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Ambient Fast Synthesis of Superaerophobic/Superhydrophilic Electrode for Superior Electrocatalytic Water Oxidation

Energy & Environmental Materials 2023年第6期6卷 356-363页

作者： Jingjun Shen Jing Li Bo Li Yun Zheng Xiaozhi Bao Junpo Guo Yan Guo Chenglong Lai Wen Lei Shuangyin Wang Huaiyu Shao Guangdong-Hong Kong-Macao Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices Institute of Applied Physics and Materials EngineeringUniversity of MacaoAvenida da UniversidadeTaipaMacaoSAR 999078China Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education Key Laboratory of High Performance Polymer-based Composites of Guangdong ProvinceSchool of ChemistrySun Yat-Sen UniversityGuangzhou 510275China School of Materials Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China The State Key Laboratory of Refractories and Metallurgy Wuhan University of Science and TechnologyWuhan 430081China State Key Laboratory of Chem/Bio-Sensing and Chemometrics Provincial Hunan Key Laboratory for Graphene Materials and DevicesCollege of Chemistry and Chemical EngineeringHunan UniversityChangsha 410082China

Developing cost-effective and facile methods to synthesize efficient and stable electrocatalysts for large-scale water splitting is highly desirable but remains a significant *** this study,a facile ambient temperature synthesis of hierarchical nickel-iron(oxy)hydroxides nanosheets on iron foam(FF-FN)with both superhydrophilicity and superaerophobicity is ***,the as-fabricated FF-FN electrode demonstrates extraordinary oxygen evolution reaction(OER)activity with an ultralow overpotential of 195 mV at 10 mA cm^(-2)and a small Tafel slope of 34 mV dec^(-1)in alkaline *** theoretical investigation indicates that the involved lattice oxygen in nickel-iron-based-oxyhydroxide during electrochemical self-reconstruction can significantly reduce the OER reaction overpotential via the dominated lattice oxygen *** rechargeable Zn-air battery assembled by directly using the as-prepared FF-FN as cathode displays remarkable cycling *** is believed that this work affords an economical approach to steer commercial Fe foam into robust electrocatalysts for sustainable energy conversion and storage systems.

关键词： electrocatalysis oxygen evolution reaction oxyhydroxide superaerophobicity superhydrophilicity

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基于拉压转换和变刚度斜坡结构的宽量程压缩传感结构

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science China Materials 2024年第3期67卷 871-878页

作者：李朋阳熊金华闫倩丁仁杰郑皓文薛福华赵旭陈仲刘宗林唐志共彭庆宇赫晓东 National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Center for Composite Materials and StructuresHarbin Institute of TechnologyHarbin150080China Frontiers Science Center for Matter Behave in Space Environment Harbin Institute of TechnologyHarbin 150080China Shenzhen STRONG Advanced Materials Research Institute Co. Ltd.Shenzhen 518000China

压力传感器仍然面临着将高灵敏度与宽检测范围相结合的挑战.基于此,我们设计了一种拉-压转换(TC)结构,并将其与变刚度策略相结合来制造压力传感器件.该结构能够将二维可拉伸材料的传感性能转换为三维可压缩设备的传感性能.传感和机械性... 详细信息

压力传感器仍然面临着将高灵敏度与宽检测范围相结合的挑战.基于此,我们设计了一种拉-压转换(TC)结构,并将其与变刚度策略相结合来制造压力传感器件.该结构能够将二维可拉伸材料的传感性能转换为三维可压缩设备的传感性能.传感和机械性能可以使用模拟和理论计算进行设计.斜面结构能够在24.3 N范围内提供线性传感.变刚度设计策略使传感器能够以高灵敏度(3.5 N^(-1))感知较小载荷,并具有宽的检测范围(0.002–24.300 N,扩展范围82.6 N).此外,该传感结构可以在水下环境中稳定工作.这种使用二维可拉伸应变传感器作为传感单元来开发压缩传感装置的设计策略将为未来提供新的思路.

