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All-Inorganic Quantum-Dot LEDs Based on a Phase-Stabilized α-CsPbI3Perovskite

Angewandte Chemie 2021年第29期133卷

作者： Ya-Kun Wang Fanglong Yuan Yitong Dong Jiao-Yang Li Andrew Johnston Bin Chen Makhsud I. Saidaminov Chun Zhou Xiaopeng Zheng Yi Hou Koen Bertens Hinako Ebe Dongxin Ma Zhengtao Deng Shuai Yuan Rui Chen Laxmi Kishore Sagar Jiakai Liu James Fan Peicheng Li Xiyan Li Yuan Gao Man-Keung Fung Zheng-Hong Lu Osman M. Bakr Liang-Sheng Liao Edward H. Sargent Department of Electrical and Computer Engineering University of Toronto 10 King's College Road Toronto Ontario M5S 3G4 Canada Institute of Functional Nano & Soft Materials (FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices Soochow University Suzhou Jiangsu 215123 P. R. China Department of Materials Science and Engineering University of Toronto 184 College Street Toronto Ontario M5S 3G4 Canada Present address: Department of Chemistry and Electrical & Computer Engineering Centre for Advanced Materials and Related Technologies (CAMTEC) University of Victoria Victoria British Columbia Canada Division of Physical Sciences and Engineering King Abdullah University of Science and Technology (KAUST) Thuwal 23955-6900 Saudi Arabia College of Engineering and Applied Sciences State Key Laboratory of Analytical Chemistry for Life Science Nanjing University Nanjing Jiangsu 210023 P. R. China Department of Electrical and Electronic Engineering Southern University of Science and Technology Shenzhen Guangdong 518055 P. R. China

The all-inorganic nature of CsPbI 3 perovskites allows to enhance stability in perovskite devices. Research efforts have led to improved stability of the black phase in CsPbI 3 films; however, these strategies—including strain and doping—are based on organic-ligand-capped perovskites, which prevent perovskites from forming the close-packed quantum dot (QD) solids necessary to achieve high charge and thermal transport. We developed an inorganic ligand exchange that leads to CsPbI 3 QD films with superior phase stability and increased thermal transport. The atomic-ligand-exchanged QD films, once mechanically coupled, exhibit improved phase stability, and we link this to distributing strain across the film. Operando measurements of the temperature of the LEDs indicate that KI-exchanged QD films exhibit increased thermal transport compared to controls that rely on organic ligands. The LEDs exhibit a maximum EQE of 23 % with an electroluminescence emission centered at 640 nm (FWHM: ≈31 nm). These red LEDs provide an operating half-lifetime of 10 h (luminance of 200 cd m −2 ) and an operating stability that is 6× higher than that of control devices.

关键词： CsPbI3 quantum dots inorganic ligand exchange perovskite LEDs pure red emission strain engineering

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Precise Control of Selenium functionalization in Non-Fullerene Acceptors Enabling High-Efficiency Organic Solar Cells

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Angewandte Chemie 2022年第46期134卷

作者： Dr. Jianquan Zhang Siwei Luo Heng Zhao Xiaoyun Xu Xinhui Zou Ao Shang Jiaen Liang Dr. Fujin Bai Dr. Yuzhong Chen Prof. Kam Sing Wong Prof. Zaifei Ma Prof. Wei Ma Prof. Huawei Hu Prof. Yiwang Chen Prof. He Yan State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and Engineering Donghua University Shanghai 201620 China Department of Chemistry Guangdong-Hong Kong-Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials Energy Institute and Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction Hong Kong University of Science and Technology Clear Water Bay Kowloon Hong Kong 999077 China State Key Laboratory for Mechanical Behavior of Materials Xi'an Jiaotong University Xi'an 710049 Shannxi Province China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Center for Advanced Low-dimension Materials College of Materials Science and Engineering Donghua University Shanghai 201620 China Department of Physics Hong Kong University of Science and Technology Clear Water Bay Kowloon Hong Kong 999077 China Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education/National Engineering Research Center for Carbohydrate Synthesis Jiangxi Normal University 99 Ziyang Avenue Nanchang 330022 China College of Chemistry/Institute of Polymers and Energy Chemistry (IPEC) Nanchang University 999 Xuefu Avenue Nanchang 330031 Jiangxi Province China Institute of Polymer Optoelectronic Materials and Devices State Key Laboratory of Luminescent Materials and Devices South China University of Technology Guangzhou 510640 Guangdong Province China

