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Dual-photoconductivity in monolayer PtSe_(2) ribbons

Nano Research 2024年第11期17卷 10189-10195页

作者： Zechen Li Honglin Wang Huaipeng Wang Jing Li Fangzhu Qing Xuesong Li Dan Xie Hongwei Zhu State Key Lab of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua University Beijing 100084 China School of Integrated Circuits Beijing National Research Center for Information Science and Technology Tsinghua University Beijing 100084 China State Key Lab of Solid Waste Reuse for Building Materials Beijing Building Materials Academy of Science Research Beijing 100041 China Shenzhen Institute for Advanced Study University of Electronic Science and Technology of China Shenzhen 518110 China

Two-dimensional platinum diselenide (PtSe_(2)) has been explored for applications in visible and infrared photodetectors, owing to its tunable electrical and optoelectronic properties governed by layer-dependent bandgaps. Studies have explored both positive photoconductivity (PPC) and negative photoconductivity (NPC) behaviors in few-layer PtSe_(2) thin films, proposing mechanisms related to gas molecule adsorption. However, these proposed mechanisms, typically based on models with ideal limit structures, often lacked consistency with the structure and scale of polycrystalline thin films employed in actual experiments. Here, photodetectors utilizing monolayer PtSe_(2) ribbons were designed, demonstrating a significant NPC effect upon exposure to visible light in atmospheric conditions, with device resistance increasing to over threefold the initial state. Under vacuum conditions, the device demonstrated PPC characteristics. Density functional theory calculations indicated that oxygen molecules physically adsorbed at the edges of PtSe_(2) ribbons were integral. Laser irradiation prompted the detachment of oxygen molecules from the ribbon’s edges, leading to a decreased carrier concentration in channel conductivity. The abundant edge sites of the ribbons endowed the photodetectors with a pronounced NPC response. This study diverted from traditional multilayer PtSe_(2) films to explore monolayer PtSe_(2) ribbons. These ribbons, as limit structures, offered a more fundamental insight into the intrinsic photoconductivity properties of PtSe_(2). Photodetectors employing PtSe_(2) ribbons presented novel application prospects in low-power photodetection, gas detection, and additional fields.

关键词： platinum diselenide photodetector negative photoconductivity positive photoconductivity photoinduced desorption

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Emerging natural clay-based materials for stable and dendrite-free lithium metal anodes:A review

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Chinese Chemical Letters 2025年第2期36卷 133-144页

作者： Haobo Wang Fei Wang Yong Liu Zhongxiu Liu Yingjie Miao Wanhong Zhang Guangxin Wang Jiangtao Ji Qiaobao Zhang School of Materials Science and Engineering Provincial and Ministerial Co-construction of Collaborative Innovation Center for Non-ferrous Metal new Materials and Advanced Processing TechnologyHenan University of Science and TechnologyLuoyang 471023China Faculty of Engineering Huanghe Science and Technology UniversityZhengzhou 450063China Henan Key Laboratory of Non-Ferrous Materials Science&Processing Technology Henan University of Science and TechnologyLuoyang 471023China College of Agricultural Equipment Engineering Henan University of Science and TechnologyLuoyang 471023China State Key Laboratory of Physical Chemistry of Solid Surfaces College of MaterialsXiamen UniversityXiamen 361005China

Lithium metal is one of the most promising anodes for lithium batteries because of their high theoretical specific capacity and the low electrochemical ***,the commercialization of lithium metal anodes(LMAs)is facing significant obstacles,such as uncontrolled lithium dendrite growth and unstable solid electrolyte interface,leading to inferior Coulombic efficiency,unsatisfactory cycling stability and even serious safety *** low-cost natural clay-based materials(NCBMs)in LMAs is deemed as one of the most effective methods to solve aforementioned *** NCBMs have received considerable attention for stabilizing LMAs due to their unique structure,large specific surface areas,abundant surface groups,high mechanical strength,excellent thermal stability,and environmental *** the rapidly growing research enthusiasm for this topic in the last several years,here,we review the recent progress on the application of NCBMs in stable and dendrite-free *** different structures and modification methods of natural clays are first *** addition,the relationship between their modification methods and nano/microstructures,as well as their impact on the electrochemical properties of LMAs are systematically ***,the current challenges and opportunities for application of NCBMs in stable LMAs are also proposed to facilitate their further development.

