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High temperature electrochemical discharge performance of LaFeO3 coated with C/Ni as anode material for NiMH batteries

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Progress in Natural science:Materials International 2022年第6期32卷 684-692页

作者： Kailiang Ren Jiajia Miao Wenzhuo Shen Huanhuan Su Yunpeng Pan Jiajin Zhao Xiangyu Pan Yuan Li Yaokun Fu Lu Zhang Shumin Han State Key Laboratory of Metastable Materials Science and Technology Yanshan University School of Environmental and Chemical Engineering Yanshan University

Perovskite LaFeO3is considered as a promising new anode material for nickel/metal hydride batteries due to its low cost,environmental friendliness and high temperature ***,the poor conductivity of LaFeO3material restricts the discharge ability,which is problematic for its future widespread *** solve the above issue,in this study,we prepared C/Ni-coated LaFeO3composite in view of the excellent electrical conductivity of carbon and nickel *** show that the C/Ni-coated LaFeO3composite delivers remarkably increased discharge capacity of ～345 mAh g-1at 60℃ in contrast to ～267 mAh g-1for pure ***,the carbon and nickel not only increase the electrical conductivity of the LaFeO3but also reduces the agglomeration of the LaFeO3,therefore,the C/Ni-coated LaFeO3composite serves superior long cycle-life,which maintains 60.9% after 100 cycles（52.9% for the LaFeO3sample）.In overall,the electrochemical behavior of the C/Ni-coated LaFeO3composite confirms its high potential as nickel/metal hydride batteries for energy storage applications.

关键词： Energy storage Perovskite-type oxide Nickel metal hydride batteries LaFeO 3 Electrochemical performance

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Controllable preparation of red phosphorus nanoribbons for enhanced photocatalytic degradation of Methyl Orange and Tetracycline

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environmental science and Pollution Research 2024年第42期31卷 55035-55045页

作者： Zhu, Jingyu Lv, Wuhua Wang, Chi Li, Kai Mei, Yi Faculty of Chemical Engineering Kunming University of Science and Technology Kunming650500 China Yunnan Province Key Laboratory of Energy Saving in Phosphorus Chemical Engineering and New Phosphorus Materials Kunming650500 China The Higher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province Kunming650500 China Faculty of Environmental Science Engineering Kunming University of Science and Technology Kunming650500 China

Nanoribbons (NRs), leveraging the flexibility of one-dimensional materials and the expansive surface area of two-dimensional materials, offer heightened exposure to edge sites and superior charge transfer rates. Consequently, they present promising prospects within the domain of photocatalysis. Crystalline red phosphorus (cRP), dcharacterized by its layered and fibrous structure, lends itself readily to the production of nanoribbons. Our study demonstrates a robust method for achieving high-yield, high-quality cRP by concurrently introducing mineralizing agent I2 and Si wafers into the Chemical Vapor Transport (CVT) synthesis process. Through ultrasound assistance, we transformed high-quality cRP into crystalline red phosphorus nanoribbons (cRP NRs) with an average thickness ranging from 7.5 to 17.5 nm and an average width between 75 and 175 nm. cRP NRs (I2 and Si) showcased impressive degradation capabilities towards Methyl Orange (MO) and Tetracycline (TC), achieving a remarkable 99% degradation of MO within 18 min under the simulated visible-light irradiation. The reactive species capturing experiments confirmed that ·O2− was the primary active agent responsible for the photocatalytic degradation of MO. Graphical Abstract: (Figure presented.) © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

关键词： Silicon wafers

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Promotional catalytic activity and reaction mechanism of Ag-modified Ce_(0.6)Zr_(0.4)O_(2) catalyst for catalytic oxidation of ammonia

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Journal of environmental sciences 2023年第2期124卷 491-504页

作者： Xiaolong Tang Yuanyuan Zhang Yaru Lei Yuanyuan Liu Honghong Yi Fengyu Gao School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants Beijing 100083China

