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engineering tiramisu-like phase change nanocomposite for superior thermal energy management and electromagnetic interference shielding

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材料科学技术（英文版） 2025年第3期206卷 113-124页

作者： Boyang Hu Hong Guo Ting Li Xiwei Cao Min Cao Weiyan Qi Ying Cui Baoan Li Carbon Neutrality Interdisciplinary Science Centre Tianjin Key Laboratory of Environmental Technology for Complex Trans-Media PollutionCollege of Environmental Science and EngineeringNankai UniversityTianjin 300350China Carbon Neutrality Interdisciplinary Science Centre Tianjin Key Laboratory of Environmental Technology for Complex Trans-Media PollutionCollege of Environmental Science and EngineeringNankai UniversityTianjin 300350China Department of Energy and Chemical Engineering Tianjin Ren'ai CollegeTianjin 301636China MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027China Laboratoire des Solides Irradiés CEA/DRF/lRAMISEcole Poly techniqueCNRSInstitut Poly technique de ParisPalaiseau F-91128France

Exploiting advanced nanocomposites isochronally integrating outstanding thermal conductivity(TC)and electromagnetic interference shielding effectiveness(EMI SE)can boost the cutting-edge application of phase change ***,we report a tiramisu-like composite(GMP),where the typical"crust-and-cheese"hierarchical structure is replicated by an innovative two-step bidirectional freezing assem-bly(BFA)and compressive ***-aligned graphene array(G-GA)with ultralow ther-mal resistance is fabricated through 1st BFA and *** the 2nd BFA,the MXene-CNF crosslinking network with hydrogen-bond actions is used for encapsulating polyethylene glycol(PEG)onto the microlayers of the G-GA ***,the microlaminated GMP4 achieves a recorded TC of 34.05 W m-1 K-1,unprecedented EMI SE of 87.4 dB,and preferable enthalpy density of 179.4 J cm-3,along with leakage-free function,and eminent thermal ***,the GMP-loaded equipment is demonstrated for efficient microelectronics cooling and sustainable solar energy *** work opens new avenues for multiscale designing multifunctional macro-composites,broadening the application prospects in advanced electronics and solar energy utilization systems.

关键词： Phase change composite Multiscale structure construction Bidirectional freezing assembly Thermal management EMI shielding

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Energy band engineering of graphitic carbon nitride for photocatalytic hydrogen peroxide production

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Carbon Energy 2024年第11期6卷 346-370页

作者： Tengyang Gao Degui Zhao Saisai Yuan Ming Zheng Xianjuan Pu Liang Tang Zhendong Lei Key Laboratory of Organic Compound Pollution Control Engineering (MOE) School of Environmental and Chemical Engineering Shanghai UniversityShanghaiChina National & Local Joint Engineering Research Center for Mineral Salt Deep Utilization Huaiyin Institute of TechnologyHuaianChina School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiangChina College of Environmental & Engineering Tongji UniversityShanghaiChina School of Materials Science and Engineering Nanyang Technological UniversitySin gaporeSingapore

Hydrogen peroxide(H_(2)O_(2))is one of the 100 most important chemicals in the world with high energy density and environmental *** with anthraquinone oxidation,direct synthesis of H_(2)O_(2) with hydrogen(H_(2))and oxygen(O_(2)),and electrochemical methods,photocatalysis has the characteristics of low energy consumption,easy operation and less pollution,and broad application prospects in H_(2)O_(2) *** photocatalysts,such as titanium dioxide(TiO_(2)),graphitic carbon nitride(g-C_(3)N_(4)),metal-organic materials,and nonmetallic materials,have been studied for H_(2)O_(2) *** them,g-C_(3)N_(4) materials,which are simple to synthesize and functionalize,have attracted wide *** electronic band structure of g-C_(3)N_(4) shows a bandgap of 2.77 eV,a valence band maximum of 1.44 V,and a conduction band minimum of−1.33 V,which theoretically meets the requirements for hydrogen peroxide *** comparison to semiconductor materials like TiO_(2)(3.2 eV),this material has a smaller bandgap,which results in a more efficient response to visible ***,the photocatalytic activity of g-C_(3)N_(4) and the yield of H_(2)O_(2) were severely inhibited by the electron-hole pair with high recombination rate,low utilization rate of visible light,and poor selectivity of *** previous reviews also presented various strategies to improve photocatalytic H_(2)O_(2) production,they did not systematically elaborate the inherent relationship between the control strategies and their energy band *** this point of view,this article focuses on energy band engineering and reviews the latest research progress of g-C_(3)N_(4) photocatalytic H_(2)O_(2) *** this basis,a strategy to improve the H_(2)O_(2) production by g-C_(3)N_(4) photocatalysis is proposed through morphology control,crystallinity and defect,and doping,combined with other materials and other ***,the challenges and prospect

