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Developing High-Energy, Stable All-Solid-State Lithium Batteries Using Aluminum-Based Anodes and High-Nickel Cathodes

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Nano-Micro Letters 2025年第1期17卷 1-15页

作者： Wu, Xin Wang, Meiyu Pan, Hui Sun, Xinyi Tang, Shaochun Zhou, Haoshen He, Ping Center of Energy Storage Materials & Technology Department of Energy Science and Engineering College of Engineering and Applied Sciences Jiangsu Key Laboratory of Artificial Functional Materials National Laboratory of Solid-State Microstructures and Collaborative Innovation Center of Advanced Microstructures Nanjing University Nanjing210093 China Department of Materials Science and Engineering College of Engineering and Applied Sciences Jiangsu Key Laboratory of Artificial Functional Materials National Laboratory of Solid-State Microstructures and Collaborative Innovation Center of Advanced Microstructures Nanjing University Nanjing210093 China

Aluminum (Al) exhibits excellent electrical conductivity, mechanical ductility, and good chemical compatibility with high-ionic-conductivity electrolytes. This makes it more suitable as an anode material for all-solid-state lithium batteries (ASSLBs) compared to the overly reactive metallic lithium anode and the mechanically weak silicon anode. This study finds that the pre-lithiated Al anode demonstrates outstanding interfacial stability with the Li6PS5Cl (LPSCl) electrolyte, maintaining stable cycling for over 1200 h under conditions of deep charge–discharge. This paper combines the pre-lithiated Al anode with a high-nickel cathode, LiNi0.8Co0.1Mn0.1O2, paired with the highly ionic conductive LPSCl electrolyte, to design an ASSLB with high energy density and stability. Using anode pre-lithiation techniques, along with dual-reinforcement technology between the electrolyte and the cathode active material, the ASSLB achieves stable cycling for 1000 cycles at a 0.2C rate, with a capacity retention rate of up to 82.2%. At a critical negative-to-positive ratio of 1.1, the battery’s specific energy reaches up to 375 Wh kg−1, and it maintains over 85.9% of its capacity after 100 charge–discharge cycles. This work provides a new approach and an excellent solution for developing low-cost, high-stability all-solid-state batteries. (Figure presented.) © The Author(s) 2025.

关键词： Solid-State Batteries

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Facile and adjustable production of self–standing oxygen–doped graphene membranes for optimized oxygen evolution electrocatalysis

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Nano Materials science 2025年第2期7卷 231-239页

作者： Chen, Liang Yang, Lanyun Hu, Liying Jin, Minghao Xu, Chenxi He, Binhong Wang, Wei Liu, Ying Li, Gangyong Hou, Zhaohui Key Laboratory of Hunan Province for Advanced Carbon‒based Functional Materials School of Chemistry and Chemical Engineering Hunan Institute of Science and Technology Hunan Yueyang414006 China College of Materials Science and Engineering Central South University of Forestry and Technology Hunan Changsha410004 China

Owing to abundant resource and affordable price, metal–free carbon has been extensively studied in the field of oxygen reduction reaction, while the related studies on oxygen evolution reaction (OER) are quite few. In this work, a facile and scalable knife coating coupled with annealing strategy is proposed to produce self–standing oxygen–doped graphene membranes (marked as O–GM–T, T represents the annealing temperature). Through systematic characterization and analysis, it is discovered the annealing treatment not only decreases the amount of oxygenic groups, but allows for controlled regulation of the oxygen configurations, leaving only C–OH/C–O–C and C[dbnd]O. Meanwhile, theoretical calculations indicate that the OER activity trend of different oxygen configurations is as follows: –COOH > C[dbnd]O ≈ C–OH > C–O–C. Despite the removal of highly active –COOH group through annealing treatment, the resulting O–GM–800 sample maintains good mechanical property and achieves a favorable balance on conductivity, hydrophilicity and catalytic sites. Consequently, it displays significantly improved OER performance compared to the counterparts, making it highly promising for applications in overall water splitting devices. Apparently, our work provides guidance for the rational design and controllable fabrication of self–standing carbon–based catalysts for energy–related reactions. © 2025 Chongqing University