Central π-core engineering of non-fullerene small molecule acceptors (NF-SMAs) is effective in boosting the performance of organic solar cells (OSCs). Especially, selenium (Se) functionalization of NF-SMAs is considered a promising strategy but the structure-performance relationship remains unclear. Here, we synthesize two isomeric alkylphenyl-substituted selenopheno[3,2-b]thiophene-based NF-SMAs named mPh4F-TS and mPh4F-ST with different substitution positions, and contrast them with the thieno[3,2-b]thiophene-based analogue, mPh4F-TT. When placing Se atoms at the outer positions of the π-core, mPh4F-TS shows the most red-shifted absorption and compact molecular stacking. The PM6 : mPh4F-TS devices exhibit excellent absorption, high charge carrier mobility, and reduced energy loss. Consequently, PM6 : mPh4F-TS achieves more balanced photovoltaic parameters and yields an efficiency of 18.05 %, which highlights that precisely manipulating selenium functionalization is a practicable way toward high-efficiency OSCs.

关键词： Acceptor Core Engineering Non-Fullerene Selenium functionalization Solar Cell

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Dynamic chloride ion adsorption on single iridium atom boosts seawater oxidation catalysis

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Nature communications 2024年第1期15卷 1973页

作者： Xinxuan Duan Qihao Sha Pengsong Li Tianshui Li Guotao Yang Wei Liu Ende Yu Daojin Zhou Jinjie Fang Wenxing Chen Yizhen Chen Lirong Zheng Jiangwen Liao Zeyu Wang Yaping Li Hongbin Yang Guoxin Zhang Zhongbin Zhuang Sung-Fu Hung Changfei Jing Jun Luo Lu Bai Juncai Dong Hai Xiao Wen Liu Yun Kuang Bin Liu Xiaoming Sun State Key Laboratory of Chemical Resource Engineering Beijing Advanced Innovation Center for Soft Matter Science and Engineering College of Chemistry Beijing University of Chemical Technology Beijing 100029 PR China. School of Chemistry Chemical Engineering and Biotechnology Nanyang Technological University Singapore 637459 Singapore. Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Colloid Interface and Chemical Thermodynamics Institute of Chemistry Chinese Academy of Sciences Beijing 100190 PR China. Ocean Hydrogen Energy R&D Center Research Institute of Tsinghua University in Shenzhen Shenzhen 518057 PR China. State Key Lab of Organic-Inorganic Composites College of Chemical Engineering Beijing University of Chemical Technology 100029 Beijing PR China. Energy & Catalysis Center School of Materials Science & Engineering Beijing Institute of Technology Beijing 100081 PR China. Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei 230026 PR China. Beijing Synchrotron Radiation Facility Institute of High Energy Physics Chinese Academy of Sciences 100049 Beijing PR China. Department of Chemistry Tsinghua University 100084 Beijing PR China. Department of Materials Science and Engineering City University of Hong Kong Hong Kong SAR 999077 PR China. College of Energy Shandong University of Science and Technology Tsingtao 266590 PR China. Beijing Key Laboratory of Energy Environmental Catalysis Beijing University of Chemical Technology 100029 Beijing PR China. Department of Applied Chemistry and Center for Emergent Functional Matter Science National Yang Ming Chiao Tung University Hsinchu 300 Taiwan. School of Materials Science and Engineering Tianjin Key Lab of Photoelectric Materials & Devices Tianjin University of Technology Tianjin 300384 PR China. ShenSi Lab Shenzhen Institute for Advanced Study University of Electronic Science and Technology of China Shen

