Three zinc(II) complexes of the amino acid Schiff base were synthesized by the one step reaction of amino acid with aldehyde, zinc acetate in solvent-freeThe compositions and structures of the complexes were character...
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Three zinc(II) complexes of the amino acid Schiff base were synthesized by the one step reaction of amino acid with aldehyde, zinc acetate in solvent-freeThe compositions and structures of the complexes were characterized by elemental analyses, FTIR, XRD, TG-DSCThe compositions of the complexes are Zn L·n H2O(L = sal-leu, sal-ala, van-leu;sal = salicylaldehyde;van = vanillic aldehyde;leu = leucine;ala = alanine)Infrared spectra of the complexes indicate that the Schiff base ligands are formed, zinc ion is coordinated to the Schiff base ligands as terdentate with O, O and N donors from carboxylic, phenolic and imino groups respectively, the coordination numbers of zinc ion is fourThe possible pyrolysis reactions in the thermal decomposition process of the complexes, the experimental and calculated percentage mass loss are also given.
Three zinc(Ⅱ) complexes of the amino acid Schiff base were synthesized by the one step reaction of amino acid with aldehyde, zinc acetate in solvent-free. The compositions and structures of the complexes were charact...
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Three zinc(Ⅱ) complexes of the amino acid Schiff base were synthesized by the one step reaction of amino acid with aldehyde, zinc acetate in solvent-free. The compositions and structures of the complexes were characterized by elemental analyses, FTIR, XRD, TG-DSC. The compositions of the complexes are Zn L·n H2O(L = sal-leu, sal-ala, van-leu;sal = salicylaldehyde;van = vanillic aldehyde;leu = leucine;ala = alanine). Infrared spectra of the complexes indicate that the Schiff base ligands are formed, zinc ion is coordinated to the Schiff base ligands as terdentate with O, O and N donors from carboxylic, phenolic and imino groups respectively, the coordination numbers of zinc ion is four. The possible pyrolysis reactions in the thermal decomposition process of the complexes, the experimental and calculated percentage mass loss are also given.
With the purpose of providing assistive technology for the communication impaired, we propose a new approach for speech prostheses using vowel speech imagery. Using a hierarchical Bayesian method, electroencephalograp...
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Efficient white-polymer-light-emitting devices (WPLEDs) have been fabricated with a single emitting layer containing a hole-transporting host polymer,poly(N-vinylcarbzole),and an electron-transporting auxiliary,1,3-bi...
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Efficient white-polymer-light-emitting devices (WPLEDs) have been fabricated with a single emitting layer containing a hole-transporting host polymer,poly(N-vinylcarbzole),and an electron-transporting auxiliary,1,3-bis[(4-tert-butylphenyl)-1,3,4-oxadiazolyl]-phenylene,codoped with two phosphorescent dyes:Iridium(III)bis (2-(4,6-difluorophenyl)-pyridinato-N,C2') picolinate (FIrpic) and home-made Ir-G2 for blue and red emission,*** the structure of ITO/PEDOT:PSS 4083(40 nm)/emission layer(80 nm)/Ba(4 nm)/Al(120 nm),the device showed a maximal luminous efficiency (LE) of 13.5 cd A-1(corresponding to an external quantum efficiency (EQE) of 6.8%),and a peak power efficiency (PE) of 6.5 lm W-1 at 6.0 ***,the device exhibited pure white emission with Commission Internationale de l'Eclairage (CIE) coordinates of (0.34,0.35) at a current density of 12 mA cm-2,which is very close to the equi-energy white point with CIE coordinates of (0.33,0.33).The device performance can be further optimized when more balanced hole/electron injection is achieved by incorporating a lower conducting type anode buffer layer (PEDOT:PSS) and incorporating poly[(9,9-bis(3'-(N,N-dimethylamino)propyl)-2,7-fluorenene)-alt-2,7-(9,9-dioctyfluorene)] (PFN) as an electron injection layer at the *** optimized device showed an LE of 24.6 cd A-1 (with an EQE of 14.1%),while the peak power efficiency reached 12.66 lm ***,the WPLEDs showed good electroluminescence (EL) stability over a wide range of operating current density and luminance.
The concept of introducing self-healing capabilities in polymer materials and systems has been based on mimicking biological self-healing materials and systems,for example,materials like proteins have phenomenal capab...
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The concept of introducing self-healing capabilities in polymer materials and systems has been based on mimicking biological self-healing materials and systems,for example,materials like proteins have phenomenal capabilities in self-healing damaged biological *** work has been extended to investigate self-healing capabilities of fibre reinforced epoxy *** epoxy and mercaptan healing agents were incorporated into a glass fibre reinforced epoxy matrix to produce a polymer composite capable of *** specimens containing the microencapsulated epoxy and mercaptan healing agents did gain excellent strength and achieved a healing efficiency up to 140%.
Highly oriented titanate nanotube (TNT) film was successfully synthesized by a simple electrophoretic deposition (EPD) method without any hard templates and surfactants. This oriented films adequately utilized the exc...
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In this paper, to further explore the excellent emission properties of rare earth boride cathode, herein we present the synthesis, characterization and properties of polycrystalline Nd 1-x Gd x B 6 (x = 0, 0.6, 0.8) b...
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In this paper, to further explore the excellent emission properties of rare earth boride cathode, herein we present the synthesis, characterization and properties of polycrystalline Nd 1-x Gd x B 6 (x = 0, 0.6, 0.8) bulk via arc plasma and reactive SPS.
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