检索结果-内蒙古大学图书馆

Nicotinamide adenine dinucleotide(NAD^(+))reduction enabled by an atomically precise Au-Ag alloy nanocluster

Nano Research 2023年第5期16卷 7770-7776页

作者： Ling Chen Yonglei Du Ying Lv Daoqing Fan Junfei Wu Lingbao Wu Mengting Cui Haizhu Yu Manzhou Zhu Department of Chemistry and Centre for Atomic Engineering of Advanced Materials Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Physical Science and Information Technology and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized MaterialsAnhui UniversityHefei 230601China Institute of Energy Hefei Comprehensive National Science CenterHefei 230601China

The redox property of the ultrasmall coinage nanoclusters(with several to tens of Au/Ag atoms)has elucidated the electrontransfer capacity of nanoclusters,has been successfully utilized in a variety of redox conversions(such as from CO_(2)to CO).Nevertheless,their biological applications are mainly restricted by the scarcity of atomically precise,water-soluble metal nanoclusters,the limited application(mainly on the decomposition of H_(2)O_(2)in these days).Herein,mercaptosuccinic acid(MSA)protected ultrasmall alloy AuAg nanoclusters were prepared,the main product was determined[Au_(3)Ag_(5)(MSA)_(3)]−by electrospray ionization mass spectrometry(ESI-MS).The clusters can not only mediate the decomposition of H_(2)O_(2)to generate hydroxyl radicals,but is also able to mediate the reduction of nicotinamide adenine dinucleotide(NAD)to its reduced form of *** is the first time that the atomically precise metal nanoclusters were used to mediate the coenzyme *** preliminary mechanistic insights imply the reaction to be driven by the hydrogen bonding between the carboxylic groups(on the surface of MSA)and the amino N–H bonds(on NAD).In this context,the presence of the carboxylic groups,the sub-nanometer size regime(~1 nm),the synergistic effect of the Au-Ag clusters are pre-requisite to the NAD reduction.

关键词： redox-activity alloy AuAg nanocluster nicotinamide adenine dinucleotide(NAD)reduction synergistic effect size-effect

来源：评论

学校读者我要写书评

暂无评论

Hybrid ionic/electronic interphase enabling uniform nucleation and fast diffusion kinetics for stable lithium metal anode

引用

Chinese Chemical Letters 2024年第2期35卷 626-633页

作者： Lun Li Pengxia Ji Meng Huang Zixin Zhang Hong Wang Francis Verpoort Jinlong Yang Daping He State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Guangdong Research Center for Interfacial Engineering of Functional Materials College of Materials Science and EngineeringShenzhen UniversityShenzhen 518060China Sanya Science and Education Innovation Park of Wuhan University of Technology Sanya 572000China Hubei Engineering Research Center of RF-Microwave Technology and Application Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430070China

Lithium(Li)dendrite issue,which is usually caused by inhomogeneous Li nucleation and fragile solid electrolyte interphase(SEI),impedes the further development of high-energy Li metal ***,the integrated construction of a high-stable SEI layer that can regulate uniform nucleation and facilitate fast Li-ion diffusion kinetics for Li metal anode still falls ***,we designed an artificial SEI with hybrid ionic/electronic interphase to regulate Li deposition by in-situ constructing metal Co clusters embedded in LiF *** generated Co and LiF both enable fast Li-ion diffusion kinetics,meanwhile,the lithiophilic properties of Co clusters can serve as Li-ion nucleation sites,thereby contributing to uniform Li nucleation and non-dendritic *** a result,a dendrite-free Li deposition with a low overpotential(16.1 mV)is achieved,which enables an extended lifespan over 750 h under strict *** full cells with high-mass-loading LiFePO_(4)(11.5 mg/cm^(2))as cathodes exhibit a remarkable rate capacity of 84.1 mAh/g at 5 C and an improved cycling performance with a capacity retention of 96.4%after undergoing 180 cycles.