Seawater electrolysis offers a renewable, scalable, and economic means for green hydrogen production. However, anode corrosion by Cl pose great challenges for its commercialization. Herein, different from conventional catalysts designed to repel Cl adsorption, we develop an atomic Ir catalyst on cobalt iron layered double hydroxide (Ir/CoFe-LDH) to tailor Cl adsorption and modulate the electronic structure of the Ir active center, thereby establishing a unique Ir-OH/Cl coordination for alkaline seawater electrolysis. Operando characterizations and theoretical calculations unveil the pivotal role of this coordination state to lower OER activation energy by a factor of 1.93. The Ir/CoFe-LDH exhibits a remarkable oxygen evolution reaction activity (202 mV overpotential and TOF = 7.46 O s) in 6 M NaOH+2.8 M NaCl, superior over Cl-free 6 M NaOH electrolyte (236 mV overpotential and TOF = 1.05 O s), with 100% catalytic selectivity and stability at high current densities (400-800 mA cm) for more than 1,000 h.

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Electronic Configuration Tuning of Centrally Extended Non-Fullerene Acceptors Enabling Organic Solar Cells with Efficiency Approaching 19 %

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Angewandte Chemie 2023年第42期135卷

作者： Tainan Duan Wanying Feng Yulu Li Zhixiang Li Zhe Zhang Huazhe Liang Hongbin Chen Cheng Zhong Seonghun Jeong Changduk Yang Shanshan Chen Shirong Lu Oleg A. Rakitin Chenxi Li Xiangjian Wan Bin Kan Yongsheng Chen State Key Laboratory and Institute of Elemento-Organic Chemistry The Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials Renewable Energy Conversion and Storage Center (RECAST) College of Chemistry Nankai University Tianjin 300071 China Chongqing Institute of Green and Intelligent Technology Chongqing School University of Chinese Academy of Sciences (UCAS Chongqing) Chinese Academy of Sciences Chongqing 400714 China Hubei Key Laboratory on Organic and Polymeric Opto-electronic Materials College of Chemistry and Molecular Sciences Wuhan University Wuhan 430072 China Department of Energy Engineering School of Energy and Chemical Engineering Perovtronics Research Center Low Dimensional Carbon Materials Center Ulsan National Institute of Science and Technology (UNIST) Ulsan 44919 Republic of Korea Key Laboratory of Low-grade Energy Utilization Technologies and Systems CQU-NUS Renewable Energy Materials & Devices Joint Laboratory School of Energy & Power Engineering Chongqing University Chongqing 400044 China N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences 47 Leninsky Prospekt 119991 Moscow Russia School of Materials Science and Engineering National Institute for Advanced Materials Nankai University Tianjin 300350 China

In the molecular optimizations of non-fullerene acceptors (NFAs), extending the central core can tune the energy levels, reduce nonradiative energy loss, enhance the intramolecular (donor-acceptor and acceptor-acceptor) packing, facilitate the charge transport, and improve device performance. In this study, a new strategy was employed to synthesize acceptors featuring conjugation-extended electron-deficient cores. Among these, the acceptor CH-BBQ, embedded with benzobisthiadiazole, exhibited an optimal fibrillar network morphology, enhanced crystallinity, and improved charge generation/transport in blend films, leading to a power conversion efficiency of 18.94 % for CH-BBQ-based ternary organic solar cells (OSCs; 18.19 % for binary OSCs) owing to its delicate structure design and electronic configuration tuning. Both experimental and theoretical approaches were used to systematically investigate the influence of the central electron-deficient core on the properties of the acceptor and device performance. The electron-deficient core modulation paves a new pathway in the molecular engineering of NFAs, propelling relevant research forward.

