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Mn-N-P doped carbon spheres as an efficient oxygen reduction catalyst for high performance Zn-Air batteries

Chinese Chemical Letters 2023年第1期34卷 177-181页

作者： Jiajie Li Shanbao Zou Jinzhen Huang Xiaoqian Wu Yue Lu Xundao Liu Bo Song Dehua Dong School of Materials Science and Engineering University of JinanJi nan 250022China National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of TechnologyHarbin 150001China

Low-cost and efficient oxygen reduction reaction(ORR)electrocatalysts are the key to developing Zn-air batteries for renewable energy ***,the Mn-N-P doped carbon sphere was prepared through polymerization of hexachlorotripolyphosphazene(HCCP)and phloroglucinol,and then followed the calcination at 900°*** calculations demonstrated the introduction of Mn in N-P doped carbon could lower the dissociation barrier of O2into O*and promote the ORR through a *** asprepared catalysts exhibited a half-wave potential of 0.82 V *** and limiting current density of 5.2 m A/cm^(2)toward ORR,which was comparable to those of the commercial Pt/C *** addition,Zn-air batteries with 0.05 Mn-N-P-C catalysts showed a high specific capacity of 830 m Ah/gZnand excellent cycle *** facile approach demonstrated herein could be a solution to develop optimum non-precious metal catalysts for the application in cathodes of proton exchange membrane fuel *** study also provides new insight to design the catalysts of multi-heteroatom coordinated metal in the carbon matrix for both fundamental researches and practical applications.

关键词： Oxygen reduction reaction Zn-air batteries Transition metal Doped carbon spheres

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Boosting bidirectional conversion of polysulfide driven by the built-in electric field of MoS_(2)/MoP Mott–Schottky heterostructures in lithium–sulfur batteries

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Journal of advanced Ceramics 2023年第10期12卷 1872-1888页

作者： Meixiu Song Yanan Liu Jingzhe Hong Xiaoshuang Wang Xiaoxiao Huang School of Materials Science and Engineering Harbin Institute of TechnologyHarbin 150001China MIIT Key Laboratory of Advanced Structural–Functional Integration Materials&Green Manufacturing Technology Harbin Institute of TechnologyHarbin 150001China

Heterostructure engineering for sulfur hosts is an effective way to achieve interfacial synergistic effects on suppressing the“shuttle effect”of polysulfides and thus improve electrochemical performance of lithium–sulfur(Li–S)*** selection and design of different components into heterostructures is vital to enhance the synergistic ***,MoS_(2)/MoP Mott–Schottky heterostructure nanoparticles decorated on reduced graphene oxide(MoS_(2)/MoP@rGO)are fabricated and used as sulfur host *** calculation and experiment results reveal that the in-situ introduction of MoP could tune the electronic structure,activate the basal plane of MoS_(2),and achieve the interfacial synergistic effects between adsorption(MoS_(2))and fast conversion(MoP).Such synergistic effects enable MoS_(2)/MoP@rGO to not only remarkably facilitate Li_(2)S deposition during the discharging process but also significantly accelerate the Li_(2)S dissolution during the charging process,demonstrating bidirectional promotion ***,the designed cathode delivers initial capacity of 919.5 mA·h·g^(−1)with capacity of 502.3 mA·h·g^(−1)remaining after 700 cycles at 0.5 *** under higher sulfur loading of 4.31 mg·cm^(−2)and lower electrolyte to sulfur(E/S)ratio of 8.21μL·mg^(−1),the MoS_(2)/MoP@rGO@S cathode could still achieve good capacity and cycle *** work provides a novel and efficient structural design strategy of sulfur hosts for high-performance Li–S energy storage systems.

关键词： MoS_(2)/MoP Mott-Schottky heterostructures synergistic effect bidirectional polysulfide conversion shuttle effect lithium-sulfur(Li-S)batteries

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Sub-nanosized vanadate hybrid clusters maintain glucose homeostasis and restore treatment response in inflammatory disease in obese mice

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Nano Research 2024年第3期17卷 1818-1826页

作者： Kun Chen Shengqiu Liu Yujun Wei South China Advanced Institute for Soft Matter Science and Technology School of Emergent Soft MatterSouth China University of TechnologyGuangzhou 510641China Guangdong Provincial Key Laboratory of Technique and Equipment for Macromolecular Advanced Manufacturing South China University of TechnologyGuangzhou 510641China Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices South China University of TechnologyGuangzhou 510641China

