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Calibration of local chemical pressure by optical probe

National science Review 2023年第9期10卷 258-269页

作者： Xiao Zhou Mei-Huan Zhao Shan-Ming Yao Hongliang Dong Yonggang Wang Bin Chen Xianran Xing Man-Rong Li Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education School of ChemistrySun Yat-sen University Center for High Pressure Science and Technology Advanced Research School of Materials Science and Engineering Peking University Beijing Advanced Innovation Center for Materials Genome Engineering Institute of Solid State Chemistry University of Science and Technology Beijing School of Science Hainan University

Chemical stabilization of a high-pressure metastable state is a major challenge for the development of advanced *** chemical pressure(Pchem) can effectively simulate the effect of physical pressure(Pphy)) experimental calibration of the pressure passed to local structural motifs,denoted as local chemical pressure(Pchem-△) which significantly governs the function of solid materials,remains absent due to the challenge of probing *** we establish an innovative methodology to experimentally calibrate the Pchem-△and build a bridge between Pchemand Pphyvia an optical probe ***-selective Bi3+-traced REVO4（RE=Y,Gd） is adopted as a prototype to introduce Bi3+optical probes and on-site sense of the Pchem-△experienced by the *** cell compression of RE0.9gBi0.02VO4under Pphyis chemically simulated by smaller-ion substitution(Sc3+→RE3+) in *** consistent red shift（△λ） of the emission spectra of Bi3+,which is dominated by locally pressure-induced REO8dodecahedral variation in RE0.98Bi0.02VO4(Pphy) and RE0.98-xScxBi0.02VO4(Pchem-△),respectively,is evidence of their similar pressure-dependent local structure *** innovative △λ-based experimental calibration of Pchem-△in the crystal-field dimension portrays the anisotropic transmission of Pchemto the local structure and builds a bridge between Pchem-△and Pphyto guide a new perspective for affordable and practical interception of metastable states.

关键词： chemical pressure high pressure ion substitution optical parameter spectra shift pressure calibration

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Stretchable polymer composites with ultrahigh piezoelectric performance

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National science Review 2023年第8期10卷 203-210页

作者： Tongxiang Tang Zhonghui Shen Jian Wang Shiqi Xu Jiaxi Jiang Jiahui Chang Mengfan Guo Youjun Fan Yao Xiao Zhihao Dong Houbing Huang Xiaoyan Li Yihui Zhang Danyang Wang Long-Qing Chen Ke Wang Shujun Zhang Ce-Wen Nan Yang Shen State Key Lab of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua University State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Center of Smart Materials and Devices Wuhan University of Technology Advanced Research Institute of Multidisciplinary Science Beijing Institute of Technology Applied Mechanics Laboratory Department of Engineering Mechanics Tsinghua University Center for Flexible Electronics Technology Tsinghua University School of Materials Science and Engineering University of New South Wales Department of Materials Science and Engineering The Pennsylvania State University State College Institute for Superconducting and Electronic Materials Australian Institute for Innovative MaterialsUniversity of Wollongong

Flexible piezoelectric materials capable of withstanding large deformation play key roles in flexible electronics. Ferroelectric ceramics with a high piezoelectric coefficient are inherently brittle, whereas polar polymers exhibit a low piezoelectric coefficient. Here we report a highly stretchable/compressible piezoelectric composite composed of ferroelectric ceramic skeleton, elastomer matrix and relaxor ferroelectric-based hybrid at the ceramic/matrix interface as dielectric transition layers, exhibiting a giant piezoelectric coefficient of 250 picometers per volt, high electromechanical coupling factor keff of 65%,ultralow acoustic impedance of 3MRyl and high cyclic stability under 50% compression strain. The superior flexibility and piezoelectric properties are attributed to the electric polarization and mechanical load transfer paths formed by the ceramic skeleton, and dielectric mismatch mitigation between ceramic fillers and elastomer matrix by the dielectric transition layer. The synergistic fusion of ultrahigh piezoelectric properties and superior flexibility in these polymer composites is expected to drive emerging applications in flexible smart electronics.

关键词： polymer composites piezoelectric materials structure design flexible electronics

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Strengthening mechanism of different morphologies of nanosized MSH on tribological performance of phosphate/MoS_(2) bonded solid lubricating coatings

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Friction 2024年第11期12卷 2563-2575页

作者： Zhengchao XI Jianbo SUN Lei CHEN Haixia CUI Yanjun MA Huidi ZHOU Jianmin CHEN State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Aerospace Research Institute of Materials&Processing Technology Beijing 100076China