关键词： Electron-Deficient Central Core Electronic Configuration Tuning Non-Fullerene Acceptor Organic Solar Cells Molecular Dynamics Simulations

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Preserving cognitive function in patients with Alzheimer's disease:The Alzheimer's disease neuroprotection research initiative(ADNRI)

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Neuroprotection 2023年第2期1卷 84-98页

作者： Jie Liu Heleen van Beusekom Xian-Le Bu Gong Chen Paulo Henrique Rosado de Castro Xiaochun Chen Xiaowei Chen Andrew N.Clarkson Tracy D.Farr Yuhong Fu Jianping Jia Jukka Jolkkonen Woojin Scott Kim Paula Korhonen Shen Li Yajie Liang Guang-Hui Liu Guiyou Liu Yu-Hui Liu Tarja Malm Xiaobo Mao Joaquim Miguel Oliveira Mike M.Modo Pedro Ramos-Cabrer Karsten Ruscher Weihong Song Jun Wang Xuanyue Wang Yun Wang Haitao Wu Lize Xiong Yi Yang Keqiang Ye Jin-Tai Yu Xin-Fu Zhou Marietta Zille Colin L.Masters Piotr Walczak Boltze Johannes Xunming Ji Yan-Jiang Wang Department of Neurology Daping HospitalThird Military Medical UniversityChongqingChina Chongqing Key Laboratory of Ageing and Brain Diseases ChongqingChina Division of Experimental Cardiology Department of CardiologyErasmus MCUniversity Medical CenterRotterdamThe Netherlands Institute of Brain and Intelligence Third Military Medical UniversityChongqingChina Guangdong-HongKong-Macao Institute of CNS Regeneration(GHMICR) Jinan UniversityGuangzhouGuangdongChina Institute of Biomedical Sciences Federal University of Rio de JaneiroRio de JaneiroRio de JaneiroBrazil Fujian Key Laboratory of Molecular Neurology Department of Neurology and GeriatricsFujian Institute of GeriatricsFujian Medical University Union HospitalInstitute of NeuroscienceFujian Medical UniversityFuzhouFujianChina Guangyang Bay Laboratory Chongqing Institute for Brain and IntelligenceChongqingChina Center for Excellence in Brain Science and Intelligence Technology Chinese Academy of SciencesShanghaiChina Department of Anatomy Brain Health Research Centre and Brain Research New ZealandUniversity of OtagoDunedinNew Zealand School of Life Sciences University of NottinghamNottinghamUK Brain and Mind Centre&School of Medical Sciences The University of SydneySydneyNew South WalesAustralia Innovation Center for Neurological Disorders and Department of Neurology Xuanwu HospitalNational Clinical Research Center for Geriatric DiseasesCapital Medical UniversityBeijingChina A.I.Virtanen Institute for Molecular Sciences University of Eastern FinlandKuopioFinland Department of Neurology and Psychiatry Beijing Shijitan HospitalCapital Medical UniversityBeijingChina Department of Diagnostic Radiology and Nuclear Medicine University of Maryland School of MedicineBaltimoreMarylandUSA University of Chinese Academy of Sciences BeijingChina State Key Laboratory of Membrane Biology Institute of ZoologyChinese Academy of SciencesBeijingChina Beijing Institute of Brain Disorders Laboratory of Brain DisordersMinistry of Sci