Ce1-xZrxO_(2) composite oxides(molar,x=0-1.0,interval of 0.2)were prepared by a cetyltrimethylammonium bromide-assisted precipitation *** enhancement of silver-species modification and catalytic mechanism of adsorption-transformationdesorption process were investigated over the Ag-impregnated catalysts for lowtemperature selective catalytic oxidation of ammonia(NH_(3)-SCO).The optimal 5 wt.%Ag/Ce_(0.6)Zr_(0.4)O_(2) catalyst presented good NH_(3)-SCO performancewith>90% NH_(3) conversion at temperature(T)≥250°C and 89% N_(2) *** the irregular block shape and underdeveloped specific surface area(∼60m2/g),the naked and Ag-modified Ce_(0.6)Zr_(0.4)O_(2) solid solution still obtained highly dispersed distribution of surface elements analyzed by scanning electron microscope-energy dispersive spectrometer(SEM-EDS)(mapping),N_(2) adsorptiondesorption test and X-ray diffraction(XRD).H2 temperature programmed reduction(H2-TPR)and X-ray photoelectron spectroscopy(XPS)results indicated that Ag-modification enhanced the mobility and activation of oxygen-species leading to a promotion on CeO_(2) reducibility and synergistic Ag0/Ag+and Ce^(4+)/Ce^(3+)redox ***,Ag+/Ag_(2)O clusters could facilitate the formation of surface oxygen vacancies that was beneficial to the adsorption and activation of ***3-temperature programmed desorption(NH_(3)-TPD)showed more adsorption-desorption capacity to ammoniawere provided by physical,weakandmedium-strong acid *** reflectance infrared Fourier transform spectroscopy(DRIFTS)experiments revealed the activation of ammonia might be the control step of NH3-SCO procedure,during which NH3 dehydrogenation derived from NHx-species and also internal selective catalytic reduction(i-SCR)reactions were proposed.

关键词： Ag/Ce_(0.6)Zr_(0.4)O_(2)catalyst Synergistic interaction Catalytic oxidation of ammonia NH3 dehydrogenation Internal selective catalytic reduction

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An insight on the mechanism of efficient leaching of vanadium from vanadium shale induced by microwave-generated hot spots

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International Journal of Minerals,Metallurgy and Materials 2023年第2期30卷 293-302页

作者： Sheng Li Yimin Zhang Yizhong Yuan Pengcheng Hu School of Resource and Environmental Engineering Wuhan University of Science and TechnologyWuhan 430081China State Environmental Protection Key Laboratory of Mineral Metallurgical Resources Utilization and Pollution Control Wuhan University of Science and TechnologyWuhan 430081China Collaborative Innovation Center of Strategic Vanadium Resources Utilization Wuhan 430081China Hubei Provincial Engineering Technology Research Center of High Efficient Cleaning Utilization for Shale Vanadium Resource Wuhan University of Science and TechnologyWuhan 430081China School of Resource and Environmental Engineering Wuhan University of TechnologyWuhan 430070China

Microwave heating can rapidly and uniformly raise the temperature and accelerate the reaction *** this paper,microwave heating was used to improve the acid leaching,and the mechanism was investigated via microscopic morphology analysis and numerical simulation by COMSOL Multiphysics *** effects of the microwave power,leaching temperature,CaF_(2) dosage,H_(2)SO_(4) concentration,and leaching time on the vanadium recovery were investigated.A vanadium recovery of 80.66%is obtained at a microwave power of 550 W,leaching temperature of 95℃,CaF_(2) dosage of 5wt%,H_(2)SO_(4) concentration of 20vol%,and leaching time of 2.5 *** with conventional leaching technology,the vanadium recovery increases by 6.18%,and the leaching time shortens by 79.17%.More obvious pulverization of shale particles and delamination of mica minerals happen in the microwave-assisted leaching *** simulation results show that the temperature of vanadium shales increases with an increase in electric field(E-field).The distributions of E-field and temperature among vanadium shale particles are relatively uniform,except for the higher content at the contact position of the *** analysis results of scaleup experiments and leaching experiments indicate high-temperature hot spots in the process of microwave-assisted leaching,and the local high temperature destroys the mineral structure and accelerates the reaction rate.