Obesity is closely related with insulin resistance and chronic ***,we report that unsaturated lipid-modified polyoxovanadates(ULPOVs)can restrict weight gain of diet-induced obese mice and improve their glycemic control and obesity-associated *** administration of the sub-nanosized ULPOVs at a low dosage for 7 weeks reduces the body weight and almost normalizes the blood glucose levels of obese mice fed on a high-fat *** treatment increases the activity of the nuclear receptor peroxisome proliferator-activated receptorγ(PPARγ)and reduces intestinal caloric intake,which may be the main reason for blood sugar and body weight *** addition to insulin-sensitizing,PPARγactivation induced by ULPOV treatment in obese mice with atopic dermatitis(AD)promotes the type 2 T helper(TH_(2))cell selective responses and therapeutic effects on immune dysregulation caused by *** data suggest sub-nanosized polyoxovanadate clusters as a class of potential candidates to relieve symptoms accompanied by diet-induced obesity.

关键词： polyoxovanadates lipid modification glucose homeostasis obesity inflammatory disease peroxisome proliferator-activated receptorγ(PPARγ)

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Electronic structure engineering of single atomic sites by plasmoninduced hot electrons for highly efficient and selective photocatalysis

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Nano Research 2024年第8期17卷 6960-6967页

作者： Xiaoya Huang Xinyuan Li Akang Chen Hongfei Gu Shouyuan Li Tailei Hou Shuwen Zhu Shuang Yu Yin Song Jiatao Zhang Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications MIIT Key Laboratory of Medical Molecule Science and Pharmaceutical EngineeringMOE Key Laboratory of Cluster ScienceSchool of Chemistry and Chemical EngineeringSchool of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China MIIT Key Laboratory of Complex-field Intelligent Exploration School of Optics and PhotonicsBeijing Institute of TechnologyBeijing 100081China

Single atom(SA)catalysts have achieved great success on highly selective heterogeneous catalysis due to their abundant and homogeneous active *** electronic structures of these active sites,restrained by their localized coordination environments,significantly determine their catalytic performances,which are difficult to ***,we investigated the effect of localized surface plasmon resonance(LSPR)on engineering the electronic structures of single atomic ***,core–shell structures consisted of Au core and transition metal SAs loaded N-doped carbon(CN)shell were constructed,namely Au@M-SA/CN(M=Ni,Fe,and Co).It was demonstrated that plasmon-induced hot electrons originated from Au were directionally injected to the M-SAs under visible light irradiation,which significantly changed their electronic structures and meanwhile facilitated improved overall charge separation *** as-prepared Au@Ni-SA/CN exhibited highly efficient and selective photocatalytic CO_(2) reduction to CO performance,which is 20.8,17.5,and 6.9 times those of Au nanoparticles,Au@CN,and Ni-SA/CN,*** spectroscopy analysis and theoretical calculations confirmed that the plasmon enhanced Ni-SA/CN sites featured increased charge density for efficient intermediate activation,contributing to the superb photocatalytic *** work provides a new insight on plasmon and atomic site engineering for efficient and selective catalysis.

关键词： single atom catalysts plasmon enhancement coupling effect photocatalysis CO_(2) reduction

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An Approach to Optimize the Mechanical Properties of Cylindrical Negative Stiffness Structures

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ce/papers 2025年第2期8卷 1078-1086页

作者： Liu, Xin Tan, Xiaojun Wang, Bing National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of Technology Harbin150080 China School of Civil Aviation Northwestern Polytechnical University Xi'an710072 China

Negative stiffness (NS) structure, as a type of mechanical metamaterial, possess numerous excellent properties and has broad potential applications in areas such as impact energy absorption, vibration damping, and noise reduction. However, their energy absorption efficiency is not high. Typically, incorporating fillers into honeycomb structures proves to be an effective strategy for augmenting the mechanical properties of honeycomb materials. In this study, we propose a model for a filled cylindrical NS structure (CNS), where the fillers are treated as springs to facilitate finite element simulation. Subsequently, we further investigate the fundamental mechanical properties and energy dissipation capacity of unfilled CNS structures as well as filled CNS structures employing distinct types of fillers, including linear elastic and viscoelastic fillers. The results indicate that linear elastic fillers do not have a positive impact on improving the energy dissipation capacity of CNS structures but can be used to adjust the response curve. When viscoelastic fillers are filled inside the CNS structure, they can effectively enhance the strength and energy dissipation capacity of the CNS structure. Moreover, the approach presented in this investigation holds significant reference value for the design of various mechanical metamaterials based on NS structures. © 2025 Ernst & Sohn GmbH.