The global trend toward aging populations has resulted in an increase in the occurrence of Alzheimer's disease(AD)and associated socioeconomic *** metabolism of amyloid-β(Aβ)has been proposed as a significant pathomechanism in AD,supported by results of recent clinical trials using anti-Aβ***,the cognitive benefits of the current treatments are *** etiology of AD is multifactorial,encompassing Aβand tau accumulation,neuroinflammation,demyelination,vascular dysfunction,and comorbidities,which collectively lead to widespread neurodegeneration in the brain and cognitive ***,solely removing Aβfrom the brain may be insufficient to combat neurodegeneration and preserve *** attain effective treatment for AD,it is necessary to(1)conduct extensive research on various mechanisms that cause neurodegeneration,including advances in neuroimaging techniques for earlier detection and a more precise characterization of molecular events at scales ranging from cellular to the full system level;(2)identify neuroprotective intervention targets against different neurodegeneration mechanisms;and(3)discover novel and optimal combinations of neuroprotective intervention strategies to maintain cognitive function in AD *** Alzheimer's Disease Neuroprotection Research Initiative's objective is to facilitate coordinated,multidisciplinary efforts to develop systemic neuroprotective strategies to combat *** aim is to achieve mitigation of the full spectrum of pathological processes underlying AD,with the goal of halting or even reversing cognitive decline.

关键词： Alzheimer's disease early intervention neural regeneration neuroprotection systematic perspective

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Selective Photoelectrochemical Oxidation of Glycerol to Glyceric Acid on (002) Facets Exposed WO3Nanosheets

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Angewandte Chemie 2023年第11期136卷

作者： Dr. Yonghao Xiao Dr. Mengran Wang Dr. Dong Liu Dr. Jiajian Gao Dr. Jie Ding Dr. Huan Wang Dr. Hong Bin Yang Dr. Fuhua Li Mengxin Chen Prof. Dr. Yangsen Xu Dr. Danyun Xu Dr. Yun-Xiao Zhang Dr. Shaofan Fang Dr. Xin Ao Dr. Jingyu Wang Prof. Dr. Chenliang Su Prof. Dr. Bin Liu International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education Engineering Technology Research Center for 2D Materials Information Functional Devices and Systems of Guangdong Province Institute of Microscale Optoelectronics Shenzhen University Shenzhen 518060 P. R. China School of Chemistry Chemical Engineering and Biotechnology Nanyang Technological University Singapore 637459 Singapore Department of Materials Science and Engineering City University of Hong Kong Hong Kong SAR 999077 P. R. China Centre for Advanced Analytical Science School of Chemistry and Chemical Engineering Guangzhou University Guangzhou 510006 P. R. China School of Chemistry and Chemical Engineering South China University of Technology 381 Wushan Road Guangzhou 510640 P. R. China Department of Chemistry & Center of Super-Diamond and Advanced Films (COSDAF) City University of Hong Kong Tat Chee Avenue Kowloon Hong Kong SAR P. R. China

Glycerol is a byproduct of biodiesel production. Selective photoelectrochemical oxidation of glycerol to high value-added chemicals offers an economical and sustainable approach to transform renewable feedstock as well as store green energy at the same time. In this work, we synthesized monoclinic WO 3 nanosheets with exposed (002) facets, which could selectively oxidize glycerol to glyceric acid (GLYA) with a photocurrent density of 1.7 mA cm −2 , a 73 % GLYA selectivity and a 39 % GLYA Faradaic efficiency at 0.9 V vs. reversible hydrogen electrode (RHE) under AM 1.5G illumination (100 mW cm −2 ). Compared to (200) facets exposed WO 3 , a combination of experiments and theoretical calculations indicates that the superior performance of selective glycerol oxidation mainly originates from the better charge separation and prolonged carrier lifetime resulted from the plenty of surface trapping states, lower energy barrier of the glycerol-to-GLYA reaction pathway, more abundant active sites and stronger oxidative ability of photogenerated holes on the (002) facets exposed WO 3 . Our findings show great potential to significantly contribute to the sustainable and environmentally friendly chemical processes via designing high performance photoelectrochemical cell via facet engineering for renewable feedstock transformation.