关键词： Coatings

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An SPH model reconstruction framework with fragment mapping method for multiplate structure hypervelocity impact simulation

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Advances in Space Research 2025年第11期75卷 8140-8157页

作者： Cao, Xu Zhou, Jianqiu Xu, Huadong Song, Di Miao, Changqing National Key Laboratory of Science and Technology on Advanced Composites in Special Environment Harbin Institute of Technology Harbin150001 China School of Basic Medical Sciences Harbin Medical University Harbin150001 China School of Mechanical and Electrical Engineering University of Electronic Science and Technology of China Sichuan Chengdu611731 China

Smoothed Particle Hydrodynamics (SPH) method is widely used in hypervelocity impact analysis, but it is computationally inefficient for common multiplate structures, such as multi-shock, mesh double-bumper, and stuffed shields. To improve the efficiency and accuracy of the SPH method, a reconstruction framework is proposed, including a fragment identification method, a fragment mapping method, and a sequential modeling and simulation approach. In the reconstruction framework, the total impact simulation of a multiplate structure consisting of n plates is decomposed into n individual impacts on each plate. To reduce the computation for each impact, a fragment identification method and a fragment mapping method are developed. Fragments generated from the impact with the i-th plate (i © 2025 COSPAR

关键词： 3D reconstruction

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Abnormal dielectric behavior of glaserite-type Ba_(3−x)Sr_(x)MgSi_(2)O_(8)solid solution

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Journal of advanced Ceramics 2025年第2期14卷 77-86页

作者： Jiaqing Yang Peng Lei Xiaoqiang Song Changzhi Yin Meng Zhang Weicheng Lei Yiyang Cai Mingfei Cheng Yaodong Liu Zihang Chen Yaqing Hu Wenzhong Lu Wen Lei School of Optical and Electronic Information Key Lab of Functional Materials for Electronic Information(B)of MOEHuazhong University of Science and TechnologyWuhan 430074China Wenzhou Key Laboratory of Microwave Communication Materials and Devices Wenzhou Advanced Manufacturing Institute of HUSTWenzhou 325035China

The temperature coefficient of the resonant frequency(τ_(f))of low-permittivity(ε_(r))microwave dielectric ceramics is required to be near 0 ppm/℃for practical ***,owing to the polarization mechanism,τ_(f)of low-ε_(r)microwave dielectric ceramics is generally ***,a novel microwave dielectric ceramic,Ba_(3−x)Sr_(x)MgSi_(2)O_(8),with an abnormal positiveτ_(f)at the applied temperature is *** this study,Sr^(2+)with a relatively small ionic radius was introduced to replace Ba^(2+),and a single-phase solid solution was formed(x>0.5).Ba_(3−x)Sr_(x)MgSi_(2)O_(8)ceramics were discussed in glaserite-type topology with space groups of P_(3)^(-)for x≤0.5,relatively high symmetry P_(3)^(-)m1 for 0.5functional theory simulation calculations revealed that the preferential occupation of Sr^(2+)ions could decrease the intrinsic formation energy and improve the microwave dielectric properties by mitigating the ionic size mismatch within the crystal *** present research offers a strategy for discovering novel microwave dielectric ceramics with abnormalτ_(f)values,which could serve as τ_(f)regulators in practical applications because of their low cost and excellent microwave dielectric properties.

关键词： microwave dielectric ceramics abnormal dielectric behavior ion size mismatch [SiO4]tetrahedra tilting phase transition density functional theory(DFT)

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Optimal Design of Composite Structures for Unmanned Aerial Vehicles Based on Deep Learning 15

Optimal Design of Composite Structures for Unmanned Aerial V...

