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Rare earth-free magnetocaloric material Fe82Hf6Zr7B4Cu1 for high-temperature applications

RSC Advances 2025年第19期15卷 15310-15317页

作者： Vinod, Anjana Diraviam, Arvindha Babu Muthuvel, Manivel Raja Wuppulluri, Madhuri School of Advanced Sciences Vellore Institute of Technology Tamil Nadu Vellore632014 India Defence Metallurgical Research Laboratory Telangana Hyderabad500058 India Ceramic Composites Laboratory Centre for Functional Materials Vellore Institute of Technology India

The magnetocaloric effect (MCE) has garnered much attention in recent years, especially for rare earth (RE)-free magnetic materials. The increasing focus on these materials arises from their prospective uses in cryogenic magnetic cooling and elevated temperature environments. The study conducts a systematic experimental examination of a novel magnetocaloric material, Fe82Hf6Zr7B4Cu1 ribbons, primarily aimed at characterising their structural, magnetic, and magnetocaloric properties. X-ray diffraction (XRD) analysis confirmed the successful incorporation of hafnium in the Fe site of the Fe-Zr-B-Cu matrix. Furthermore, the magnetic properties of the ribbon were also investigated, yielding a Curie transition temperature of 678 K and a magnetic entropy change of 0.448 J kg−1 K−1 at 2.0 T. Notably, the relative cooling power and refrigeration capacity were determined to be 11.87 J kg−1 and 14.0 J kg−1, respectively, highlighting the potential of the material for high-temperature magnetocaloric applications. These findings collectively demonstrate that the novel Fe82Hf6Zr7B4Cu1 ribbon exhibits promising magnetocaloric properties, rendering it a suitable candidate for further investigation and potential applications in high-temperature magnetocaloric devices. © 2025 The Royal Society of Chemistry.

关键词： Chilling

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Crystalline@amorphous core-shell structure of WO3@WO_(3-x)S_(x) established via doping strategy for enhancing magnesium ions storage performance

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Journal of Magnesium and Alloys 2025年第3期13卷 1353-1363页

作者： Shiqi Ding Yuxin Tian Jiankang Chen Guofeng Wang Bing Sun He Lv Lei Wang Guicun Li Alan Meng Zhenjiang Li College of Materials Science and Engineering Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life ScienceMOEShandong Key Laboratory of Biochemical AnalysisCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042ShandongPR China Qingdao Engineering Research Center for New Metallic Functional Materials Characteristic Laboratory of Advanced Metal Functional Materials and Processing in Universities of ShandongQingdao Binhai UniversityQingdao 266555ShandongPR China

Designing cathode possessing crystalline@amorphous core-shell structure with both active core and shell is a meaningful work for resolving the low speciﬁc capacity,unstable cycling performance and sluggish reaction kinetics issues of rechargeable magnesium batteries(RMBs)by providing more active sites as well as releasing inner stress during ***,WO_(3)@WO_(3-x)S_(x) owning crystalline@amorphous core-shell structure containing both active core and active shell is constructed successfully by introducing S into metastable WO3 structure under temperatureﬁeld *** such structure,amorphous shell would provide continuous Mg^(2+)diffusion channels due to its isotropy property for most Mg^(2+)migrating rapidly to interface and then adsorb at ions reservoir formed by interfacial electricﬁeld for increasing speciﬁc *** also makes security for stable structure of WO_(3)@WO_(3-x)S_(x) by alleviating volume expansion of crystalline core WO_(3) during cycling to prolong cycling ***,“softer”ions S^(2-)would weaken interaction between hard acid Mg^(2+) and ionic lattice to enhance Mg^(2+)storage ***,WO_(3)@WO_(3-x)S_(x) delivers the superior cycling performance(1000 cycles with 83.3%),rate capability(88.5 mAh g^(-1) at 1000 mA g^(-1))and speciﬁc capacity(about 150 mAh g^(-1) at 50 mA g^(-1)),which is near 2 times higher than that of *** is believed that the crystalline@amorphous core-shell structure with both active core and shell designing via doping strategy is enlightening for the development of high-performance RMBs,and such design can be extended to other energy storage devices for better electrochemical performance.