关键词： Natural clay-based materials Aolid-state electrolyte Surface modification Li metal anodes Rechargeable batteries

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Transient logic operations in acoustics through dynamic modulation

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Physical Review Applied 2024年第1期21卷 L011001-L011001页

作者： Zhao-xian Chen Ling-ling Ma Shi-jun Ge Ze-Guo Chen Ming-hui Lu Yan-feng Chen Yan-qing Lu College of Engineering and Applied Sciences Collaborative Innovation Center of Advanced Microstructures and National Laboratory of Solid State Microstructures Nanjing University Nanjing 210023 China School of Materials Science and Intelligent Engineering Nanjing University Suzhou 215163 China

In quantum logic operations, information is carried by the wave function rather than the energy distribution. Therefore, the relative phase is essential. Abelian and non-Abelian phases can be emulated in classical waves using passive coupled waveguides with geometric modulation. However, the dynamic phase interference induced by waveguide structure variation is inevitable. To overcome the challenges, we introduce an electroacoustic coupled system that enables the precise control of phase distribution through dynamic modulation of hopping. Such effective hopping is electronically controlled and is utilized to construct various paths in parameter space. These paths lead to state evolution with matrix-valued geometric phases, which correspond to logic operations. We report experimental realizations of several logic operations, including the Y gate, Z gate, Hadamard gate, and non-Abelian braiding. Our work introduces a temporal process to manipulate transient modes in a compact structure, providing a versatile experimental testbed for exploring other logic gates and exotic topological phenomena.

关键词： Acoustic metamaterials Acoustic wave phenomena Geometric & topological phases Transport phenomena Devices for digital logic, storage & processing Waveguide arrays Cavity resonators Sound wave techniques

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Gate Tunable Labyrinth Domain Structures in a van der Waals Itinerant Ferromagnet Cr_(7)Te_(8)

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Chinese Physics Letters 2024年第9期41卷 122-132页

作者： Kui Meng Zeya Li Yicheng Shen Xiangyu Bi Junhao Rao Yuting Qian Zhansheng Gao Peng Chen Caiyu Qiu Feng Qin Jinxiong Wu Feng Luo Junwei Huang Hongtao Yuan National Laboratory of Solid State Microstructures Jiangsu Key Laboratory of Artificial Functional MaterialsCollege of Engineering and Applied Sciencesand Collaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210000China Center for the Physics of Low-Dimensional Materials Henan Joint International Research Laboratory of New Energy Materials and DevicesSchool of Physics and ElectronicsHenan UniversityKaifeng 475004China Tianjin Key Lab for Rare Earth Materials and Applications Center for Rare Earth and Inorganic Functional MaterialsSmart Sensor Interdisciplinary Science CenterSchool of Materials Science and EngineeringNankai UniversityTianjin 300350China

Manipulating magnetic domain structure plays a key role in advanced spintronics *** rationale is that the labyrinthine domain structure,normally appearing in ferromagnetic thin films with strong magnetic anisotropy,shows a great potential to increase data storage density for designing magnetic nonvolatile memory and logic ***,an electrical control of labyrinthine domain structure remains ***,we demonstrate the gate-driven evolution of labyrinthine domain structures in an itinerant ferromagnet Cr_(7)Te_(8).By combining electric transport measurements and micromagnetic finite difference simulations,we find that the hysteresis loop of anomalous Hall effect in Cr_(7)Te_(8)samples shows distinct features corresponding to the generation of labyrinthine domain *** labyrinthine domain structures are found to be electrically tunable via Li-electrolyte gating,and such gate-driven evolution in Cr_(7)Te_(8)originates from the reduction of the magnetic anisotropic energy with gating,revealed by our micromagnetic *** results on the gate control of anomalous Hall effect in an itinerant magnetic material provide an opportunity to understand the formation and evolution of labyrinthine domain structures,paving a new route towards electric-field driven spintronics.

关键词： rational electrolyte ferromagnetic

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Tribological study of two ammonium chloride-decanoic acid deep eutectic solvents(DESs)as high-performance lubricants

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Friction 2024年第11期12卷 2441-2457页

作者： Zhuocheng LI Enhui ZHANG Weimin LI Haichao LIU State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Zibo Innovation Center of High-End Synthetic Lubricating Materials Zibo 255000China

Deep eutectic solvents(DESs)are acknowledged as a novel class of functional *** share similar physical properties with ionic liquids(ILs)and have the potential to be a novel class of *** this study,two DESs,namely tetrabutylammonium chloride-decanoic acid DES(C4-DES)and methyl tricaprylmethylammonium chloride-decanoic acid DES(C8-DES),were synthesized,and their physico-chemical properties and tribological performances were ***-analysis of the rubbing surfaces used multiple techniques to gain insights into the lubrication *** show that the coefficient of friction(COF)and wear were reduced by approximately 29%and 91%for the C4-DES,and 36%and 94%for the C8-DES,compared to an ester base *** friction reduction behavior of the DESs is attributed to the monolayer adsorption of the polar group in the decanoic acid(DEAC),whose effectiveness is affected by the component of the ammonium salts in the DESs and the operating *** addition to the adsorbed film,worn surface analysis revealed that an ultra-thin tribochemical film with a thickness of 3–7 nm was formed on the surfaces lubricated with the *** composition of the film was studied,and the lubrication mechanisms of the two DESs were discussed.