关键词： vanadium shale microwave-assisted leaching hot spots numerical simulation

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Establishment of compound database of emerging antioxidants and high-resolution mass spectrometry screening in lake sediment from Taihu Lake Basin, China

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environmental science and Pollution Research 2024年第19期31卷 28341-28352页

作者： Su, Huijun Li, Jianhua Ye, Langjie Su, Guanyong Key Laboratory of Environmental Remediation and Ecological Health Ministry of Industry and Information Technology School of Environmental and Biological Engineering Nanjing University of Science and Technology Nanjing210094 China Shaanxi Key Laboratory of Low Metamorphic Coal Clean Utilization Yulin Engineering Research Center of Coal Chemical Wastewater School of Chemistry and Chemical Engineering Yulin University Yulin719000 China

Antioxidants are ubiquitous in various environmental samples, leading to increasing concern regarding their potential risk to environments or humans. However, there is dearth of information regarding the environmental fate of antioxidants and unknown/unexpected antioxidants in the environment. Here, we established a compound database (CDB) containing 320 current-used antioxidants by collecting the chemicals from EPA’s functional use database and published documents. Physical–chemical characteristics of these antioxidants were estimated, and 19 ones were considered as persistent and bioaccumulative (P&B) substances. This CDB was further coupled with high resolution mass spectrometry (HRMS) technique, which was employed for suspect screening of antioxidants in extracts of sediments (n = 88) collected from Taihu Lake basin. We screened 119 HRMS features that can match 135 chemical formulas in the CDB, and 20 out of them exhibited the detection frequencies ≥ 90%. The total concentrations of suspect antioxidants in sediments ranged from 6.41 to 830 ng/g dw. Statistical analysis demonstrated that concentrations of suspect antioxidants in Taihu Lake were statistically significantly lower than those in Shihu and Jiulihu Lake, but greater than those from other small lakes. Collectively, this study provided a CDB that could be helpful for further monitoring studies of antioxidant in the environments, and also provided the first evidence regarding the ubiquity of antioxidants in aquatic environment of Taihu Lake basin. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

关键词： Antioxidants

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Bioleaching and biosorption behavior of vanadium-bearing stone coal by Bacillus mucilaginosus

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International Journal of Minerals,Metallurgy and Materials 2023年第2期30卷 283-292页

作者： Yingbo Dong Shijia Chong Hai Lin School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China Beijing Key Laboratory on Resource-oriented Treatment of Industrial Pollutants Beijing 100083China

The recovery of vanadium(V)from stone coal by bioleaching is a promising *** bioleaching experiments and the biosorption experiments were carried out,aiming to explore the adsorption characteristics of Bacillus mucilaginosus(***)on the surface of vanadium-bearing stone coal,and the related mechanisms have been *** bioleaching at 30℃ for 28 d,the cumulative leaching rate of V reached 60.2%.The biosorption of *** on stone coal was affected by many *** the pH value of leaching system is 5.0,strong electrostatic attraction between bacteria and stone coal promoted *** in the logarithmic growth phase had mature and excellent biosorption *** initial bacterial concentration of 3.5×10^(8) CFU/mL was conducive to adhesion,with 38.9%adsorption rate and 3.6×10^(7) CFU/g adsorption *** adsorption of *** on the stone coal conformed to the Freundlich model and the pseudo-second-order kinetic *** surface carried functional groups(-CH_(2),-CH_(3),-NH_(2),etc.),which were highly correlated with the adsorption *** addition,biosorption changed the surface properties of stone coal,resulting in the isoelectric point(IEP)approaching the *** results could provide an effective reference for the adsorption laws of bacteria on minerals.