关键词： nanocomposites strain-sensing film pressure sensor 3D printing variable stiffness structures

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In-situ self-templating synthesis of 3D hierarchical porous carbonsfrom oxygen-bridged porous organic polymers for highperformance supercapacitors

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Nano Research 2022年第9期15卷 7759-7768页

作者： Qi Xiong Bei Liu Yijiang Liu Pu Wang Hua Cheng Huaming Li Zhouguang Lu Mei Yang College of Chemistry Xiangtan UniversityXiangtan 411105China Key Laboratory of Polymeric Materials&Application Technology of Hunan Province Key Laboratory of Advanced Functional Polymeric Materialsof College of Hunan Provinceand Key Lab of Environment-Friendly Chemistry and Application in Ministry of EducationXiangtan UniversityXiangtan 411105China Department of Materials Science&Engineering Shenzhen Key Laboratory of Interfacial Science and Engineering of MaterialsSouthern Universityof Science and TechnologyShenzhen 518055China

It is a big challenge to well control the porous structure of carbon materials for supercapacitor ***,a simple in-situ self-templating strategy is developed to prepare three-dimensional(3D)hierarchical porous carbons with good combination of micro and meso-porous architecture derived from a new oxygen-bridged porous organic polymer(OPOP).The OPOP is produced by the condensation polymerization of cyanuric chloride and hydroquinone in NaOH ethanol solution and NaCl is in-situ formed as by-product that will serve as template to construct an interconnected 3D hierarchical porous architecture upon *** large interface pore architecture,and rich doping of N and O heteroatoms effectively promote the electrolyte accessibility and electronic conductivity,and provide abundant active sites for energy ***,the supercapacitors based on the optimized OPOP-800 sample display an energy density of 8.44 and 27.28 Wh·kg^(−1)in 6.0 M KOH and 1.0 M Na2SO4 electrolytes,*** capacitance retention is more than 94%after 10,000 ***,density functional theory(DFT)calculations have been employed to unveil the charge storage mechanism in the *** results presented in this job are inspiring in finely tuning the porous structure to optimize the supercapacitive performance of carbon materials.

关键词： in-situ self-templating porous organic polymer three-dimensional(3D)hierarchical porous carbons supercapacitors

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Remarkably enhanced dielectric stability and energy storage properties in BNT–BST relaxor ceramics by A-site defect engineering for pulsed power applications

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Journal of advanced Ceramics 2022年第2期11卷 283-294页

作者： Zhipeng LI Dong-Xu LI Zong-Yang SHEN Xiaojun ZENG Fusheng SONG Wenqin LUO Xingcai WANG Zhumei WANG Yueming LI Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province China National Light Industry Key Laboratory of Functional Ceramic MaterialsSchool of Materials Science and EngineeringJingdezhen Ceramic UniversityJingdezhen 333403China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Chengdu Hongke Electronic Technology Co. Ltd.Chengdu 610000China

Lead-free bulk ceramics for advanced pulsed power capacitors show relatively low recoverable energy storage density(Wrec)especially at low electric field *** address this challenge,we propose an A-site defect engineering to optimize the electric polarization behavior by disrupting the orderly arrangement of A-site ions,in which Ba_(0.105)Na_(0.325)Sr_(0.245−1.5x)□_(0.5x)Bi_(0.325)+xTiO_(3)(BNS_(0.245−1.5x)□_(0.5x)B_(0.325+x)T,x=0,0.02,0.04,0.06,and 0.08)lead-free ceramics are selected as the *** BNS_(0.245−1.5x)□_(0.5x)B_(0.325+x)T ceramics are prepared by using pressureless solid-state sintering and achieve large W_(rec)(1.8 J/cm^(3))at a low electric field(@110 kV/cm)when x=*** value of 1.8 J/cm3 is super high as compared to all other W_(rec) in lead-free bulk ceramics under a relatively low electric field(<160 kV/cm).Furthermore,a high dielectric constant of 2930 within 15%fluctuation in a wide temperature range of 40–350℃is also obtained in BNS_(0.245−1.5x)□_(0.5x)B_(0.325+x)T(x=0.06)*** excellent performances can be attributed to the A-site defect engineering,which can reduce remnant polarization(P_(r))and improve the thermal evolution of polar nanoregions(PNRs).This work confirms that the BNS_(0.245−1.5x)□_(0.5x)B_(0.325+x)T(x=0.06)ceramics are desirable for advanced pulsed power capacitors,and will push the development of a series of Bi0.5Na0.5TiO3(BNT)-based ceramics with high W_(rec) and high-temperature stability.

