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Performance of a polymerization-based electrochemically assisted persulfate process on a real coking wastewater treatment

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Journal of environmental sciences 2024年第12期146卷 149-162页

作者： Suiqin Yang Yuhong Cui Zhengqian Liu Chao Peng Shiquan Sun Jingjing Yang Mingkui Wang Wuhan National Laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan 430074China School of Environmental Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China Eawag Swiss Federal Institute of Aquatic Science and TechnologyÜberlandstrasse 133Dübendorf CH-8600Switzerland School of Hydraulic Engineering Changsha University of Science&TechnologyChangsha 410114China Center for Separation and Purification Materials&Technologies Suzhou University of Science and TechnologySuzhou 215009China

Industrial wastewater should be treated with caution due to its potential environmental *** this study,a polymerization-based cathode/Fe^(3+)/peroxydisulfate(PDS)process was employed for the first time to treat a raw coking wastewater,which can achieve simulta-neous organics abatement and recovery by converting organic contaminants into separable solid *** results confirm that several dominant organic contaminants in coking wastewater such as phenol,cresols,quinoline and indole can be induced to poly-merize by self-coupling or *** total chemical oxygen demand(COD)abate-ment from coking wastewater is 46.8%and the separable organic-polymer formed from or-ganic contaminants accounts for 62.8%of the abated *** organic carbon(DOC)abatement of 41.9%is achieved with about 89%less PDS consumption than conventional degradation-based *** conditions such as PDS concentration,Fe3+concen-tration and current density can affect the COD/DOC abatement and organic-polymer yield by regulating the generation of reactive ***-MS result shows that some organic-polymers are substituted by inorganic ions such as Cl^(-),Br^(-),I^(-),NH_(4)^(+),SCN^(-)and CN^(-),suggest-ing that these inorganic ionsmay be involved in the *** specific consump-tion of this coking wastewater treatment is 27 kWh/kg COD and 95 kWh/kg *** values are much lower than those of the degradation-based processes in treating the same coking wastewater,and also are lower than those of most processes previously reported for coking wastewater treatment.

关键词： Polymerization Coking wastewater Organics recovery Advanced oxidation process Water treatment

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Mn-MOF derived manganese sulfide as peroxymonosulfate activator for levofloxacin degradation: An electron-transfer dominated and radical/nonradical coupling process

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Journal of environmental sciences 2023年第8期130卷 197-211页

作者： Xiaolin Han Wei Zhang Shuai Li Congyu Cheng Qi Yu Qilong Jia Lei Zhou Guangli Xiu State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process School of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai 200237China Shanghai Environmental Protection Key Laboratory on Environmental Standard and Risk Management of Chemical Pollutants East China University of Science and TechnologyShanghai 200237China Shanghai Institute of Pollution Control and Ecological Security Tongji UniversityShanghai 200092China

Recently,transitionmetal sulfides have attractedmuch attention due to their better catalytic capacities as peroxymonosulfate(PMS)activator than their metal oxide ***,the systematic studies on PMS activation using transition metal sulfides are still *** this work,manganese sulfide(MnS)materials were synthesized via a MOFs-derived method and utilized for PMS activation to degrade levofloxacin(LVF)in water for the first *** expected,MnS exhibited remarkable LVF degradation efficiency by PMS activation,whichwas distinctly higher than Mn_(2)O_(3).The results of quenching experiments,electro spin resonance identification and electrochemical tests indicated that electron-transfer progress was the dominant mechanism inα-MnS/PMS ***,the presence of ^(1)O_(2) and radicals further became the removal of LVF byα-MnS/PMS system into a radical/nonradical coupling *** superior electrical conductivity ofα-MnS thanα-Mn_(2)O_(3) was revealed by DFT calculations,which resulted in the higher catalytic capacity ofα-*** result of XPS also indicated the S species in MnS accelerated the recycle of Mn(IV)/Mn(II)and then promoted the generation of ***,the influence of various environmental conditions on LVF removal and the reusability ofα-MnS were also investigated,which demonstrated the high application potential ofα-MnS/PMS ***,six possible pathways of LVF oxidation in the system were proposed based on the identified byproducts and their ecotoxicity was evaluated with ECOSAR *** work promotes the fundamental understanding of PMS activation byα-MnS and provides useful information for practical application of manganese sulfide in water treatment.

