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Insights into the effect of Y substitution on superlattice structure and electrochemical performance of A5B19-type La-Mg-Ni-based hydrogen storage alloy for nickel metal hydride battery

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材料科学技术（英文版） 2025年第4期207卷 60-69页

作者： Yanan Guo Wenfeng Wang Huanhuan Su Hang Lu Yuan Li Qiuming Peng Shumin Han Lu Zhang College of Environmental and Chemical Engineering Hebei Key Laboratory of Applied ChemistryYanshan UniversityQinhuangdao 066004China State Key Laboratory of Metastable Materials Science and Technology Yanshan UniversityQinhuangdao 066004China College of Environmental and Chemical Engineering Hebei Key Laboratory of Applied ChemistryYanshan UniversityQinhuangdao 066004China State Key Laboratory of Metastable Materials Science and Technology Yanshan UniversityQinhuangdao 066004China Baotou Zhongke Xuanda New Energy Technology Co.Ltd. Baotou 014030China

La-Mg-Ni-based hydrogen storage alloys with superlattice structures are the new generation anode mate-rial for nickel metal hydride(Ni-MH)batteries owing to the advantages of high capacity and exceptional activation ***,the cycling stability is not currently satisfactory enough which plagues its ***,a strategy of partially substituting La with the Y element is proposed to boost the capacity durability of La-Mg-Ni-based ***,phase structure regulation is implemented simultaneously to obtain the A5B19-type alloy with good crystal stability *** is found that Y promotes the phase formation of the Pr5Co19-type phase after annealing at 985 ℃.The alloy containing Y contributes to the superior rate capability resulting from the promoted hydrogen diffusion ***,Y substitution enables strengthening the anti-pulverization ability of the alloy in terms of increasing the volume match between[A2B4]and[AB5]subunits,and effectively enhances the anti-corrosion ability of the alloy due to high electronegativity,realizing improved long-term cycling stability of the alloy from 74.2％to 78.5％after cycling 300 *** work is expected to shed light on the composition and structure design of the La-Mg-Ni-based hydrogen storage alloy for Ni-MH batteries.

关键词： Nickel metal hydride battery Y element La-Mg-Ni-based alloy A5B19-type superlattice structure Electrochemical performance

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Direct generation of Zn metal using laser-induced ZnS to eradicate carbon emissions from electrolysis Zn production

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Frontiers of environmental science & engineering 2024年第1期18卷 83-95页

作者： Ying Chen Ning Duan Linhua Jiang Fuyuan Xu Guangbin Zhu Yao Wang Yong Liu Wen Cheng Yanli Xu State Key Laboratory of Pollution Control and Resources Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China School of Environmental Science and Engineering Tianjin UniversityTianjin 300350China School of Materials Science and Engineering Anhui University of Science&TechnologyHuainan 232001China

In response to the goal of net-zero emissions proposed by Intergovernmental Panel on Climate Change, Chinese government has pledged that carbon emissions will peak by 2030, and achieve carbon neutrality by 2060. However, the high carbon energy structure of traditional industries has aggravated environmental problems, such as greenhouse effect and air pollution. The goal of carbon neutrality will be difficult to achieve without the development of disruptive theories and technologies. The electrolytic zinc industry requires high-temperature roasting at ~1000 ℃, generating large amounts of greenhouse gases and SO_(2). High concentrations of sulfuric acid (200 g/L) are subsequently used for electrolysis, and each ton of zinc produced generates 50 kg of anode slime with lead content of up to 16%, as well as 0.35 m3 of wastewater containing zinc and lead. To solve these problems, an optical metallurgy method is proposed in this study. The proposed method uses laser-induced photoreduction to decompose ZnS and reduce metal ions to metal. Results indicate that Zn0 and S8 can be detected on the surface of ZnS at a specific wavelength and laser fluence. The generation mechanism of Zn0 is such that laser induces an electronic transition that breaks ionic bond in ZnS, resulting in its decomposition and photoreduction to Zn0 under an inert argon gas atmosphere. This method does not reduce other metals in the mineral since it does not use high-temperature roasting, providing a new way of producing high-purity metal without greenhouse gas emissions and heavy metal pollution caused by traditional zinc electrolysis.

