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Surface and structure engineering of MXenes for rechargeable batteries beyond lithium

Journal of Materiomics 2024年第1期10卷 253-268页

作者： Zefu Huang Majid Farahmandjou Frederick Marlton Xin Guo Hong Gao Bing Sun Guoxiu Wang Centre for Clean Energy Technology School of Mathematical and Physical SciencesFaculty of ScienceUniversity of Technology SydneyUltimoNSW2007Australia Joint International Laboratory on Environmental and Energy Frontier Materials School of Environmental and Chemical Engineering Shanghai UniversityShanghai200444China

With the rapid growth in renewable energy,researchers worldwide are trying to expand energy storage *** development of beyond-lithium battery technologies has accelerated in recent years,amid concerns regarding the sustainability of battery ***,the absence of suitable high-performance materials has hampered the development of the next-generation battery ***,a family of 2D transition metal carbides and/or nitrides,have drawn significant attention recently for electrochemical energy storage,owing to their unique physical and chemical *** extraordinary electronic conductivity,compositional diversity,expandable crystal structure,superior hydrophilicity,and rich surface chemistries make MXenes promising materials for electrode and other components in rechargeable *** report especially focuses on the recent MXene applications as novel electrode materials and functional separator modifiers in rechargeable batteries beyond *** particular,we highlight the recent advances of surface and structure engineering strategies for improving the electrochemical performance of the MXene-based materials,including surface termination modifications,heteroatom doping strategies,surface coating,interlayer space changes,nanostructure engineering,and heterostructures and secondary materials ***,perspectives for building future sustainable rechargeable batteries with MXenes and MXene-based composite materials are presented based upon material design and a fundamental understanding of the reaction mechanisms.

关键词： MXenes Energy storage materials 2D materials Surface engineering Structure engineering

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Dealuminated Hβ zeolite for selective conversion of fructose to furfural and formic acid

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Green Energy & Environment 2024年第2期9卷 311-320页

作者： Rui Li Qixuan Lin Junli Ren Xiaobao Yang Yingxiong Wang Lingzhao Kong State Key Laboratory of Pulp and Paper Engineering School of Light Industry and EngineeringSouth China University of TechnologyGuangzhou510640China Institute of Coal Chemistry Chinese Academy of Sciences27 South Taoyuan RoadTaiyuan030001China CAS Key Laboratory of Low-Carbon Conversion Science and Engineering Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai201210China School of Environmental Science and Technology Suzhou University of Science and Technology Suzhou Jiangsu215009China

The fructose-to-furfural transformation is facing major challenges in the selectivity and high efficiency. Herein, we have developed a simple and effective approach for the selective conversion of fructose to furfural using Hβ zeolite modified by organic acids for dealuminization to regulate its textural and acidic properties. It was found that citric acid-dealuminized Hβ zeolite possessed high specific surface areas, wide channels and high Brønsted acid amount, which facilitated the selective conversion of fructose to furfural with a maximum yield of 76.2% at433 K for 1 h in the γ-butyrolactone(GBL)-H_(2)O system, as well as the concomitant formation of 83.0% formic acid. The^(13)C-isotope labelling experiments and the mechanism revealed that the selective cleavage of C1–C2 or C5–C6 bond on fructose was firstly occurred to form pentose or C5 intermediate by weak Brønsted acid, which was then dehydrated to furfural by strong Brønsted acid. Also this dealuminized Hβ catalyst showed the great recycling performance and was active for the conversion of glucose and mannose.

关键词： Fructose Dealuminated-Hb zeolite Selective conversion Furfural

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Enhancing the photocatalytic efficiency by the molecular modification effect derived from pollutant adsorption on highly crystalline BiOBr

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Journal of environmental sciences 2025年第2期148卷 263-273页

作者： Yang Jin Tongyin Liu Yanpeng Mao Fan Li Chun Hu National Engineering Laboratory for Reducing Emissions from Coal Combustion Engineering Research Center of Environmental Thermal Technology of Ministry of EducationShandong Key Laboratory of Energy Carbon Reduction and Resource UtilizationSchool of Energy and Power EngineeringShandong UniversityJinan 250061China Beijing Enterprises Water Group<China>Investment Limited Beijing 100102China Institute of Environmental Research at Greater Bay Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationGuangzhou UniversityGuangzhou 510006China Key Laboratory of Drinking Water Science and Technology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China