关键词： Lithium metal anode Hybrid ionic/electronic interphase Solid electrolyte interphase Fast diffusion kinetics Dendritic growth of lithium

来源：评论

学校读者我要写书评

暂无评论

Tuning the exciton binding energy of covalent organic frameworks for efficient photocatalysis

引用

Chinese Chemical Letters 2024年第2期35卷 577-583页

作者： Zhangjie Gu Zhen Shan Yulan Wang Jinjian Wang Tongtong Liu Xiaoming Li Zhiyang Yu Jian Su Gen Zhang Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education School of Chemistry and Chemical EngineeringNanjing University of Science and TechnologyNanjing 210094China State Key Laboratory of Photocatalysis on Energy and Environment College of ChemistryFuzhou UniversityFuzhou 350002China MIIT Key Laboratory of Advanced Display Material and Devices School of Materials Science and EngineeringNanjing University of Science and TechnologyNanjing 210094China Key Laboratory of Preclinical Study for New Drugs of Gansu Province School of Basic Medical SciencesLanzhou UniversityLanzhou 730000China

Owing to the large exciton binding energy(>100 meV)of most organic materials,the process of exciton dissociation into free electrons and holes is seriously hindered,which plays a key role in the photocatalytic *** this study,a series of chalcogen(S,Se)-substituted mesoporous covalent organic frameworks(COFs)have been synthesized for enhanced photocatalytic organic *** measurements indicate that the introduction of semi-metallic Se atom and the enlargement of conjugation degree can not only reduce the exciton binding energy accelerating the charge separation,but also reduce the band gap of *** a result,the COF-NUST-36 with the lowest exciton binding energy(39.5 meV)shows the highest photocatalytic performance for selective oxidation of amines(up to 98%*** 97.5%Sel.).This work provides a feasible method for designing COFs with high photocatalytic activity by adjusting exciton binding energy.

关键词： Covalent organic frameworks Exciton binding energy Atom substitution Extended conjugation Photocatalysis

来源：评论

学校读者我要写书评

暂无评论

Fluorogenic sensing of amorphous aggregates,amyloid fibers,and chaperone activity via a near-infrared aggregation-induced emission-active probe

Aggregate

引用

Aggregate 2024年第1期5卷 309-320页

作者： Wei He Yuanyuan Yang Yuhui Qian Zhuoyi Chen Yongxin Zheng Wenping Zhao Chenxu Yan Zhiqian Guo Shu Quan State Key Laboratory of Bioreactor Engineering Shanghai Collaborative Innovation Center for Biomanufacturing(SCICB)East China University of Science and TechnologyShanghaiChina Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering Shanghai Key Laboratory of Functional Materials ChemistryFrontiers Science Center for Materiobiology and Dynamic ChemistryInstitute of Fine ChemicalsSchool of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghaiChina Shanghai Frontiers Science Center of Optogenetic Techniques for Cell Metabolism East China University of Science and TechnologyShanghaiChina

The presence of protein aggregates in numerous human diseases underscores the significance of detecting these aggregates to comprehend disease mechanisms and develop novel therapeutic approaches for combating these *** the development of various biosensors and fluorescent probes that selectively target amyloid fibers or amorphous aggregates,there is still a lack of tools capable of simultaneously detecting both types of ***,we demonstrate the quantitative discernment of amorphous aggregates by QM-FN-SO3,an aggregationinduced emission(AIE)probe initially designed for detecting amyloid *** probe easily penetrates the membranes of the widely-used prokaryotic model organism Escherichia coli,enabling the visualization of both amorphous aggregates and amyloid fibers through near-infrared ***,the probe exhibits sensitivity in distinguishing the varying aggregation propensities of proteins,regardless of whether they form amorphous aggregates or amyloid fibers in *** properties contribute to the successful application of the QM-FN-SO3 probe in the subsequent investigation of the antiaggregation activities of two outer membrane protein(OMP)chaperones,both in vitro and in their physiological ***,our work introduces a near-infrared fluorescent chemical probe that can quantitatively detect amyloid fibers and amorphous aggregates with high sensitivity in vitro and in ***,it demonstrates the applicability of the probe in chaperone biology and its potential as a high-throughput screening tool for protein aggregation inhibitors and folding factors.