关键词： deep eutectic solvent(DES) lubricants tribological performance boundary lubrication

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Structural superlubricity at homogenous interface of pentagraphene

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Friction 2024年第9期12卷 2004-2017页

作者： Xinqi ZHANG Jiayi FAN Zichun CUI Tengfei CAO Junqin SHI Feng ZHOU Weimin LIU Xiaoli FAN State Key Laboratory of Solidification Processing Center for Advanced Lubrication and Seal MaterialsSchool of Material Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072China School of Material Science and Engineering Northwestern Polytechnical UniversityXi’an 710072China State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China

Two-dimensional(2D)van der Waals layered materials have been widely used as ***-graphene(PG),a 2D carbon allotrope exclusively composed of irregular carbon pentagons has recently been predicted to have superlubricating *** the present study,by combining the molecular dynamics simulation and first-principles calculations,we investigated the frictional property of PG in both commensurate and incommensurate *** calculations show the ultra-low friction at the interface of relatively rotated bilayer PG with twist angles of more than 10°away from the commensurate ***,our calculations demonstrate the isotropy of the ultra-low friction at the interface of incommensurate contact,in contrast to the anisotropic of the commensurate contacting ***,the evolution of friction force and the fluctuation of potential energy along sliding path correlate closely with the interface’s *** energetics and charge density explain the difference between the friction at the interfaces of the commensurate and incommensurate *** only that,we found the correlation between the intrinsic structural feature and interlayer binding ***,our findings on the retainment of the ultra-low friction under work conditions indicates that the superlubricating state of PG has good practical adaptability.

关键词： structural superlubricity penta-graphene molecular dynamics incommensurate contact

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A Review:Pre-lithiation Strategies Based on Cathode Sacrificial Lithium Salts for Lithium-Ion Capacitors

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Energy & Environmental materials 2023年第6期6卷 10-32页

作者： Kailimai Su Yan Wang Bao Yang Xu Zhang Wei Wu Junwei Lang Xingbin Yan Laboratory of Clean Energy Chemistry and Materials State Key Laboratory of Solid LubricationLanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Qingdao Center of Resource Chemistry&New Materials Qingdao 266000China State Key Laboratory of Optoelectronic Materials and Technologies School of Materials Science and EngineeringSun Yat-Sen UniversityGuangzhou 510275China

Similar to lithium-ion batteries(LIBs),during the first charge/discharge process of lithium-ion capacitors(LICs),lithium-intercalated anodes(e.g.,silicon,graphite,and hard carbon)also exhibit irreversible lithium intercalation behaviors,such as the formation of a solid electrolyte interface(SEI),which will consume Li^(+)in the electrolyte and significantly reduce the electrochemical performance of the ***,pre-lithiation is an indispensable procedure for *** present,commercial LICs mostly use lithium metal as the lithium source to compensate for the irreversible capacity loss,which has the demerits of operational complexity and ***,the pre-lithiation strategy based on cathode sacrificial lithium salts(CSLSs)has been proposed,which has the advantages of low cost,simple operation,environmental protection,and ***,there is an urgent need for a timely and comprehensive summary of the application of CSLSs to *** this review,the important roles of pre-lithiation in LICs are detailed,and different pre-lithiation methods are reviewed and compared systematically and *** that,we systematically discuss the pre-lithiation strategies based on CSLSs and mainly introduce the lithium extraction mechanism of CSLSs and the influence of intrinsic characteristics and doping amount of CSLSs on LICs *** addition,a summary and outlook are conducted,aiming to provide the essential basic knowledge and guidance for developing a new pre-lithiation technology.

关键词： cathode sacrificial lithium salts lithium-ion battery capacitors lithium-ion capacitors perspectives pre-lithiation strategies

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Electrolyte engineering and interphase chemistry toward high-performance nickel-rich cathodes:Progress and perspectives

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materials Reports(Energy) 2025年第1期5卷 19-31页

作者： Shangjuan Yang Ke Yang Jinshuo Mi Shaoke Guo Xufei An Hai Su Yanbing He Shenzhen All-Solid-State Lithium Battery Electrolyte Engineering Research Center Institute of Materials Research(IMR)Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen518055China School of Materials Science and Engineering Tsinghua UniversityBeijing100084China