关键词： relaxor ferroelectrics energy storage ceramics ceramic capacitor Bi_(0.5)Na_(0.5)TiO_(3)(BNT) defect engine

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Interfacial and confined molecular-assembly of poly(3-hexylthiophene) and its application in organic electronic devices (vol 23, pg 619, 2022)

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science AND technology OF advanced MATERIALS 2022年第1期23卷 691-691页

作者： Liang, Junhao Ouyang, Xing Cao, Yan Advanced Institute for Soft Matter Science and Technology (AISMST) School of Emergent Soft Matter South China University of Technology Guangzhou China College of Materials Science and Engineering Shenzhen University Shenzhen Guangdong China Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices South China University of Technology Guangdong China

Poly(3-hexylthiophene) (P3HT) is a typical conducting polymer widely used in organic thin-film transistors, polymer solar cells, etc., due to good processability and remarkable charging carrier and hole mobility. It is known that the ordered structure assembled by π-conjugated P3HT chains could promote the performance of electronic devices. Interfacial and confined molecular-assembly is one effective way to generate an ordered structure by tuning surface geometry and substrate interaction. Great efforts have been made to investigate the molecular chain assembly of P3HT on a curved surface that is confined to different geometry. In this report, we review the recent advances of the interfacial chain assembly of P3HT in a flat or curved confined space and its application to organic electronic devices. In principle, this interfacial assembly of P3HT at a nanoscale could improve the electronic properties, such as the current transport, power conversion efficiency, etc. Therefore, this review on interfacial and confined assembly of P3HT could give general implications for designing high-performance organic electronic devices.

关键词： P3HT interfacial assembly confinement nanomaterials organic electronic device

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advanced surface engineering of titanium materials for biomedical applications:From static modification to dynamic responsive regulation

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Bioactive Materials 2023年第9期27卷 15-57页

作者： Pinliang Jiang Yanmei Zhang Ren Hu Bin Shi Lihai Zhang Qiaoling Huang Yun Yang Peifu Tang Changjian Lin South China Advanced Institute for Soft Matter Science and Technology School of Emergent Soft MatterGuangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and DevicesSouth China University of TechnologyGuangzhou510640China State Key Lab of Physical Chemistry of Solid Surfaces Department of ChemistryCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen361005China Department of Orthopaedics General Hospital of Chinese PLABeijing100853China Research Institute for Biomimetics and Soft Matter Fujian Provincial Key Laboratory for Soft Functional Materials ResearchCollege of Physical Science and TechnologyXiamen UniversityXiamen361005China

Titanium(Ti)and its alloys have been widely used as orthopedic implants,because of their favorable mechanical properties,corrosion resistance and *** their significant success in various clinical applications,the probability of failure,degradation and revision is undesirably high,especially for the patients with low bone density,insufficient quantity of bone or osteoporosis,which renders the studies on surface modification of Ti still active to further improve clinical *** is discerned that surface physicochemical properties directly influence and even control the dynamic interaction that subsequently determines the success or rejection of orthopedic ***,it is crucial to endow bulk materials with specific surface properties of high bioactivity that can be performed by surface modification to realize the *** article first reviews surface characteristics of Ti materials and various conventional surface modification techniques involving mechanical,physical and chemical treatments based on the formation mechanism of the modified *** conventional methods are able to improve bioactivity of Ti implants,but the surfaces with static state cannot respond to the dynamic biological cascades from the living cells and ***,beyond traditional static design,dynamic responsive avenues are then *** dynamic stimuli sources for surface functionalization can originate from environmental triggers or physiological *** short,this review surveys recent developments in the surface engineering of Ti materials,with a specific emphasis on advances in static to dynamic functionality,which provides perspectives for improving bioactivity and biocompatibility of Ti implants.

