analysis has revealed conversion mechanism of hybrid film to Li–Si alloy/Li F biphasic interface layer, suggesting that the Li–Si alloy and Li F-rich interface layer promoted rapid Li+transport and shielded the Li anodes from corrosive reactions with electrolyte-derived products. When coupled with nickel-cobalt-manganese-based cathodes, the batteries achieve outstanding capacity retention over 1000 cycles at 1 C. Additionally the developed film coated on Li enabled high coulombic efficiency(99.5%) after long-term cycling when coupled with S cathodes. Overall, the results presented herein confirm an effective strategy for the development of high-energy batteries.

关键词： Lithium metal batteries Nano silica aerogel In situ crosslinking Biphasic interface layer Li–Si alloy

来源：评论

学校读者我要写书评

暂无评论

Insights into the mechanism of the deterioration of mainstream partial nitritation/anammox under low residual ammonium

引用

Journal of environmental sciences 2023年第4期126卷 29-39页

作者： Yandong Yang Yiming Jiang Yanan Long Jiarui Xu Changqing Liu Liang Zhang Yongzhen Peng School of Environmental and Municipal Engineering Qingdao University of TechnologyQingdao 266033China National Engineering Laboratory for Advanced Municipal Wastewater Treatment and Reuse Technology Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery EngineeringBeijing University of TechnologyBeijing 100124China

Residual ammonium is a critical parameter affecting the stability of mainstream partial nitritation/anammox(PN/A), but the underlying mechanism remains unclear. In this study,mainstream PN/A was established and operated with progressively decreasing residual ammonium. PN/A deteriorated as the residual ammonium decreased to below 5 mg/L, and this was paralleled by a significant loss in anammox activity in situ and an increasing nitrite oxidation rate. Further analysis revealed that the low-ammonium condition directly decreased anammox activity in situ via two distinct mechanisms. First, anammox bacteria were located in the inner layer of the granular sludge, and thus were disadvantageous when competing for ammonium with ammonium-oxidizing bacteria(AOB) in the outer layer. Second, the complete ammonia oxidizer(comammox) was enriched at low residual ammonium concentrations because of its high ammonium affinity. Both AOB and comammox presented kinetic advantages over anammox bacteria. At high residual ammonium concentrations,nitrite-oxidizing bacteria(NOB) were effectively suppressed, even when their maximum activity was high due to competition for nitrite with anammox bacteria. At low residual ammonium concentrations, the decrease in anammox activity in situ led to an increase in nitrite availability for nitrite oxidation, facilitating the activation of NOB despite the dissolved oxygen limitation(0.15–0.35 mg/L) for NOB persisting throughout the operation. Therefore, the deterioration of mainstream PN/A at low residual ammonium was primarily triggered by a decline in anammox activity in situ. This study provides novel insights into the optimized design of mainstream PN/As in engineering applications.

关键词： Mainstream partial nitritation/anammox Residual ammonium Granular sludge Comammox

来源：评论

学校读者我要写书评

暂无评论

A critical review on thermodynamic mechanisms of membrane fouling in membrane-based water treatment process

引用

Frontiers of environmental science & engineering 2023年第10期17卷 147-169页

作者： Jiaheng Teng Ying Deng Xiaoni Zhou Wenfa Yang Zhengyi Huang Hanmin Zhang Meijia Zhang Hongjun Lin Key Laboratory of Watershed Earth Surface Processes and Ecological Security College of Geography and Environmental SciencesZhejiang Normal UniversityJinhua 321004China Key Laboratory of Industrial Ecology and Environmental Engineering(Ministry of Education) School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China

Membrane technology is widely regarded as one of the most promising technologies for wastewater treatment and reclamation in the 21st century. However, membrane fouling significantly limits its applicability and productivity. In recent decades, research on the membrane fouling has been one of the hottest spots in the field of membrane technology. In particular, recent advances in thermodynamics have substantially widened people’s perspectives on the intrinsic mechanisms of membrane fouling. Formulation of fouling mitigation strategies and fabrication of anti-fouling membranes have both benefited substantially from those studies. In the present review, a summary of the recent results on the thermodynamic mechanisms associated with the critical adhesion and filtration processes during membrane fouling is provided. Firstly, the importance of thermodynamics in membrane fouling is comprehensively assessed. Secondly, the quantitative methods and general factors involved in thermodynamic fouling mechanisms are critically reviewed. Based on the aforementioned information, a brief discussion is presented on the potential applications of thermodynamic fouling mechanisms for membrane fouling control. Finally, prospects for further research on thermodynamic mechanisms underlying membrane fouling are presented. Overall, the present review offers comprehensive and in-depth information on the thermodynamic mechanisms associated with complex fouling behaviors, which will further facilitate research and development in membrane technology.