The adsorption of pollutants can not only promote the direct surface reaction,but also modify the catalyst itself to improve its photoelectric characteristics,which is rarely studied for water treatment with inorganic photocatalyst.A highly crystalline BiOBr(c-BiOBr)was synthesized by a two-step preparation *** to the calcination,the highly crystalline enhanced the interface interaction between pollutant and *** complex of organic pollutant and[Bi_(2)O_(2)]^(2+)could promote the active electron transfer from the adsorbed pollutant to c-BiOBr for the direct pollutant degradation by holes(h^(+)).Moreover,the pollutant adsorption actually modified c-BiOBr and promoted more unpaired electrons,which would coupling with the photoexcitation to promote generate more O_(2)^(•-).The molecular modification effect derived from pollutant adsorption significantly improved the removal of *** work strongly deepens the understanding of the molecularmodification effect from the pollutant adsorption and develops a novel and efficient approach for water treatment.

关键词： Highly crystalline BiOBr Pollutant adsorption Molecular modification Photocatalysis Water treatment

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Research on the mechanism of rockburst induced by mined coal-rock linkage of sharply inclined coal seams

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International Journal of Minerals,Metallurgy and Materials 2024年第5期31卷 929-942页

作者： Xingping Lai Huicong Xu Pengfei Shan Qinxin Hu Weixi Ding Shangtong Yang Zhongming Yan College of Energy Science and Engineering Xi’an University of Science and TechnologyXi’an 710054China State Key Laboratory of Green Low Carbon Development of Oil-rich Coal in Western China Xi’an 710054China College of Future Technology Xi’an University of Science and TechnologyXi’an 710054China Department of Civil and Environmental Engineering University of StrathclydeGlasgowG11XJUK

In recent years,the mining depth of steeply inclined coal seams in the Urumqi mining area has gradually *** deformation of mining coal-rock results in frequent *** has become a critical issue that affects the safe mining of deep,steeply inclined coal *** this work,we adopt a perspective centered on localized deformation in coal-rock mining and systematically combine theoretical analyses and extensive data mining of voluminous microseismic *** describe a mechanical model for the urgently inclined mining of both the sandwiched rock pillar and the roof,explaining the mechanical response behavior of key disaster-prone zones within the deep working face,affected by the dynamics of deep *** exploring the spatial correlation inherent in extensive microseismic data,we delineate the“time-space”response relationship that governs the dynamic failure of coal-rock during the progression of the sharply inclined working *** results disclose that(1)the distinctive coal-rock occurrence structure characterized by a“sandwiched rock pillar-B6 roof”constitutes the origin of rockburst in the southern mining area of the Wudong Coal Mine,with both elements presenting different degrees of deformation localization with increasing mining depth.(2)As mining depth increases,the bending deformation and energy accumulation within the rock pillar and roof show nonlinear *** localized deformation of deep,steeply inclined coal-rock engenders the spatial superposition of squeezing and prying effects in both the strike and dip directions,increasing the energy distribution disparity and stress asymmetry of the“sandwiched rock pillar-B3+6 coal seam-B6 roof”*** makes worse the propensity for frequent dynamic disasters in the working face.(3)The developed high-energy distortion zone“inner-outer”control technology effectively reduces high stress concentration and energy distortion in the surrounding *** implementation,the averag

关键词： steeply inclined coal seam localized deformation mechanism of induced rockburst prevention and control of rockburst

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4.9 GHz A1-mode Lamb Wave Resonator based on Partially Released LN Film 6

4.9 GHz A1-mode Lamb Wave Resonator based on Partially Relea...

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6th International Conference on Electronics technology, ICET 2023

作者： Zhang, Zhuo Zhang, Ting-Yang Huang, Qin-Wen Yang, Shao-Hua Zhang, Xiao-Sheng Tu, Cheng University of Electronic Science and Technology of China School of Electronic Science and Engineering Chengdu China Sci. and Technol. on Reliability Phys. and Application Technology of Electronic Component Laboratory China Electronic Product Reliability and Environmental Testing Research Institute Guangzhou China