关键词： energy band engineering graphitic carbon nitride hydrogen peroxide photocatalysis various strategies

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Synergistically S/N self-doped biochar as a green bifunctional cathode catalyst in electrochemical degradation of organic pollutant

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Green Energy & Environment 2025年第1期10卷 214-230页

作者： Xuechun Wang Huizhong Wu Jiana Jing Ge Song Xuyang Zhang Minghua Zhou Raf Dewil Key Laboratory of Pollution Process and Environmental Criteria Ministry of EducationCollege of Environmental Science and EngineeringNankai UniversityTianjin300350China Tianjin Key Laboratory of Environmental Technology for Complex Trans-Media Pollution Nankai UniversityTianjin300350China Tianjin Advanced Water Treatment Technology International Joint Research Center College of Environmental Science and EngineeringNankai UniversityTianjin300350China Department of Chemical Engineering KU LeuvenJ.De Nayerlaan 5Sint-Katelijne-Waver B2860Belgium

Biomass-derived heteroatom self-doped cathode catalysts has attracted considerable interest for electrochemical advanced oxidation processes(EAOPs)due to its high performance and sustainable ***,we illustrated the morphological fates of waste leaf-derived graphitic carbon(WLGC)produced from waste ginkgo leaves via pyrolysis temperature regulation and used as bifunctional cathode catalyst for simultaneous H_(2)O_(2) electrochemical generation and organic pollutant degradation,discovering S/N-self-doping shown to facilitate a synergistic effect on reactive oxygen species(ROS)*** the optimum temperature of 800℃,the WLGC exhibited a H_(2)O_(2) selectivity of 94.2%and tetracycline removal of 99.3%within 60 *** functional theory calculations and in-situ Fourier transformed infrared spectroscopy verified that graphitic N was the critical site for H_(2)O_(2) *** pyridinic N and thiophene S were the main active sites responsible for OH generation,N vacancies were the active sites to produce ^(1)O_(2) from O_(2).The performance of the novel cathode for tetracycline degradation remains well under a wide pH range(3–11),maintaining excellent stability in 10 *** is also industrially applicable,achieving satisfactory performance treating in real water *** system facilitates both radical and non-radical degradation,offering valuable advances in the preparation of cost-effective and sustainable electrocatalysts and hold strong potentials in metal-free EAOPs for organic pollutant degradation.

关键词： Biochar S and N self-doping H_(2)O_(2)production In-situ FTIR Metal-free electrochemical advanced oxidation processes

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Life cycle assessment of homogeneous Fenton process as pretreatment for refractory pharmaceutical wastewater

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Frontiers of Chemical science and engineering 2024年第5期18卷 1-11页

作者： Maojun Zou Jie Wei Yuanyuan Qian Yanjing Xu Zhihuang Fang Xuejing Yang Zhiyuan Wang School of Energy and Power Engineering University of Shanghai for Science and TechnologyShanghai 200093China Shanghai Engineering Laboratory of Lean Operational Technologies for Full Water System East China University of Science and TechnologyShanghai 200237China Mcwong Environmental Technology Company Limited Shanghai 200135China National Engineering Laboratory of High Concentration and Refractory Organic Wastewater Treatment Technology East China University of Science and TechnologyShanghai 200237China