关键词： MnS Metal organic frameworks PMS Levofloxacin Electron-transfer pathway

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Temperature-controlled fabrication of hydrophilic manganese oxide microspheres as high-performance electrode materials for supercapacitors

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Chinese Chemical Letters 2023年第5期34卷 516-520页

作者： Yuchen Wang Yaoyu Liu Ahsan Ejaz Kai Yan Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology School of Environmental Science and EngineeringSun Yat-sen UniversityGuangzhou 510275China Department of Civil Engineering Mirpur University of Science and TechnologyAJKMirpur 10250Pakistan

The supercapacitive properties of manganese oxides(MnO_(x))are strongly affected by their crystal ***,the relationship between the crystal structure and supercapacitive performance of Mn O_(x)is ***,a temperature-controlled fabrication method was developed to achieve MnO_(2),Mn_(3)O_(4),MnO and Mn_(2)O_(3)microspheres with various crystal structure as electrode materials tunable for *** detailed material and electrochemical characterizations revealed the structureactivity relationship of Mn O_(x)microspheres by systematically investigating the effect of valence state,specific surface area,conductivity and morphology on supercapacitive *** these MnO_(x)materials,nanoneedle-like Mn O_(2)delivered a relatively high specific capacitance of 274.1 F/g at 1 A/g due to a high Mn valence state of+4,a large specific surface area of 113.4 m^(2)/g and a desirable electronic conductivity of 1.73×10^(-5)S/***,MnO_(2)presented a remarkable cycle stability with 115%capacitance retention after 10,000 cycles owing to the enhancement of *** work not only provides a facile strategy to modulate MnO_(x)crystal structure,but also offers a deep understanding of structure-dependent supercapacitive performance of MnO_(x).

关键词： Temperature-controlled Manganese oxide Microsphere Supercapacitors Hydrophilic

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Hierarchical Fe-Bi/Bi_7O_9I_(3)/OVs microspheres coupled with natural air diffusion electrode to achieve efficient heterogeneous visible-light-driven photoelectro-Fenton degradation of tetracycline without aeration

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Chinese Chemical Letters 2025年第4期36卷 384-391页

作者： Ruiheng Liang Huizhong Wu Zhongzheng Hu Ge Song Xuyang Zhang Omotayo A.Arotiba Minghua Zhou Tianjin Key Laboratory of Environmental Technology for Complex Trans-Media Pollution College of Environmental Science and EngineeringNankai UniversityTianjin 300350China Tianjin Advanced Water Treatment Technology International Joint Research Center College of Environmental Science and EngineeringNankai UniversityTianjin 300350China Department of Chemical Sciences University of JohannesburgDoornfontein 2028South Africa Centre for Nanomaterials Science Research University of JohannesburgDoornfontein 2028South Africa

A novel Fe-doping three-dimensional fiower-like Bi_(7)O_(9)I_(3) microspheres with plasmonic Bi and rich surface oxygen vacancies(Fe-Bi/Bi_(7)O_(9)I_(3)/OVs)was prepared as catalysts,and further coupled with natural air diffusion electrode(NADE)to construct the heterogeneous visible-light-driven photoelectro-Fenton(HEVL-PEF)process to enhance the degradation and mineralization of tetracycline(TC).Interfacial≡Fe sites,OVs and Bi metal were simultaneously constructed via Fe doping,which effectively improved visible light absorption and the separation efficiency of photogenerated carriers to further accelerate the transformation of Fe(Ⅲ)to Fe(Ⅱ),achieving Fenton reaction ***-VL-PEF process could achieve enhanced treatment of pollutants,thanks to the synergistic effect of electro-Fenton(EF)and photo-Fenton(PF).NADE exhibited excellent H_(2)O_(2) electrosynthesis without external oxygen-pumping *** the irradiation of visible light,Fe-Bi/Bi_(7)O_(9)I_(3)/OVs could achieve more photoelectrons to accelerate the transformation of Fe(Ⅲ)to Fe(Ⅱ)or directly activate *** calculations also clearly demonstrated that except for the fast charge separation and transfer,Fe-Bi/Bi_(7)O_(9)I_(3)/OVs could achieve a faster electron transport between Fe-O,facilitating Fe site acquire more ***,the Fe-Bi/Bi_(7)O_(9)I_(3)/OVs in HE-VL-PEF process presented performance superiorities including excellent pollutant removal(91.91%),low electric energy consumption of 66.34 k Wh/kg total organic carbon(TOC),excellent reusability and wide p H adaptability(3–9).

