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Emergent symmetry in quantum phase transition:From deconfined quantum critical point to gapless quantum spin liquid

science Bulletin 2024年第2期69卷 190-196页

作者： Wen-Yuan Liu Shou-Shu Gong Wei-Qiang Chen Zheng-Cheng Gu Department of Physics The Chinese University of Hong KongHong KongChina Division of Chemistry and Chemical Engineering California Institute of TechnologyPasadena CA 91125USA School of Physical Sciences Great Bay UniversityDongguan 523000China Great Bay Institute for Advanced Study Dongguan 523000China Department of Physics and Shenzhen Institute for Quantum Science and Engineering Southern University of Science and TechnologyShenzhen 518055China Shenzhen Key Laboratory of Advanced Quantum Functional Materials and Devices Southern University of Science and TechnologyShenzhen 518055China

The emergence of exotic quantum phenomena in frustrated magnets is rapidly driving the development of quantum many-body physics,raising fundamental questions on the nature of quantum phase *** we unveil the behaviour of emergent symmetry involving two extraordinarily representative phenomena,i.e.,the deconfined quantum critical point(DQCP)and the quantum spin liquid(QSL)*** large-scale tensor network simulations,we study a spatially anisotropic spin-1/2 square-lattice frustrated antiferromagnetic(AFM)model,namely the J1x-J1y-J2 model,which contains anisotropic nearestneighbor couplings J1x,J1y and the next nearest neighbor coupling *** small J1y/J1x,by tuning J2,a direct continuous transition between the AFM and valence bond solid phase is *** growing J1y/J1x,a gapless QSL phase gradually emerges between the AFM and VBS *** observe an emergent O(4)symmetry along the AFM–VBS transition line,which is consistent with the prediction of DQCP *** surprisingly,we find that such an emergent O(4)symmetry holds for the whole QSL–VBS transition line as *** findings reveal the intrinsic relationship between the QSL and DQCP from categorical symmetry point of view,and strongly constrain the quantum field theory description of the QSL *** phase diagram and critical exponents presented in this paper are of direct relevance to future experiments on frustrated magnets and cold atom systems.

关键词： Tensor network Quantum phase transition Emergent symmetry Quantum spin liquid Deconfined quantum critical point Anisotropic

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Achieving strong microwave absorption capability and wide absorption bandwidth through a combination of high entropy rare earth silicide carbides/rare earth oxides

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Journal of Materials science & technology 2020年第12期47卷 216-222页

作者： Heng Chen Biao Zhao Zifan Zhao Huimin Xiang Fu-Zhi Dai Jiachen Liu Yanchun Zhou Science and Technology on Advanced Functional Composite Laboratory Aerospace Research Institute of Materials&Processing TechnologyBeijing 100076China Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education School of Materials Science and EngineeringTianjin UniversityTianjin 300072China Henan Key Laboratory of Aeronautical Materials and Application Technology School of Material Science and EngineeringZhengzhou University of AeronauticsZhengzhou 450046China

Developing electromagnetic(EM) wave absorbing materials with low reflection coefficient and optimal operating frequency band is urgently needed on account of the increasingly serious EM pollution. However, the applications of common EM absorbing materials are encumbered by poor high-temperature stability, poor oxidation resistance, narrow absorption bandwidth or high density. Herein, the strong EM absorption capability and wide efficient absorption bandwidth of high entropy ceramics are reported for the first time, which are designed by a combination of the novel high entropy(HE) rare earth silicide carbides/rare earth oxides(RE3 Si2 C2/RE2 O3). Three HE powders, i.e., HERSC-1(HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)3 Si2 C2),HERSC-2 HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)3 Si2 C2/HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)2 O3) and HERSC-3(HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)3 Si2 C2/HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)2 O3), are synthesized. Although HERSC-1 exhibits a limited absorption effect(the minimum reflection loss(RLmin) is-11.6 d B at 3.4 mm) and a relatively narrow effective absorption bandwidth(EAB) of 1.7 GHz, the optimal absorption RLminvalue and EAB of HERSC-2 and HERSC-3 are-40.7 d B(at 2.9 mm), 3.4 GHz and-50.9 d B(at 2.0 mm), 4.5 GHz,respectively, demonstrating strong microwave absorption capability and wide absorption *** the better stability, low density and strong EM absorption effect, HE ceramics are promising as a new type of EM absorbing materials.

