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Self-healing of active site in Co(OH)_(2)/MXene electrocatalysts for hydrazine oxidation

Journal of Materials science & technology 2024年第36期203卷 108-117页

作者： Kun Xiang Yongjing Wang Zechao Zhuang Jing Zou Neng Li Dingsheng Wang Tianyou Zhai Jizhou Jiang School of Environmental Ecology and Biological Engineering School of Chemistry and Environmental EngineeringKey Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationNovel Catalytic Materials of Hubei Engineering Research CenterWuhan Institute of TechnologyWuhan 430205China Department of Chemistry Tsinghua UniversityBeijing 100084China State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Material Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

The development of efficient hydrazine oxidation reaction(HzOR)catalysts is important for the construc-tion of remarkable energy storage and conversion ***,after a period of electrochemical reaction,the active site of the catalyst will be irreversibly reduced or inactivated,and how to recover the active site is a major ***,we report 2D Co(OH)_(2)/Ti_(3)C_(2)(OH)_(x)MXene composites with rapid re-construction and self-healing behaviors as efficient and stable electrocatalysts during HzOR *** experimental and theoretical results indicate that the introduction of Ti_(3)C_(2)(OH)_(x)MXene can effectively reduce the dehydrogenation barrier of Co(OH)_(2),from 0.584 eV to 0.481 eV to form the real catalytic active center Co(OH)***,Co(OH)O/Ti_(3)C_(2)(OH)_(x)MXene composites with metal-like conductiv-ity not only present spontaneous adsorption capacity of N_(2)H_(4),but also can modulated rate-determining step of dehydrogenation of∗N_(2)H_(4)to∗N_(2)H_(3)(0.54 eV)compared with Co(OH)***,the electrophilic oxygen of Co(OH)O/Ti_(3)C_(2)(OH)_(x)can spontaneously obtain electrons and protons from N_(2)H_(4),achieving the oxidation of N_(2)H_(4)while reducing Co(OH)O to Co(OH)_(2),thus completing the self-healing of the efficient catalyst.

关键词： Hydrazine oxidation Self-healing Reconstruction Co(OH)_(2)/MXene Electrocatalysis

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Rapid and real-time analysis of multi-component dissolved gas in seawater by Raman spectroscopy combined with continuous gas-liquid separator

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Chinese Journal of Chemical engineering 2024年第9期73卷 146-153页

作者： Dewang Yang Wenhua Li Lei Guo Yuhang Ji Yanzhe Gong Junwei Chu Libin Du Yongmei Wang College of Ocean Science and Engineering Shandong University of Science and TechnologyQingdao 266590China Xi'an Institute of Applied Optics Xi'an 710065China College of Safety and Environmental Engineering Shandong University of Science and TechnologyQingdao 266590China State Key Laboratory of Mining Disaster Prevention and Control Co-founded by Shandong Province and the Ministry of Science and Technology Shandong University of Science and TechnologyQingdao 266590China

Rapid and sensitive detection of dissolved gases in seawater is quite essential for the investigation of the global carbon *** quantities of in situ optical detection techniques showed restricted measurement efficiency,owing to the single gas sensor without the identification ability of multiple *** this work,a novel gas-liquid Raman detection method of monitoring the multi-component dissolved gases was proposed based on a continuous gas-liquid separator under a large difference of partial *** limit of detection(LOD)of the gas Raman spectrometer could arrive at about 14 μl·L^(-1)for N_(2)***,based on the continuous gas-liquid separation process,the detection time of the dissolved gases could be largely decreased to about 200 s compared with that of the traditional detection method(30 min).Effect of equilibrium time on gas-liquid separation process indicated that the extracted efficiency and decay time of these dissolved gases was CO_(2)>O_(2)>N_(2).In addition,the analysis of the relationship between equilibrium time and flow speed indicated that the decay time decreased with the increase of the flow *** validation and application of the developed system presented its great potential for studying the components and spatiotemporal distribution of dissolved gases in seawater.