Nickel(Ni)-rich layered oxides have drawn great attention as cathode for lithium batteries due to their high capacity,high working voltage and competitive ***,the operation of Ni-rich cathodes suffers from the notorious structural degradation and interfacial side reactions with electrolytes and thus incurs premature failure,especially at high charge cut-off voltages(≥4.4 V).For this,various structural and interphase regulation strategies(such as coating modification,element doping,and electrolyte engineering)are developed to enhance the cycling survivability of Ni-rich *** them,electrolyte engineering by changing solvation structure and introducing additives has been considered an efficient method for constructing robust cathode-electrolyte interphases(CEI),inhibiting the formation of harmful species(such as HF and H_(2)O)or restraining the dissolution of transition metal ***,there is still an absence of systematic guidelines for selecting and designing competitive electrolyte systems for Ni-rich layered *** this review,we comprehensively summarize the recent research progress on electrolyte engineering for Ni-rich layered cathodes according to their working ***,we propose future perspectives of improving the electrolyte performance,which will provide new insights for designing novel electrolytes toward high-performance Ni-rich layered cathodes.

关键词： Ni-rich cathodes Solvation structure regulation Electrolyte additives Cathode-electrolyte interphase High charging cut-off voltage

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Volume-complementary bipolar layered oxide enables stable symmetric sodium-ion batteries

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Nano Research 2024年第5期17卷 4125-4133页

作者： Bo Peng Feng Wang Nazir Ahmad Lai Yu Shenghua Chen Genqiang Zhang School of Materials Science and Engineering Key Laboratory of Efficient Conversion and Solid-state Storage of Hydrogen and Electricity of Anhui ProvinceAnhui University of TechnologyMa’anshan 243002China Hefei National Research Center for Physical Sciences at the Microscale Chinese Academy of Sciences(CAS)Key Laboratory of Materials for Energy ConversionDepartment of Materials Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China National Innovation Platform(Center)for Industry-Education Integration of Energy Storage Technology School of Chemical Engineering and TechnologyXi’an Jiaotong UniversityXi’an 710049China

The commercialization of sodium-ion batteries is based on developing low-cost,highly stable,and safe cathode and anode ***,the promising hard carbon anode and layered oxide cathode suffer from low sodium-embedded potential near 0.1 V and severe phase transitions,which cause safe problem and short lifespan,***,we design a low-strain bipolar P2-Na_(0.7)Ni_(0.25)Fe_(0.2)Ti_(0.55)O_(2) to solve the mentioned obstacles,whereas(Ni,Fe)and Ti provide charge compensation when it is used as cathode and anode,*** is revealed that the bipolar layered oxide undergoes solid-solution reaction when used as cathode or anode,and exhibits volume-complementary feature in a sodium-ion full-cell,as identified by in-situ X-ray ***,the safe symmetric sodium-ion full-cell exhibits excellent cyclic stability with 91.7%capacity retention after 200 *** work will provide a new horizon for designing safe and stable sodium-ion batteries.

关键词： sodium-ion batteries bipolar layered oxides solid-solution reaction volume complementation symmetric battery

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Thermodynamically controllable synthesis of ZIF-8 exposing different facets and their applications in single atom catalytic oxygen reduction reactions

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Nano Research 2023年第7期16卷 9618-9624页

作者： Runze Ma Qiheng Li Jun Yan Yu Tao Shouyao Hu Donghao Liu Jiaxin Gong Yu Xiong College of Chemistry and Chemical Engineering Central South UniversityChangsha 410083China Beijing Advanced Innovation Center for Materials Genome Engineering Institute of Solid State ChemistryUniversity of Science and Technology BeijingBeijing 100083China

The development of thermodynamically controllable synthetic strategy to manipulate the morphology of ZIF-8 without capping agent is essential to help understanding their facet effect and the structure-activity relationship of single atom catalysts derived from ***,we prepared ZIF-8 with different morphologies(cube,truncated rhombododecahedral and rhombododecahedral)and thus area ratio of exposed{100},{110}facets by a thermodynamically controllable synthetic *** the reaction proceeds under room temperature(30℃),the assembling of ZIF-8 followed an area-reducing layered growth mode,while switched to an integral layered growth mode at lower temperature-40℃.Moreover,this strategy also works to obtain ZIF-8 encapsulated with metal precursors(Fe(acac)_(3),Cu(acac)_(2)and Co(acac)_(2)).Single Fe atom anchored on nitrogen doped carbon catalysts(SA-Fe/CN)derived from Fe-ZIF-8 retain their original morphologies and the unsaturated surface-active sites on{100}facet,which further displays different catalytic performance towards oxygen reduction reaction(ORR).This work not only reveals the different growth pattern of ZIF-8,but also points out a new direction for designing and synthesizing MOFs with different morphology rationally.

关键词： ZIF-8 facet effect single atom catalyst oxygen reduction reaction

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