关键词： Membrane fouling Thermodynamic mechanism XDLVO theory Flory-Huggins theory Fouling migration

来源：评论

学校读者我要写书评

暂无评论

Enhancing anoxic denitrification of low C/N ratio wastewater with novel ZVI composite carriers

引用

Journal of environmental sciences 2022年第2期34卷 180-191页

作者： Yanping Shi Tao Liu Hongtao Yu Xie Quan Key Laboratory of Industrial Ecology and Environmental Engineering(Ministry of Education) School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China

External organic carbon sources are needed to provide electron donors for the denitrification of wastewater with a low COD/NO_(3)^(-)-N(C/N)ratio,increasing the treatment *** economic strategy is to enhance the bioactivity and/or biodiversity of denitrifiers to efficiently utilize organic substances in *** this study,novel zero-valent iron(ZVI)composite carriers were prepared and implemented in a suspended carrier biofilm reactor to enhance the bioactivity and/or biodiversity of *** the influent C/N ratio of 4(COD was 179.5±5.0 mg/L and TN was 44.2±0.8 mg/L),COD and TN removal efficiencies were 85.1%and 66.4%,respectively,in the reactors filled with 3 wt%ZVI composite *** contrast,COD and TN removal efficiencies were 70.4%and 55.3%,respectively,in the reactor filled with conventional high-density polyethylene(HDPE)biofilm *** biofilm formation on the 3 wt%ZVI composite carriers was optimized due to its higher roughness(surface square roughness increased from 76.0 nm to 93.8 nm)and favorable hydrophilicity(water contact angle dropped to 72.5°±1.4°from 94.3°±3.2°)compared with the HDPE biofilm *** addition,heterotrophic denitrifiers,Thauera and Dechloromonas,were enriched,whereas autotrophic denitrifiers,Raoultella and Thiobacillus,exhibited high relative abundance in the biofilm of ZVI composite *** coexistence of heterotrophic denitrifiers and autotrophic denitrifiers on the surface of ZVI composite carriers provided mixotrophic metabolism of denitrification(including heterotrophic and iron-based autotrophic),thereby ensuring effective denitrification for wastewater with a low C/N ratio without external organic carbon source addition.

关键词： ZVI Biofilm carrier Low C/N ratio Integrated floating fixed-film and activated sludge(IFFAS) Denitrification

来源：评论

学校读者我要写书评

暂无评论

Bibliometric analysis and scientific trends on perfluorinated and polyfluoroalkyl substances (PFASs) as an emerging pollutant

引用

Water-Energy Nexus 2024年第1期7卷 187-199页

作者： Guo, Hongan Xing, Meiyan Sun, Xiaojie Liu, Tao Key Laboratory of Yangtze Water Environment for Ministry of Education College of Environmental Science and Engineering Tongji University Shanghai200092 China Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology Guilin University of Technology Guilin541004 China

The persistence, bioaccumulation, and toxicity of perfluorinated and polyfluoroalkyl substances (PFASs), along with their concentrations in the environment and humans, have attracted global attention. However, so far, there have been seldom reports providing a systematical review in the entire field of PFASs research. Therefore, this study summarizes 14,112 relevant publications (2005–2022) and conducts bibliometric analysis using Vosviewer and CiteSpace. The findings offer insights into global PFASs research trends, assisting scientists in establishing their research directions. Unlike traditional literature reviews, this article presents a new method for data collection and analysis that achieves quantitative visualization of the information from the past 18 years in the field of PFASs. Results show a significant increase in global PFASs publications, with China leading in publication output and the US in international collaborations. Author Kurunthachalam Kanna has the highest publication records. Document co-citation clustering and key line analysis identifies four major research areas and landmarks, while betweenness centrality analysis reveals developmental processes. Citation burst analysis finds that PFASs toxicity and monitoring have been hot areas, suggesting the need for greater attention towards the types and levels of PFASs in various environmental media and the removal processes of PFASs responsible for pollution, which may emerge as future research hotspots. © 2024

关键词： Toxicity

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：