关键词： aggregation-induced emission fluorescence molecular chaperone protein aggregation

来源：评论

学校读者我要写书评

暂无评论

Temperature-adaptive metasurface radiative cooling device with excellent emittance and low solar absorptance for dynamic thermal regulation

引用

advanced Photonics 2024年第4期6卷 70-82页

作者： Junlin Yang Qianyi Li Shiqiao Liu Debao Fang Jingyao Zhang Haibo Jin Jingbo Li Beijing Institute of Technology School of Materials Science and EngineeringBeijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green ApplicationsBeijingChina

Passive radiative cooling is a promising passive cooling technology that emits heat to deep space without energy ***,the persistent challenge of overcooling in static radiative techniques has raised *** a desirable solution is suggested based on vanadium dioxide(VO_(2))in the form of a Fabry-Perot(F-P)resonant cavity,the inherent contradiction between desired high emissivity(ε)and low solar absorptance(α_(sol))remains a notable ***,we employed a simple mask-filling technique to develop a temperature-adaptive metasurface radiative cooling device(ATMRD)for dynamic thermal *** and experimental results substantially evidenced that multiple localized polariton resonances were induced by the VO_(2)metasurface,significantly enhancing the thermal emittance of the *** engineered ATMRD achieved an amazing switch of the atmospheric window emittance from 0.13 to 0.85 when the surface temperature exceeds a pre-set transition temperature,accompanied by a commendableα_(sol)of 27.71%.The mechanism of multiple localized polariton resonances is discussed in detail to understand the enhanced performance based on the investigation of the relationship between the metasurface structure and multiple localized polariton *** demonstrate an efficient smart radiative technique achieved by a simple micro/nanoprocess and,most importantly,contribute a valuable reference for the design of radiative devices,which is crucial in various areas such as passive cooling,smart windows,multifunctional electromagnetic response,and space application technologies.

关键词： dynamic radiative cooling metasurface vanadium dioxide emittance plasmon resonance

来源：评论

学校读者我要写书评

暂无评论

advanced 3D-printed antibacterial nano 58S bioglass/AgNPs/CeO2-based scaffolds for bone tissue engineering

引用

Ceramics International 2025年第15期51卷 20939-20953页

作者： Singh, Indrajeet Kong, Ing Viswakarma, Ashok Balani, Kantesh Advanced Polymer and Composite Materials Laboratory Department of Engineering School of Computing Engineering and Mathematical Sciences La Trobe University BendigoVIC3550 Australia Department of Materials Science and Engineering Indian Institute of Technology Kanpur208016 India Department of Mechanical Engineering Indian Institute of Technology Kanpur208016 India

58S bioglass (BG) has been considered an effective bioceramic in bone tissue engineering due to its good osteoinductive and osteoconductive properties;however, its poor antibacterial and printing properties remain a challenge in the development of ideal patient-specific, fully interconnected, bone-like scaffolds. To address this issue, this study presents novel 3D-printed BG/AgNPs/CeO2 (BGAC3D) composite scaffolds. These scaffolds exhibit a fully interconnected pore network (≈99 %) with a porosity of ≈64 % and optimally designed pore and strut sizes of 404 ± 15 μm and 394 ± 30 μm, respectively, making them suitable for bone healing applications. Adding AgNPs and ceria nanoparticles significantly increased the shear-thinning properties of Pluronic F-127/BG/AgNPs/CeO2-based ink, as compared to Pluronic F-127/BG-based ink. As a result, BGAC3D scaffold showed improved dimensional accuracy during printing relative to pristine BG. Nanoindentation studies revealed substantial increase in the mechanical properties of BGAC3D scaffolds, with elastic modulus, hardness, and compressive strength showing enhancement of 76 % (57.9 ± 8 GPa), 24 % (3.1 ± 1 GPa), and 275 % (1.5 ± 0.4 MPa), respectively. The antibacterial properties of BGAC3D scaffolds were investigated using disc diffusion and bacterial adhesion assays, which demonstrated an exceptional bactericidal efficacy of 99.3 % against Escherichia coli (E. coli) and 99.4 % against Staphylococcus aureus (S. aureus) compared to pristine BG. The cytocompatibility of the scaffolds was assessed using resazurin assays with mouse BMSCs and MTT assays with mouse fibroblasts, revealing enhanced cell viability for the BGAC3D composition compared to BG. Additionally, both BG and BGAC3D composites showed similar apatite mineralization on their surfaces, as observed under a scanning electron microscope. These findings indicate that BGAC3D scaffolds possess the necessary mechanical, antibacterial, and cytocompatibility properties, making th

