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Boosting oxygen reduction in acidic media through integration of Pt-Co alloy effect and strong interaction with carbon defects

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Nano Research 2024年第9期17卷 7900-7908页

作者： Nannan Ji Haoyun Sheng Shilong Liu Yangyuan Zhang Hongfei Sun Lingzhi Wei Ziqi Tian Peng Jiang Qianwang Chen Jianwei Su Institutes of Physical Science and Information Technology Key Laboratory of Structure and Functional Regulation of Hybrid MaterialsAnhui UniversityHefei 230601China Ningbo Institute of Materials Technology and Engineering Chinese Academy of SciencesNingbo 315201China Hefei National Laboratory for Physical Science at Microscale Department of Materials Science&EngineeringUniversity of Science and Technology of ChinaHefei 230026China International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education Institute of Microscale OptoelectronicsShenzhen UniversityShenzhen 518060China

Optimization of Pt atom utilization efficiency is critical for the development of proton-exchange-membrane fuel *** we aim to develop an efficient oxygen reduction reaction(ORR)catalyst with a low Pt content through the concurrent modification of Pt-Co alloy catalysts and carbon *** the present study,ultrafine Pt-Co alloy nanoparticles are successfully synthesized and stabilized by topological carbon defects via adopting the ammonia thermal *** the low Pt loading,the obtained catalyst exhibits an impressive half-wave potential of 0.926 V versus the reversible hydrogen electrode in 0.1 M HClO_(4)***,the durability testing using the timed-current method demonstrates a tiny loss of only 3.6%after 12 *** experimental results and theoretical calculations demonstrate that topological carbon defects significantly enhance the charge transfer processes at the alloy/carbon interface,contributing to the strong electronic metal-support interactions between the Pt-Co alloy nanoparticles and topological carbon *** interactions,along with the alloy effect,play a crucial role in promoting the ORR performance in acidic media.

关键词： electrocatalysis oxygen reduction reaction Pt-Co alloy electronic interaction topological carbon defects

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Contract-Based Incentive Mechanisms for UAV Networks in Covert Communications

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IEEE Transactions on Vehicular technology 2025年第5期74卷 7378-7391页

作者： Tian, Wen Fan, Hao Liu, Guangjie Du, Miao Liu, Yinqiu Niyato, Dusit Han, Zhu Nanjing University of Information Science and Technology School of Electronic and Information Engineering Nanjing University of Information Science and Technology Key Laboratory of Intelligent Support Technology In Complex Environment Ministry of Education Nanjing210044 China Southeat University School of Computer Science and Engineering China Southeast University Key Laboratory of Computer Network and Information Integration Ministry of Education Nanjing China Nanyang Technological University School of Computer Science and Engineering 639798 Singapore University of Houston Department of Electrical and Computer Engineering HoustonTX77004 United States Kyung Hee University Department of Computer Science and Engineering Seoul446-701 Korea Republic of

Covert communication is considered a promising technology for hiding transmission processes and activities from malicious eavesdropping. With the development of detection technology, the traditional point-to-point covert communication method cannot effectively guarantee the reliability of covert communication. In order to solve this problem, unmanned aerial vehicle (UAV) are widely adopted in covert communication as common relay equipment. However, the UAV maximizes its benefits by taking advantage of the information asymmetry between itself and the covert communication sender. Therefore, it is necessary to encourage UAV-assisted potential users (UPU) to transmit covert data honestly by designing an information asymmetry-based incentive mechanism. In this paper, we propose a UAV-assisted contract-theoretic (UACT) model to improve the covert communication performance, where UPU honestly transmits covert data and the throughput of UACT can be increased. Specifically, we first divide UPU into finite types and model the data transfer contract between the sender, UPU, and receiver. Then, the contract feasibility of UACT is derived with sufficient and necessary conditions. Finally, we analyze the contract optimization in the continuous case of UPUs. Numerical simulations show that the UACT can incentivize UPUs to transmit covert data through UAV assistance and make covert communication performance close to the information symmetry case. © 1967-2012 IEEE.