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15th Asia Conference on Mechanical and Aerospace Engineering, ACMAE 2024

作者： Xiang, Zijian Ma, Zhenyu Yang, Xixiang Deng, Xiaolong Lin, Guochang College of Aerospace Science and Engineering National University of Defense Technology Changsha410073 China National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of Technology Harbin150080 China

ISBN: (纸本)9781643685892

Composite materials are characterized by their lightweight and high-strength properties. Modern drone bodies predominantly utilize laminate structures made from composite materials. This article explores the application of deep learning methods in the design process of drone composite material structures, aiming to achieve weight reduction while maintaining structural strength and stiffness. To this end, we first conducted a study on the mechanical properties of composite laminates and employed a generative adversarial network (GAN) model to perform an inversion analysis of the single-layer parameters of the laminate. Subsequently, we executed a finite element simulation study of the UAV composite structure and applied the GAN model for inversion analysis. The laminate layering parameters were optimized and analyzed. The results indicate that the deep learning approach significantly enhances the accuracy of parameter inversion and the efficiency of layering design for composite laminate structures, demonstrating substantial application value for the optimal design of UAV composite material structures. © 2025 The Authors.

关键词： Laminated composites

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Prediction of New functional Fluorooxoborates with Expected Anionic Framework:A Case of CaB_(3)O_(5)F

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Chinese Physics Letters 2025年第3期42卷 85-92页

作者： Ke-Wang Zhang Wen-Qi Jin Ke Li Abudukadi Tudi Lin-Lin Liu Cong-Wei Xie Yu Xie Research Center for Crystal Materials CAS Key Laboratory of Functional Materials and Devices for Special Environmental ConditionsXinjiang Key Laboratory of Functional Crystal MaterialsXinjiang Technical Institute of Physics&ChemistryCASUrumqi 830011China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Key Laboratory of Materials Simulation Methods&Software of Ministry of Education International Center of Future ScienceKey Laboratory of Physics and Technology for Advanced Batteries(Ministry of Education)College of PhysicsJilin UniversityChangchun 130012China

The prediction of new fluorooxoborates as ultraviolet(UV)/deep ultraviolet(DUV)opto-electronic functional materials from a largely unexplored chemical space is a challenging *** has been suggested that the anionic frameworks formed by B–O and B–O–F units significantly determine the physical properties of ***,the rational design of anionic frameworks could facilitate the materials discovery ***,we propose that a candidate anionic framework can be efficiently derived from an existing one by slightly altering its oxygen *** this idea,we hypothesized the existence of a 1D[B_(3)O_(5)F]_(∞)chain from the wellknown 2D[B_(6)O_(9)F_(2_)]_(∞)***,seven CaB_(3)O_(5)F structures with the expected anionic framework were successfully ***-principles calculations show that all these structures have potential in the UV/DUV birefringent or nonlinear optical(NLO)material field,indicating that the 1D[B_(3)O_(5)F]_(∞)chain is indeed a promising anionic framework for achieving UV/DUV birefringent and NLO performance.

关键词： process borate anionic

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Ultrasonic sprayed hollow ceramic/carbon microspheres function as thermal insulation, ablative resistance, and electromagnetic shielding materials

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Ceramics International 2025年第13期51卷 18029-18037页

作者： Qin, Chuhui Zhong, Hangyu Hu, Hongli Kang, Zhonglei Zhang, Bo-xing South China Advanced Institute for Soft Matter Science and Technology School of Emergent Soft Matter South China University of Technology Guangzhou510640 China Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices South China University of Technology Guangzhou510640 China

