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LnCu_(3)(OH)_(6)Cl_(3) (Ln=Gd, Tb, Dy): Heavy lanthanides on spin-1/2 kagome magnets

Chinese Physics B 2021年第10期30卷 245-251页

作者： Ying Fu Lianglong Huang Xuefeng Zhou Jian Chen Xinyuan Zhang Pengyun Chen Shanmin Wang Cai Liu Dapeng Yu Hai-Feng Li Le Wang Jia-Wei Mei Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials EngineeringUniversity of MacaoAvenida da UniversidadeTaipaMacao SAR 999078China Shenzhen Institute for Quantum Science and Engineering and Department of PhysicsSouthern University of Science and TechnologyShenzhen 518055China Department of Physics Southern University of Science and TechnologyShenzhen 518055China Institute of Functional Crystals Tianjin University of TechnologyTianjin 300384China Institute of Resources Utilization and Rare-earth Development Guangdong Academy of SciencesGuangzhou 51065China Shenzhen Key Laboratory of Advanced Quantum Functional Materials and Devices Southern University of Science and TechnologyShenzhen 518055China

The spin-1/2 kagome antiferromagnets are key prototype materials for studying frustrated *** isostructural kagome antiferromagnets LnCu_(3)(OH)_(6)Cl_(3)(Ln=Gd,Tb,Dy)have been successfully synthesized by the hydrothermal ***_(3)(OH)_(6)Cl_(3) adopts space group P3m1 and features the layered Cu-kagome lattice with lanthanide Ln3+cations sitting at the center of the *** heavy lanthanides(Ln=Gd,Tb,Dy)in LnCu_(3)(OH)_(6)Cl_(3) provide a large effective magnetic moment and ferromagnetic-like spin correlations compared to light-lanthanides(Nd,Sm,Eu)analogues,Cu-kagome holds an antiferromagnetically ordered state at around 17 K like YCu_(3)(OH)_(6)Cl_(3).

关键词： kagome lattice hydrothermal method frustrated magnetism spin-1/2

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Self-assembled CoOOH on TiO_(2) for enhanced photoelectrochemical water oxidation

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Journal of Energy Chemistry 2021年第9期30卷 512-521页

作者： Xiangrong Ren Yujin Ji Yiyue Zhai Ningyi Yuan Jianning Ding Youyong Li Junqing Yan Shengzhong Frank Liu Key Laboratory of Applied Surface and Colloid Chemistry Ministry of EducationShaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi’an 710119ShaanxiChina Institute of Functional Nano&Soft Materials(FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials&DevicesSoochow UniversitySuzhou 215123JiangsuChina iChEM Dalian Institute of Chemical PhysicsUniversity of Chinese Academy of SciencesChinese Academy of SciencesDalian 116023LiaoningChina School of Materials Science and Engineering Jiangsu Collaborative Innovation Center of Photovoltaic Science and EngineeringJiangsu Cultivation Base for State Key Laboratory of Photovoltaic Science and TechnologyChangzhou UniversityChangzhou 213164JiangsuChina

Providing efficient charge transfer through the interface between the semiconductor and co-catalyst is greatly desired in photoelectrocatalytic (PEC) energy ***,we excogitate a novel and facile means,via electrochemical activation,to successfully load the amorphous CoOOH layer architecture onto the surface of TiO_(2).Intriguingly,the as-obtained 6%CoOOH-TiO_(2)photoelectrode manifests optimal PEC performance with a high photocurrent density of 1.3 mA/cm~2,3.5 times higher than that of pristine TiO_(2).Electrochemical impedance spectroscopy (EIS),Tafel analysis and cyclic voltammetry (CV) methods show that the carrier transfer barrier within the electrode and the transition of Co^(3+)OOH to Co^(4+)OOH have the dominating effects on the PEC *** calculation reveals that the interface between the CoOOH and TiO_(2)improves the homogeneity of effective d-orbital electronic-transfer ability among Co *** research sheds light on the water oxidation reaction and the design of more favorable PEC cocatalysts.

关键词： Amorphous Co-catalyst Water oxidation Mechanism TiO_(2)

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Nano-needle strontium-substituted apatite coating enhances osteoporotic osseointegration through promoting osteogenesis and inhibiting osteoclastogenesis

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Bioactive Materials 2021年第4期6卷 905-915页

作者： Zhen Geng Luli Ji Zhaoyang Li Jing Wang Hongyan He Zhenduo Cui Xianjin Yang Changsheng Liu Key Laboratory for Ultrafine Materials of Ministry of Education East China University of Science and TechnologyShanghai200237China Tianjin Key Laboratory of Composite and Functional Materials School of Materials Science and EngineeringTianjin UniversityTianjin300350China Engineering Research Center for Biomedical Materials of the Ministry of Education East China University of Science and TechnologyShanghai200237China The State Key Laboratory of Bioreactor Engineering East China University of Science and TechnologyShanghai200237China