关键词： Bi_7O_9I_(3) Fe doping Heterogeneous visible-light-driven photoelectron-Fenton Plasmonic Bi Oxygen vacancies

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Co_(3)O_(4)as an efficient passive NO_(x) adsorber for emission control during cold-start of diesel engines

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Chinese Journal of Chemical engineering 2024年第2期66卷 1-7页

作者： Jinhuang Cai Shijie Hao Yun Zhang Xiaomin Wu Zhenguo Li Huawang Zhao Department of Environmental Science&Engineering College of Chemical EngineeringHuaqiao UniversityXiamen 361021China Wuxi Weifu Environmental Catalysts Co. LtdWuxi 214000China National Engineering Laboratory for Mobile Source Emission Control Technology China Automotive Technology&Research Center Co.Ltd.Tianjin 300300China

The Co_(3)O_(4)nanoparticles,dominated by a catalytically active(110)lattice plane,were synthesized as a low-temperature NO_(x) adsorbent to control the cold start emissions from *** nanoparticles boast a substantial quantity of active chemisorbed oxygen and lattice oxygen,which exhibited a NO_(x) uptake capacity commensurate with Pd/SSZ-13 at 100℃.The primary NO_(x) release temperature falls within a temperature range of 200-350℃,making it perfectly suitable for diesel *** characterization results demonstrate that chemisorbed oxygen facilitate nitro/nitrites intermediates formation,contributing to the NO_(x) storage at 100℃,while the nitrites begin to decompose within the 150-200℃***,lattice oxygen likely becomes involved in the activation of nitrites into more stable nitrate within this particular temperature *** concurrent processes of nitrites decomposition and its conversion to nitrates results in a minimal NO_(x) release between the temperatures of 150-200℃.The nitrate formed via lattice oxygen mainly induces the NO_(x) to be released as NO_(2) within a temperature range of 200-350℃,which is advantageous in enhancing the NO_(x) activity of downstream NH_(3)-SCR catalysts,by boosting the fast SCR reaction *** to its low cost,considerable NO_(x) absorption capacity,and optimal release temperature,Co_(3)O_(4)demonstrates potential as an effective material for passive NO_(x) adsorber applications.

关键词： Emission control Cold-start Low-temperature adsorption Co_(3)O_(4) Nitrate formation

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Degradation properties of fulvic acid and its microbially driven mechanism from a partial nitritation bioreactor through multi-spectral and bioinformatic analysis

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Journal of environmental sciences 2024年第1期135卷 318-331页

作者： Quanhao Dou Li Zhang Tingjun Dong Zixuan Song Xuepeng Fan Yongzhen Peng Xiayan Wang Jiachun Yang National Engineering Laboratory for Advanced Municipal Wastewater Treatment and Reuse Technology Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery EngineeringBeijing University of TechnologyBeijing 100124China Department of Chemistry and Biology Center of Excellence for Environmental Safety and Biological EffectsBeijing Key Laboratory for Green Catalysis and SeparationBeijing University of TechnologyBeijing 100124China Environmental Protection Development Group Co. Ltd.Shandong 250101China

