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Dual-functional additive of cesium ion for achieving ultrahigh efficiency of persistent phosphorescence in existing polymer-based materials

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science China Chemistry 2025年第2期68卷 754-762页

作者： Yao Liu Jinzheng Chen Yiling Miao Kaimin Zhang Faxu Lin Huahua Huang Lina Zhang Zhan Yang Yi Zhang Zhenguo Chi Zhiyong Yang Key Laboratory for Polymeric Composite&Functional Materials of Ministry of Education Guangdong Engineering Technology Research Center for High-performance Organic and Polymer Photoelectric Functional FilmsGuangdong Basic Research Center of Excellence(GBRCE)for Functional Molecular EngineeringSchool of ChemistrySun Yat-sen UniversityGuangzhou 510275China School of Materials Science and Engineering Sun Yat-sen UniversityGuangzhou 510275China College of Materials Science and Engineering Hebei University of EngineeringHandan 056038China School of Environmental and Chemical Engineering Wuyi UniversityJiangmen 529020China

Despite great achievements obtained for polymer-based room-temperature phosphorescence(RTP)materials,the limited efficiencies of persistent RTP still hinder their ***,a simple and universal strategy of using the dual-functional additive of Cs+was presented,which could simultaneously enhance the efficiency(Φp)and maintain the long lifetime(τp)of RTP in existing polymer-based systems with various phosphors and *** them,the commercial emitter(TpB)-doped polyvinyl alcohol(PVA)/Cs_(2)CO_(3) system possessed an extremely high Φp up to 75.5% and still maintained a longτp of 2.13 s,by introducing the heavy-atom effect and an extra network of ionic bonding through the Cs+***,the temperature resistance of RTP in TpB@PVA/Cs+film could also be improved to 85℃.More satisfactorily,the efficiency of Förster resonance energy transfer(FRET)from RTP to near-infrared(NIR)was also remarkably enhanced in the multi-component *** work provides a simple and universal strategy for developing polymer systems with high RTP performance.

关键词： persistent phosphorescence cesium carbonate efficiency heavy-atom effect ionic interaction

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Promoting effect of d-band center and in-situ precipitation strategy on sulfur evolution reaction

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Journal of Energy Chemistry 2025年第5期104卷 740-748页

作者： Jun Pu Yun Tan Jiasen Yin Zihan Shen Shoujie Liu Kai Zhang Lei Zhou Yagang Yao Key Laboratory of Functional Molecular Solids Ministry of Education Anhui Provincial Engineering Laboratory for New-Energy Vehicle Battery Energy-Storage Materials College of Chemistry and Materials Science Anhui Normal University National Laboratory of Solid State Microstructures College of Engineering and Applied Sciences Jiangsu Key Laboratory of Artificial Functional Materials Collaborative Innovation Center of Advanced Microstructures Nanjing University State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences School of Materials Science and Engineering Anhui University School of Energy and Power Engineering Jiangsu University Department of Electrical Engineering Eindhoven University of Technology

The slow conversion of polyphase in lithium-sulfur （Li-S） batteries not only intensifies the shuttle effect of lithium polysulfides （LiPSs）,but also causes the continuous accumulation of inactive sulfur species,resulting in rapid capacity attenuation and sluggish dynamic ***,the promoting effect of atomic interface stress on sulfur reaction was investigated via CoFe-CoFe2O4heterogeneous nanosheets with a cavity *** strain force induced by the in-situ precipitation of Co Fe bimetallic alloy in oxide matrix increased the d-band center,which was conducive to the interaction between catalyst and Li *** sulfur cathode based on this two-dimensional （2D） nanosheet design showed an extremely high capacity of 751 mAh g-1at 4 *** with a sulfur loading of 5.55 mg cm-2,its area capacity was still as high as 7.15 mAh ***,the enhanced stability greatly improved the practical potential of Li-S batteries.