ISBN: (纸本)9798350337693

This work presents a 4.9 GHz A1 -mode Lamb wave resonator (LWR) based on partially released Z-cut lithium niobate (LN) thin film, which is aimed at application of 5G communication in N79 band. The designed LWR utilizes the horizontal electric field for efficient excitation of first-order antisymmetric (A1) mode in the acoustic cavity made of LN film. The fabrication process for the designed LWR is described and validated. The measured results show that the partially released devices achieve large electromechanical coupling coefficient (kt2=27%), which is comparable to that of reported fully released devices. The measured results are in good agreement with the finite element (FE) simulations. The presented partially released LWRs show prospect to improve the mechanical robustness of such devices without much sacrifice to performance. © 2023 IEEE.

关键词： Surface waves

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Phase transformation of Cr(Ⅵ)-adsorbed ferr ihydr ite in the presence of Mn(Ⅱ): Fate of Mn(Ⅱ)and Cr(Ⅵ)

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Journal of environmental sciences 2022年第3期34卷 251-259页

作者： Zecong Ding Guangzhao Sun Fenglian Fu Chujia Ye School of Environmental Science and Engineering Guangdong Key Laboratory of Environmental Catalysis and Health Risk ControlGuangdong University of TechnologyGuangzhou 510006China

Ferrihydrite is an important sink for the toxic heavy metal ions, such as Cr(Ⅵ). As ferrihydrite is thermodynamically unstable and gradually transforms into hematite and goethite, the stability of Cr(Ⅵ)-adsorbed ferrihydrite is environmentally significant. This study investigated the phase transformation of Cr(Ⅵ)-adsorbed ferrihydrite at different pH in the presence of aqueous Mn(Ⅱ), as well as the fate of Mn(Ⅱ) and Cr(Ⅵ) in the transformation process of ferrihydrite. Among the ferrihydrite transformation products, hematite was dominant, and goethite was minor. The pre-adsorbed Cr(Ⅵ) inhibited the conversion of ferrihydrite to goethite at initial pH 3.0, whereas little amount of adsorbed Mn(Ⅱ) favored the formation of goethite at initial pH 7.0. After the aging process, Cr species in solid phase existed primarily as Cr(Ⅲ) in the presence of Mn(Ⅱ) at initial pH 7.0 and 11.0. The aqueous Mn concentration was predominantly unchanged at initial pH 3.0, whereas the aqueous Mn(Ⅱ) was adsorbed onto ferrihydrite or form Mn(OH)_(2) precipitates at initial pH 7.0 and 11.0, promoting the immobilization of Cr(Ⅵ). Moreover, the oxidation of Mn(Ⅱ) occurred at initial pH 7.0 and 11.0, forming Mn(Ⅲ/Ⅳ)(hydr)oxides.

关键词： Ferrihydrite Phase transformation Gr(Ⅵ)adsorption and reduction Mn(Ⅱ)adsorption and oxidation

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Prestoring lithium into SnO_(2)coated 3D carbon fiber cloth framework as dendrite-free lithium metal anode

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Particuology 2024年第1期84卷 89-97页

作者： Tao Wei Yanyan Zhou Cheng Sun Lesheng Liu Sijia Wang Mengting Wang Ye Liu Qing Huang Quanchao Zhuang Yongfu Tang School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang212003China College of Materials Science and Engineering Nanjing Forestry UniversityNanjing210037China Li-ion Batteries Lab School of Materials Science and EngineeringChina University of Mining and TechnologyXuzhouChina Hebei Key Laboratory of Applied Chemistry School of Environmental and Chemical EngineeringYanshan UniversityQinhuangdao066004China