关键词： Escherichia coli

来源：评论

学校读者我要写书评

暂无评论

Mechanical enhancement and weakening in Mo_(6)S_(6)nanowire by twisting

引用

Chinese Physics B 2023年第4期32卷 534-542页

作者：徐克林演文石桥付越群杨毅张志森吴建洋 Department of Physics Research Institute for Biomimetics and Soft MatterJiujiang Research Institute and Fujian Provincial Key Laboratory for Soft Functional Materials ResearchXiamen UniversityXiamen 361005China Jiangsu Key Laboratory of Advanced Food Manufacturing Equipment and Technology Jiangnan UniversityWuxi 214122China NTNU Nanomechanical Laboratory Norwegian University of Science and TechnologyTrondheim 7491Norway

The torsional,bending and tensile mechanical properties of Mo_(6)S_(6)nanowire are examined by molecular dynamics(MD)simulations with a first-principles-based reactive force field(ReaxFF).It is found that Mo_(6)S_(6)nanowire shows unique mechanical properties such as high torsional and bending flexibility,high Young's modulus and strength,and negative Poisson's *** Mo_(6)S_(6)nanowire can be strengthened or weakened via twisting,depending on the twist *** Mo_(6)S_(6)nanowire with a slight twist angle shows brittle failure,whereas it with a large twist angle exhibits ductile failure and necking *** Mo_(6)S_(6)nanowires show a crossover in the negative Poisson's ratio at critical strains,that is,Poisson's ratio first decreases but then increases,with a minimum value down to around-0.8 at the strain of 0.01 as the twist angle is 21.0°/*** negative Poisson's ratio and the crossover are explained by the bond transform that makes zero angles to the wire cross-section.

关键词： Mo_(6)S_(6)nanowire mechanical properties twisting negative Poisson's ratio

来源：评论

学校读者我要写书评

暂无评论

Anion-templated Self-assembly for the Preparation of Silver-t-butylthiolate Clusters

引用

Chinese Journal of Structural Chemistry 2022年第3期41卷 100-107,I0010页

作者： JIN Jun-Ling SHEN Yang-Lin MI Li-Wei XIE Yun-Peng LU Xing Henan Key Laboratory of Functional Salt Materials Center for Advanced Materials ResearchZhongyuan University of TechnologyZhengzhou 450007China College of Materials Engineering Henan International Joint Laboratory of Rare Earth Composite MaterialsHenan University of EngineeringZhengzhou 451191China State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

Silver thiolate polymers are intercepted to form different structural fragments when reacting with variant solubilizing reagents,which usually serve as the starting point for the preparation of ***,such a process is still far from ***,we report the controlled synthesis of silver-t-butylthiolate clusters from reactions of polymeric[Ag^(t)BuS]n and suitable templates in the presence of solubilizing reagents to offer a detailed look at the mechanism of cluster’s *** the provided solubilizing reagents have weak coordina-tion ability,such as O-or N-donating ligands,the obtained polymeric compound retains the linear structure pat-tern that S and Ag atoms are arranged *** extra templates NO_(3)^(−)and CO_(3)^(2−)are applied,the disk-like clusters Ag_(19)and Ag_(20)are constructed with the same[Ag^(t)BuS]_(5)circles that may directly cyclize from the linear[Ag^(t)BuS]_(n)*** contrast,(EtO)_(2)PS_(2)^(−)and(iPrO)_(2)PS_(2)^(−)anions have large size and strong coordination abil-ity rendering the structure of the polymer completely *** extremely short[Ag^(t)BuS]n pieces with silver ions and solubilizing ligands assemble around the templates V_(2)O_(7)^(4−)and W_(2)O_(9)^(4−),leading to the formation of clusters Ag_(22)and Ag_(24).