Hollow ceramic/carbon microspheres (HCCMs) have widespread applications for thermal insulation and ablative resistance materials in aerospace areas, attributed to their multiple advantages such as low density, low thermal conductivity, oxidation and high-temperature resistance. In this work, we fabricated HCCMs with diameters around 18–242 μm by the ultrasonic spray method, using mixed solutions of poly(acrylonitrile) (PAN), polyvinyl pyrrolidone (PVP), and preceramic polymers as starting materials. After optimizing the morphology of HCCMs, we introduced them as fillers into phenolic resin (PR). By adjusting the ratio between HCCMs and PR, the optimal properties were obtained at a loading content of 30 wt% of HCCMs. The density of as-obtained PR composite was 0.70 g/cm3, the thermal conductivity was 0.27 W/(m·K), and the maximum electromagnetic shielding effectiveness was 76.30 dB at the frequency of 8–12 GHz. This work develops a powerful approach to fabricating HCCMs, and demonstrates their typical application as fillers in PR to improve thermal insulation, electromagnetic shielding, and ablative resistance performance. © 2025 Elsevier Ltd and Techna Group S.r.l.

关键词： Microspheres

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Coordinated Regulation of Bonding Interfacial Structure and Mechanical Properties of Al/Mg Alloy Composite Plates by Electrically Assisted Rolling

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Chinese Journal of Mechanical Engineering 2025年第1期38卷 246-260页

作者： Tingting Zhang Xingrun An Yan Wang Gongbo Bian Tao Wang College of Mechanical and Vehicle Engineering Taiyuan University of TechnologyTaiyuan 030024China Engineering Research Center of Advanced Metal Composites Forming Technology and Equipment of Ministry of Education Taiyuan University of TechnologyTaiyuan 030024China National Key Laboratory of Metal Forming Technology and Heavy Equipment Taiyuan University of TechnologyTaiyuan 030024China College of Materials Science and Engineering Taiyuan University of TechnologyTaiyuan 030024China.

Current research on the fabrication of rolled composite plates primarily focuses on processing and bonding *** with hot-rolling technology,the electrically assisted rolling process has demonstrated excellent performance in interfacial bonding ***,the influence of different current loading modes on the interfacial recombination process of composite panels varies *** this study,low-frequency electrically assisted rolling was used in the first pass to pre-bond a composite plate at a low reduction rate of 15%.High-frequency electrically assisted rolling was used during the second pass,and Al/Mg alloy composite plates were *** interfacial microstructure and mechanical properties of the composite plate were coordinated regulation by designing the rolling reduction *** results showed the interfacial morphology of the alternating distribution of the melt-diffusion layer,diffusion layer,and the formation of a new Al/Mg bonding *** the melt-diffusion interface,the irregular intermetallic compounds(IMCs)and the new Al/Mg bonding interface were alternately distributed,and the IMCs contained theα-Mg,Mg17Al12,and Mg2Al3 *** addition,an extremely high shear strength of 78.26 MPa was *** of the Mg alloy matrix was observed on the fracture surface of the Al alloy *** high shear strength was mainly attributed to the formation of a unique interfacial structure and the appearance of a melt-diffusion *** to the diffusion-reduction interface,the regular rectangular IMCs and the new Al/Mg bonding interface were alternately distributed,and the IMCs consisted of the Mg17Al12 and Mg2Al3 *** shear test results showed that the shear strength of the interface reached 68.69 MPa,and a regular distribution of the Mg alloy matrix with dimples and the Al alloy matrix with a necking zone was observed on the fracture surface of the Al *** strength test results revealed a maximum value of

关键词： Al/Mg alloy composite plate Electrically assisted rolling Bonding properties Interfacial structure

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The thermal stability of Er2O3 anti-reflective films deposited on CVD diamond by magnetron sputtering

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Ceramics International 2025年第13期51卷 17568-17574页

作者： Huang, Yabo Zhao, Xia Zhu, Xiaohua Liu, Shengji Wang, Xulei Yue, Yuehan Sun, Weishuai Wang, Pei Guo, Xiaoqin Li, Chengming Henan Key Laboratory of Aeronautical Materials and Application Technologies Zhengzhou University of Aeronautics School of Materials Science and Engineering Henan Zhengzhou450046 China Beijing Institute of Metrology Beijing100029 China SF Diamond Co. LTD Zhengzhou450016 China Henan Key Laboratory of High Performance Carbon Fiber Reinforced Composites Institute of Carbon Matrix Composites Henan Academy of Sciences Zhengzhou450046 China Institute for Advanced Materials and Technology State Key Laboratory for Advanced Metals and Materials University of Science and Technology Beijing Beijing100083 China