For several decades,the promise of implementing of lithium(Li)metal anodes has been regarded as the"holy grail"for Li-based ***,we have proposed a facile design of a carbon fiber cloth(CFC)framework coated with SnO_(2)nanoparticles through a hydrothermal process,which served as a reliable host for prestoring molten Li to produce a CFC@SnO_(2)@Li composite ***,TEM,HRTEM,XPS and different electrochemical characterizations were carried *** to the synergetic effects of the 3D conductive CFC and the coated lithiophilic SnO_(2)nanoparticles,the designed CFC@SnO_(2)@Li electrodes can buffer the volume changes and reduce the local current density,thus suppress the Li dendrites during ***,the CFC@SnO_(2)electrodes showed a high and stable CE of 98.6%for 1000 cycles at a current density of 1 mA cm^(-2)(1 mAh cm^(-2)).What is more,at a high current density of 5 mA cm^(-2)and a high areal capacity of 5 mAh cm^(-2),the symmetric cell displayed relatively low overpotential and long cycling lifetime of 1600 *** results confirm its great potential as lithium metal anodes in practical battery applications.

关键词： Lithiophilic Lithium metal anodes SnO_(2) 3D anode Dendrite-free

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Boosting the catalytic performance of Cu-SAPO-34in NO_(x) removal via hydrothermal treatment

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Journal of environmental sciences 2024年第1期135卷 640-655页

作者： Xiaoyan Tian Huimin Wang Siyuan Xu Lianyun Gao Jinyan Cao Jianjun Chen Qiulin Zhang Ping Ning Jiming Hao Faculty of Environmental Science and Engineering Kunming University of Science and TechnologyKunming 650500China National-Regional Engineering Center for Recovery of Waste Gases from Metallurgical and Chemical Industries Kunming University of Science and TechnologyKunming 650500China School of Environment State Key Joint Laboratory of Environment Simulation and Pollution ControlTsinghua UniversityBeijing 100084China

Phosphate ions promoted Cu-SAPO-34(P-Cu-SAPO-34)were prepared using bulk CuO particles as Cu^(2+)precursor by a solid-state ion exchange technique for the selective catalytic reduction of NO_(x) with NH_3(NH_3-SCR).The effects of high temperature(H-T)hydrothermal aging on the NO_(x) removal(de-NO_(x))performance of Cu-SAPO-34 with and without phosphate ions were systematically investigated at atomic *** results displayed that both Cu-SAPO-34 and P-Cu-SAPO-34 presented relatively poor NO_(x) removal activity with a low conversion(<30%)at 250-500℃.However,after H-T hydrothermal treatment(800℃ for 10 hr at 10%H_2O),these two samples showed significantly satisfied NO_(x) elimination performance with a quite high conversion(70%-90%)at 250-500℃.Additionally,phosphate ions decoration can further enhance the catalytic performance of Cu-SAPO-34 after hydrothermal treatment(Cu-SAPO-34H).The textural properties,morphologies,structural feature,acidity,redox characteristic,and surface-active species of the fresh and hydrothermally aged samples were analyzed using various characterization *** systematical characterization results revealed that increases of 28%of the isolated Cu^(2+)active species(Cu^(2+)-2Z,Cu(OH)^(+)-Z)mainly from bulk CuO and 50%of the Bronsted acid sites,the high dispersion of isolated Cu^(2+)active component as well as the Bronsted acid sites were mainly responsible for the accepted catalytic activity of these two hydrothermally aged samples,especially for P-Cu-SAPO-34H.

关键词： NH_(3)-SCR Cu-SAPO-34 Hydrothermal induced Phosphate ions

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Recycling of waste aluminum scraps to fabricate sulfidated zero-valent iron-aluminum particles for enhanced chromate removal

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Journal of environmental sciences 2024年第4期138卷 650-659页

作者： Yahui Zhang Liguo Zhang Jiajia Zeng Shuqun Xu Jianyu Pan Wenzhuo Huang Jianliang Sun Feng Jiang Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety&MOE Key Laboratory of Theoretical Chemistry of Environment School of EnvironmentSouth China Normal UniversityGuangzhou 510006China Guangdong Provincial Key Lab of Environmental Pollution Control and Remediation Technology School of Environmental Science&EngineeringSun Yat-Sen UniversityGuangzhou 510275China