关键词： silver cluster X-ray crystal structure silver thiolate polymer self-assembly

来源：评论

学校读者我要写书评

暂无评论

Construction of a High-Quality Organic-Inorganic Hybrid Heterostructure and Its Photo-response Performance

引用

Chinese Journal of Chemistry 2023年第1期41卷 50-56页

作者： Yadan Zhang Guanghua Yu Di Xue Jie Lu Xing Meng Yao Yin Qi Wang Zi Wang Lizhen Huang Lifeng Chi Institute of Functional Nano&Soft Materials(FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials&DevicesSoochow University199 Ren'ai RoadSuzhouJiangsu 215123China Gusu Laboratory of Materials 388 Ruoshui RoadSuzhouJiangsu 215123China Macao Institute of Materials Science and Engineering(MIMSE) MUST-SUDA Joint Research Center for Advanced Functional MaterialsMacao University of Science and TechnologyTaipa 999078MacaoChina

The combination of metal oxide and organic semiconductor for constructing organic-inorganic hybrid heterostructure is promising to offer unique optoelectronic ***,the distinct difference in electron structure and processing technology of the two types of materials makes it usually difficult to fully deliver their complementary ***,we report the construction of a high quality organic/In_(2)O_(3) hybrid heterostructure presenting a good ambipolar transport with average electron mobility>1 cm^(2)V^(-1)·s^(-1) and hole mobility up to 0.4 cm^(2)·V^(-1)·s^(-1),respectively,together with a high-gain *** addition,the incorporation with organic film on top of In_(2)O_(3) remarkably reduces the dark current,enabling the realization of high photoconductivity response with photo-sensitivity of two magnitudes higher than that of pure *** photoconductor and phototransistor of the hybrid structure demonstrate high photoresponsivity>10^(3) AW^(-1) and detectivity up to 10^(14) Jones,demonstrating the promising functionality of such a high quality hybrid heterostructure.

关键词： Sol-gel process Thin films Semiconductors Phthalocyanines Hybrid heterostructure

来源：评论

学校读者我要写书评

暂无评论

Highly conductive calcium ion-reinforced MXene/sodium alginate aerogel meshes by direct ink writing for electromagnetic interference shielding and Joule heating

引用

Journal of Materials science & technology 2023年第4期135卷 213-220页

作者： Cheng-Zhang Qi Xinyu Wu Ji Liu Xin-Jie Luo Hao-Bin Zhang Zhong-Zhen Yu Beijing Key Laboratory of Advanced Functional Polymer Composites Beijing University of Chemical TechnologyBeijing 100029China State Key Laboratory of Organic-Inorganic Composites College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China School of Chemistry CRANN and AMBERTrinity College DublinD2DublinIreland

Although MXene sheets possess high electrical conductivity and rich surface chemistry and are well suit-able for fabricating electrically conductive nanocomposites for electromagnetic interference(EMI)shield-ing applications,it remains challenging for MXene nanocomposites to achieve tunable EMI shielding per-formances and customized ***,an aqueous MXene/sodium alginate ink is developed to print aerogel meshes with customized geometries using a direct ink writing *** ion-enhanced strategy is proposed to reinforce the printed aerogel meshes by multi-level *** resultant 3D printed aerogel mesh exhibits an ultrahigh electrical conductivity of 2.85×10^(3)S m^(−1),outstanding mechanical properties,and excellent structural stability in wet *** importantly,a wide range of tunable EMI shielding efficiencies from 45 to 100 dB is achieved by the structural design of the 3D printed ion-enhanced MXene/sodium alginate aerogel *** a Joule heater,in addition,the printed aerogel meshes can achieve a wide temperature range of 40-135℃at low driving *** work demonstrates a direct ink writing approach for the fabrication of ion-enhanced MXene/sodium al-ginate aerogel meshes with tunable EMI shielding properties and multi-functionalities for applications in many scenarios.

关键词： MXene inks Aerogels Electromagnetic interference shielding Direct ink writing Joule heating

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：