关键词： Laser metallurgy ZnS Photochemical reduction Zinc

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Microplastics enhance the adsorption capacity of zinc oxide nanoparticles:Interactive mechanisms and influence factors

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Journal of environmental sciences 2025年第1期147卷 665-676页

作者： Weiping Xiong Min Hu Siying He Yuhang Ye Yinping Xiang Haihao Peng Zhaomeng Chen Zhengyong Xu Honglin Zhang Weixiang Li Shudian Peng College of Environmental Science and Engineering Hunan University and Key Laboratory of Environmental Biology and Pollution Control(Hunan University)Ministry of EducationChangsha 410082China Hunan Boke Environmental Engineering Co.Ltd. Hengyang 421099China College of Environmental Protection and Safety Engineering University of South ChinaHengyang 421001China Hunan Modern Environmental Technology Co.Ltd. Changsha 410004China

Microplastics(MPs)are of particular concern due to their ubiquitous occurrence and propensity to interact and concentrate various waterborne contaminants from aqueous *** on the interaction and joint toxicity of MPs on engineered nanoparticles(ENPs)are exhaustive,but limited research on the effect of MPs on the properties of ENPs in multisolute ***,the effect of MPs on adsorption ability of ENPs to antibiotics was investigated for the first *** results demonstrated that MPs enhanced the adsorption affinity of ENPs to antibiotics and MPs before and after aging showed different effects on *** polyamide prevented aggregation of ZnONPs by introducing negative charges,whereas virgin polyamide affected ZnONPs with the help of electrostatic ***-IR and XPS analyses were used to probe the physicochemical interactions between ENPs and *** results showed no chemical interaction and electrostatic interactionwas the dominant force between ***,the adsorption rate of antibiotics positively correlated with pH and humic acid but exhibited a negative correlation with ionic *** study highlights that ENPs are highly capable of accumulating and transporting antibiotics in the presence of MPs,which could result in a widespread distribution of antibiotics and an expansion of their environmental risks and toxic effects on *** also improves our understanding of the mutual interaction of various co-existing contaminants in aqueous environments.

关键词： Microplastics Engineered nanoparticles Adsorption Tetracycline

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Advancing Toxicity Predictions:A Review on in Vitro to in Vivo Extrapolation in Next-Generation Risk Assessment

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Environment & Health 2024年第7期2卷 499-513页

作者： Peiling Han Xuehua Li Jingyuan Yang Yuxuan Zhang Jingwen Chen Key Laboratory of Industrial Ecology and Environmental Engineering School of Environmental Science and TechnologyDalian University of TechnologyLiaoningDalian 116024China

As a key step in next-generation risk assessment(NGRA),in vitro to in vivo extrapolation(IVIVE)aims to mobilize a mechanism-based understanding of toxicology to translate bioactive chemical concentrations obtained from in vitro assays to corresponding exposures likely to induce bioactivity in *** conversion can be achieved via physiologically-based toxicokinetic(PBTK)models and machine learning(ML)*** last 5 years have witnessed a period of rapid development in IVIVE,with the number of IVIVE-related publications increasing *** Review aims to(1)provide a comprehensive overview of the origin of IVIVE and initiatives undertaken by multiple national agencies to promote its development;(2)compile and sort out IVIVE-related publications and perform a clustering analysis of their high-frequency keywords to capture key research hotspots;(3)comprehensively review PBTK and ML model-based IVIVE studies published in the last 5 years to understand the research directions and methodology developments;and(4)propose future perspectives for IVIVE from two aspects:expanding the scope of application and integrating new *** former includes focusing on metabolite toxicity,conducting IVIVE studies on susceptible populations,advancing ML-based quantitative IVIVE models,and extending research to ecological *** latter includes combining systems biology,multiomics,and adverse outcome networks with IVIVE,aiming at a more microscopic,mechanistic,and comprehensive toxicity *** Review highlights the important value of IVIVE in NGRA,with the goal of providing confidence for its routine use in chemical prioritization,hazard assessment,and regulatory decision making.