关键词： Dissolved gas Rapid quantitative analysis Gas-liquid separator Gas-liquid Raman spectroscopy

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Numerical insight into heat transfer enhancement by granules inner-migration in a moving bed:A performance comparison between slanted-stick and plow-shaped agitator

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Particuology 2024年第6期89卷 109-116页

作者： Binfan Jiang Hao Pei Dehong Xia Haiyang Wang School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China Shunde Graduate School of University of Science and Technology Beijing Guangdong 528399China Jianlong Group&USTB Joint Laboratory Beijing 100083China

Waste heat recovery of high-temperature granules is one of the most promising sustainable energy supply and carbon reduction ways for industry.A moving bed indirect heat exchanger(MBIHE)with inner-migration was proposed for granular heat *** migration and the enhanced heat transfer induced by two types of agitators(i.e.,agitator with slanted stick A_(s)and with plow-shaped surface A_(p))in the MBIHE are analyzed based on DEM coupled with *** to the effective agitation,the average heat transfer coefficient in the granule side is enhanced to∼3 times compared to that without *** heat recovery efficiency in the moving bed reached more than 70%with the agitations of either A_(s)or A_(p).The heat efficiency of A_(s)is∼7%higher than that of A_(p),but with at least 60%greater rotational *** ensure reliable agitation,the A_(p)is suggested to be adopted in the MBIHE to induce granule migration.

关键词： Waste heat recovery High-temperature granule Granule migration Heat transfer enhancement Industry energy saving

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Controllable CPL response driven by achiral UV-photosensitive dichroic dye through cholesteric liquid crystals

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science China Chemistry 2024年第4期67卷 1250-1255页

作者： Yihan Chen Yang Li Hang Li Lulu Li Yiwu Quan Yixiang Cheng State Key Laboratory of Analytical Chemistry for Life Science School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China Key Laboratory of High-Performance Polymer Material and Technology of Ministry of Education School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China

Versatile stimuli-responsive circularly polarized luminescent(CPL)materials have potential applications in information storage,security encryption,and intelligent *** this study,the Z/E isomerization of ultraviolet(UV)-photosensitive achiralα-cyanostilbene derivative was used as an achiral dichroic dye(Switch)to drive the controllable CPL-active response in cholesteric liquid crystals(CLCs).Under irradiation by 365 nm UV light,the resulting CLCs-Z-Switch underwent a Z-to-E configuration isomerization as CLCs-E-Switch,accompanied by a decrease in its dichroic order parameter(SFvalue)from 0.15to *** the quantum yield(QY)of CLCs-E-Switch increased from 8.1%(CLCs-Z-Switch)to 16.8%,the corresponding glumvalues of CPL emission decreased from+0.55/-0.57 to+0.37/-0.39 due to a decrease in the order of helical arrangement of E-Switch in E7 *** study enables photosensitive CLCs-Switch to be applied for optical information storage devices.

关键词： circularly polarized luminescent photosensitive dichroic dye cholesteric liquid crystals chiral induction

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In Situ Coupling of Reduction and Oxidation Processes with Alternating Current-Driven Bioelectrodes for Efficient Mineralization of Refractory Pollutants

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engineering 2024年第12期43卷 125-138页

作者： Ye Yuan Junjie Zhang Wanxin Yin Lulu Zhang Lin Li Tianming Chen Cheng Ding Wenzong Liu Aijie Wang Fan Chen School of Environmental Science and Engineering Yancheng Institute of TechnologyYancheng 224051China School of Ecology and Environment Northwestern Polytechnical UniversityXi’an 710129China State Key Laboratory of Urban Water Resource and Environment School of Civil and Environmental EngineeringHarbin Institute of Technology ShenzhenShenzhen 518055China