Implant loosening remains a major clinical challenge for osteoporotic *** is because osteoclastic bone resorption rate is higher than osteoblastic bone formation rate in the case of osteoporosis,which results in poor bone ***(Sr)has been widely accepted as an anti-osteoporosis *** this study,we fabricated a series of apatite and Sr-substituted apatite coatings via electrochemical deposition under different acidic *** results showed that Ca and Sr exhibited different mineralization *** main mineralization products for Ca were CaHPO4⋅2H2O and Ca3(PO4)2 with the structure changed from porous to spherical as the pH values *** main mineralization products for Sr were SrHPO4 and Sr5(PO4)3OH with the structure changed from flake to needle as the pH values *** in vitro experiment demonstrated that coatings fabricated at high pH condition with the presence of Sr were favorable to MSCs adhesion,spreading,proliferation,and osteogenic *** addition,Sr-substituted apatite coatings could evidently inhibit osteoclast differentiation and ***,the in vivo study indicated that nano-needle like Sr-substituted apatite coating could suppress osteoclastic activity,improve new bone formation,and enhance bone-implant *** study provided a new theoretical guidance for implant coating design and the fabricated Sr-substituted coating might have potential applications for osteoporotic patients.

关键词： Calcium Strontium Mineralization Osteoclast activity Osseointegration

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Stable confinement of Fe/Fe_(3)C in Fe,N-codoped carbon nanotube towards robust zinc-air batteries

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Chinese Chemical Letters 2021年第3期32卷 1121-1126页

作者： Lingbo Zong Xin Chen Shuming Dou Kaicai Fan Zumin Wang Wenjun Zhang Yunmei Du Jie Xu Xiaofei Jia Qi Zhang Xia Li Yida Deng Yanan Chen Lei Wang Taishan Scholar Advantage and Characteristic Discipline Team of Eco Chemical Process and Technology Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life ScienceMOEState Key Laboratory of Eco-chemical EngineeringCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China School of Materials Science and Engineering Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of EducationTianjin Key Laboratory of Composite and Functional MaterialsTianjin UniversityTianjin 300072China Centre for Clean Environment and Energy School of Environment and ScienceGriffith UniversityQueensland 4222Australia Institute of Process Engineering Chinese Academy of SciencesBeijing 100190China

Catalytic oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)have garnered great attention as the key character in metal-air ***,we developed a superior nonprecious bifunctional oxygen electrocatalyst,fabricated through spatial confinement of Fe/Fe_(3)C nanocrystals in pyridinic N and Fe-Nx rich carbon nanotubes(Fe/Fe_(3)C-N-CNTs).During ORR,the resultant electrocatalyst exhibits positive onset pote ntial of 1.0 V(***),large half-wave potentials of 0.88 V(***),which is more positive than Pt/C(0.98 V and 0.83 V,respectively).Remarkably,Fe/Fe_(3)C-N-CNTs exhibits outstanding durability and great methanol tolerance,exceeding Pt/C and most reported nonprecious metal-based oxygen reduction ***,Fe/Fe_(3)C-N-CNTs show a markedly low potential at j=10 mA/cm^(2),small Tafel slopes and extremely high stability for ***,the Fe/Fe_(3)C-N-CNTs-based Zn-air batteries demonstrate high power density of 183 mW/cm^(2)and robust charge/discharge *** is revealed that the spatial confinement effect can impede the aggregation and corrosion of Fe/Fe_(3)C ***,Fe/Fe_(3)C and Fe-Nx play synergistic effect on boosting the ORR/OER activity,which provides an important guideline for construction of inexpensive nonprecious metal-carbon hybrid nanomaterials.

关键词： Patial confinement Nonprecious metal Bifunctional Oxygen electrocatalyst Synergistic effect Zn-air batterie

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Integrating thin wall into block:A new scanning strategy for laser powder bed fusion of dense tungsten

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Journal of Materials science & technology 2022年第25期120卷 167-171页

作者： Zhengang Xiong Ji Zou Zhaoyang Deng Jinhan Chen Wei Liu Yuchi Fan Minshi Wang Xiaoqing Zhao Chunfeng Yu Dongdong Dong Wenyou Ma Weimin Wang Zhengyi Fu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Institute of New Materials Guangdong Academy of SciencesGuangzhou 510650China School of Materials Science and Engineering Tsinghua UniversityBeijing 100084China Institute of Functional Materials Donghua University201620China School of Metallurgy and Materials University of BirminghamBeijing 100084China

Due to a combination of outstanding properties including high melting point,high density,low thermal expansion coefficient,low saturated vapor pressure and excellent thermal conductivity,tungsten(W)parts have been widely used as electrodes,heating elements,anti-scatter grids for Computed Tomography(CT)equipment,rocket nozzles and divertor materials for nuclear fusion[1].