The applicability of the life cycle assessment(LCA)to the Fenton process should be considered not only at the laboratory-scale but also at the *** this study,the LCA process was applied to evaluate the homo-geneous Fenton process for the treatment of high salinity pharmaceutical *** potential environmental impacts were calculated using Simapro software implemen-ting the CML 2001 methodology with normalization factors of 1995 *** data obtained directly from the full-scale wastewater treatment plant and labora-tory were used to conduct a life cycle inventory analysis,ensuring highly accurate *** normalized results,the Fenton process reveals sensitive indicators,primarily toxi-city indicators(human toxicity,freshwater aquatic toxicity,and marine aquatic toxicity),as well as acidification and eutrophication impacts,contributed by hydrogen peroxide and iron sludge incineration,***,hydrogen peroxide and iron sludge incineration contribute significantly,accounting for at least 78%of these *** sludge treatment phase,treatment of iron mud and infrastructure of hazardous waste incineration plants were the key contributors of environmental impacts,adding up to more than 95%.This study suggests the need to develop efficient oxidation processes and effective iron sludge treatment methods to reduce resource utilization and improve environmental benefits.

关键词： advanced oxidation processes full-scale life cycle assessment Fenton process pharmaceutical high-salinity wastewater

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Mesoporous molecular sieve-based materials for catalytic oxidation of VOC: A review

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Journal of environmental sciences 2023年第3期125卷 112-134页

作者： Wei Gao Xiaolong Tang Honghong Yi Shanxue Jiang Qingjun Yu Xizhou Xie Ruijie Zhuang Department of Environmental Science and Engineering School of Energy and Environmental EngineeringUniversity of Science and Technology BeijingBeijing 100083China State Environmental Protection Key Laboratory of Food Chain Pollution Control Beijing Technology and Business UniversityBeijing 100048China Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants Beijing 100083China

As the main contributor of the formation of particulate matter as well as ozone, volatile organic compounds(VOCs) greatly affect human health and the environmental quality. Catalytic combustion/oxidation has been viewed as an efficient, economically feasible and environmentally friendly way for the elimination of VOCs. Supported metal catalyst is the preferred type of catalysts applied for VOCs catalytic combustion because of the synergy between active components and support as well as its flexibility in the composition. The presence of support not only plays the role of keeping the catalyst with good stability and mechanical strength, but also provides a large specific surface for the good dispersion of active components, which could effectively improve the performance of catalyst as well as decrease the usage of active components, especially the noble metal amount. Mesoporous molecular sieves, owing to their large surface area, unique porous structures, large pore size as well as uniform pore-size distribution, were viewed as superior support for dispersing active components. This review focuses on the recent development of mesoporous molecular sieve supported metal catalysts and their application in catalytic oxidation of VOCs. The effect of active component types, support structure, preparation method, precursors, etc. on the valence state, dispersion as well as the loading of active species were also discussed and summarized. Moreover, the corresponding conversion route of VOCs was also *** review aims to provide some enlightment for designing the supported metal catalysts with superior activity and stability for VOCs removal.

关键词： Volatile organic compound Mesoporous molecular sieves Supported catalyst Catalytic oxidation Reaction mechanism Influencing factors

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Recent advances of metal vacancies in energy and environmental catalysis:Synthesis,characterization,and roles

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Green Energy & Environment 2025年第1期10卷 84-108页

作者： Long Sun Shunzheng Zhao Sirui Gao Ronghui Zhu Yiran Tan Xiaolong Tang Honghong Yi School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing100083China Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants Beijing100083China

With the ongoing depletion of fossil fuels,energy and environmental issues have become increasingly critical,necessitating the search for effective ***,being one of the hallmarks of modern industry,offers a promising avenue for ***,the question of how to significantly enhance the performance of catalysts has gradually drawn the attention of *** engineering,a commonly employed and effective approach to improve catalyst activity,has become a significant research focus in the catalysis field in recent *** vacancies have received extensive attention due to their simple ***,exploration of metal vacancies has remained stagnant for a considerable period,resulting in a scarcity of comprehensive reviews on this ***,based on the latest research findings,this paper summarizes and consolidates the construction strategies for metal vacancies,characterization techniques,and their roles in typical energy and environmental catalytic ***,it outlines potential challenges in the future,aiming to provide valuable references for researchers interested in investigating metal vacancies.