关键词： Titanium materials Orthopedic implants Bioactivity Static modification Dynamic responsive regulation

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Two-color emissive AIEgens with anti-Kasha property for dual-organelle imaging and phototherapy

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science China Chemistry 2024年第5期67卷 1740-1752页

作者： Pu Chen Guogang Shan Qingli Nie Yuting Yan Pengfei Zhang Zujin Zhao Hai-Tao Feng Ben Zhong Tang AIE Research Center Shaanxi Key Laboratory of PhytochemistryCollege of Chemistry and Chemical EngineeringBaoji University of Arts and SciencesBaoji 721013China Institute of Functional Material Chemistry and National&Local United Engineering Lab for Power Battery Faculty of ChemistryNortheast Normal UniversityChangchun 130024China College of Chemistry&Materials Science Northwest UniversityXi’an 710127China Guangdong Key Laboratory of Nanomedicine CAS-HK Joint Lab of BiomaterialsCAS Key Laboratory of Biomedical Imaging Science and SystemShenzhen Engineering Laboratory of Nanomedicine and NanoformulationsCAS Key Lab for Health InformaticsShenzhen Institutes of Advanced TechnologyChinese Academy of SciencesShenzhen 518055China State Key Laboratory of Luminescent Materials and Devices Key Laboratory of Luminescence from Molecular Aggregates of Guangdong ProvinceSouth China University of TechnologyGuangzhou 510640China School of Science and Engineering Shenzhen Institute of Aggregate Science and TechnologyThe Chinese University of Hong KongShenzhen(CUHK-Shenzhen)Shenzhen 518172China

Despite the rapid development of probes for targeting single organelle, the construction of robust dual-organelle targeting probes with multicolor emission was rarely reported. Herein, two dual-emissive aggregation-induced emission luminogens(AIEgens)with donor-π-acceptor structures were designed and synthesized, namely QT-1 and QF-2. Both two AIEgens exhibited excitation wavelength-dependence defying the Kasha's rule, and could stain lipid droplets(LDs) and mitochondria in blue and red fluorescence, respectively. Moreover, thanks to the near-infrared emission and abundant reactive oxygen species(ROS) generation efficiency of QT-1, it was chosen as a photodynamic therapy agent to selectively kill cancer cells from normal cells. Upon light irradiation, an obvious decrease of mitochondrial membrane potential(MMP) and serious change of mitochondrial shape in cells were observed, which corresponded to the efficient inhibition of tumor growth in vivo. This work afforded a promising strategy for the construction of multicolor emission by tuning anti-Kasha behaviors and expanding their application in dualorganelle targeting-based phototheranostics.

关键词： aggregation-induced emission anti-Kasha luminescence fluorescent probe bioimaging photodynamic therapy

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Oxidation behavior of non-stoichiometric(Zr,Hf,Ti)C_(x) carbide solid solution powders in air

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Journal of advanced Ceramics 2021年第4期10卷 741-757页

作者： Huilin LUN Yi ZENG Xiang XIONG Ziming YE Zhongwei ZHANG Xingchao LI Haikun CHEN Yufeng LIU State Key Laboratory of Powder Metallurgy Central South UniversityChangsha 410083China Institute of Advanced Structure Technology Beijing Institute of TechnologyBeijing 100081China Science and Technology of Advanced Functional Composites Laboratory Aerospace Research Institute of Materials&Processing TechnologyBeijing 100076China

Multi-component solid solutions with non-stoichiometric compositions are characteristics of ultra-high temperature carbides as promising materials for hypersonic ***,for group IV transition-metal carbides,the oxidation behavior of multi-component non-stoichiometric(Zr,Hf,Ti)C_(x)carbide solid solution has not been clarified *** present work fabricated four kinds of(Zr,Hf,Ti)C_(x)carbide solid solution powders by free-pressureless spark plasma sintering to investigate the oxidation behavior of(Zr,Hf,Ti)C_(x)in *** effects of metallic atom composition on oxidation resistance were *** results indicate that the oxidation kinetics of(Zr,Hf,Ti)C_(x)are composition dependent.A high Hf content in(Zr,Hf,Ti)C_(x)was beneficial to form an amorphous Zr-Hf-Ti-C-0 oxycarbide layer as an oxygen barrier to enhance the initial oxidation ***,an equiatomic ratio of metallic atoms reduced the growth rate of(Zr,Hf,Ti)O_(2)oxide,increasing its phase stability at high temperatures,which improved the oxidation activation energy of(Zr,Hf,Ti)C_(x).