Magnesium silicate hydroxides(MSHs)with granular,schistose,and tubular morphologies were separately incorporated to enhance the tribological properties of phosphate/MoS_(2) composite *** nano-schistose MSH demonstrated superior tribological performance due to its effective interactions with the worn surface and frictional synergies with solid *** of nano-schistose MSH decreased the friction coefficient of composite coatings by about 34.7%and increased the anti-wear performance of composite coatings by about thirteen ***-schistose MSH facilitated the formation of a friction-induced multi-layer heterogenous slipping structure with layered solid lubricants at the friction ***,tribo-chemical reactions between nano-schistose MSH and worn surface promoted the in-situ formation of a cermet supporting film,and this also induced the gradual in-situ formation of a lubrication film on the top of worn ***,the contact state between tribo-pairs was timely regulated and the invalidation of the nanocomposite slipping structure was effectively restrained during the friction *** a result,the service life of the phosphate composite coatings was significantly extended and further abrasion on the worn surface was notably reduced.

关键词： nano-sized magnesium silicate hydroxide(MSH) morphology regulation nanocomposite slipping structure tribo-film

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MOF and its derivative materials modified lithium-sulfur battery separator:a new means to improve performance

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Rare Metals 2024年第6期43卷 2418-2443页

作者： Rong-Wei Huang Yong-Qi Wang Dan You Wen-Hao Yang Bin-Nan Deng Fei Wang Yue-Jin Zeng Yi-Yong Zhang Xue Li National Local Joint Engineering Research Center for Lithium-Ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Batteries Materials of Yunnan ProvinceFaculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunming 650093China State Key Laboratory of Physical Chemistry of Solid Surfaces Collaborative Innovation Centre of Chemistry for Energy MaterialsState-Province Joint Engineering Laboratory of Power Source Technology for New Energy VehicleEngineering Research Center of Electrochemical TechnologyMinistry of EducationCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China

In recent years,lithium-sulfur batteries(LSBs)are considered as one of the most promising new generation energies with the advantages of high theoretical speeific capacity of sulfur(1675 mAh·g^(-1)),abundant sulfur resources,and environmental friendliness storage technologies,and they are receiving wide attention from the ***,the problems of the shuttle effect and lithium dendrite growth in LSBs have limited their practical application,so there is a need to find ways to solve these *** is an excellent choice to use novel materials to modify battery *** those novel materials,the metal-organic framework(MOF)has the properties of regular pores and controllable *** applied as a positive electrode and diaphragm,it can restrain the shuttle effect and lithium dendrite growth,especially since it shows excellent performance in diaphragm ***,various design strategies and synthesis methods of MOF-modified separators are reviewed in this paper,and the applications of MOF in LSBs separators in different forms are introduced,including the composite of MOF and carbon-based materials,the compounding of MOF and polymer,self-carbonization to form MOF-derived *** the same time,different characterization techniques are systematically reviewed to obtain the physical and chemical properties of MOF particles and the working mechanism of MOF-modified diaphragm,which provides a basis for further research in this ***,some future research trends and directions are put forward to fully tap the future commercial potential of MOF-modified diaphragm in LSBs.

关键词： MOF Lithium-sulfur battery Modified diaphragms Design strategies Prospect Characterization

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An interfacial robust and entire self-healing ionogel-elastomer hybrid for elastic electronics enables discretionary assembly and reconfiguration

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science China Chemistry 2024年第4期67卷 1316-1323页

作者： Lei Yang Lijie Sun Hongfei Huang Rasoul Esmaeely Neisiany Zhengwei You State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Institute of Functional MaterialsCollege of Materials Science and EngineeringDonghua UniversityResearch Base of Textile Materials for Flexible Electronics and Biomedical Applications(China Textile Engineering Society)Shanghai Engineering Research Center of Nano-Biomaterials and Regenerative MedicineShanghai 201620China Department of Polymer Engineering Hakim Sabzevari UniversitySabzevar ***Iran Biotechnology Centre Silesian University of TechnologyGliwice 44-100Poland

Inspired by the multi-layer architecture of mammal skins,interfacial robust,stretchable,and entirely healable gel-elastomer hybrids hold great potential in diverse fields including biomedical devices,wearable electrical devices,and soft ***,existing gel-elastomer hybrids have numerous limitations including low interfacial bonding toughness,complex and time-consuming preparation process,unhealable,and ***,we propose a simple and general chemical strategy through the interfacial dynamic bonding between gel and elastomer to simultaneously address the abovementioned *** covalent bonds readily and repeatably covalent bonding ionogel and elastomer(interfacial toughness:390 J m^(-2)),endowed the hybrids with entire self-healing features like skin and enabled discretionary assembly and ***,this strategy resolved the troublesome contradiction between interfacial stability and *** advantage of the aforementioned features,we readily constructed a multi-module,self-healing,self-powered,and realtime monitoring of personal status integrated elastic electronics,which could simply reconfigure the output signal of elastic electronics into an input signal of the devices-braille keyboard.