关键词： Metal vacancies Catalysis Construction strategies Characterization techniques Roles

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Influences of clean fracturing fluid viscosity and horizontal in-situ stress difference on hydraulic fracture propagation and morphology in coal seam

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International Journal of Coal science & technology 2024年第3期11卷 159-175页

作者： Gang Wang Shuxin Wang Yixin Liu Qiming Huang Shengpeng Li Shuliang Xie Jinye Zheng Jiuyuan Fan College of Safety and Environmental Engineering Shandong University of Science and TechnologyQingdao266590China Mine Disaster Prevention and Control-Ministry of State Key Laboratory Breeding Base Shandong University of Science and TechnologyQingdao266590China

The viscosity of fracturing fluid and in-situ stress difference are the two important factors that affect the hydraulic fracturing pressure and propagation morphology. In this study, raw coal was used to prepare coal samples for experiments, and clean fracturing fluid samples were prepared using CTAB surfactant. A series of hydraulic fracturing tests were conducted with an in-house developed triaxial hydraulic fracturing simulator and the fracturing process was monitored with an acoustic emission instrument to analyze the influences of fracturing fluid viscosity and horizontal in-situ stress difference on coal fracture propagation. The results show that the number of branched fractures decreased, the fracture pattern became simpler, the fractures width increased obviously, and the distribution of AE event points was concentrated with the increase of the fracturing fluid viscosity or the horizontal in-situ stress difference. The acoustic emission energy decreases with the increase of fracturing fluid viscosity and increases with the increase of horizontal in situ stress difference. The low viscosity clean fracturing fluid has strong elasticity and is easy to be compressed into the tip of fractures, resulting in complex fractures. The high viscosity clean fracturing fluids are the opposite. Our experimental results provide a reference and scientific basis for the design and optimization of field hydraulic fracturing parameters.

关键词： Clean fracturing fluid Hydraulic fracturing Viscosity Horizontal in-situ stress difference Hydraulic fracture morphology Acoustic emission

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Structure-performance relationship between denitration performance and catalytic interface morphologies of MnCeO_(x)/P84 catalytic filters

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Journal of Rare Earths 2025年第3期43卷 516-525,I0004页

作者： Bo Yang Yujie Lei Maosen Ni Liuying Wang Qiong Huang Mindong Chen Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology(CICAEET) Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlSchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjing210044China

MnCeO_(x)/P84 catalytic filters with spherical,flower-like,cubic and rod-like catalytic interfaces were synthesized respectively,and their catalytic activities in the NH_(3)-SCR reaction were *** MnCeO_(x)/P84 catalytic filter with spherical catalytic interfaces(recorded as S-MnCeO_(x)/P84)exhibits the best catalytic denitration *** NO_(x)removal efficiency of S-MnCeO_(x)/P84 reaches the highest value of 98.6%at 160℃when the catalyst loading is 100 g/m^(2).At the same time,S-MnCeO_(x)/P84 exhibits good SO_(2)resistance and stability,achieving a NO_(x)removal rate of 83%at 190℃with 30 ppm SO_(2).The characterization results illustrate that the MnCeO_x active component in S-MnCeO_(x)/P84 is present in weak crystalline states,tightly wrapped around the surface of the filter fiber,and uniformly dispersed,and the mesopore is the main pore structure of the S-MnCeO_(x)/P84,which can provide a channel for the catalytic reaction to *** the same time,transmission electron microscopy(TEM)characterization shows that y-MnO_(2)is the main form of MnO_(2)in the S-MnCeO_(x)/*** analysis of H_(2)temperature programmed reduction(H_(2)-TPR).NH_(3)temperature programmed desorption(NH_(3)-TPD)and in-situ diffuse reflectance infrared spectra(DRIFTS)show that S-MnCeO_(x)/P84 has good redox ability at 100-200℃and has abundant Lewis acid sites and Bronsteds acid sites,which provides an important guarantee for its superior low-temperature NH_(3)-SCR denitration performance.