关键词： High entropy ceramics Rare earth silicide carbides Absorption materials Reflection loss Interfacial polarization

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Facile synthesis of Ni-,Co-,Cu-metal organic frameworks electrocatalyst boosting for hydrogen evolution reaction

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Journal of Materials science & technology 2021年第13期72卷 172-179页

作者： Man Zhang Di Hu Zhenhao Xu Biying Liu Mebrouka Boubeche Zuo Chen Yuchen Wang Huixia Luo Kai Yan Guangdong Provincial Key Laboratory of Environmental Pollution and Remediation Technology School of Environmental Science and EngineeringSun Yat-sen UniversityGuangzhou 510275China Key Lab of Polymer Composite&Functional Materials School of Materials Science and EngineeringSun Yat-sen UniversityGuangzhou510275China

The conductive metal-organic frameworks(MOFs)are suggested as the ideal electrocatalysts for hydrogen evolution reaction(HER)because of the high utilization of metal *** design and facile synthesis of MOFs with large specific surface area,proper metals as center,and tunable chemical components is still full of ***,we report the facile synthesis three types of porous MOFs by regulating metal center using benzene-1,3,5-tricarboxylic acid(H3 BTC)as organic ligand and have successfully synthesized the rhombic octahedral Cu-BTC,rod-shaped Co-BTC and spherical Ni-BTC materials with large specific surface area ranged in 350-500 m^(2)g^(-1).These as-prepared MOFs materials exhibit high performance of HER in 0.5 M H_(2)SO_(4).Ni-BTC material exhibits the lowest overpotential of 53 mV at 10 mA cm-2 and the smallest Tafel slope of 62 mV dec^(-1)than those of Cu-BTC(270 mV,155 mV dec^(-1))and Co-BTC(123 mV,100 mV dec^(-1)),which are much superior to these previously reported MOFs *** addition,the fast catalytic kinetic of Ni-BTC was confirmed by the smaller charge transfer resistance(Rct)value of 0.9Ωand larger electrochemical active surface area(ECSA)of 35.5 cm^(2)than those of Cu-BTC(8.2Ω,22.5 cm^(2))and Co-BTC(1.9Ω,27.7 cm^(2)).Because of the structural advantage and large ECSA,the turnover frequency(TOF)value of Ni-BTC reaches up to 0.041 s-1 at 120 mV overpotential,which is 20.5 and 2.6 times greater than that of Cu-BTC(0.002 s-1)and Co-BTC(0.016 s-1).Besides,these three types of MOFs exhibited excellent durability over 12 *** study unfolds diverse insights into the design and facile synthesis of MOFs for electrochemical energy conversion system.

关键词： Metal-organic frameworks Hydrogen evolution reaction Activity Overpotential Durability

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Mechanical Properties and Thermal Shock Resistance of SrAl_(2)Si_(2)O_(8) Reinforced BN Ceramic composites

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无机材料学报 2024年第10期39卷 1182-1188页

作者： WANG Bo CAI Delong ZHU Qishuai LI Daxin YANG Zhihua DUAN Xiaoming LI Yanan WANG Xuan JIA Dechang ZHOU Yu International Joint Laboratory of Advanced Nanomaterials of Heilongjiang Province College of Materials Science and Chemical EngineeringHarbin Engineering UniversityHarbin 150001China Key Laboratory of Advanced Structural-Functional Integration Materials School of Materials Science and EngineeringHarbin Institute of TechnologyHarbin 150001China China Resources Cement Technology R&D Co. LtdGuangzhou 510000China The First Military Representative Office of the Army Equipment Department in Beijing Beijing 100072China The Fourth System Design Department Fourth AcademyChina Aerospace Science and Industry Corporation LimitedBeijing 100048China School of Materials Science and Engineering Harbin Institute of Technology(Shenzhen)Shenzhen 518055China

Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric ***,their densification during sintering still poses challenges for researchers,and their mechanical properties are rather *** this study,SrAl_(2)Si_(2)O_(8)(SAS),with low melting point and high strength,was introduced into the h-BN ceramics to facilitate the sintering and reinforce the strength and ***,BN-SAS ceramic composites were fabricated via hot press sintering using h-BN,SrCO_(3),Al_(2)O_(3),and SiO_(2) as raw materials,and effects of sintering pressure on their microstructure,mechanical property,and thermal property were *** thermal shock resistance of BN-SAS ceramic composites was *** show that phases of as-preparedBN-SAS ceramic composites are h-BN and h-SrAl_(2)Si_(2)O_(8).With the increase of sintering pressure,the composites’densities increase,and the mechanical properties shew a rising trend followed by a slight *** a sintering pressure of 20 MPa,their bending strength and fracture toughness are(138±4)MPa and(1.84±0.05)MPa·m^(1/2),*** sintered at 10 MPa exhibit a low coefficient of thermal expansion,with an average of 2.96×10^(-6) K^(-1) in the temperature range from 200 to 1200℃.The BN-SAS ceramic composites prepared at 20 MPa display higher thermal conductivity from 12.42 to 28.42 W·m^(-1)·K^(-1) within the temperature range from room temperature to 1000℃.Notably,BN-SAS composites exhibit remarkable thermal shock resistance,with residual bending strength peaking and subsequently declining sharply under a thermal shock temperature difference ranging from 600 to 1400℃.The maximum residual bending strength is recorded at a temperature difference of 800℃,with a residual strength retention rate of 101%.As the thermal shock temperature difference increase,the degree of oxida

关键词： BN matrix composite hot-press sintering mechanical property thermal shock resistance service reliability

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Long-term oxidation resistance of a Ti65 alloy with Cr2AlC coating by magnetron sputtering

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Corrosion Communications 2025年 18卷 66-75页

作者： Ma, Ke Li, Yang Li, Jingjing Wang, Jinming Xu, Jingjun Zuo, Jun Li, Meishuan Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of Sciences Shenyang110016 China School of Materials Science and Engineering University of Science and Technology of China Hefei230026 China School of Materials Science and Engineering Shenyang Ligong University Shenyang110159 China Science and Technology on Advanced Functional Composites Laboratory Aerospace Research Institute of Material and Processing Technology Beijing 100076 China

In this study, novel high-quality Cr2AlC coating was fabricated on Ti65 alloy substrate as its protective oxidation resistance coating. Isothermal oxidation tests were performed at 650 and 750 °C for up to 400 h in air. The results indicated that Ti65 alloy underwent severe oxidation at 750 °C, accompanied by the presence of the cracking and exfoliating of the oxide scale during oxidation. Compared to the bare Ti65 substrate, the coated samples revealed more excellent oxidation resistance, meeting the parabolic law with low oxidation rate constants of 8.70×10−13 kg2·m−4·s−1 at 650 °C and 2.80×10−13 kg2·m−4·s−1 at 750 °C. At the surface, Al preferentially oxidized to form the protective Al2O3 layer and synchronously Cr7C3 sublayer, retarding the inward diffusion of oxygen and presenting excellent oxidation resistance. Besides, at the coating/substrate interface, Al diffused from Cr2AlC coating into the substrate to form an Al-rich layer in substrate adjacent to the coating/substrate interface. Due to the Al consumption, Cr-carbide and nitride, as well as TiN, were thereby formed at the interface reaction layer, which could act as a barrier for the interdiffusion process. © 2025

关键词： Magnetron sputtering

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Research prospects of graphene-based catalyst for seawater electrolysis

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Materials Futures 2023年第4期2卷 80-97页

作者： Xinyu Li Yingjie Liu Yanhui Feng Yunwei Tong Zhenbo Qin Zhong Wu Yida Deng Wenbin Hu Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education Tianjin University Tianjin 300072People’s Republic of China Key Laboratory of Composite and Functional Materials School of Material Science and Engineering Tianjin UniversityTianjin 300072People’s Republic of China State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and EngineeringHainan UniversityHaikou 570228People’s Republic of China Joint School of National University of Singapore and Tianjin University International Campus of Tianjin University Binhai New CityFuzhou 350207People’s Republic of China