关键词： Honeycomb structures

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Super-Tough and Environmentally Stable Aramid Nanofiber@MXene Coaxial Fibers with Outstanding Electromagnetic Interference Shielding Efficiency

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Nano-Micro Letters 2022年第7期14卷 72-85页

作者： Liu-Xin Liu Wei Chen Hao-Bin Zhang Lvxuan Ye Zhenguo Wang Yu Zhang Peng Min Zhong-Zhen Yu State Key Laboratory of Organic-Inorganic Composites College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029People’s Republic of China Beijing Key Laboratory of Advanced Functional Polymer Composites Beijing University of Chemical TechnologyBeijing 100029People’s Republic of China Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical TechnologyBeijing 100029People’s Republic of China

Although electrically conductive and hydrophilic MXene sheets are promising for multifunctional fibers and electronic textiles,it is still a challenge to simultaneously enhance both conductivity and mechanical properties of MXene fibers because of the high rigidity of MXene sheets and insufficient inter-sheet ***,we demonstrate a core-shell wet-spinning methodology for fabricating highly conductive,super-tough,ultra-strong,and environmentally stable Ti_(3)C_(2)T_(x) MXene-based core-shell fibers with conductive MXene cores and tough aramid nanofiber(ANF)*** highly orientated and low-defect structure endows the ANF@MXene core-shell fiber with supertoughness of~48.1 MJ m^(-3),high strength of~502.9 MPa,and high conductivity of~3.0×10^(5)S m^(-1).The super-tough and conductive ANF@MXene fibers can be woven into textiles,exhibiting an excellent electromagnetic interference(EMI)shielding efficiency of 83.4 dB at a small thickness of 213μ***,the protection of the ANF shells provides the fibers with satisfactory cyclic stability under dynamic stretching and bending,and excellent resistance to acid,alkali,seawater,cryogenic and high temperatures,and *** oxidation resistance of the fibers is demonstrated by their wellmaintained EMI shielding *** multifunctional core-shell fibers would be highly promising in the fields of EMI shielding textiles,wearable electronics and aerospace.

关键词： Core-shell fibers MXene sheets Electromagnetic interference shielding Aramid nanofibers Super-toughness

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Thermal response, oxidation and ablation of ultra–high temperature ceramics, C/SiC, C/C, graphite and graphite–ceramics

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Journal of Materials science & technology 2022年第7期102卷 137-158页

作者： Xinghong Zhang Baihe Du Ping Hu Yuan Cheng Jiecai Han National Key Laboratory of Science and Technology on Advanced Composites in Special Environments and Center for Composite Materials and StructuresHarbin Institute of TechnologyHarbin 150001China

Various thermal protection materials exhibit obviously different and complicated thermal response,oxidation and ablation behavior,which are very important for the appropriate design and ***,the relative researches are very few *** this work,the thermal response,oxidation and ablation behavior of representative thermal protection materials including ultra-high temperature ceramics,C/SiC,C/C, graphite and graphite-ceramic were investigated systematically in strong heat flux,high enthalpy and low-pressure *** response of these materials was analyzed based on experimental results and thermal energy balance that accounts for all of the heat transfer processes transporting energy into and out of the *** factors were playing important roles in the thermal response including thermal conductivity,volumetric heat capacity,catalytic efficiency,emissivity and oxidation characteristics of the *** importance of each factor not only depends on the material characteristics such as material composition and phase content but also environment parameters including heat flux,enthalpy,pressure and testing *** comparisons and relationships of oxidation and ablation behaviors for these materials under extreme environments were also illustrated in ***,thermal response and ablation behaviors of pre-oxidized material or repeated tests were also performed to evaluate the effect of pre-treatment on the performance and reusability of thermal protection *** work offers guiding significance for the appropriate design and selection of thermal protection materials.

关键词： Thermal protection materials Ceramic Thermal response Oxidation Ablation

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Co-pyrolysis of soybean soapstock with iron slag/aluminum scrap,and characterization and analysis of their products

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Chinese Journal of Chemical Engineering 2023年第1期53卷 25-36页

作者： Xueguang Li Mengyan Yu Changfa Zhang Xiangtong Li Guangqing Liu Jianjun Dai Chunbao Zhou Yang Liu Jie Fu Yingwen Zhang Bang Yao State Key Laboratory of Organic-Inorganic Composites College of Chemical EngineeringBeijing Advanced Innovation Center for Soft Matter Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China

Soybean soapstock(SS) is one of the main solid wastes produced in the refinery of edible oil processing. In this study, the co-pyrolysis of SS with iron slag(IS) and aluminum scrap(AS) was carried out in a tubular furnace. The gas, liquid and solid products were characterized and the char yield decreased with increasing IS/AS ratio. IS and AS can improve the gas yield, and when the ratio of SS/IS was 1:0.25, the total pyrolysis gas and hydrogen contents were significantly increased. The content of oxygen compounds in pyrolysis oil decreased during co-pyrolysis, while AS promoted the content of polycyclic aromatic hydrocarbons in pyrolysis oil. The co-pyrolysis reaction can be divided into four stages, the mass loss rate reaches the maximum at the third stage(390–575 ℃). The molar ratio of H/C was lower for pyrolysis,indicating good stability of pyrolysis char owing to the high degree of carbonization and *** possible co-pyrolysis reaction mechanism was explored.