关键词： 2D nanosheets D-band center In-situ precipitation Li-S batteries Strain effect

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Ultralight and superelastic MXene/reduced graphene oxide aerogels for electromagnetic interference shielding

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Nano Research 2025年第1期18卷 1-9页

作者： Xinfeng Zhou Yang Dai Guoyao Yue Yiman Zhang Lulu Li Zhong-Zhen Yu Peng Min Hao-Bin Zhang State Key Laboratory of Organic-Inorganic Composites College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China Beijing Key Laboratory of Advanced Functional Polymer Composites College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China Present address:BOE Technology Innovation Center BOE Technology Group Co.Ltd.Beijing 100176China Xi’an Modern Chemistry Research Institute Xi’an 710065China

Lightweight aerogels feature multifunctionality and a high porosity,yet accompanied with poor structure recovery under large strain *** this work,we develop an air bubble-ice crystal dual template and annealing strategy to integrate low density and high resilience for the conductive transition metal carbides/nitrides(MXene)composite *** air bubbles and ice crystals synergistically exclude the nanosheets to the gas-liquid interfaces,thereby constructing unique Y-shaped junctions and robust *** annealing process greatly enhances the interlayer *** external load,the Yshaped structures prevent the stress concentration at the junctions by transferring the forces to the skeleton for maintaining structural *** addition,the wrinkled and thick cell walls,together with the enhanced interlayer interactions,endow the aerogel with exceptional structural stability and *** a result,the MXene/reduced graphene oxide(RGO)composite aerogels exhibit superelasticity with reversible compressive strains of up to 95%.In addition,the electron bridging effect of the RGO sheets affords the aerogel to deliver excellent electromagnetic interference shielding performance,as high as 46.3 dB at 2.5 ***,the remarkable reshapeability of the aerogels allows for precise regulation of structure and performance(33.5-75.1 dB)by a simple wetting compression *** summary,this work offers helpful inspirations for developing lightweight and superelasticity aerogels for extensive applications.

关键词： lightweight superelasticity MXene aerogel electromagnetic interference shielding reshapeability

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Distributed monitoring of internal strain in photosensitive polymers based on self-reference OFDR system

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Journal of Lightwave technology 2025年第10期43卷 4771-4777页

作者： Song, Zhuo Liang, Chaoping Zou, Dongjiang Chen, Hongdong Li, Songwei Lu, Hanglin Tang, Jian Shao, Laipeng Yang, Li Hu, Junhui University Engineering Research Center of Advanced Functional Materials and intelligent sensing Guangxi China Guangxi Normal University Guangxi Key Laboratory of Nuclear Physics and Technology College of Physics Science and Technology Guangxi Guilin541004 China

Photosensitive polymers serve as critical adhesives in optical devices, with their thermal strain coefficient determining the performance of temperature-dependent loss in such devices. To accurately measure the true thermal strain coefficient of the adhesive, we proposed a measurement scheme of internal strain distribution in photosensitive polymers by using an optical frequency domain reflectometry (OFDR) system. In our scheme, a self-referencing approach is used to eliminate the temperature-tostrain crosstalk caused by temperature variations in the tested sample, thereby obtaining the true thermal strain coefficient of the tested sample. In our experiment, a 10 cm single-mode fiber (SMF) is embedded within the 2 mm × 2 mm × 100 mm photosensitive polymer, and we use the high spatial resolution of the OFDR system to realize the distributed strain measurements of the SMF. A thermal strain coefficient of 19.108 μϵ/°C is obtained when the temperature ranges from 30°C to 120°C. The temperature-tostrain crosstalk is 9.131 μϵ/°C, and the spatial resolution of the OFDR is 1.28 mm. In addition, we validated the stability of the entire experimental setup by conducting long-term measurements under fixed environmental conditions, during which the system fluctuations remained within approximately ± 3 GHz. The experimental results can provide valuable insights for the selection of adhesives and the determination of optimal curing time of the passive optical devices fabrication in the field of optical fiber communication © 2025 IEEE.