关键词： Facet Engineering Glycerol Photoelectrochemical Selective Oxidation WO3

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Artificial Synapses: A Reliable All-2D Materials Artificial Synapse for High Energy-Efficient Neuromorphic Computing (Adv. Funct. Mater. 27/2021)

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advanced functional Materials 2021年第27期31卷

作者： Jian Tang Congli He Jianshi Tang Kun Yue Qingtian Zhang Yizhou Liu Qinqin Wang Shuopei Wang Na Li Cheng Shen Yanchong Zhao Jieying Liu Jiahao Yuan Zheng Wei Jiawei Li Kenji Watanabe Takashi Taniguchi Dashan Shang Shouguo Wang Wei Yang Rong Yang Dongxia Shi Guangyu Zhang Beijing National Laboratory for Condensed Matter Physics Key Laboratory for Nanoscale Physics and Devices Institute of Physics Chinese Academy of Sciences Beijing 100190 China Institute of Advanced Materials Beijing Normal University Beijing 100875 China Institute of Microelectronics Beijing National Research Center for Information Science and Technology (BNRist) Tsinghua University Beijing 100084 China Beijing Innovation Center for Future Chips (ICFC) Tsinghua University Beijing 100084 China Ming Hsieh Department of Electrical Engineering University of Southern California Los Angeles CA 90089 USA RIKEN Center for Emergent Matter Science (CEMS) Wako 351-0198 Japan School of Physical Sciences University of Chinese Academy of Sciences Beijing 100190 China Songshan Lake Materials Laboratory Dongguan Guangdong 523808 China Research Center for Functional Materials National Institute for Materials Science 1-1 Namiki Tsukuba 305-0044 Japan International Center for Materials Nanoarchitectonics National Institute for Materials Science 1-1 Namiki Tsukuba 305-0044 Japan The Key Laboratory of Microelectronics Device & Integrated Technology Institute of Microelectronics Chinese Academy of Sciences Beijing 100029 China Beijing Key Laboratory for Nanomaterials and Nanodevices Beijing 100190 China

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In-Situ Cross-Linked Polymers for Enhanced Thermal Cycling Stability in Flexible Perovskite Solar Cells

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Angewandte Chemie 2024年第10期137卷

作者： Zhihao Li Chunmei Jia Hongzhuo Wu Ying Tang Jinbo Zhao Zhenhuang Su Xingyu Gao Shuai Qiu Hongxing Yuan Meng Li Key Lab for Special Functional Materials of Ministry of Education National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology School of Nanoscience and Materials Engineering Collaborative Innovation Center of Nano Functional Materials and Applications Henan University Kaifeng 475004 P. R. China Center for Nano Energy Materials School of Materials Science and Engineering Northwestern Polytechnical University Xi'an 710072 P. R. China Shanghai Synchrotron Radiation Facility (SSRF) Shanghai Advanced Research Institute Chinese Academy of Sciences 239 Zhangheng Road Shanghai 201204 P. R. China Institute of Nanoscience and Engineering Henan University Kaifeng 475004 P. R. China Institute of Materials Henan Key Laboratory of Advanced Conductor Materials Henan Academy of Sciences Zhengzhou 450001 China

Flexible perovskite solar cells (FPSCs) are a promising emerging photovoltaic technology, with certified power conversion efficiencies reaching 24.9 %. However, the frequent occurrence of grain fractures and interface delamination raises concerns about their ability to endure the mechanical stresses caused by temperature fluctuations. In this study, we employ an in situ polymerization molecule with extended functional end groups to preserve mechanical integrity during thermal cycling. The AMPS-DEA molecule chemically anchors to grain boundaries and cross-links neighboring grains, protecting the structure from stress accumulation. Additionally, its hydroxyl groups form bidentate chelation with SnO 2 , enhancing interfacial adhesion and preventing delamination. More importantly, the relaxed residual stress provided by AMPS-DEA allows the perovskite layer to adapt to temperature changes, effectively matching adjacent layers and preventing mechanical failure. Our findings demonstrate that AMPS-DEA modification not only boosts PCE to 25.78 % in rigid PSCs and 24.54 % in flexible PSCs but also improves stability, maintaining over 95 % efficiency after 10,000 bending cycles and 200 thermal cycles.