关键词： Catalytic filter Nitrogen oxides(NO_x) Denitration Catalytic interface Rare earths

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Research status and prospect of purification technology of sulfur-containing odor gas

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Journal of environmental sciences 2025年第3期149卷 301-313页

作者： Yuhan Long Shunzheng Zhao Xiaolong Tang Qingjun Yu Fengyu Gao Jun Liu YaWang Yuansong Zhou Honghong Yi School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants Beijing 100083China

Catalytic purification of sulphur-containing malodorous gases has attracted wide attention because of its advantages of high purification efficiency,low energy consumption and lack of secondary *** selection of efficient catalysts is the key to the problem,while the preparation and optimisation of catalysts depend on the analysis of experimental results and in-depth mechanistic *** analysing the published literature,bibliometric analysis can identify existing research hotspots,the areas of interest and predict development trends,which can help to identify hot catalysts in the catalytic purification of sulphurcontaining odours and to investigate their catalytic purification ***,this paper uses bibliometric analysis,based on Web Of science and CNKI databases,CiteSpace and VOS viewer software to collate and analyse the literature on the purification of sulphurcontaining odour pollutants,to identify the current research hotspots,to summarise the progress of research on the catalytic purification of different types of sulphur-containing odours,and to analyse their reaction mechanisms and *** this basis,the research progress of catalytic purification of different kinds of sulfur odour is summarized,and the reaction mechanism and dynamics are summarized.

关键词： Bibliometric Sulphur-containing odor gases Catalytic oxidation Catalytic decomposition

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Simultaneous Degradation, Dehalogenation, and Detoxification of Halogenated Antibiotics by Carbon Dioxide Radical Anions

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engineering 2024年第6期37卷 78-86页

作者： Yanzhou Ding Xia Yu Shuguang Lyu Huajun Zhen Wentao Zhao Cheng Peng Jiaxi Wang Yiwen Zhu Chengfei Zhu Lei Zhou Qian Sui State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process School of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai 200237China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Academy of Environmental Sciences Shanghai 200233China

Despite the extensive application of advanced oxidation processes(AOPs)in water treatment,the efficiency of AOPs in eliminating various emerging contaminants such as halogenated antibiotics is constrained by a number of *** moieties exhibit strong resistance to oxidative radicals,affecting the dehalogenation and detoxification *** address these limitations of AOPs,advanced reduction processes(ARPs)have been ***,a novel nucleophilic reductant—namely,the carbon dioxide radical anion(CO_(2)^(·-))—is introduced for the simultaneous degradation,dehalogenation,and detoxification of florfenicol(FF),a typical halogenated *** results demonstrate that FF is completely eliminated by CO_(2)^(·-),with approximately 100%of Cland 46%of Freleased after 120 min of *** detoxification is observed,which exhibits a linear response to the release of free inorganic halogen ions(R^(2)=0.97,p<0.01).The formation of halogen-free products is the primary reason for the superior detoxification performance of this method,in comparison with conventional hydroxyl-radical-based *** identification and density functional theory(DFT)calculations reveal the underlying dehalogenation mechanism,in which the chlorine moiety of FF is more susceptible than other moieties to nucleophilic attack by CO_(2)^(·-).Moreover,CO_(2)^(·-)-based ARPs exhibit superior dehalogenation efficiencies(>75%)in degrading a series of halogenated antibiotics,including chloramphenicol(CAP),thiamphenicol(THA),diclofenac(DLF),triclosan(TCS),and ciprofloxacin(CIP).The system shows high tolerance to the pH of the solution and the presence of natural water constituents,and demonstrates an excellent degradation performance in actual groundwater,indicating the strong application potential of CO_(2)^(·-)-based ARPs in real ***,this study elucidates the feasibility of CO_(2)^(·-)for the simultaneous degradation,dehalogenation,and detoxification of halog

关键词： Carbon dioxide radical anions Advanced reduction processes Halogenated antibiotics Dehalogenation Detoxification

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