关键词： ultra-high temperature ceramics(UHTCs) (Zr,Hf,Ti)C_(x)carbides oxidation behavior oxidation resistance free-pressureless spark plasma sintering

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(Cr_(0.2)Mn_(0.2)Fe_(0.2)Co_(0.2)Mo_(0.2))B:A novel high-entropy monoboride with good electromagnetic interference shielding performance in K-band

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Journal of Materials science & technology 2021年第18期77卷 58-65页

作者： Haiming Zhang Biao Zhao Fu-Zhi Dai Huimin Xiang Zhili Zhang Yanchun Zhou Science and Technology on Advanced Functional Composite Laboratory Aerospace Research Institute of Materials&Processing TechnologyNo.1 South Dahongmen RoadBeijing100076China School of Mechanical Electronic and Control EngineeringBeijing Jiaotong UniversityBeijing100044China Henan Key Laboratory of Aeronautical Materials and Application Technology School of Material Science and EngineeringZhengzhou University of AeronauticsZhengzhou450046China

A novel equimolar high-entropy(HE)transition metal monoboride,(Cr_(0.2)Mn_(0.2)Fe_(0.2)Co_(0.2)Mo_(0.2))B,was designed and prepared in powder and bulk form by high temperature elemental reaction method and spark plasma sintering(SPS)method,*** analysis shows that HE(Cr_(0.2)Mn_(0.2)Fe_(0.2)Co_(0.2)Mo_(0.2))B possesses orthorhombic structure with Pnma space *** Rietveld refinement,the lattice parameters of HE(Cr_(0.2)Mn_(0.2)Fe_(0.2)Co_(0.2)Mo_(0.2))B are a=5.6675,b=2.9714,c=4.2209 and the theoretical density is 6.95 g/cm~*** Vickers hardness and electrical conductivity of HE(Cr_(0.2)Mn_(0.2)Fe_(0.2)Co_(0.2)Mo_(0.2))B bulk with relative density of 90%is 12.3±0.5 GPa and 0.49±0.04×10~6 S/m,*** to high electrical conductivity,HE(Cr_(0.2)Mn_(0.2)Fe_(0.2)Co_(0.2)Mo_(0.2))B bulk with 3.0 mm thickness displays superior EMI shielding performance in 18.0–26.5 GHz(K-band),and the average values of SET,SER,and SEAare 23.3 dB,13.9 dB,and 9.4 dB,*** EMI shielding mechanism of HE(Cr_(0.2)Mn_(0.2)Fe_(0.2)Co_(0.2)Mo_(0.2))B mainly results from reflection.

关键词： High-entropy ceramics Transition metal monoboride Electromagnetic interference(EMI)shielding Mechanical properties Electrical conductive ceramics

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Zr_(55)Al_(10)Ni_(5)Cu_(30)amorphous alloy film prepared by magnetron sputtering method

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Rare Metals 2021年第8期40卷 2237-2243页

作者： Dong-Mei Mi Sheng-Li Zhu Yan-Qin Liang Zhao-Yang Li Zhen-Duo Cui Xian-Jin Yang Akihisa Inoue School of Materials Science and Engineering Tianjin UniversityTianjin300072China Tianjin Key Laboratory of Composite and Functional Materials Tianjin300072China Key Laboratory of Advanced Ceramics and Machining Technology Ministry of EducationTianjin300072China Department of Physics Kings Abudulaziz UniversityJeddah22254Saudi Arabia

In this work,amorphous Zr_(55)Al_(10)Ni_(5)Cu_(30)alloy thin film was prepared on D36 steel substrate by magnetron sputtering *** film was characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD),atomic force microscopy(AFM),hardness tester and nano *** behavior of the film was investigated in 3.5%NaCl aqueous solutions by an electrochemical *** room temperature,the amorphous alloy film was formed completely after sputtering for 5 *** surface morphology of the amorphous alloy film was uniform and *** of the amorphous alloy film improved the microhardness and corrosion resistance of the D36 *** amorphous alloy film(prepared at room temperature for 5 h)exhibited good adhesion strength with the *** as-sputtered sample exhibited a crevice corrosion trend when the sputtering time was too short(1 h)or too long(10 h).

关键词： Magnetron sputtering Amorphous alloy Thin film Corrosion resistance Zr_(55)Al_(10)Ni_(5)Cu_(30)

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