关键词： Single mode fibers

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Highly electrically conductive MOF/conducting polymer nanocomposites toward tunable electromagnetic wave absorption

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材料科学技术（英文版） 2025年第2期205卷 258-269页

作者： Xin Wu Peiyuan Kang Yinghan Zhang Haocheng Guo Shuoying Yang Qi Zheng Lianjun Wang Wan Jiang State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering Donghua UniversityShanghai 201620China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering Donghua UniversityShanghai 201620China Engineering Research Center of Advanced Glasses Manufacturing Technology Ministry of EducationDonghua UniversityShanghai 201620China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering Donghua UniversityShanghai 201620China Institute of Functional Materials Donghua UniversityShanghai 201620China

Metal-organic frameworks(MOFs)have attracted significant interest as self-templates and precursors for the synthesis of carbon-based composites aimed at electromagnetic wave(EMW)***,the utilization of high-temperature treatments has introduced uncertainties regarding the compositions and microstructures of resulting ***,complete carbonization has led to diminished yields of the produced carbon composites,significantly limiting their practical ***,the exploration of pristine MOF-based EMW absorbers presents an intriguing yet challenging endeavor,primarily due to inherently low electrical *** this study,we showcase the utilization of struc-turally robust Zr-MOFs as scaffolds to build highly conductive Zr-MOF/PPy composites via an inner-outer dual-modification approach,which involves the production of conducting polypyrrole(PPy)both within the confined nanoporous channels and the external surface of Zr-MOFs via post-synthetic *** interconnection of confined PPy and surface-lined PPy together leads to a consecutive and extensive conducting network to the maximum *** therefore entails outstanding conductivity up to～14.3 S cm-1 in Zr-MOF/PPy composites,which is approximately 1-2 orders of magnitude higher than that for conductive MOF nanocomposites constructed from either inner or outer *** from the strong and tunable conduction loss,as well as the induced dielectric polarization originated from the porous structures and MOF-polymer interfaces,Zr-MOF/PPy exhibits excellent microwave attenuation capabilities and a tunable absorption frequency ***,with only 15 wt.％loading,the mini-mum reflection loss(RLmin)can reach up to-67.4 dB,accompanied by an effective absorption bandwidth(EAB)extending to 6.74 ***,the microwave absorption characteristics can be tailored from the C-band to the Ku-band by adjusting the loading of *** work provide

关键词： Conductive mof nanocomposites Electromagnetic wave absorption MOF/conducting polymer Electrical conductivity Zr-MOF/PPy

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Enhanced exciton dissociation through scandium-decorated conjugated polymers for artificial photosynthesis of hydrogen peroxide

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Journal of Energy Chemistry 2025年第4期103卷 714-722页

作者： Xingxing Chen Yongli Shen Fan Yang Shuang Yao Wen Zhang Baojuan Xi Xuguang An Shenglin Xiong Jinhua Ye Changhua An Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion School of Chemistry and Chemical Engineering Tianjin Key Laboratory of Advanced Functional Porous Materials Institute of New Energy Materials & Low-Carbon Technologies Tianjin University of Technology School of Chemistry and Chemical Engineering Shandong University School of Mechanical Engineering Chengdu University International Center for Materials Nanoarchitectonics (WPI-MANA) National Institute for Materials Science (NIMS)

Solar-driven hydrogen peroxide（H2O2） production offers a sustainable and environmentally friendly alternative to the traditional anthraquinone oxidation *** polymers（CPs） are emerging as promising photocatalysts for H2O2production due to their unique electronic,optical properties,and tunable ***,the high exciton binding energy of CPs hinders efficient exciton dissociation and charge separation,limiting their photocatalytic *** this work,we synthesized scandium（Sc） atoms decorated CPs with enhanced ordered stacking and crystallinity by introducing benzaldehyde as an end-capping *** strong interaction between charged Sc atoms and electrons facilitates exciton dissociation and improves charge transfer ***,the Lewis acidic nature of Sc atoms promotes oxygen adsorption and enhances the stabilization of superoxide anion intermediate（·O2-）.As a result,the as-synthesized photocatalysts exhibit a high H2O2production rate of 18 μmol h-1in pure water,which is three times that of pristine CPs,This work provides valuable insights into the design of organic polymer photocatalysts for various photocatalytic reactions.