关键词： Unmanned aerial vehicles (UAV)

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Conversion-type anode chemistry with interfacial compatibility toward Ah-level near-neutral high-voltage zinc ion batteries

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National science Review 2024年第7期11卷 226-238页

作者： Shan Guo Liping Qin Jia Wu Zhexuan Liu Yuhao Huang Yiman Xie Guozhao Fang Shuquan Liang School of Materials Science and Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan ProvinceCentral South University College of Biological and Chemical Engineering Guangxi University of Science and Technology Information and Network Center Central South University

High-voltage aqueous zinc ion batteries（AZIBs） with a high-safety near-neutral electrolyte is of great significance for practical sustainable application; however, they suffer from anode and electrode/electrolyte interfacial incompatibility. Herein, a conversion-type anode chemistry with a low anodic potential, which is guided by the Gibbs free energy change of conversion reaction, was designed for high-voltage near-neutral AZIBs. A reversible conversion reaction between ZnC2O4·2H2O particles and three-dimensional Zn metal networks well-matched in CH3COOLi-based electrolyte was revealed. This mechanism can be universally validated in the battery systems with sodium or iodine ions. More importantly, a cathodic crowded micellar electrolyte with a water confinement effect was proposed in which lies the core for the stability and reversibility of the cathode under an operating platform voltage beyond 2.0 V, obtaining a capacity retention of 95% after 100 cycles. Remarkably, the scientific and technological challenges from the coin cell to Ah-scale battery, sluggish kinetics of the solid-solid electrode reaction, capacity excitation under high loading of active material, and preparation complexities associated with large-area quasi-solid electrolytes,were explored, successfully achieving an 88% capacity retention under high loading of more than 20 mg cm-2and particularly a practical 1.1 Ah-level pouch cell. This work provides a path for designing low-cost, eco-friendly and high-voltage aqueous batteries.

关键词： zinc compound anode conversion reaction voltage regulation interfacial design pouch cell

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Analysis of Network Resilience for Logical-Physical Dual-Layer Networks in Configuring Backup Paths 9

Analysis of Network Resilience for Logical-Physical Dual-Lay...

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9th International Conference on Big Data and information Analytics, BigDIA 2023

作者： Li, Zhe Long, Zhitao Yu, Zhuoting Diao, Boyang Liu, Jin National University of Defense Technology Science and Technology on Information Systems Engineering Laboratory Changsha China National University of Defense Technology College of Systems Engineering Changsha China

ISBN: (纸本)9798350330076

The logical-physical dual-layer network is standardized in this paper, and three attack modes-random attack, maximum betweenness attack, and minimum betweenness attack are used to simulate and analyze the network resilience of the logical-physical dual-layer network with backup path and without backup path. The variation curves of network load loss under various attack edges are derived through simulation analysis, and it is determined that setting up backup path can significantly increase network resilience. On the basis of this conclusion, the impact of different backup path stowage schemes on network resilience is further explored, and the network load configuration scheme is designed based on duplication degree and average path length. It is determined that the network resistance is inversely related to duplication degree and average path length under the simulation study of random attack technique. © 2023 IEEE.

关键词： Network layers

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Enhanced Tube-Based Event-Triggered Stochastic Model Predictive Control With Additive Uncertainties

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IEEE/CAA Journal of Automatica Sinica 2025年第3期12卷 596-605页

作者： Chenxi Gu Xinli Wang Kang Li Xiaohong Yin Shaoyuan Li Lei Wang the School of Control Science and Engineering Shandong University IEEE the School of Electronic and Electrical Engineering University of Leeds the Qingdao University of Science and Technology the Department of Automation Shanghai Jiao Tong University the Key Laboratory of System Control and Information Processing Ministry of Education of China

This paper proposes an event-triggered stochastic model predictive control for discrete-time linear time-invariant(LTI) systems under additive stochastic disturbances. It first constructs a probabilistic invariant set and a probabilistic reachable set based on the priori knowledge of system *** with enhanced robust tubes, the chance constraints are then formulated into a deterministic form. To alleviate the online computational burden, a novel event-triggered stochastic model predictive control is developed, where the triggering condition is designed based on the past and future optimal trajectory tracking errors in order to achieve a good trade-off between system resource utilization and control performance. Two triggering parameters σ and γ are used to adjust the frequency of solving the optimization problem. The probabilistic feasibility and stability of the system under the event-triggered mechanism are also examined. Finally, numerical studies on the control of a heating, ventilation, and air conditioning(HVAC) system confirm the efficacy of the proposed control.