This study employed multispectral techniques to evaluate fulvic acid(FA)compositional characteristic and elucidate its biodegradation mechanisms during partial nitritation(PN)*** showed that FA removal efficiency(FRE)decreased from 90.22 to 23.11%when FA concentrations in the reactor were increased from 0 to 162.30 mg/L,and that molecular size,degree of aromatization and humification of the effluent FA macromolecules all increased after *** population analysis indicated that the proliferation of the Comamonas,OLB12 and Thauera exhibit high FA utilization capacity in lower concentrations(<50.59 mg/L),promoting the degradation and removal of macromolecular *** addition,the sustained increase in external FA may decrease the abundance of above functional microorganisms,resulting in a rapid drop in ***,from the genetic perspective,the elevated FA levels restricted carbohydrate(ko00620,ko00010 and ko00020)and nitrogen(HAO,AMO,NIR and NOR)metabolism-related pathways,thereby impeding FA removal and total nitrogen loss associated with N_(2)O emissions.

关键词： Partial nitritation Fulvic acid 3DEEM-PARAFAC UV/Vis Microbially driven mechanism

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Shape-dependence in seeded-growth of Pd-Cu solid solution from Pd nanostructure towards methanol oxidation electrocatalyst

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Nano Research 2023年第7期16卷 9116-9124页

作者： Lianxi Si Hui Li Yu Zhang Donghao Zhang Xiaowei An Mengmeng Yao Yuanyuan Shao Jesse Zhu Shi Hu School of Chemical Engineering and Technology Tianjin UniversityTianjin 300072China Department of Chemistry School of ScienceTianjin Key Laboratory of Molecular Optoelectronic ScienceTianjin UniversityTianjin 300072China College of Environmental Science and Engineering Taiyuan University of TechnologyTaiyuan 030024China

Ultrathin Pd nanosheets(NSs)have great advantages in catalysis due to their large specific surface area and high percentage of under-coordinated ***,the electrochemical performance still can be improved via composition-controllable growth of their solid ***,seeded alloying strategy was proposed to synthesize Pd-Cu solid solution from Pd NSs and Pd-Cu nanostructures with tunable molar ratios obtained by changing the amount of Cu *** compared to the pristine Pd NSs,the Pd-Cu solid solution shows significantly enhanced methanol oxidation reaction(MOR)performance over those of Pd NSs and homemade Pd/C as the incorporation of Cu weakens the adsorption of CO intermediate on Pd in the MOR *** choice of template is pivotal to the growth,as a shape-dependent behavior could be identified in the alloying of Cu with Pd nanosheets enclosed by{111}and{100}facets,Pd nanocubes enclosed by{100}facet,and Pd nano-tetrahedrons enclosed by{111}*** Pd-Cu solid solution with tunable composition can only be obtained from Pd NSs and the shape-dependent alloying process is mainly determined by the diffusion barrier and the minimum diffusion depth of the different facets.

关键词： Pd-Cu alloy nanosheets tunable composition methanol oxidation reaction optimized electronic structure weakened COadsorption

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1D/2D CoTe_(2)@MoS_(2)composites constructed by CoTe_(2)nanorods and MoS_(2)nanosheets for efficient electromagnetic wave absorption

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Nano Research 2023年第7期16卷 10698-10706页

作者： Naixin Zhai Juhua Luo Pengcheng Shu Jie Mei Xiaopeng Li Wenxing Yan School of Materials Science and Engineering Yancheng Institute of TechnologyYancheng 224051China Jiangsu Provincial Key Laboratory of Eco-Environmental Materials Yancheng Institute of TechnologyYancheng 224051China