关键词： powder thermal saturated

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“On Water”Effect for Green Click Reaction:Spontaneous Polymerization of Activated Alkyne with“Inert”Aromatic Amine in Aqueous Media

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CCS Chemistry 2023年第2期5卷 385-396页

作者： Xinyue Liu Chen Zhang Lianrui Hu Jinghan Wang Kai Li Hai-Tao Feng Jacky WYLam Benzhao He Ben Zhong Tang Department of Chemistry Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and ReconstructionGuangdong-Hong Kong-Macao Joint Laboratory of Optoelectronic and Magnetic Functional MaterialsThe Hong Kong University of Science and TechnologyClear Water BayKowloonHong Kong 999077 HKUST-Shenzhen Research Institute Shenzhen 518057 Department of Biomedical Engineering SUSTech Academy for Advanced Interdisciplinary StudiesSouthern University of Science and TechnologyShenzhen 518055 AIE Research Center Shaanxi Key Laboratory of PhytochemistryCollege of Chemistry and Chemical EngineeringBaoji University of Arts and SciencesBaoji 721013 Center for Advanced Materials Research Beijing Normal University at ZhuhaiZhuhai 519085 School of Science and Engineering Shenzhen Institute of Aggregate Science and TechnologyThe Chinese University of Hong KongShenzhen 518172

Organic reactions in water have attracted great attention due to their advantages such as unique reaction performance and environmental *** reactions as well as polymerizations in aqueous media have been extensively investigated,and so far,there has been a massive amount of reporting about polymerizations in ***,reports about click polymerization in water have been ***,click polymerization of activated alkyne and aromatic amine in aqueous media is ***“on water”effect facilitates polymerization in aqueous media better than in organic solvents,and its mechanism is deciphered through experimental data and theoretical *** participates in the reaction and reduces the energy barrier to some ***,polymerization makes it possible for aromatic amine with low reactivity to be *** using this strategy,polymers with high molecular weights can be obtained in high yields(up to 95.4%).They show good thermal stability and high *** can be *** polymers with tetraphenylethylene moieties show aggregation-induced emission and can be used as materials for generating photopatterns and visualizing agents for specific staining of lysosome in living cells.

关键词： “on water”effect click polymerization aromatic amine photodegradation specific lysosome-staining

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纳米多晶316L奥氏体不锈钢高温蠕变行为的原子尺度研究

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Acta Mechanica Sinica 2023年第5期39卷 19-27页

作者：王冰王千罗容阚前华古斌 Key Laboratory of Testing for Manufacturing Process Ministry of EducationSchool of Manufacturing Science and EngineeringSouthwest University of Science and TechnologyMianyang621010China Tianjin Key Laboratory of Composite&Functional Materials School of Materials Science and EngineeringTianjin UniversityTianjin300072China Institute of Applied Mechanics State Key Laboratory of Traction PowerSouthwest Jiaotong UniversityChengdu610031China Applied Mechanics and Structure Safety Key Laboratory of Sichuan Province School of Mechanics and Aerospace EngineeringSouthwest Jiaotong UniversityChengdu611756China

通过分子动力学模拟研究了纳米多晶316L奥氏体不锈钢在不同峰值应力下的高温蠕变变形行为和蠕变机制.数值模拟结果表明纳米多晶316L奥氏体不锈钢的高温蠕变变形是由位错、晶粒内部和晶界扩散以及晶界滑移之间的交互作用引起.在初始蠕变... 详细信息

通过分子动力学模拟研究了纳米多晶316L奥氏体不锈钢在不同峰值应力下的高温蠕变变形行为和蠕变机制.数值模拟结果表明纳米多晶316L奥氏体不锈钢的高温蠕变变形是由位错、晶粒内部和晶界扩散以及晶界滑移之间的交互作用引起.在初始蠕变和稳态蠕变阶段,纳米多晶316L奥氏体不锈钢高温蠕变的主导性机制是晶粒内部和晶界的扩散以及晶界的滑移.在加速蠕变阶段,一些晶界被摧毁后,位错滑移成为纳米多晶316L奥氏体不锈钢的主要蠕变机制.这项工作旨在揭示纳米多晶316L奥氏体不锈钢的高温蠕变机理,为增强型抗蠕变316L奥氏体不锈钢的设计和制造提供指导.