关键词： in vitro to in vivo extrapolation physiologically-based toxicokinetic model big data machine learning in vivo toxicity

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Underestimated contribution of fugitive emission to VOCs in pharmaceutical industry based on pollution characteristics, odorous activity and health risk assessment

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Journal of environmental sciences 2023年第4期126卷 722-733页

作者： Qinhao Lin Zhong Gao Weikun Zhu Jiangyao Chen Taicheng An Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control Guangdong Technology Research Center for Photocatalytic Technology Integration and Equipment EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health Guangzhou Key Laboratory of Environmental Catalysis and Pollution ControlSchool of Environmental Science and EngineeringGuangdong University of TechnologyGuangzhou 510006China

Fugitive emission has been becoming an important source of volatile organic compounds(VOCs) in pharmaceutical industry,but the exact contribution of fugitive emission remains incompletely *** present study,pollution characteristics,odorous activity and health risk of stack and fugitive emissions of VOCs from four functional units (e.g.,workshop,sewage treatment station,raw material storage and hazardous waste storage) of three representative pharmaceutical factories were *** was the dominant contributor to VOCs of fugitive emission in comparison with other functional *** high concentration of VOCs from fugitive emission in unsealed workshop (94.87 mg/m^(3))was observed relative to sealed one (1.18 mg/m^(3)),accounting for 31%and 5%of total VOCs,*** emission of VOCs in the unsealed workshop mainly consisted of nhexane,1-hexene and *** activity indexes and non-cancer hazard ratios of these VOCs from fugitive emission in the unsealed workshop were as high as that from stack ***,cancer risk of dichloromethane from fugitive emission and stack exhaust was up to (1.6-1.8)×10^(-5).Odorous activity or health risk index of the VOCs from fugitive emission was up to 13 or 11 times of the corresponding threshold value,posing remarkable health threat on pharmaceutical ***?ndings highlighted the possibly underestimated contribution of fugitive emission on VOCs in the pharmaceutical industry.

关键词： Pharmaceutical industry VOC pollution Fugitive emission Odorous activity index Health risk

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Evolution hydrothermal aging resistance mechanism study of zirconium and manganese doped CeO_(2)catalysts in soot catalytic combustion based on low Miller indices crystal surface effect

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Journal of Rare Earths 2024年第7期42卷 1272-1281,I0003页

作者： Zonglin Li Pan Wang Hong Ni Chengcheng Ao Lidong Zhang Hefeng Zhang Kai Li School of Automotive and Traffic Engineering Jiangsu UniversityZhenjiang212013China State Environmental Protection Key Laboratory of Vehicle Emission Control and Simulation Chinese Research Academy of Environmental ScienceBeijing100012China National Synchrotron Radiation Laboratory University of Science and Technology of ChinaHefei230026China

The thermogravimetric analysis(TGA)experiments were carried out to reveal the mechanism of Zr and Mn doping on catalytic activity of CeO_(2)catalyst both fresh and after hydrothermal aging,and the lattice morphology and valence changes were characterized by means of Brunauer-Emmett-Teller(BET)method,X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),and H_(2)-temperature programmed reduction(H_(2)-TPR).Density functional theory(DFT)and molecular thermodynamics calculations were applied to investigate the change in catalytic activity,crystal surface energy and crystal morphology caused by hydrothermal *** maximum reaction rate temperature of fresh Mn/CeO_(2)(389℃)is similar to that of CeO_(2)(371℃)and lower than that of Zr/CeO_(2)(447℃),but the catalytic performance of CeO_(2)decreases more severely after hydrothermal *** catalyst crystals show different degrees of crystal surface migration after hydrothermal aging,which leads to the reduction of Ce^(3+)/Ce^(4+) ratio and the active sites *** calculations indicate that the doping of Zr and Mn reduces the surface energy of the low Miller indices surface and increases the oxygen vacancy formation energy,leading to better thermal stability and lower catalytic *** Zr and Mn doping also changes the adsorption energy and Gibbs free energy of H_(2)O,which dominates the migration of(111)to(110)and(100)in the vapor *** crystal surface migration mechanism of CeO_(2)catalysts doped with Zr and Mn induced by H_(2)O molecules at high temperature obtained in this study can provide a valuable addition to the regeneration of CeO_(2)catalysts in the after-treatment systems of diesel engines.

