The robustness of recent Large Language Models (LLMs) has become increasingly crucial as their applicability expands across various domains and real-world applications. Retrieval-Augmented Generation (RAG) is a promis...
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Retrieval-Augmented Large Language Models (LLMs), which incorporate the non-parametric knowledge from external knowledge bases into LLMs, have emerged as a promising approach to enhancing response accuracy in several ...
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Li-rich Mn-based materials provide higher capacity than commercial NCM layered materials due to the synergistic redox effect of cations and anions. However, lattice straining and structural collapse caused by the irre...
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Li-rich Mn-based materials provide higher capacity than commercial NCM layered materials due to the synergistic redox effect of cations and anions. However, lattice straining and structural collapse caused by the irreversible oxygen release at high voltage range during cycling, which results in severe capacity and voltage decay. Herein, a synergistic strategy of surface-induced spinel structure and F doping is provided to improve the structural stability. The surface spinel structure helps to reduce the structural collapse caused by electrolyte corrosion on the cathode and effectively inhibits voltage decay resulted from structural evolution. The stronger Mn-F bonds are formed by F doping to inhibit migration of transition metal(TM) and induce the uniform deposition of Li F to form the thinner and more stable CEI on the cathode. Accordingly, the designed cathode(LMNO-NF) shows remarkable cycling performance with the capacity retention of 86.68 % and voltage retention of 96.6 % for 200 cycles at 1C,higher than pristine material(68.76 % and 85.75 %). Therefore, this simple dual-modification strategy of one-step synthesis is promising for solving the structural evolution and voltage decay of Li-rich Mn-based cathode materials effectively, achieving further commercialization.
Anomalous thermal expansion,or other words,negative thermal expansion(NTE),resulting from the lattice contraction upon temperature increasing,has been an enduring topic for material science and *** variation of a latt...
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Anomalous thermal expansion,or other words,negative thermal expansion(NTE),resulting from the lattice contraction upon temperature increasing,has been an enduring topic for material science and *** variation of a lattice go with the temperature is straightly originated from its electronic structures and is inseparable from those physical *** the past several decades,many efforts have been made to searching new series of NTE compounds or control the thermal expansion performance in order to supply various demands of different extreme *** development of new NTE systems also dependences on the theoretical ***,we carried out theoretical calculation on CrB_(2) and FeZr_(2) with anisotropic negative thermal ***,theoretical calculations reveal that the binding of either Cr-Cr pair or Fe-Fe pair is relatively *** results reveal that the origin of NTE is the ordered magnetic state during the increasing of *** localized electrons would prevent the lattice parameters increase with heating,which shows macroscopic NTE phenomenon.
In this work,the microstructure evolution and mechanical behavior of extruded SiC/ZA63 Mg matrix composites are investigated via combined experimental study and three-dimensionalfinite element modelling(3D FEM)based on...
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In this work,the microstructure evolution and mechanical behavior of extruded SiC/ZA63 Mg matrix composites are investigated via combined experimental study and three-dimensionalfinite element modelling(3D FEM)based on the actual 3D microstructure achieved by synchrotron *** results show that the average grain size of composite increases from 0.57μm of 8μm-SiC/ZA63 to 8.73μm of 50μm-SiC/*** type of texture transforms from the typicalfiber texture in 8μm-SiC/ZA63 to intense basal texture in 50μm-SiC/ZA63 composite and the intensity of texture increases sharply with increase of SiC particle *** dynamic recrystallization(DRX)mechanism is also changed with increasing SiC particle *** and simulation results verify that the strength and elongation both decrease with increase of SiC particle *** 8μm-SiC/ZA63 composite possesses the optimal mechanical property with yield strength(YS)of 383 MPa,ultimate tensile strength(UTS)of 424 MPa and elongation of 6.3%.The outstanding mechanical property is attributed to the ultrafine grain size,high-density precipitates and dislocation,good loading transfer effect and the interface bonding between SiC and matrix,as well as the weakened basal *** simulation results reveal that the micro-cracks tend to initiate at the interface between SiC and matrix,and then propagate along the interface between particle and Mg matrix or at the high strain and stress regions,and further connect with other *** main fracture mechanism in 8μm-SiC/ZA63 composite is ductile damage of matrix and interfacial *** the increase of particle size,interface strength and particle strength decrease,and interface debonding and particle rupture become the main fracture mechanism in the 30μm-and 50μm-SiC/ZA63 composites.
The as-extruded Mg-3Nd-0.2Zn-0.4Zr-xAg(x=0,0.2,0.5,1 wt%)alloys were prepared for biomedical *** electron microscope,electron backscattered diffraction,X-ray diffraction,tensile test machine,electrochemical workstatio...
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The as-extruded Mg-3Nd-0.2Zn-0.4Zr-xAg(x=0,0.2,0.5,1 wt%)alloys were prepared for biomedical *** electron microscope,electron backscattered diffraction,X-ray diffraction,tensile test machine,electrochemical workstation,and immersion experiments were used to study microstructures,mechanical properties,and corrosion behavior of the as-extruded *** results indicate that the microstructures of all the as-extruded alloys are composed of coarse undynamic recrystallized grains,fine equiaxed recrystallized grains,and precipitated *** element plays a positive role in promoting dynamic recrystallization and grain *** during the extrusion,all the four alloys generate a <1010>//ED fiber *** the increase of Ag element,the volume fraction of Mg_(12)Nd phase increases and then decreases *** increasing Ag addition,both yield strength and ultimate tensile strength of the as-extruded alloys reduce first and then improve,and the elongation improves gradually from 9.4 to 12.7%.More importantly,the addition of Ag accelerates corrosion of the as-extruded alloys in simulated body fluid,and all the as-extruded alloys show uniform corrosion mode.