Seawater has obvious resource reserve advantages compared to fresh water,and so the huge potential advantages for large-scale electrolysis of hydrogen production has been paid more attention to;but at the same time,electrolysis of seawater requires more stable and active catalysts to deal with seawater corrosion ***-based materials are very suitable as composite supports for catalysts due to their high electrical conductivity,specific surface area,and ***,the review introduces the problems faced by seawater electrolysis for hydrogen production and the various catalysts *** them,the advantages of catalysis of graphene-based catalysts and the methods of enhancement the catalytic performance of graphene are ***,the development direction of composite catalysts is prospected,hoping to provide guidance for the preparation of more efficient electrocatalysts for seawater electrolysis.

关键词： graphene seawater electrolysis catalyst

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Environmentally Adaptive Passive Temperature-Regulating Flexible Energy-Saving Radiator

SSRN

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SSRN 2024年

作者： Wang, Han Zhang, Xun Yang, Meng-Qi Zhou, Xinyu Wang, Chao Xing, Lin Wang, Changhao Wang, Bing Wang, Ruzhi Institute of Advanced Energy Materials and Devices College of Material Science and Engineering Key Laboratory of Advanced Functional Materials of Education Ministry of China Beijing University of Technology Beijing100124 China

Due to the different thermal radiative properties of the materials, it is difficult to comprehensively utilize solar heating (SH) and radiation cooling (RC). By innovatively coupling two traditional optical devices, resonant cavities and photonic structures, we propose a smart radiator (SR) with a resonant-localization effect that can be synergistically controlled for near-infrared(NIR) and long-wave infrared(LIR). A resonant cavity with a temperature-converting switch driven by a metal-insulator phase transition automatically activates and deactivates the RC according to the external temperature, while the photonic structure structurally controls the NIR absorption, thereby realizing on-demand modulation of the SH capability. The flexible SR integrates RC and ST capabilities to cool the space by 11.61℃ in hot weather (35℃) and warm the space by 18.95℃ in cold weather (0℃). The results show that the SR's all-season thermoregulation capability can save buildings from 6.4% ~ 43.5% of cooling and heating energy in different climate zones around the world. It can be widely applied to the external surfaces of buildings, vehicles, or other shading structures, providing strong assistance for cooling/heating without energy consumption. © 2024, The Authors. All rights reserved.

关键词： Radiators

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Inversion of Spatially Distributed Elastic Moduli of 2.5d Woven composites Based on Dic Strain Field Using Pinn Method

SSRN

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SSRN 2024年

作者： Wang, Hongyue Fang, Guodong Gao, Bo Wang, Bing Meng, Songhe Center for Composite Materials and Structures Harbin Institute of Technology Harbin150001 China Science and Technology on Advanced Composites in Special Environments Key Laboratory Harbin Institute of Technology Harbin150001 China

Due to the stochastic geometries from micro-scale to meso-scale, the elastic modulus of fiber reinforced ceramic matrix woven composites exhibits significant spatial variabilities, as evidenced by the surface strain distribution captured through Digital Image Correlation method. These spatial variabilities, resulting in significant heterogeneous material properties, are of essential importance in both engineering and material science. Inspired by the excellent performances of Physics-Informed Neural Networks (PINNs), a data-driven method integrating invariant-based theory based on iteration strategy is proposed to identify the non-homogeneous modulus field of 2.5D SiO2f/SiO2 composites inversely. The constitutive equation has been normalized by the Tsai’s modulus, effectively alleviating the ill-posed nature of the problem. Furthermore, the results of PINNs show a high prediction accuracy, which have been validated through virtual testing and experimental tensile tests. The method proposed in this paper provides a powerful approach for inversely identifying the spatial variabilities of orthotropic composite material properties, which also holds potential for applications such as high-throughput non-destructive evaluation techniques. © 2024, The Authors. All rights reserved.