The effective elimination of aromatic compounds from wastewater is imperative for safeguarding the ecological *** processes that combine cathodic reduction and anodic oxidation represent a promising approach for the biomineralization of aromatic ***,conventional direct current bioelectrochemical methods have intrinsic *** this study,a low-frequency and low-voltage alternating current(LFV-AC)-driven bioelectrode offering periodic in situ coupling of reduction and oxidation processes was developed for the biomineralization of aromatic compounds,as exemplified by the degradation of alizarin yellow R(AYR).LFV-AC stimulated biofilm demonstrated efficient bidirectional electron transfer and oxidation–reduction bifunctionality,considerably boosting AYR reduction(63.07%±1.91%)and subsequent mineralization of intermediate products(98.63%±0.37%).LFV-AC stimulation facilitated the assembly of a collaborative microbiome dedicated to AYR metabolism,characterized by an increased abundance of functional consortia proficient in azo dye reduction(Stenotrophomonas and Bradyrhizobium),aromatic intermediate oxidation(Sphingopyxis and Sphingomonas),and electron transfer(Geobacter and Pseudomonas).The collaborative microbiome demonstrated a notable enrichment of functional genes encoding azo-and nitro-reductases,catechol oxygenases,and redox mediator *** findings highlight the effectiveness of LFV-AC stimulation in boosting azo dye biomineralization,offering a novel and sustainable approach for the efficient removal of refractory organic pollutants from wastewater.

关键词： Alternating current Bioelectrode Redox process Bio-mineralization Electrode microbiome Refractory organic pollutants

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Synergistic surface restructuring and cation mixing via ultrafast Joule heating enhancing ultrahigh-nickel cathodes for advanced lithium-ion batteries

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Journal of Energy Chemistry 2025年第4期103卷 371-382页

作者： Haoyu Wang Jinyang Dong Meng Wang Yun Lu Hongyun Zhang Jinzhong Liu Yun Liu Na Liu Ning Li Qing Huang Feng Wu Yuefeng Su Lai Chen School of Materials Science and Engineering Beijing Key Laboratory of Environmental Science and EngineeringBeijing Institute of TechnologyBeijing 100081China Chongqing Innovation Center Beijing Institute of TechnologyChongqing 401120China Testing Centre of Power Batteries China North Vehicle Research InstituteBeijing 100072China

The implementation of ultrahigh-Ni cathodes in high-energy lithium-ion batteries(LIBs)is constrained by significant structural and interfacial degradation during *** this study,doping-induced surface restructuring in ultrahigh-nickel cathode materials is rapidly facilitated through an ultrafast Joule heating *** functional theory(DFT)calculations,synchrotron X-ray absorption spectroscopy(XAS),and single-particle force test confirmed the establishment of a stable crystal framework and lattice oxygen,which mitigated H2-H3 phase transitions and improved structural ***,the Sc doping process exhibits a pinning effect on the grain boundaries,as shown by scanning transmission electron microscopy(STEM),enhancing Li~+diffusion kinetics and decreasing mechanical strain during *** in situ development of a cation-mixing layer at grain boundaries also creates a robust cathode/electrolyte interphase,effectively reducing interfacial parasitic reactions and transition metal dissolution,as validated by STEM and time-of-flight secondary ion mass spectrometry(TOF-SIMS).These synergistic modifications reduce particle cracking and surface/interface degradation,leading to enhanced rate capability,structural integrity,and thermal ***,the optimized Sc-modified ultrahigh-Ni cathode(Sc-1)exhibits 93.99%capacity retention after 100 cycles at 1 C(25℃)and87.06%capacity retention after 100 cycles at 1 C(50℃),indicating excellent cycling and thermal *** presenting a one-step multifunctional modification approach,this research delivers an extensive analysis of the mechanisms governing the structure,microstructure,and interface properties of nickel-rich layered cathode materials(NCMs).These results underscore the potential of ultrahigh-Ni cathodes as viable candidates for advanced lithium-ion batteries(LIBs)in next-generation electric vehicles(EVs).