Erbium oxide (Er2O3) films with excellent thermal and optical performance are essential for application as heat-resistant and anti-reflective (AR) materials in chemical vapor deposition (CVD) diamond infrared windows. In this study, the thermal stability of Er2O3 AR films was investigated by heat treatment. The phase composition, microstructure, thermogravimetric analysis, mechanical properties, and infrared (IR) transmission performances of the Er2O3 AR films were thoroughly investigated. The results show that the cubic (222) plane orientation of the Er2O3 AR films after heat treatment was preferential to that at room temperature. No significant change was observed in the DSC and TG curve at the temperature varied, but the DSC curve of the Er2O3 AR films revealed two distinct stages at 502 °C and 798 °C owing to the formation of Er2O3 (420) and (134) planes. Specifically, the phase structure remained unchanged by high-resolution transmission electron microscope (HRTEM) observation, and the peak at 578.4 cm−1 was the only obvious impurity peak in the Raman spectrum owing to the introduction of the Er–O bond. Additionally, significant shedding of the Er2O3 AR films on the surface of the CVD diamond occurred at high temperatures. The grain size and roughness increased as the temperature increased, adversely affecting the continuous abrasion resistance of the Er2O3 AR films. Moreover, the Er2O3 AR films exhibited outstanding mechanical and optical properties at 800 °C, achieving a depth of only 0.65 μm and a maximum transmittance increased from 65 % of diamond to 76 %. This study provides valuable insights into the thermal stability of the Er2O3 AR films under high temperature application scenarios. © 2025 Elsevier Ltd and Techna Group S.r.l.

关键词： Oxide films

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PtPdAg nanotrees with low Pt content for high CO tolerance within formic acid and methanol electrooxidation

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Rare Metals 2025年第1期44卷 300-310页

作者： Yu-Fei Wang Shou-Lin Zhang Yu-Xin Deng Shi-Han Luan Cai-Kang Wang Lin-Fei Ding Xian Jiang Dong-Mei Sun Ya-Wen Tang Jiangsu Key Laboratory of New Power Batteries Jiangsu Collaborative Innovation Centre of Biomedical Functional MaterialsSchool of Chemistry and Materials ScienceNanjing Normal UniversityNanjing 210023China School of New Energy Nanjing University of Science and TechnologyJiangyin 214443China Advanced Analysis and Testing Center Nanjing Forestry UniversityNanjing 210037China

To efficiently diminish the Pt consumption while concurrently enhancing the anodic reaction kinetics,a straightforward synthesis for PtPdAg nanotrees(NTs)with exceedingly low Pt content is presented,utilizing the galvanic replacement reaction between the initially prepared PdAg NTs and Pt *** to the multilevel porous tree-like structure and the incorporation of low amounts of Pt,the electrocatalytic activity and stability of PtPdAg NTs are markedly enhanced,achieving 1.65 and 1.69 A·mg^(-1)Pt+Pd for the anodic reactions of formic acid oxidation(FAOR)and methanol oxidation(MOR)within DLFCs,surpassing the performance of PdAg NTs,as well as that of commercial Pt and Pd *** functional theory(DFT)calculations reveal that the addition of low amounts of Pt leads to an increase in the d-band center of PtPdAg NTs and lower the COads adsorption energy to-1.23 eV,enhancing the anti-CO toxicity properties *** approach offers an effective means for designing low Pt catalysts as exceptional anodic electrocatalysts for direct liquid fuel cells.

关键词： PtPdAg nanotrees Low Pt Bifunctional electrocatalysts Methanol oxidation reaction Formic acid oxidation

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