关键词： Flexible perovskite solar cells Delamination Cracks Mechanical stability Thermal cycling

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Front Cover: Titanium Vacancies in TiO2Nanofibers Enable Highly Efficient Photodriven Seawater Splitting (Chem. Eur. J. 57/2021)

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Chemistry – A European Journal 2021年第57期27卷

作者： Yan-Xiang Zhang Dr. Si-Ming Wu Dr. Ge Tian Xiao-Fang Zhao Dr. Li-Ying Wang Dr. Yi-Xia Yin Lu Wu Qian-Ni Li Prof. Dr. Yue-Xing Zhang Prof. Dr. Jin-Song Wu Prof. Dr. Christoph Janiak Prof. Dr. Kenneth I. Ozoemena Prof. Dr. Menny Shalom Prof. Dr. Xiao-Yu Yang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & School of Materials Science and Engineering & NRC (Nanostructure Research Centre) Wuhan University of Technology Wuhan 430070 P. R. China School of Chemical Engineering and Technology Sun Yat-sen University (Zhuhai) Zhuhai 519000 P. R. China School of Engineering and Applied Sciences Harvard University Cambridge MA 02138 USA State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics Wuhan Institute of Physics and Mathematics The Chinese Academy of Sciences Wuhan 430071 P. R. China Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules College of Chemistry and Chemical Engineering Hubei University Wuhan 430062 P. R. China Institut für Anorganische Chemie und Strukturchemie Heinrich-Heine-Universität Düsseldorf Düsseldorf 40204 Germany Molecular Sciences Institute School of Chemistry University of the Witwatersrand Johannesburg 2050 South Africa Department of Chemistry and Ilse Katz Institute for Nanoscale Science and Technology Ben-Gurion University of the Negev Beer-Sheva 8410501 Israel

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Inside Back Cover: Adamantylidene Addition to M3N@Ih-C80(M=Sc, Lu) and Sc3N@D5h-C80: Synthesis and Crystallographic Characterization of the -Open and -Open Adducts (Chem. Eur. J. 27/2017)

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Chemistry – A European Journal 2017年第27期23卷 6701-6701页

作者： Prof. Dr. Michio Yamada Tsuneyuki Abe Chiharu Saito Toshiki Yamazaki Dr. Satoru Sato Dr. Naomi Mizorogi Prof. Dr. Zdenek Slanina Prof. Dr. Filip Uhlík Dr. Mitsuaki Suzuki Prof. Dr. Yutaka Maeda Prof. Dr. Yongfu Lian Prof. Dr. Xing Lu Prof. Dr. Marilyn M. Olmstead Prof. Dr. Alan L. Balch Prof. Dr. Shigeru Nagase Prof. Dr. Takeshi Akasaka Department of Chemistry Tokyo Gakugei University Tokyo 184–8501 Japan Life Science Center of Tsukuba Advanced Research Alliance University of Tsukuba Ibaraki 305–8577 Japan Department of Chemistry and Biochemistry National Chung-Cheng University Chia-Yi 62117 Taiwan R.O.C. Department of Physical and Macromolecular Chemistry Charles University in Prague 128 43 Prague 2 Czech Republic Department of Chemistry Faculty of Science Josai University Saitama 350–0295 Japan Key Laboratory of Functional Inorganic Material Chemistry Ministry of Education School of Chemistry and Materials Science Heilongjiang University Harbin 150080 P.R. China State Key Laboratory of Materials Processing and Die and Mold Technology School of Materials Science and Engineering Huazhong University of Science and Technology Wuhan 430074 P.R. China Department of Chemistry University of California Davis California 95616 USA Fukui Institute for Fundamental Chemistry Kyoto University Kyoto 606–8103 Japan Foundation for Advancement of International Science Ibaraki 305–0821 Japan

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