关键词： 316L austenitic stainless steels Creep Molecular dynamics simulation Dislocation Diffusion Grain boundaries sliding

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Fabrication of lightweight 3D interpenetrated NiTi@Mg composite with superior bending properties

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Transactions of Nonferrous Metals Society of China 2024年第11期34卷 3569-3584页

作者： Yu-jing LIU Xiao-chun LIU Kun-mao LI Xiang WU Sheng-feng ZHOU Wei LI Wen-cai ZHANG Institute of Metals School of Materials Science and EngineeringChangsha University of Science&TechnologyChangsha 410004China Institute of Advanced Wear&Corrosion Resistance and Functional Materials Jinan UniversityGuangzhou 510632China State Key Laboratory of Mechanical Transmissions Chongqing UniversityChongqing 400044China Department of Orthopedics First Affiliated HospitalJinan UniversityGuangzhou 510632China

A NiTi@Mg interpenetrating phase composite with high strength and lightweight was prepared by additive manufacturing(AM)and infiltration technology,and the interface bonding,three-point bending properties and cyclic compressive properties of NiTi@Mg composites were *** results show that the metallurgically bonded interface is formed at the NiTi/Mg *** bending strength and compressive strength of the NiTi@Mg composite are 2.5 and 1.7 times higher than those of the NiTi scaffold,*** the bending deformation process,a large number of dislocations are observed to accumulate in the soft Mg area at the ***,the finite element model showed that the stress accumulation area,where the bending crack is initiated,is located at the interface of NiTi and *** strengthening mechanism of NiTi@Mg composites is attributed to the twinning strengthening of Mg and heterogeneous structure strengthening.

关键词： metal composites NiTi@Mg bending properties finite element simulation strengthening mechanism

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Metal-organic framework-based single-atom electro-/ photocatalysts: Synthesis, energy applications, and opportunities

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Carbon Energy 2024年第1期6卷 1-43页

作者： Munir Ahmad Jiahui Chen Jianwen Liu Yan Zhang Zhongxin Song Shahzad Afzal Waseem Raza Liaqat Zeb Andleeb Mehmood Arshad Hussain Jiujun Zhang Xian-Zhu Fu Jing-Li Luo Shenzhen Key Laboratory of Energy Electrocatalytic Materials Guangdong Research Center for Interfacial Engineering of Functional MaterialsCollege of Materials Science and EngineeringShenzhen UniversityShenzhenGuangdongChina College of Physics and Optoelectronic Engineering Shenzhen UniversityShenzhenGuangdongChina College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhenGuangdongChina Department of Environmental Engineering China Jiliang UniversityHangzhouZhejiangChina Institute for Advanced Study Shenzhen UniversityShenzhenGuangdongChina School of Bioengineering Dalian University of TechnologyDalianLiaoningChina College of Materials Science and Engineering Fuzhou UniversityFuzhouFujianChina Institute for Sustainable Energy Shanghai UniversityShanghaiChina

Single-atom catalysts(SACs)have gained substantial attention because of their exceptional catalytic ***,the high surface energy limits their synthesis,thus creating significant challenges for further *** the last few years,metal–organic frameworks(MOFs)have received significant consideration as ideal candidates for synthesizing SACs due to their tailorable chemistry,tunable morphologies,high porosity,and chemical/thermal *** this perspective,this review thoroughly summarizes the previously reported methods and possible future approaches for constructing MOF-based(MOF-derived-supported and MOF-supported)***,MOF-based SAC's identification techniques are briefly assessed to understand their coordination environments,local electronic structures,spatial distributions,and catalytic/electrochemical reaction *** review systematically highlights several photocatalytic and electrocatalytic applications of MOF-based SACs for energy conversion and storage,including hydrogen evolution reactions,oxygen evolution reactions,O_(2)/CO_(2)/N_(2) reduction reactions,fuel cells,and rechargeable *** light is also shed on the future development of this highly exciting field by highlighting the advantages and limitations of MOF-based SACs.

关键词： carbon energy generation MOF-derived-supported MOF-supported single atoms

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Progress and perspectives in dielectric energy storage ceramics

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Journal of advanced Ceramics 2021年第4期10卷 675-703页

作者： Dongxu LI Xiaojun ZENG Zhipeng LI Zong-Yang SHEN Hua HAO Wenqin LUO Xingcai WANG Fusheng SONG Zhumei WANG Yueming LI Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province China National Light Industry Key Laboratory of Functional Ceramic MaterialsSchool of Materials Science and EngineeringJingdezhen Ceramic UniversityJingdezhen 333403China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Chengdu Hongke Electronic Technology Co. Ltd.Chengdu 610000China

Dielectric ceramic capacitors,with the advantages of high power density,fast chargedischarge capability,excellent fatigue endurance,and good high temperature stability,have been acknowledged to be promising candidates for solid-state pulse power *** review investigates the energy storage performances of linear dielectric,relaxor ferroelectric,and antiferroelectric from the viewpoint of chemical modification,macro/microstructural design,and electrical property *** progress of ceramic bulks and films for Pb-based and/or Pb-free systems is ***,we propose the perspectives on the development of energy storage ceramics for pulse power capacitors in the future.

关键词： energy storage ceramics dielectric relaxor ferroelectric antiferroelectric pulse power capacitor

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