关键词： Doping Sulfuration Crystalline@amorphous core-shell structure WO_(3) Rechargeable magnesium batteries

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An Approach to Optimize the Mechanical Properties of Cylindrical Negative Stiffness Structures

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ce/papers 2025年第2期8卷 1078-1086页

作者： Liu, Xin Tan, Xiaojun Wang, Bing National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of Technology Harbin150080 China School of Civil Aviation Northwestern Polytechnical University Xi'an710072 China

Negative stiffness (NS) structure, as a type of mechanical metamaterial, possess numerous excellent properties and has broad potential applications in areas such as impact energy absorption, vibration damping, and noise reduction. However, their energy absorption efficiency is not high. Typically, incorporating fillers into honeycomb structures proves to be an effective strategy for augmenting the mechanical properties of honeycomb materials. In this study, we propose a model for a filled cylindrical NS structure (CNS), where the fillers are treated as springs to facilitate finite element simulation. Subsequently, we further investigate the fundamental mechanical properties and energy dissipation capacity of unfilled CNS structures as well as filled CNS structures employing distinct types of fillers, including linear elastic and viscoelastic fillers. The results indicate that linear elastic fillers do not have a positive impact on improving the energy dissipation capacity of CNS structures but can be used to adjust the response curve. When viscoelastic fillers are filled inside the CNS structure, they can effectively enhance the strength and energy dissipation capacity of the CNS structure. Moreover, the approach presented in this investigation holds significant reference value for the design of various mechanical metamaterials based on NS structures. © 2025 Ernst & Sohn GmbH.

关键词： Honeycomb structures

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Interfacial Zn^(2+)-solvation regulator towards reversible and stable Zn anode

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Journal of Energy Chemistry 2025年第1期100卷 684-692页

作者： Miao Zhou Xiongbin Luo Hang Li Shan Guo Zhuang Tong Xiaotao Zhou Xu Li Zhaohui Hou Shuquan Liang Guozhao Fang College of Mechanical Engineering Key Laboratory of Hunan Province for Advanced Carbon-based Functional MaterialsHunan Institute of Science and TechnologyYueyang 414006HunanChina School of Materials Science and Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan ProvinceCentral South UniversityChangsha 410083HunanChina College of Materials and Metallurgy Guizhou UniversityGuiyang 550000GuizhouChina National Energy Metal Resources and New Materials Key Laboratory Central South UniversityChangsha 410083HunanChina

Aqueous zinc-ion batteries (AZIBs) are fundamentally challenged by the instability of the electrode/electrolyte interface,predominantly due to irreversible zinc (Zn) deposition and hydrogen ***,the intricate mechanisms behind the electrochemical discrepancies induced by interfacial Zn^(2+)-solvation and deposition behavior demand comprehensive *** molecules endowed with special functional groups (such as hydroxyl,carboxyl,etc.) have the potential to significantly optimize the solvation structure of Zn^(2+)and regulate the interfacial electric double layer (EDL).By increasing nucleation overpotential and decreasing interfacial free energy,these functional groups facilitate a lower critical nucleation radius,thereby forming an asymptotic nucleation model to promote uniform Zn ***,this study presents a pioneering approach by introducing trace amounts of n-butanol as solvation regulators to engineer the homogenized Zn (H-Zn) anode with a uniform and dense *** interfacial reaction and structure evolution are explored by in/ex-situ experimental techniques,indicating that the H-Zn anode exhibits dendrite-free growth,no by-products,and weak hydrogen evolution,in sharp contrast to the bare ***,the H-Zn anode achieves a remarkable Zn utilization rate of approximately 20% and simultaneously sustains a prolonged cycle life exceeding 500 ***,the H-Zn//NH_(4)V_(4)O^(10)(NVO) full battery showcases exceptional cycle stability,retaining 95.04%capacity retention after 400 cycles at a large current density of 5 A g^(-1).This study enlightens solvation-regulated additives to develop Zn anode with superior utilization efficiency and extended operational lifespan.