关键词： Conjugated polymers Exciton dissociation H2O2 Photocatalysis

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Enhancing the mechanical properties and oxidation resistance of high-entropy (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C0.95 ceramics through nitrogen doping

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Journal of materials science and technology 2025年 235卷 12-27页

作者： Xia, Liansen Hu, Peitao Dong, Shun Xin, Jianqiang Gui, Kaixuan Zhang, Xinghong Zhou, Yanchun Science and Technology on Advanced Composite in Special Environments Laboratory Harbin Institute of Technology Harbin150001 China Institute for Aero Engine Tsinghua University Beijing100084 China School of Materials Science and Engineering Anhui Polytechnic University Wuhu241000 China School of Materials Science and Engineering Zhengzhou University Zhengzhou450001 China

High-entropy carbide ceramics (HECCs) exhibit superior properties compared to their constituent binary compounds. However, high synthesis and sintering temperature are main obstacles that limit their widespread applications. To address this issue, compositional and particle size controllable high-entropy (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)Cx powders were successfully prepared by a sugar hydrogel combined with the carbothermal reduction method. Owing to the introduction of carbon vacancy, the temperature for the formation of single-phase solid solution of the high-entropy (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)Cx powders was decreased, and the addition of nitrogen decreased the densification temperature of the high-entropy (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C0.95 ceramic by 200 °C. In addition, the flexural strength and fracture toughness of the high-entropy (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C0.95 ceramic were improved by 29 % and 30 %, respectively, compared with those without nitrogen doping. Atomic-resolution high angle annular dark field scanning transmission electron microscopy (HAADF-STEM) and energy dispersive spectroscopy (EDS) mapping reveal that the segregation of N and small cation Ti as well as large lattice strains are responsible for the enhanced mechanical properties. Furthermore, with the introduction of nitrogen, the onset oxidation temperature (OOT) was increased, while the parabolic oxidation rate constant was decreased, revealing the beneficial effect of nitrogen doping on oxidation resistance. These results demonstrate that nitrogen doping can not only improve the mechanical properties of HECCs but also enhance the oxidation resistance, which paves the way for the wide application of HECCs. © 2025

关键词： Fracture toughness

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PtPdAg nanotrees with low Pt content for high CO tolerance within formic acid and methanol electrooxidation

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Rare Metals 2025年第1期44卷 300-310页

作者： Yu-Fei Wang Shou-Lin Zhang Yu-Xin Deng Shi-Han Luan Cai-Kang Wang Lin-Fei Ding Xian Jiang Dong-Mei Sun Ya-Wen Tang Jiangsu Key Laboratory of New Power Batteries Jiangsu Collaborative Innovation Centre of Biomedical Functional MaterialsSchool of Chemistry and Materials ScienceNanjing Normal UniversityNanjing 210023China School of New Energy Nanjing University of Science and TechnologyJiangyin 214443China Advanced Analysis and Testing Center Nanjing Forestry UniversityNanjing 210037China

To efficiently diminish the Pt consumption while concurrently enhancing the anodic reaction kinetics,a straightforward synthesis for PtPdAg nanotrees(NTs)with exceedingly low Pt content is presented,utilizing the galvanic replacement reaction between the initially prepared PdAg NTs and Pt *** to the multilevel porous tree-like structure and the incorporation of low amounts of Pt,the electrocatalytic activity and stability of PtPdAg NTs are markedly enhanced,achieving 1.65 and 1.69 A·mg^(-1)Pt+Pd for the anodic reactions of formic acid oxidation(FAOR)and methanol oxidation(MOR)within DLFCs,surpassing the performance of PdAg NTs,as well as that of commercial Pt and Pd *** functional theory(DFT)calculations reveal that the addition of low amounts of Pt leads to an increase in the d-band center of PtPdAg NTs and lower the COads adsorption energy to-1.23 eV,enhancing the anti-CO toxicity properties *** approach offers an effective means for designing low Pt catalysts as exceptional anodic electrocatalysts for direct liquid fuel cells.