关键词： Soot CeO_(2)-based catalyst CDPF Rare earth metal oxides DFT calculations

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Formation of organic chloride in the treatment of textile dyeing sludge by Fenton system

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Journal of environmental sciences 2023年第3期125卷 376-387页

作者： Xiaojun Lai Xun-an Ning Yang Li Nuoyi Huang Yaping Zhang Chenghai Yang Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control Institute of Environmental Health and Pollution ControlSchool of Environmental Science and EngineeringGuangdong University of TechnologyGuangzhou 510006China School of Environmental and Chemical Engineering Foshan UniversityFoshan 528000China

In the oxidation treatment of textile dyeing sludge,the quantitative and transformation laws of organic chlorine are not clear ***,this study mainly evaluated the treatment of textile dyeing sludge by Fenton and Fenton-like system from the aspects of the influence of Cl^(-),the removal of polycyclic aromatic hydrocarbons (PAHs) and organic carbon,and the removal and formation mechanism of organic *** results showed that the organic halogen in sludge was mainly hydrophobic organic chlorine,and the content of adsorbable organic chlorine (AOCl) was 0.30 mg/g (dry sludge).In the Fenton system with pH=3,500 mg/L Cl-,30 mmol/L Fe^(2+)and 30 mmol/L H_(2)O_(2),the removal of phenanthrene was promoted by chlorine radicals (·Cl),and the AOCl in sludge solid phase increased to 0.55 mg/g (dry sludge) at 30 *** to spectral analysis,it was found that ·Cl could chlorinate aromatic and aliphatic compounds (excluding PAHs) in solid phase at the same time,and eventually led to the accumulation of aromatic chlorides in solid *** the oxidation ability of Fenton system increased the formation of organic chlorines in liquid and solid *** weak acidity,the oxidation and desorption of superoxide anion promoted the removal and migration of PAHs and organic carbon in solid phase,and reduced the formation of total organic *** Fenton-like system dominated by nonhydroxyl radical could realize the mineralization of PAHs,organic carbon and organic chlorines instead of *** paper builds a basis for the selection of sludge conditioning methods.

关键词： Textile dyeing sludge Oxidation treatment Polycyclic aromatic hydrocarbons (PAHs) Adsorbable organic chlorine(AOCl) Chlorine radicals Superoxide anions

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Carbazole-Bearing Conjugated Microporous Polymer Electrodes for Uranium Extraction from Seawater with Good Anti-biofouling Feature

Chem and Bio Engineering

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Chem and Bio engineering 2025年第1期2卷 53-63页

作者： Zhang, Xinyue Lei, Xinying Sun, Hongfei Ke, Hanming Xu, Jingxuan Yang, Yuhao Zhang, Sai Wen, Tao Ji, Zhuoyu Wang, Xiangke MOE Key Laboratory of Resources and Environmental Systems Optimization College of Environmental Science and Engineering North China Electric Power University Beijing102206 China Beijing Key Laboratory of Environmental and Viral Oncology College of Chemistry and Life Science Beijing University of Technology Beijing100124 China

Emerging electrochemical uranium extraction from seawater offers a promising route for a sustainable fuel supply for nuclear reactor operation. In this work, we intentionally synthesized a conjugated microporous polymer (CMP) with π-conjugated skeletons and permanent porosity, which was induced by in situ electropolymerization on flexible carbon cloths, followed by postdecorating amidoxime groups to create functional materials (CMP-AO). Driven by an extra asymmetrical alternating current electrochemical extraction, the self-supporting and binder-free electrode is exceptionally capable of selectively and rapidly capturing U(VI) from simulated solution, affording an extraction capacity of ∼1806.4 mg/g without saturation. Experimental observation in combination with ex/in situ spectroscopy revealed that CMP-AO enabled surface selective binding sites (amidoxime groups) to U(VI), followed by electrocatalytic reduction (carbazole groups) to yield yellow precipitates (Na2O(UO3·H2O)x) via reversible electron transfer in the presence of sodium electrolyte. Furthermore, the integrating adsorption-electrocatalysis system achieved an extraction capacity of 18.8 mg/g in real seawater for 21 days and good antibiofouling abilities, validating its feasibility for practical application. © 2024 The Authors. Co-published by Zhejiang University and American Chemical Society.