关键词： Bacillus mucilaginosus vanadium-bearing stone coal bioleaching biosorption

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Efficient and eco-friendly carbon dioxide capture with metal phosphate catalysts in monoethanolamine solutions

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Chinese Journal of Chemical engineering 2024年第11期75卷 121-130页

作者： Chunjin Zhang Xue Yao Linlin Chen Hua Tang Siming Chen School of Environmental Science and Engineering Carbon Neutrality and Eco-Environmental Technology Innovation Center of QingdaoQingdao UniversityQingdao 266075China Jiangsu Key Laboratory of Coal-based Greenhouse Gas Control and Utilization China University of Mining and TechnologyXuzhou 221008China Carbon Neutralization Institute China University of Mining and TechnologyXuzhou 221008China School of Chemical Engineering China University of Mining and TechnologyXuzhou 221008China

Catalytic carbon dioxide(CO_(2))desorption has emerged as a promising approach to enhance the efficiency of CO_(2)capture while minimizing energy demands,crucial for advancing chemical absorption *** study investigates the catalytic potential of three metal phosphates(aluminium phosphate(AlPO4),cobaltous phosphate(Co_(3)(PO_(4))_(2)),and zinc phosphate(Zn_(3)(PO_(4))_(2)))in improving the MEA(monoethanolamine)-based CO_(2)absorption-desorption *** the catalysts tested,AlPO_(4)demonstrated superior performance,enhancing CO_(2)absorption capacity by 4.2%to 9.3%and desorption capacity by 12.3%to 22.7%across five ***,AlPO_(4)increased the CO_(2)desorption rate by over 104.4%at a desorption temperature of 81.3℃,simultaneously reducing the required sensible heat by 12.3%to 22.7%,compared to processes without *** improved efficiency is attributed to AlPO_(4)'s ability to effectively transfer hydrogen protons from protonated MEA to carbamate,thereby facilitating the decomposition of carbamate and regenerating CO_(2).This research introduces a viable,cost-effective,and eco-friendly solid acid catalyst strategy for CO_(2)desorption,contributing to the development of more energy-efficient CO_(2)capture technologies.

关键词： CO_(2) CO_(2) capture Catalytic desorption Energy reduction Metal phosphate Stability

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Enhanced structural stability and durability in lithium-rich manganese-based oxide via surface double-coupling engineering

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Journal of Energy Chemistry 2024年第11期98卷 274-283页

作者： Jiayu Zhao Yuefeng Su Jinyang Dong Xi Wang Yun Lu Ning Li Qing Huang Jianan Hao Yujia Wu Bin Zhang Qiongqiong Qi Feng Wu Lai Chen School of Materials Science and Engineering Beijing Key Laboratory of Environmental Science and EngineeringBeijing Institute of TechnologyBeijing 100081China Chongqing Innovation Center Beijing Institute of TechnologyChongqing 401120China Yibin Libode New Materials Co. Ltd.Yibin 64400SichuanChina Initial Energy Science&Technology(Xiamen)Co. LtdXiamen 361000FujianChina

Lithium-rich manganese-based oxides(LRMOs) exhibit high theoretical energy densities, making them a prominent class of cathode materials for lithium-ion batteries. However, the performance of these layered cathodes often declines because of capacity fading during cycling. This decline is primarily attributed to anisotropic lattice strain and oxygen release from cathode surfaces. Given notable structural transformations, complex redox reactions, and detrimental interface side reactions in LRMOs, the development of a single modification approach that addresses bulk and surface issues is challenging. Therefore,this study introduces a surface double-coupling engineering strategy that mitigates bulk strain and reduces surface side reactions. The internal spinel-like phase coating layer, featuring threedimensional(3D) lithium-ion diffusion channels, effectively blocks oxygen release from the cathode surface and mitigates lattice strain. In addition, the external Li_(3)PO_(4) coating layer, noted for its superior corrosion resistance, enhances the interfacial lithium transport and inhibits the dissolution of surface transition metals. Notably, the spinel phase, as excellent interlayer, securely anchors Li_(3)PO_(4) to the bulk lattice and suppresses oxygen release from lattices. Consequently, these modifications considerably boost structural stability and durability, achieving an impressive capacity retention of 83.4% and a minimal voltage decay of 1.49 m V per cycle after 150 cycles at 1 C. These findings provide crucial mechanistic insights into the role of surface modifications and guide the development of high-capacity cathodes with enhanced cyclability.