关键词： Pyrolysis Soybean soapstock Iron slag Aluminum scrap Adsorption Catalyst

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Spray pyrolysis-derived W-doped MoSe_(2)/rGO paper-like microspheres:optimization of microstructure and mesostructure for enhanced lithium storage

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Rare Metals 2024年第7期43卷 3019-3031页

作者： Wei Wang Jun-Yu Chen Jie Ouyang Hong Yin Ao-Jie Li Liang Chen Jun-Lin Huang Yu-Can Zhu Gang-Yong Li Zhao-Hui Hou Key Laboratory of Hunan Province for Advanced Carbon-based Functional Materials Hunan Institute of Science and TechnologyYueyang 414006China School of Chemistry and Chemical Engineering Hunan Institute of Science and TechnologyYueyang414006China Hunan Province Key Laboratory of Materials Surface&Interface Science and Technology Material Science and Engineering SchoolCentral South University of Forestry and TechnologyChangsha 410004China International Iberian Nanotechnology Laboratory(INL) AvMestre Jose Veiga4715-330 BragaPortuga

Two-dimensional MoSe_(2) is a promising candidate for lithium-ion battery ***,its conductivity and lithium storage volumetric effect still need to be *** this work,W-doped MoSe_(2)/rGO paper-like microspheres are successfully prepared through ultrasonic spray pyrolysis,achieving optimization at both the microstructure and mesostructure to enhance the lithium storage performance of the ***,by utilizing the similar two-dimensional structure between MoSe_(2) and rGO,self-assembly is achieved through spray pyrolysis,resulting in a well-defined van der Waals heterostructure at the interface on the microscale,enhancing the electron and ion transfer capability of the ***,the mesoscale paper-like microsphere morphology provides additional volume expansion buffering ***,W-doping not only increases the interlayer spacing of MoSe_(2)(0.73 nm),thereby reducing the diffusion resistance of Li+,but also allow for the modulation of the energy band structure of the *** functional theory(DFT)calculations confirm that W-doped MoSe_(2)/rGO exhibits the narrowest bandgap(0.892 eV).Therefore,the composite demonstrates excellent lithium storage performance,maintaining a specific capacity of 732.9 mAh·g^(-1)after 300 cycles at a current density of 1 A·g^(-1).

关键词： Molybdenum selenide Heterostructure Microspheres Li-ion batteries Kinetics

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Modeling of the process-induced stress, damage, microstructure, and deformation evolution during the pyrolysis process manufacturing CMCs

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Journal of advanced Ceramics 2023年第12期12卷 2345-2359页

作者： Qiang Liu Suwan Ma Zeshuai Yuan Yuan Li Xiaodong Gong Junping Li Man Zhu Tianjian Lu State Key Laboratory of Mechanics and Control for Aerospace Structures Nanjing University of Aeronautics and AstronauticsNanjing 210016China Key Laboratory of Advanced Functional Composites Technology Aerospace Research Institute of Materials&Processing TechnologyBeijing 100076China College of Civil Engineering Nanjing Tech UniversityNanjing 211800China

An insightful understanding of the formation mechanism of process-inherent defects anddeformation is increasingly important for the property evaluation and structural design of ceramicmatrix composites (CMCs). For this purpose, a coupled thermal–diffusive–mechanical modelingapproach was proposed by considering three important phenomena that occur during the pyrolysisprocess for manufacturing CMCs: variations of the physical and mechanical properties of theconstituents, generation and diffusive of pyrolysis gas, and multiple thermal deformations. Thesynergistic effects of these three phenomena on the stress, damage development, microstructuralmorphology, and process deformation of SiC matrix composites were investigated using finiteelement simulations. This new approach was validated by comparing the simulation and experimentalresults. Significant volume shrinkage of the matrix during the polymer-to-ceramic transformationresulted in large tensile stresses and subsequent highly fragmented microstructure in CMCs. Thepyrolysis-gas-induced expansion on the matrix under a damage state may yield a positive processdeformation of CMCs at the macroscale, overcoming the effects of the volume shrinkage of the bulkmatrix at the microscale. The modeling approach is expected to guide high-quality manufacturing ofCMCs and comprehensive studies of structure–processing–property relationships.

关键词： SiC pyrolysis gas process simulation damage process deformation

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