关键词： Electropolymerization

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Renewable biosynthesis of isoprene from wastewater through a synthetic biology approach:the role of individual organic compounds

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Frontiers of environmental science & engineering 2024年第3期18卷 13-24页

作者： Min Yang Xianghui Li Weixiang Chao Xiang Gao Huan Wang Lu Lu State Key Laboratory of Urban Water Resource and Environment School of Civil and Environmental EngineeringHarbin Institute of TechnologyShenzhen 518055China Center for Materials Synthetic Biology CAS Key Laboratory of Quantitative Engineering Biology of CASShenzhen Institute of Synthetic BiologyShenzhen Institutes of Advanced TechnologyChinese Academic of ScienceShenzhen 518000China Institute of Urban Ecology and Environmental Technology School of Materials and Environmental EngineeringShenzhen Polytechnic UniversityShenzhen 518055China

The biosynthesis of isoprene offers a more sustainable alternative to fossil fuel-based approaches,yet its success has been largely limited to pure organic compounds and the cost remains a *** study proposes a waste-to-wealth strategy for isoprene biosynthesis utilizing genetically engineered *** bacteria to convert organic waste from real food *** impact of organic compounds present in wastewater on *** growth and isoprene production was systematically *** results demonstrated that with filtration pretreatment of wastewater,isoprene yield,and production achieved 115 mg/g COD and 7.1 mg/(L·h),***,even without pretreatment,isoprene yield only decreased by~24%,indicating promising ***,maltose,glycerol,and lactate are effective substrates for isoprene biosynthesis,whereas starch,protein,and acetate do not support *** *** optimum C/N ratio for isoprene production was found to be 8:***,augmenting essential nutrients in wastewater elevated the isoprene yield increased to 159 mg/g *** wastewater biosynthesis significantly reduced the cost(44%–53%decrease,p-value<0.01)and CO_(2)emission(46%–55%decrease,p-value<0.01)compared with both sugar fermentation and fossil fuel–based *** study introduced a more sustainable and economically viable approach to isoprene synthesis,offering an avenue for resource recovery from wastewater.

关键词： Wastewater Resource recovery Genetic engineering Biosynthesis Isoprene

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Research on IC-LOGO Extraction Algorithm Based on Deep Semantic Segmentation Network 6

Research on IC-LOGO Extraction Algorithm Based on Deep Seman...

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6th International Conference on Artificial Intelligence and Computer Applications, ICAICA 2024

作者： Zhao, Yue Guan, Mingfeng Luo, Jun Zhang, Qiuzhen China Electronic Product Reliability and Environmental Testing Research Institute Science and Technology on Reliability Physics and Application of Electronic Component Laboratory Guangzhou China China Electronic Product Reliability and Environmental Testing Research Institute Testing Center of Electronic Components Guangzhou China

ISBN: (纸本)9798350377255

Considering the characteristics of the logo and character areas being intertwined, along with the variability in size and irregularity in shape of logos within integrated circuit (IC) identification images, this paper propose a logo extraction algorithm based on a deep semantic segmentation network. Initially, preprocessing and data augmentation techniques are employed to facilitate the creation of an IC identification dataset, alongside the establishment of a semantic segmentation dataset specifically for the LOGO area. Subsequently, network models including DeepLabv3+, U-Net, PSPNet, and HRNet are trained and validated to identify the optimal model for IC logo extraction. The experimental results indicate that the deep semantic segmentation network demonstrates effective segmentation performance in the extraction of integrated circuit logos, with the HRNet model achieving high segmentation accuracy and an average intersection-over-union ratio of 80%. © 2024 IEEE.

关键词： Semantic Segmentation

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