Massive waste aluminum scraps produced from the spent aluminum products have high electron capacity and can be recycled as an attractive alternative to materials based on zerovalent iron(Fe^(0))for the removal of oxidative contaminants from *** study thus proposed an approach to fabricate micron-sized sulfidated zero-valent iron-aluminum particles(S-Al^(0)@Fe^(0))with high reactivity,electron selectivity and capacity using recycled waste aluminum scraps.S-Al^(0)@Fe^(0)with a three-layer structure contained zero-valent aluminum(Al^(0))core,Fe^(0) middle layer and iron sulfide(FeS)*** rates of chromate(Cr(Ⅵ))removal by S-Al^(0)@Fe^(0)at pH 5.0-9.0 were 1.6-5.9 times greater than that by sulfidated zero-valent iron(S-Fe^(0)).The Cr(Ⅵ)removal capacity of S-Al^(0)@Fe^(0)was 8.2-,11.3-and 46.9-fold greater than those of S-Fe0,zero-valent iron-aluminum(Al^(0)-Fe^(0))and Fe^(0),*** chemical cost of S-Al^(0)@Fe^(0) for the equivalent Cr(Ⅵ)removal was 78.5%lower than that of S-Fe^(0).Negligible release of soluble aluminum during the Cr(Ⅵ)removal was *** significant enhancement in the reactivity and capacity of S-Al^(0)@Fe^(0)was partially ascribed to the higher reactivity and electron density of the Al0core than Fe^(0).More importantly,S-Al^(0)@Fe^(0) served as an electric cell to harness the persistent and selective electron transfer from the Al^(0)-Fe^(0) core to Cr(Ⅵ)at the surface via coupling Fe^(0)-Fe^(2+)-Fe^(3+)redox cycles,resulting in a higher electron utilization ***,S-Al^(0)@Fe^(0) fabricated using recycled waste aluminum scraps can be a cost-effective and environmentally-friendly alternative to S-Fe^(0) for the enhanced removal of oxidative contaminants in industrial wastewater.

关键词： Recycled waste aluminum scraps Oxidative contaminants Cr(Ⅵ)reduction Sulfidated Al^(0)@Fe^(0)particle Electron transfer

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Study on total dose radiation effect of γ rays on β-Ga2O3SBD

Study on total dose radiation effect of γ rays on β-Ga2O3S...

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2023 Advanced Fiber Laser Conference, AFL 2023

作者： Fu, Weili Ma, Teng Zhong, Xiangli Lei, Zhifeng Wang, Jinbin Song, Hongjia Xiao, Tao Zhang, Hong Peng, Chao Zhang, Zhangang National-Provincial Laboratory of Special Function Thin Film Materials School of Materials Science and Engineering Xiangtan University Xiangtan Hunan411105 China Reliability Physics and Application Technology of Electronic Component Key Laboratory China Electronic Product Reliability and Environmental Testing Research Institute Guangzhou511370 China

ISBN: (纸本)9781510677661

Gallium oxide Ga2O3 has recently gained attention as a new power electronics semiconductor for aerospace applications. β-Ga2O3 has an extremely high bandgap energy of 4.8-4.9 eV and an expected high breakdown field of 8 MV/cm, which exceed those of traditional wide-bandgap semiconductor materials such as silicon carbide (SiC) and gallium nitride (GaN). These qualities make β-Ga2O3 a favorable choice for micro high-power and high-frequency devices. It is important to consider device application in a radiation environment. Due to its wide bandgap and high breakdown field, β- Ga2O3 has significant potential for use in Schottky barrier diodes (SBDs) in environments with extremely high radiation. In the radiation environment of space, it is crucial to contemplate the dependability of semiconductor devices in radiation, as alpha particles, gamma rays, heavy ions, X-rays, and other factors could induce single event effects, total ionizing dose effects, and displacement damage effects on semiconductor devices in spacecraft. Therefore, the impact of gamma-ray radiation with a total dose was analyzed on a new SBD device which can tolerate 650 V. The results indicate that radiation has a minor impact on the diode's forward performance. Conversely, the device's reverse electrical properties are significantly impacted by radiation. In addition, we examined the internal physical mechanism of diode performance deterioration triggered by gamma-ray radiation utilizing the outcomes of β-Ga2O3 Schottky diode radiation testing and analysis. To characterize the radiation tolerance of this material, studies on irradiation damage are required. © COPYRIGHT SPIE. Downloading of the abstract is permitted for personal use only.

关键词： Schottky barrier diodes

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