关键词： Elastic moduli

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A novel, green method for the preparation of biodegradable PLA membranes without pore-forming agent

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Journal of Water Process Engineering 2025年 74卷

作者： Cai, Jiayi Han, Zunbo Sun, Yinjie Chen, Haoran Li, Haoran Wang, Ruoxi Ji, Yanhong He, Benqiao State Key Laboratory of Separation Membranes and Membrane Processes School of Material Science and Engineering Tiangong University Tianjin 300387 China Cangzhou Institute of Tiangong University Cangzhou 061000 China Science and Technology on Advanced Functional Composite laboratory Aerospace Research Institute of Materials & Processing Technology Beijing 100076 China

Polylactic acid (PLA) membranes have attracted significant attention in separation technologies due to their biodegradable properties. This study proposes a novel and eco-friendly pore-forming strategy for fabricating PLA membranes by triggering the in situ reaction between CaCO₃ nanoparticles and citric acid during the phase inversion process. Unlike conventional methods requiring synthetic pore-forming additives, this approach leverages the sacrificial role of CaCO₃ and the reaction-generated CO₂ nanobubble to synergistically construct a porous structure. The overall porosity increases from 70.2 % (pristine PLA membrane, M0) to 85.6 % (membrane prepared from a 6 wt% CaCO₃-containing casting solution, M6), while pure water flux rises dramatically from 20.1 L·m⁻²·h⁻¹ to 218.3 L·m⁻²·h⁻¹, with bovine serum albumin rejection maintained at 96.8 %. Furthermore, the flux recovery rate improves from 53.2 % (M0) to 71.2 % (M6), demonstrating enhanced antifouling properties. This entirely green fabrication process, employing only natural CaCO₃ and citric acid, represents a significant advancement in sustainable membrane technology and provides a viable route for developing high-performance biodegradable separation membranes. © 2025 Elsevier Ltd

关键词： Biodegradable membrane CaCO3 nanoparticles Citric acid Polylactic acid

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A Single-Layer Piezoelectric composite Separator for Durable Operation of Li Metal Anode at High Rates

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Energy & Environmental Materials 2024年第1期7卷 265-274页

作者： Yuanpeng Ji Botao Yuan Jiawei Zhang Zhezhi Liu Shijie Zhong Jipeng Liu Yuanpeng Liu Mengqiu Yang Changguo Wang Chunhui Yang Jiecai Han Weidong He National Key Laboratory of Science and Technology on Advanced Composites in Special Environments and Center for Composite Materials and StructuresHarbin Institute of TechnologyHarbin 150080China MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150080China School of Petroleum Engineering Chongqing University of Science and TechnologyChongqing 401331China State Key Laboratory of Urban Water Resource and Environment Harbin Institute of TechnologyHarbin 150080China Chongqing Research Institute Harbin Institute of TechnologyChongqing 401151China School of Mechanical Engineering Chengdu UniversityChengdu 610106China

Piezoelectric ceramic and polymeric separators have been proposed to effectively regulate Li deposition and suppress dendrite growth,but such separators still fail to satisfactorily support durable operation of lithium metal batteries owing to the fragile ceramic layer or low-piezoelectricity polymer as ***,by combining PVDF-HFP and ferroelectric BaTiO_(3),we develop a homogeneous,single-layer composite separator with strong piezoelectric effects to inhibit dendrite growth while maintaining high mechanical *** squeezed by local protrusion,the polarized PVDF-HFP/BaTiO_(3)composite separator generates a local voltage to suppress the local-intensified electric field and further deconcentrate regional lithium-ion flux to retard lithium deposition on the protrusion,hence enabling a smoother and more compact lithium deposition morphology than the unpoled composite separator and the pure PVDF-HFP separator,especially at high ***,the homogeneous incorporation of BaTiO_(3)highly improves the piezoelectric performances of the separator with residual polarization of 0.086 pC cm^(-2)after polarization treatment,four times that of the pure PVDF-HFP separator,and simultaneously increases the transference number of lithium-ion from 0.45 to *** from the prominent piezoelectric mechanism,the polarized PVDF-HFP/BaTiO_(3)composite separator enables stable cyclic performances of Li||LiFePO_(4)cells for 400 cycles at 2 C(1 C=170 mA g^(-1))with a capacity retention above 99%,and for 600 cycles at 5 C with a capacity retention over 85%.

关键词： composite separator Li metal anodes piezoelectric materials PVDF-HFP uniform Li deposition

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