关键词： ionogel elastomer interface bonding self-healing dynamic covalent bond

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Bipolarized intrinsic faradaic layer on a semiconductor surface under illumination

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National science Review 2023年第4期10卷 114-122页

作者： Mengfan Xue Zhiqiang Chu Dongjian Jiang Hongzheng Dong Pin Wang Gengzhi Sun Yingfang Yao Wenjun Luo Zhigang Zou Eco-Materials and Renewable Energy Research Center (ERERC) Jiangsu Key Laboratory for Nano Technology National Laboratory of Solid State Microstructures and Department of Physics Nanjing University National Laboratory of Solid State Microstructures College of Engineering and Applied Sciences Nanjing University Key Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM) Nanjing Tech University

Interface charge transfer plays a key role in the performance of semiconductors for different kinds of solar energy utilization, such as photocatalysis, photoelectrocatalysis, photochromism and photo-induced superhydrophilicity. In previous studies, different mechanisms have been used to understand interface charge transfer processes. However, the charge transfer mechanism at the solid/liquid interface remains a controversial topic. Here, taking TiO2as a model, we find and prove, via experiments, the new characteristic of photo-induced bipolarity of the surface layer（reduction faradaic layer and oxidation faradaic layer） on a semiconductor for the first time. Different from energy level positions in the classic surface states transfer mechanism, the potential window of a surface faradaic layer is located out of the forbidden band. Moreover,we find that the reduction faradaic layer and oxidation faradaic layer serve as electron and hole transfer mediators in photocatalysis, while the bipolarity or mono-polarity of the surface layer on a semiconductor depends on the applied potential in photoelectrocatalysis. The new characteristic of bipolarity can also offer new insights into the charge transfer process at the semiconductor/liquid interface for solar energy utilization.

关键词： semiconductor surface interface charge transfer reduction faradaic layer oxidation faradaic layer faradaic layer descriptor

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Gate-tunable Berry curvature in van der Waals itinerant ferromagnetic Cr_(7)Te_(8)

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InfoMat 2024年第3期6卷 108-116页

作者： Kui Meng Zeya Li Zhansheng Gao Xiangyu Bi Peng Chen Feng Qin Caiyu Qiu Lingyun Xu Junwei Huang Jinxiong Wu Feng Luo Hongtao Yuan National Laboratory of Solid State Microstructures Collaborative Innovation Center of Advanced MicrostructuresCollege of Engineering and Applied SciencesJiangsu Key Laboratory of Artificial Functional MaterialsNanjing UniversityNanjingthe People's Republic of China Center for the Physics of Low-Dimensional Materials Henan Joint International Research Laboratory of New Energy Materials and DevicesSchool of Physics and ElectronicsHenan UniversityKaifengthe People's Republic of China Tianjin Key Lab for Rare Earth Materials and Applications Center for Rare Earth and Inorganic Functional MaterialsSmart Sensor Interdisciplinary Science CenterSchool of Materials Science and EngineeringNankai UniversityTianjinthe People's Republic of China

The anomalous Hall effect(AHE)that associated with the Berry curvature of occupied electronic states in momentum-space is one of the intriguing aspects in condensed matter physics,and provides an alternative for potential applications in topological *** experiments reported the tunable Berry curvature and the resulting magnetization switching process in the AHE based on strain engineering or chemical ***,the AHE modulation by these strategies are usually irreversible,making it difficult to realize switchable control of the AHE and the resultant spintronic ***,we demonstrated the switchable control of the Berry-curvature-related AHE by electrical gating in itinerant ferromagnetic Cr_(7)Te_(8)with excellent ambient *** gate-tunable sign reversal of the AHE can be attributed to the redistribution of the Berry curvature in the band structure of Cr_(7)Te_(8)due to the intercalation-induced change in the Fermi *** work facilitates the applications of magnetic switchable devices based on gate-tunable Berry curvature.

关键词： anomalous Hall effect Berry curvature van der Waals itinerant ferromagnetism

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Plasmon-enhanced self-powered GaN/ZnTe core/shell nanopillar array photodetector

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Nano research 2024年第6期17卷 5569-5577页

作者： Jianqi Dong Dongqi Zhang Yi Ma Daotong You Jinping Chen Bin Liu Xingfu Wang Zengliang Shi Chunxiang Xu State Key Laboratory of Digital Medical Engineering School of Biological Science and Medical EngineeringSoutheast UniversityNanjing 210096China Jiangsu Provincial Key Laboratory of Advanced Photonic and Electronic Materials National Laboratory of Solid State MicrostructuresSchool of Electronic Science and EngineeringNanjing UniversityNanjing 210093China Institute of Photonics Technology Jinan UniversityGuangzhou 510632China Guangdong Engineering Research Center of Optoelectronic Functional Materials and Devices Institute of SemiconductorsSouth China Normal UniversityGuangzhou 510631China