关键词： Lithium-ion battery Layered lithium-rich cathode Surface double-coupling engineering Lattice strain Oxygen release

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Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery

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Chinese Chemical Letters 2024年第6期35卷 206-210页

作者： Yue Qian Zhoujia Liu Haixin Song Ruize Yin Hanni Yang Siyang Li Weiwei Xiong Saisai Yuan Junhao Zhang Huan Pang School of Environmental&Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China School of Chemistry&Chemical Engineering Yangzhou UniversityYangzhou 225009China Shandong Key Laboratory of Biochemical Analysis College of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China

Covalent organic frameworks(COFs)exhibiting reversible redox behaviors have been identified as promising candidates for constructing electrode materials in lithium-ion batteries(LIBs).However,their extensive application has been limited due to finite redox sites and poor structural *** this study,we design and synthesize a novel polyimide covalent organic framework(PI-COF)using the traditional solvothermal method and successfully apply it as an anode material for *** large conjugated structure of PI-COF accelerates charge transfer,while its large surface area provides more active sites,making PI-COF an attractive anode material for ***,the PI-COF anode material demonstrates high reversible specific capacity and excellent long-term cycling stability due to its COF ***,the PI-COF electrodes deliver a specific capacity of 800 m Ah/g at a current density of 200 m A/g after 200 cycles,while a specific capacity of 450 m Ah/g at a current density of 1000 m A/g is sustained after 800 *** outstanding lithium storage capacity,particularly the satisfactory long-term cycling stability,establishes PI-COF as a promising material for LIBs.

关键词： Ethylenediaminetetraacetic dianhydride Covalent organic frameworks Polyimide Lithium-ion battery Anode material

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In vitro degradation and multi-antibacterial mechanisms ofβ-cyclodextrin@curcumin embodied Mg(OH)_(2)/MAO coating on AZ31 magnesium alloy

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Journal of Materials science & technology 2023年第1期132卷 179-192页

作者： Kui Xue Pei-Hong Tan Ze-Hui Zhao Lan-Yue Cui M Bobby Kannan Shuo-Qi Li Cheng-Bao Liu Yu-Hong Zou Fen Zhang Zhuo-Yuan Chen Rong-Chang Zeng Corrosion Laboratory for Light Metals College of Materials Science and EngineeringShandong University of Science and TechnologyQingdao 266590China School of Engineering The University of NewcastleCallaghanNSW 2308Australia College of Chemical and Environmental Engineering Shandong University of Science and TechnologyQingdao 266590China School of Materials Science and Energy Engineering Foshan UniversityFoshan 528000China School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450002China

It is a challenging task to prepare a coating on Mg alloys for desirable corrosion resistance,good antibac-terial ability and *** this research work,an in-situ Mg(OH)_(2)coating incorporated with sodium alginate(SA)andβ-cyclodextrin(β-CD)@curcumin(Cur)was formed on the surface of micro arc oxidation(MAO)coated AZ31 alloy via a low temperature hydrothermal *** tech-niques such as X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),Fourier transform infrared spectrometer(FT-IR)and scanning electron microscope(SEM)were employed to characterize the chemi-cal composition and surface morphology of the *** corrosion protection ability of the coatings was monitored via electrochemical polarization,hydrogen evolution and immersion *** antibacterial ability and cytocompatibility of the coatings were evaluated by plate counting method under the irradiation of 808 nm-near infrared light,in vitro cytotoxicity tests(MTT)and live/dead cell *** results indicate that a chelation of the organic molecules led to the formation of a MAO/(β-CD@Cur)-SA-Mg(OH)_(2)coating with excellent corrosion protection,multi-antibacterial ability and almost no toxic-ity to the ***,the coating provided photothermal performance through the light absorption of Cur,which was encapsulated byβ-CD to improve its *** enhanced the binding force between the drug and the *** novel coating designated the potential application on bioab-sorbable magnesium alloys.

关键词： Magnesium alloys Photothermal ability Antibacterial coating Corrosion Biomaterials

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