Magnesium(Mg)alloys have been widely used in automobile,aviation,computer,and other fields due to their lightweight,high specific strength and stiffness,low pollution,and good electromagnetic shielding ***,the chemica...
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Magnesium(Mg)alloys have been widely used in automobile,aviation,computer,and other fields due to their lightweight,high specific strength and stiffness,low pollution,and good electromagnetic shielding ***,the chemical stability of Mg alloys is poor,especially in the corrosive medium environment with high stress corrosion sensitivity,which causes sudden damage to structural components and restricts their application *** recent years,owing to the increasing failure rate of engineering structures caused by stress corrosion of Mg alloys,it has become necessary to understand and pay more attention to the stress corrosion cracking(SCC)behavior of Mg *** this paper,the SCC mechanisms and test methods of Mg alloys have been *** recent research progress on SCC of Mg alloys has been reviewed from the aspects of alloying,preparation process,surface modification,corrosive medium,and strain *** importantly,future research trends in the field of SCC of Mg alloys have also been proposed.
Natrium superionic conductor(NASICON)-type phosphates have aroused a great interest as cathode materials for sodium-ion batteries(SIBs)by virtue of their stable 3-dimensional frameworks,flexible molecular formula tuna...
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Natrium superionic conductor(NASICON)-type phosphates have aroused a great interest as cathode materials for sodium-ion batteries(SIBs)by virtue of their stable 3-dimensional frameworks,flexible molecular formula tunability,and superior ionic ***,the intrinsic low electronic conductivity and relatively low theoretical specific capacity place obstacles in their way toward achieving higher electrochemical *** addition,only 2-electron reactions in most NASICON cathodes and poor reversibility of high-voltage redox couples severely limit their energy *** address the above tough issues,an in-depth understanding of transition metal selection,elements ratio optimization,and Na-storage mechanism is of paramount ***,this mini review summarizes the latest progresses on the NASICON-type phosphate cathodes for SIBs from the perspective of redox couple *** cathodes featuring high operating voltage and multielectron reactions are discussed in ***,the remaining challenges and personal outlooks based on redox couple regulation are put forward,shedding light on the designing rules for high-energy and long-durability NASICON-type phosphate cathodes for SIBs in the future.
Spectral bandpass filters serving as crucial signal processing components are widely applied in various electromagnetic/optical ***,the filtering of reflection signal always faces problems of notably accompanied trans...
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Spectral bandpass filters serving as crucial signal processing components are widely applied in various electromagnetic/optical ***,the filtering of reflection signal always faces problems of notably accompanied transmission or strict angular ***,we propose novel transmissionless metagratings for specular-reflection bandpass filtering under wide oblique incidence *** metagratings are composed of metallic groove gratings and high-refractive-index dielectric particles,which of them respectively provide continuum of localized cavity mode and discrete magnetic dipole resonance under oblique transverse magnetic waves,and produce broadband and narrowband anomalous *** destructive interference gives rise to a Fano-type narrow bandpass filter in the specular *** integrating CaTiO3ceramic particles with metallic groove gratings,we experimentally demonstrate a single-bandpass metagrating filter at microwave frequency which exhibits a low insertion loss and narrow bandwidth under wide-angle oblique incidence,and agrees with simulations ***,by arranging two different sized CaTiO3ceramic particles or changing the temperature,the metagrating filter is endowed with dual-bandpass or thermally tunable feature,***,the design is extended to terahertz frequencies by improving the structure to a double-groove *** proposed composite metagratings with novel bandpass filtering function and angular insensitivity not only enrich the category of spatial filter but have promising applications in microwave communication systems and optical devices.
Recently,the biologically inspired intelligent artificial visual neural system has aroused enormous ***,there are still significant obstacles in pursuing large-scale parallel and efficient visual memory and *** this s...
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Recently,the biologically inspired intelligent artificial visual neural system has aroused enormous ***,there are still significant obstacles in pursuing large-scale parallel and efficient visual memory and *** this study,we demonstrate a 28×28 synaptic devices array for the artificial visual neuromorphic system,within the size of 0.7×0.7 cm 2,which integrates sensing,memory,and processing *** highly uniform floating-gate synaptic transistors array were constructed by the wafer-scale grown monolayer molybdenum disulfide with Au nanoparticles(NPs)acting as the electrons capture *** synaptic plasticity behaviors have been achieved owing to the switchable electronic storage *** excellent optical/electrical coordination capabilities were implemented by paralleled processing both the optical and electrical signals the synaptic array of 784 devices,enabling to realize the badges and letters writing and erasing ***,the established artificial visual convolutional neural network(CNN)through optical/electrical signal modulation can reach the high digit recognition accuracy of 96.5%.Therefore,our results provide a feasible route for future large-scale integrated artificial visual neuromorphic system.
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