Nanostructure photodetectors,as the core component of optoelectronic devices,are mainly focused on the precise preparation of mixed-component nano-heterostructures and the realization of zero power consumption ***,we successfully fabricated n-GaN/p-ZnTe core/shell nanopillar array and realized self-power ultraviolet/violet *** radial heterojunction nanodevice reveals high light-dark current ratio of 104 at 0 V bias,indicating effective carriers’*** more,by integrating plasmonic effect,the responsivity and detectivity of the Au nanoparticles decorated device are increased from 3.85 to 148.83 mA/W and 4.45×1011 to 2.33×1012 Jones under 325 nm UV light *** the rise and the fall time are decreased 1.3 times and 6.8 times under 520 nm visible light irradiation at 0 V *** high photocurrent gain is derived from that the oscillating high-energy hot electrons in Au nanoparticles spontaneously inject into the ZnTe conduction band to involve the photodetection *** work presents an effective route to prepare high-performance self-power photodetector and provides a promising blueprint to realize different functional photoelectronic devices based on core/shell nanostructure.

关键词： GaN/ZnTe core/shell nanopillar array self-power ultraviolet/visible photodetector plasmonic effect

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Volume-complementary bipolar layered oxide enables stable symmetric sodium-ion batteries

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Nano research 2024年第5期17卷 4125-4133页

作者： Bo Peng Feng Wang Nazir Ahmad Lai Yu Shenghua Chen Genqiang Zhang School of Materials Science and Engineering Key Laboratory of Efficient Conversion and Solid-state Storage of Hydrogen and Electricity of Anhui ProvinceAnhui University of TechnologyMa’anshan 243002China Hefei National Research Center for Physical Sciences at the Microscale Chinese Academy of Sciences(CAS)Key Laboratory of Materials for Energy ConversionDepartment of Materials Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China National Innovation Platform(Center)for Industry-Education Integration of Energy Storage Technology School of Chemical Engineering and TechnologyXi’an Jiaotong UniversityXi’an 710049China

The commercialization of sodium-ion batteries is based on developing low-cost,highly stable,and safe cathode and anode ***,the promising hard carbon anode and layered oxide cathode suffer from low sodium-embedded potential near 0.1 V and severe phase transitions,which cause safe problem and short lifespan,***,we design a low-strain bipolar P2-Na_(0.7)Ni_(0.25)Fe_(0.2)Ti_(0.55)O_(2) to solve the mentioned obstacles,whereas(Ni,Fe)and Ti provide charge compensation when it is used as cathode and anode,*** is revealed that the bipolar layered oxide undergoes solid-solution reaction when used as cathode or anode,and exhibits volume-complementary feature in a sodium-ion full-cell,as identified by in-situ X-ray ***,the safe symmetric sodium-ion full-cell exhibits excellent cyclic stability with 91.7%capacity retention after 200 *** work will provide a new horizon for designing safe and stable sodium-ion batteries.

关键词： sodium-ion batteries bipolar layered oxides solid-solution reaction volume complementation symmetric battery

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Extremely fast vortex dynamics in Bi_(2)Sr_(2)Ca_(2)Cu_(3)O_(10+δ) crystalline nanostrip

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Chinese Physics B 2023年第6期32卷 563-568页

作者：于奥博林成天张孝富尤立星 State Key Laboratory of Functional Materials for Informatics Shanghai Institute of Microsystem and Information TechnologyChinese Academy of SciencesShanghai 200050China CAS Center for Excellence in Superconducting Electronics(CENSE) Shanghai 200050China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Max Planck Institute for Solid State Research Heisenbergstrasse 1D-70569 StuttgartGermany

The maximum velocity of a mobile vortex in movement is generally limited by the phenomenon of flux-flow instability(FFI),which necessitates weak vortex pinning and fast heat removal from non-equilibrium *** here demonstrate exfoliations and nano-fabrications of Bi_(2)Sr_(2)Ca_(2)Cu_(3)O_(10+δ) crystalline nanostrips,which possess a rather weak pinning volume of vortices,relatively low resistivity,and large normal electron diffusion *** deduced vortex velocity in Bi_(2)Sr_(2)Ca_(2)Cu_(3)O_(10+δ) crystalline nanostrips can be up to 300 km/s near the superconducting transition temperature,well above the speed of *** observed vortex velocity is an order of magnitude faster than that of conventional superconducting systems,representing a perfect platform for exploration of ultra-fast vortex matter and a good candidate for fabrications of superconducting nanowire single photon detectors or superconducting THz modulator.

关键词： Bi_(2)Sr_(2)Ca_(2)Cu_(3)O_(10+δ)(Bi2223) vortices dynamics ultra thin single crystal nanowire

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