关键词： PtPdAg nanotrees Low Pt Bifunctional electrocatalysts Methanol oxidation reaction Formic acid oxidation

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Understanding the iodine electrochemical behaviors in aqueous zinc batteries

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Journal of Energy Chemistry 2025年第2期101卷 402-415,I0009页

作者： Xuefang Xie Xiaoxin Xu Shuquan Liang Guozhao Fang College of Physical Science and Technology Xinjiang UniversityUrumqi 830017XinjiangChina Xinjiang Key Laboratory of Solid State Physics and Devices Xinjiang UniversityUrumqi 830046XinjiangChina School of Materials Science&Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan ProvinceCentral South UniversityChangsha 41003 HunanChina National Energy Metal Resources and New Materials Key Laboratory Central South UniversityChangsha 410083HunanChina

Iodine is widely used in aqueous zinc batteries(ZBs)due to its abundant resources,low cost,and active redox *** addition to the active material in zinc-iodine batteries,iodine also plays an important role in other ZBs,such as regulating the electrochemical behavior of zinc ions,promoting the reaction kinetic and reversibility of other redox pairs,catalytic behaviors related to iodine reactions,coupling with other halogen ions,shuttle behaviors of polyiodides,***,there is currently a lack of comprehensive discussion on these ***,this review provides a comprehensive overview of the electrochemical behaviors of iodide in the aqueous *** effect of iodine ions on the Zn^(2+)desolvation behaviors and the interfacial behaviors of Zn anode was *** redox pairs boosting other redox pairs,such as MnO_(2)/Mn^(2+)redox pair and vanadium redox pair to obtain high reversibility and capacity was also ***,the catalytic behaviors related to iodine reactions in aqueous ZBs,synergistic reaction with other halogen ions and suppression of shuttle behaviors for high performance zinc-iodine batteries were systematically ***,future prospects for designing effective iodine electrochemical behaviors with practicability are proposed,which will provide scientific guidance for the practical application of iodine-related aqueous ZBs.

关键词： lodide ion Redox pairs Catalytic behavior Shuttle effect Zinc batteries

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Carbon Nanofiber/Polyaniline composite Aerogel with Excellent Electromagnetic Interference Shielding,Low Thermal Conductivity,and Extremely Low Heat Release

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Nano-Micro Letters 2025年第4期17卷 77-95页

作者： Mingyi Chen Jian Zhu Kai Zhang Hongkang Zhou Yufei Gao Jie Fan Rouxi Chen Hsing-Lin Wang School of Textile Science and Engineering Tiangong UniversityTianjin 300387People’s Republic of China Department of Materials Science and Engineering Southern University of Science and TechnologyShenzhen 518055People’s Republic of China School of Innovation and Entrepreneurship Southern University of Science and TechnologyShenzhen 518055People’s Republic of China Guangdong Provincial Key Laboratory of Energy Materials for Electric Power Southern University of Science and TechnologyShenzhen 518055People’s Republic of China Ministry of Education Key Laboratory of Advanced Textile Composite Materials Tiangong UniversityTianjin 300387People’s Republic of China

The rapid development of communication technology and high-frequency electronic devices has created a need for more advanced electromagnetic interference(EMI)shielding *** response to this demand,a study has been conducted to develop multifunctional carbon nanofibers(CNFs)/polyaniline(PANI)aerogels with excellent electromagnetic interference shielding,flame retardancy,and thermal insulation *** process involved freeze-drying of electrospun CNFs and PANI nanoparticles followed by in situ growth PANI to coat the CNFs,creating the core-shell structured CNFs/PANI composite fiber and its hybrid aerogels(CP-3@PANI).The interaction between PANI and aniline(ANI)provides attachment sites,allowing additional ANI adsorption into the aerogel for in situ *** results in PANI uniformly covering the surface of the CNFs,creating a core-shell composite fiber with a flexible CNF core and PANI *** process enhances the utilization rate of the ANI monomer and increases the PANI content loaded onto the ***,effective connections are established between the CNFs,forming a stable,conductive three-dimensional network *** prepared CP-3@PANI aerogels exhibit excellent EMI shielding efficiency(SE)of 85.4 dB and specific EMI SE(SE d^(-1))of 791.2 dB cm^(3)g^(-1)in the *** to the synergistic flame-retardant effect of CNFs,PANI,and the dopant(phytic acid),the CP-3@PANI aerogels demonstrate outstanding flame-retardant and thermal insulation properties,with a peak heat release rate(PHRR)as low as 7.8 W g^(-1)and a total heat release of only 0.58 kJ g^(-1).This study provides an effective strategy for preparing multifunctional integrated EMI shielding materials.

关键词： CNFs/PANI hybrid aerogels EMI shielding Flame retardancy Thermal insulation

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