Rational design of the components and microstructure is regarded as an efficacious strategy for the high-performance electromagnetic wave absorbing(EMWA)***,the CoTe_(2)@MoS_(2)nanocomposites with CoTe_(2)nanorods and MoS_(2)nanosheets were synthesized via a hydrothermal *** microstructure and composition of the samples were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),energy dispersive X-ray spectroscopy(EDS),transmission electron microscopy(TEM),and X-ray photoelectron spectroscopy(XPS).The CoTe_(2)@MoS_(2)composite was composed of stacked CoTe_(2)as the core and intertwined MoS_(2)nanosheets as the *** electromagnetic parameters of the CoTe_(2)@MoS_(2)composites were investigated by vector network analyzer(VNA).The EMWA property of the composite showed a trend of first increasing and then decreasing with the increasing content of MoS_(2).When the mass ratio of MoS_(2)and CoTe_(2)was 1:1,the CoTe_(2)@MoS_(2)composite exhibited the minimum reflection loss value of-68.10 dB at 4.71 GHz,and the effective absorption bandwidth value might reach 4.64 GHz(13.08-17.72 GHz)at a matching thickness of 1.60 mm with filler loading of 50 wt.%.The extraordinary EMWA property was attributed to the optimized impedance matching,multiple scattering and reflections,dipole polarization,conductive loss,and interfacial ***,the present approach to the design of microstructure and interface engineering offers a crucial way to construct high-performance EMW absorbers.

关键词： transition metal tellurides microstructure design heterostructure engineering electromagnetic wave absorption

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Effect of Integration Time on the Performance Parameters of InGaAs Detectors

Effect of Integration Time on the Performance Parameters of ...

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2024 Conference on Spectral technology and Applications, CSTA 2024

作者： Luo, Xi Liu, Yuebo Zhang, Yichi Lu, Jianting Wei, Zhipeng Yang, Shaohua State Key Laboratory of High Power Semiconductor Lasers Changchun University of Science and Technology Changchun130022 China Reliability Physics and Application Technology of Electronic Component Key Laboratory China Electronic Product Reliability and Environmental Testing Research Institute Guangzhou511370 China

ISBN: (纸本)9781510683082

Shortwave infrared imaging has the characteristics of high recognition and all-weather adaptation. Consequently, InGaAs short-wave infrared (SWIR) detectors find extensive applications in military and civilian fields, which imposes higher performance demands on InGaAs SWIR detectors. To optimize the performance and effectiveness of InGaAs SWIR detectors, this study delves into the fluctuation patterns of detectivity, responsivity, and dynamic range concerning integration time. Furthermore, it examines the outcomes of these parameters at various integration times. It is observed that the performance of InGaAs SWIR detectors changes at different integration times, and each parameter exhibits specific variation patterns with integration time. © 2024 SPIE.

关键词： Infrared detectors

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Carbon nanotubes decorated FeNi/nitrogen-doped carbon composites for lightweight and broadband electromagnetic wave absorption

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Journal of Materials science & technology 2023年第27期158卷 207-217页

作者： Juhua Luo Wenxing Yan Xiaopeng Li Pengcheng Shu Jie Mei Yafan Shi School of Materials Science and Engineering Yancheng Institute of TechnologyYancheng 224051China Jiangsu Provincial Key Laboratory of Eco-Environmental Materials Yancheng Institute of TechnologyYancheng 224051China

Magnetic-dielectric component modulation and heterogeneous interface engineering were considered as an effective strategy for designing lightweight and broadband electromagnetic wave(EMW)***,a series of carbon nanotubes(CNTs)decorated core-shell nitrogen-doped carbon(CNTs/FeNi/NC)composites were successfully fabricated via the carbonization of CNTs/NiFe_(2)O_(4)/PDA precursors obtained by hydrothermal and polymerization *** EMW absorption(EMWA)properties of CNTs/FeNi/NC composites were explored by varying the CNTs *** the CNTs content was 15%,the minimum reflection loss(RL_(min))value was-51.13 dB at 9.52 GHz and the corresponding effective absorption band-width(EAB)value was 2.96 GHz(8.96-11.12 GHz)at 2.5 ***,the maximum EAB value can reach up to 4.64 GHz(12.80-17.44 GHz)at 1.7 *** excellent EMW attenuation capability resulted from the enhanced conductive loss,polarization loss,magnetic loss,and improved impedance *** work offers a novel reference for designing lightweight and broadband EMWA materials.

关键词： Carbon nanotubes Nano-heterogeneous interface engineering Electromagnetic wave absorption Impedance matching

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