关键词： Aqueous zinc-ion batteries Zn^(2+)-solvation structure Interfacial reaction Asymptotic nucleation model Reversible and stable Zn anode

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Remission of iron overload in adipose tissue of obese mice by fatty acid-modified polyoxovanadates

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Rare Metals 2025年第1期44卷 461-471页

作者： Kun Chen Yu-Rong Qin Sheng-Qiu Liu Rou-Ling Chen South China Advanced Institute for Soft Matter Science and Technology School of Emergent Soft MatterSouth China University of TechnologyGuangzhou 510641China Guangdong Provincial Key Laboratory of Technique and Equipment for Macromolecular Advanced Manufacturing South China University of TechnologyGuangzhou 510641China Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices South China University of TechnologyGuangzhou 510641China Department of Computer Science City University of Hong KongHong Kong 999077China

Iron overload has been evidenced to contribute to obesity-associated metabolic disorders,including insulin *** to reduce iron levels might help manage the metabolic complications associated with ***,it is demonstrated that the specific accumulation of oleic acid-modified polyoxovanadates(OPOVs)in adipose tissue leads to the reduction of iron concentrations in adipocytes in mice fed with a high-fat diet(HFD).Conjugation of oleic acids to polyoxovanadates enables tissue-specific depletion of iron from white adipose tissue(WAT)by OPOVs,protecting mice from HFD-induced obesity and obesity-associated metabolic *** tolerance and insulin sensitivity are improved in OPOV-treated mice,which demonstrates that the OPOV-induced iron depletion can reverse the metabolic degeneration caused by HFD-induced ***,a decrease in expression of the marker genes of iron overload suggests the participation of OPOVs in maintaining iron homeostasis and a potential medical application of vanadium clusters in targeting the iron overload caused by *** findings underscore the potential of vanadate-based clusters tailored to address the complex interplay between iron metabolism and metabolic health.

关键词： Polyoxovanadates Lipophilic conjugation Obesity Iron overload Insulin resistance

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Dynamic Regulation of Hydrogen Bonding Networks and Solvation Structures for Synergistic Solar‑Thermal Desalination of Seawater and Catalytic Degradation of Organic Pollutants

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Nano-Micro Letters 2025年第2期17卷 548-565页

作者： Ming‑Yuan Yu Jing Wu Guang Yin Fan‑Zhen Jiao Zhong‑Zhen Yu Jin Qu Beijing Key Laboratory of Advanced Functional Polymer Composites Beijing University of Chemical TechnologyBeijing 100029People’s Republic of China State Key Laboratory of Organic‑Inorganic Composites College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029People’s Republic of China

Although solar steam generation strategy is efficient in desalinating seawater,it is still challenging to achieve continuous solar-thermal desalination of seawater and catalytic degradation of organic ***,dynamic regulations of hydrogen bonding networks and solvation structures are realized by designing an asymmetric bilayer membrane consisting of a bacterial cellulose/carbon nanotube/Co_(2)(OH)_(2)CO_(3)nanorod top layer and a bacterial cellulose/Co_(2)(OH)_(2)CO_(3)nanorod(BCH)bottom ***,the hydrogen bonding networks inside the membrane can be tuned by the rich surface–OH groups of the bacterial cellulose and Co_(2)(OH)_(2)CO_(3)as well as the ions and radicals in situ generated during the catalysis ***,both SO_(4)^(2−)and HSO_(5)−can regulate the solvation structure of Na^(+)and be adsorbed more preferentially on the evaporation surface than Cl^(−),thus hindering the de-solvation of the solvated Na^(+)and subsequent nucleation/growth of ***,the heat generated by the solar-thermal energy conversion can accelerate the reaction kinetics and enhance the catalytic degradation *** work provides a flow-bed water purification system with an asymmetric solar-thermal and catalytic membrane for synergistic solar thermal desalination of seawater/brine and catalytic degradation of organic pollutants.