关键词： Lithium-ion batteries Ultrahigh-nickel layered cathodes In situ surface doping Cation mixing layer Structure and thermal stability

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Selenium-modified activated coke: a high-capacity and facile designed Hg0 adsorbent for coal-fired flue gas

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environmental science and Pollution Research 2024年第20期31卷 29656-29668页

作者： Zheng, Yang Zhang, Lin Wang, Xiaocong Guo, Fenghui Xing, Yi Li, Guoliang Yue, Tao School of Energy and Environmental Engineering University of Science and Technology Beijing Beijing100083 China State Key Laboratory of Advanced Metallurgy University of Science and Technology Beijing Beijing100083 China

The substantial amount of mercury emissions from coal-fired flue gas causes severe environmental contamination. With the Minamata Convention now officially in force, it is critical to strengthen mercury pollution control. Existing activated carbon injection technologies suffer from poor desulfurization performance and risk secondary-release risks. Therefore, considering the potential industrial application of adsorbents, we selected cost-effective and readily available activated coke (AC) as the carrier in this study. Four metal selenides—copper, iron, manganese, and tin—were loaded onto the AC to overcome the application problems of existing technologies. After 120 min of adsorption, the CuSe/AC exhibited the highest efficiency in removing Hg0, surpassing 80% according to the experimental findings. In addition, the optimal adsorption temperature window was 30–120 °C, the maximum adsorption rate was 2.9 × 10−2 mg·g−1·h−1, and the effectiveness of CuSe/AC in capturing Hg0 only dropped by 5.2% in the sulfur-containing atmosphere. The physicochemical characterization results indicated that the AC surface had a uniform loading of CuSe with a nanosheet structure resembling polygon and that the Cu-to-Se atomic ratio was close to 1:1. Finally, two possible Hg0 reaction pathways on CuSe/AC were proposed. Moreover, it was elucidated that the highly selective binding of Hg0 with ligand-unsaturated Se− was the key factor in achieving high adsorption efficiency and sulfur resistance in the selenium-functionalized AC adsorbent. This finding offers substantial theoretical support for the industrial application of this adsorbent. Graphical Abstract: (Figure presented.) © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

关键词： Mercury compounds

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Spatial and Temporal Distribution of Metal Elements in the Rivers of Northern Jiangsu Province

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Journal of Ocean University of China 2025年第1期24卷 157-168页

作者： YUAN Liping LIU Qian JIAN Huimin MI Tiezhu YANG Fuxia YAO Qingzhen Frontiers Science Center for Deep Ocean Multispheres and Earth System and Key Laboratory of Marine Chemistry Theory and TechnologyMinistry of EducationOcean University of ChinaQingdao 266100China Laboratory of Marine Ecology and Environmental Science Qingdao National Laboratory for Marine Science and TechnologyQingdao 266071China College of Environmental Science and Engineering Ocean University of ChinaQingdao 266100China Key Laboratory of Land and Sea Ecological Governance and Systematic Regulation of the Ministry of Ecology and Environment Shandong Academy for Environmental PlanningJinan 250101China

The concentrations of V,Cr,Mn,Fe,Co,Ni,Cu,Zn,As,Mo,Cd,and Pb were determined in Doulonggang River,Xinyanggang River,Huangshagang River,Sheyanghe River,Guangaizongqu River,and Linhonghe River at the North of Jiangsu Province in *** annual average concentrations of V,Cr,Mn,Fe,Co,Ni,Cu,Zn,As,Mo,Cd and Pb in the six rivers were 2.20,1.22,4.53,21.9,0.13,2.79,1.77,4.00,2.97,3.87,0.01,0.19μg L^(-1)*** highest concentration of most trace metals were found in Guangaizongqu River and Linhonghe River,and the lowest concentration were found in Xinyanggang River and Huangshagang *** principal component analysis(PCA)resulted of two factors together explained 91.2%of the variance with>1initial eigenvalue,indicating that both natural and anthropogenic activities were contributing factors as the source of metal abundance in rivers of northern Jiangsu *** first major component represented the influence of anthropogenic activities,including industry and agriculture,with a contribution rate of 54.1%,affected Cr,Fe,Cu,Zn,Mo,Cd and *** second(such as V,Mn,Co,Ni,As)was a mixed source,including the natural processes such as precipitation,erosion and weathering and anthropogenic action like industry and agriculture,with a contribution rate of 37.1%.Seasonal variations in trace metal concentrations were influenced by temperature,salinity,water discharge,and input of external *** highest concentrations were found in wet season and were strongly influenced by rainfall and seasonal industrial and agricultural activities.