关键词： Solar steam generation Seawater desalination Catalytic degradation Bacterial cellulose Cobalt hydroxycarbonate nanorods

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Self-assembly of graphene foam anchored with magnetic Fe2O3 nanocrystals for high efficient electromagnetic wave absorption

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Journal of Materials science: Materials in Electronics 2025年第14期36卷 1-17页

作者： Yu, Qi Wang, Yunlong Wang, Yiyi Du, Chenglong Zhang, Zhengqian Zheng, Daming School of Materials Science and Engineering Shenyang Aerospace University Shenyang110136 China Liaoning Key Laboratory of Advanced Polymer Matrix Composites Manufacturing Technology Shenyang Aerospace University Shenyang110136 China

Three-dimensional (3D) graphene based materials have many advantages including low density, large specific surface area, high electrical conductivity, abundance of pores and good mechanical compressibility, which make them considered as potential candidate for electromagnetic wave (EMW) absorption materials. In this study, the 3D graphene foam anchored with magnetic Fe2O3 nanocrystals using diethylene glycol as solvent (3D-DEG-rGO@Fe2O3) were prepared by solvothermal method, synchronously realizing the self-assembly of 3D graphene and in-situ reduction of magnetic Fe2O3 nanoparticles without any reducing agent. The 3D-DEG-rGO@Fe2O3 demonstrates excellent microwave absorption due to good impedance matching and synergistic electromagnetic loss mechanisms as well as porous network structure. The minimum reflection loss (RLmin) is − 63.86 dB at 12.47 GHz with a thin thickness of only 2.28 mm, and the effective frequency bandwidth with the RL values less than − 10 dB is 5.53 GHz in the range of 12.47–18 GHz. The 3D-DEG-rGO@Fe2O3 foam with extremely low bulk density, excellent EMW absorption ability and good compression recovery, can be attractive candidate materials for EMW absorption applications. © The Author(s), under exclusive licence to Springer science+Business Media, LLC, part of Springer Nature 2025.

关键词： Infrared radiation

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Multi-cyclic Swelling for Self-regulated Growth of Covalently Crosslinked Polymers

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Chinese Journal of Polymer science 2025年第3期43卷 509-516页

作者： De-Fu Zhu Hong Wang Jian Chen Xin-Hong Xiong Jia-Xi Cui Yangtze Delta Region Institute(Huzhou) University of Electronic Science and Technology of ChinaHuzhou 313001China Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine PolymersHunan Provincial Key Lab of Advanced Materials for New Energy Storage and ConversionHunan Province College Key Laboratory of QSAR/QSPRSchool of Chemistry and Chemical EngineeringHunan University of Science and TechnologyXiangtan 411201China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of China ChengduChengdu 611731China

Organisms are capable of self-growth through the integration of the nutrients provided by the external *** process slows down when they *** this study,we mimicked this self-regulated growth via a simple swelling-polymerization strategy in which the stretching polymer chains in the original networks provide entropic elasticity to restrict growth in high growth *** typical covalently crosslinked polymers,such as acrylamide-based hydrogels and HBA-based elastomers,as examples,we demonstrate that the crosslinked polymers can absorb polymerizable compounds through a swelling-polymerization process to expand their sizes,but the growth extent becomes smaller with increasing growth cycle until reaching a *** addition to their size,these materials become stiffer and exhibit less swelling ability in *** work not only provides a new growing mode to tune the properties of crosslinked polymers but also discloses the underlying mechanism of crosslinked polymers in multi-cyclic swelling conditions.

关键词： Crosslinked polymers Swelling Self-growing Mechanical property

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Brief review of external physical field-boosted low-temperature electrodeposition for metals and alloys

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International Journal of Minerals,Metallurgy and Materials 2025年第5期32卷 992-1007页

作者： Junjian Zhou Zhiyuan Li Qi Wang Na Li Xu Li Yana Wang Weili Song Institute of Advanced Structure Technology Beijing Institute of TechnologyBeijing 100081China Beijing Key Laboratory of Lightweight Multi-Functional Composite Materials and Structures Beijing Institute of TechnologyBeijing 100081China School of Materials Science and Engineering Sun Yat-Sen UniversityGuangzhou 510006China Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai) Zhuhai 519082China State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China School of Mechanical and Vehicular Engineering Beijing Institute of TechnologyBeijing 100081China

Electrochemical metallurgy at low temperature(<473 K)shows promise for the extraction and refinement of metals and alloys in a green and sustainable ***,the kinetics of the electrodeposition process is generally slow at low temperature,resulting in large overpotential and low current ***,the application of external physical fields has emerged as an effective strategy for improving the mass and charge transfer processes during electrochemical *** review highlights the challenges associated with low-temperature electrochemical processes and briefly discusses recent achievements in optimizing electrodeposition processes through the use of external physical *** regulating effects on the optimization of the electrodeposition process and the strategies for select-ing various external physical fields,including magnetic,supergravity,and ultrasonic fields are summarized from the perspectives of equipment and ***,advanced methods for in-situ characterization of external physical field-assisted electrodeposition processes are reviewed to gain a deeper understanding of metallic *** in-depth exploration of the mechanism by which external physical fields affect the electrode process is essential for enhancing the efficiency of metal extraction at low temperatures.

关键词： low-temperature electrodeposition external physical field electrode kinetics low-temperature electrolyte in-situ characteriz-ation methods

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Polybenzimidazolium-reinforced polyimide separators to inhibit dendrites for high-security lithium-ion batteries

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science China Chemistry 2025年

作者： Guohua Sun Jiaqi Cui Qingsong Zhang Yisong Zhou Xinluo Li Yingying Zhang Zhanao Zhang Xin Zhang Jiantao Fan Pengpeng Li Lianlong Hou Nanjun Chen Hebei Key Laboratory of Flexible Functional Materials School of Materials Science and Engineering Hebei University of Science and Technology State Key Laboratory of Organic-Inorganic Composites Beijing University of Chemical Technology Academy for Advanced Interdisciplinary Studies Southern University of Science and Technology State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering Xiamen University

Lithium dendrite formation poses a significant safety hazard in lithium-ion batteries（LIBs）, severely impeding their widespread adoption and further technological advancements. Here, we present a novel quaternized polybenzimidazolium（q-PBI） to armor polyimide（PI） nanofiber separator（q-PBI@PI）, in which the q-PBI containing lithiophilicity and anionphilicity sites serves as the multifunctional nano-layers to suppress the Li dendrite and reinforce the mechanical properties of PI nanofiber ***, the q-PBI@PI separator displays an unprecedented mechanical strength of 82.8 MPa, significantly outperforming previously reported PI nanofiber membranes（typically below 50.0 MPa）. Besides, we demonstrate that the q-PBI@PI separator simultaneously possesses low nucleation overpotential（59 mV） and exceptional average coulombic efficiency due to the suppression of Li dendrite. Importantly, q-PBI@PI-based Li||Li battery enables a stable Li plating-stripping at 1.0 m A cm-2for600 h. Attributing to these exceptional merits, the armored PI separator-based LIBs display remarkable specific capability and capacity retention. The density function theory calculations reveal that q-PBI is conducive to the desolvation of Li+and can immobilize Li+and PF6-ions near affinity sites of PI nanofibers for inhibiting the formation of Li dendrites. Our work paves a new avenue for the design of next-generation high-performing separators in LIBs.

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