关键词： trace metal distribution rivers northern Jiangsu Province

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Atomically precise M-N-C electrocatalysts for oxygen reduction:Effects of inter-site distance,metal-metal interaction,coordination environment,and spin states

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Journal of Energy Chemistry 2025年第2期101卷 132-155,I0004页

作者： Junfeng Huang Saira Ajmal Anuj Kumar Jianwen Guo Mohammed Mujahid Alam Abdullah G.Al-Sehemi Ghulam Yasin School of Mechanical Engineering Dongguan University of TechnologyDongguan 523808GuangdongChina Nano-Technology Research Laboratory Department of ChemistryGLA UniversityMathuraUttar Pradesh 281406India Department of Chemistry College of ScienceKing Khalid UniversityAbha 61413Saudi Arabia School of Environmental Science and Engineering Tianjin UniversityTianjin 300350China State Key Laboratory of Chemical Resource Engineering College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China

Inspired by molecular catalysts,researchers developed atomically precise nitrogen-coordinated single or dual metal sites imbedded in graphitized carbon(M-N-C)to fully utilize metallic sites for *** catalysts performed remarkably well in the electrocatalytic oxygen reduction reaction(ORR)due to their distinct coordination and electrical structures,Nonetheless,their maximum efficacy in practical applications has yet to be *** agenda identifies tailoring the coordination environment,spin states,intersite distance,and metal-metal interaction as innovative approaches to regulate the ORR performance of these ***,it is necessary to undertake a precise assessment of these methodologies and the knowledge obtained to be implemented in the design of future M-N-C catalysts for ***,this review aims to analyze recent progress in M-N-C ORR catalysts,emphasizing their innovative engineering with aspects such as alteration in intersite distance,metal-metal interaction,coordination environment,and spin ***,we critically discuss how to logically monitor the atomic structure,local coordination,spin,and electronic states of M-N-C catalysts to modulate their ORR *** have also highlighted the challenges associated with M-N-C catalysts and proposed suggestions for their future design and fabrication.

关键词： Electrocatalysis M-N-C electrocatalysts ORR Activity descriptors Spin states

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Adaptive Threshold Real-Time Condition Monitoring and Assessment of Unmanned Aircraft Actuator Based on Two-Stage Observer

Adaptive Threshold Real-Time Condition Monitoring and Assess...

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International Conference on Guidance, Navigation and Control, ICGNC 2022

作者： Liu, Xue Han, Hongwei Ma, Jian Wu, Xinman Zhang, Yan Institute of Reliability Engineering Beihang University Beijing100191 China Science and Technology Laboratory on Reliability and Environmental Engineering Beihang University Beijing100191 China School of Reliability and System Engineering Beihang University Beijing100191 China Beijing Institute of Computing Technology Beijing100086 China

ISBN: (纸本)9789811966125

With the wide applications of unmanned aircraft, the flight safety of unmanned aircraft has attracted the attention of many scholars. The actuator controls the flight direction and attitude, and its actuating performance affects the whole unmanned aircraft. Real-time dynamic monitoring of actuator operation status is critical to unmanned aircraft flight safety. However, the existing fixed-threshold-based monitoring methods do not pay enough attention to the unmanned aircraft flight environment and operating conditions, resulting in false alarms or insufficient accuracy. This paper proposed a condition monitoring and quantitative assessment method of unmanned aircraft actuator based on radial basis function two-stage observer. We constructed the fault detection observer by fitting the relationship between the command signal and the position signal of the actuator, and the adaptive threshold observer is constructed by the command signal, output position, and standard threshold. The residuals between position signal and observer output represent the state of the actuator, and the dynamic threshold can reduce the interference of operational conditions in monitoring assessment results. Finally, we monitored the actuator performance of an unmanned aircraft during flight based on the proposed method. The results showed that the method accurately monitored and assessed the actuator under different flight conditions. © 2023, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.

关键词： Actuators

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