关键词： Event-triggered mechanism heating, ventilation, and air conditioning (HVAC) control probabilistic reachable set stochastic model predictive control

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Evolutionary Plasmonic Properties of Single Truncated Ag Nanowire-on-Au Film Nanocavity

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Chinese Physics Letters 2023年第5期40卷 104-108页

作者：朱鑫张静云杨翠红李莹陈云云 School of Physics&Optoelectronic Engineering Nanjing University of Information Science and TechnologyNanjing 210044China Jiangsu Key Laboratory for Optoelectronic Detection of Atmosphere and Ocean Nanjing University of Information Science and TechnologyNanjing 210044China Jiangsu International Joint Laboratory on Meterological Photonics and Optoelectronic Detection Nanjing University of Information Science and TechnologyNanjing 210044China

Noble metal nanocavities have been widely demonstrated to possess great potential applications in nanooptics and nanophotonics due to their extraordinary localized surface plasmon ***,most metal nanocrystals synthesized by chemical methods often suffer from truncation with different degrees due to oxidation and dissolution of metal atoms at corner and *** investigate the influence of shape truncation on the plasmonic properties of single Ag nanowire on Au film nanocavity using the finite difference time domain *** the Ag nanowire(the circumradius R_(2)=50 nm)is gradually truncated from pentagonal to circular geometry,the scattering peak position of the nanocavity shows prominent blue shift from 962 nm to 608 nm,suggesting a nonnegligible role of truncation on plasmonic *** electric field strength and charge distribution of the structure reveal the evolution from dipole mode to quadrupole *** is also found that the plasmon resonance wavelength is linearly dependent on the truncation ratio R_(1)/R_(2)(R_(1) is the inradius)and the modulation slope is also reliable to the size of Ag *** observations could shed light on developing high-performance tunable optical nano-devices in future.

关键词： cavity truncation radius

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Cold sintered BaTiO_(3)–poly(ether imide)nanocomposites with superior comprehensive performances

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Journal of Advanced Ceramics 2024年第9期13卷 1453-1460页

作者： Xinyi Li Li Li Mingming Si Xiaoqian Tai Hong Wang Jing Guo State Key Laboratory for Mechanical Behavior of Materials&School of Materials Science and Engineering Xi’an Jiaotong UniversityXi’an 710049China Guangdong Provisional Key Laboratory of Functional Oxide Materials and Devices Southern University of Science and TechnologyShenzhen 518055China Department of Materials Science and Engineering&Shenzhen Engineering Research Center for Novel Electronic Information Materials and Devices Southern University of Science and TechnologyShenzhen 518055China

With the rapid development of the electronics industry,the demand for dielectric materials with high permittivities,low losses,and excellent electrical breakdown strengths prepared via low-temperature fabrication techniques is ***,we propose a one-step cold sintering process route to improve the comprehensive performance of BaTiO_(3)−based ceramics by integrating polyetherimide(PEI).Dense BaTiO_(3)–PEI nanocomposites can be prepared via a cold sintering process at 250℃ using Ba(OH)_(2)∙8H_(2)O and H_(2)TiO_(3) as the transient liquid *** grain growth of BaTiO_(3) is inhibited,and thin PEI layers less than 10 nm in size are located at the grain *** dissolution‒precipitation process triggered by the transient liquid phase and viscous flow assisted by PEI dominates the cold sintering mechanism of the(1−x)BaTiO_(3)–xPEI *** dielectric properties are stable over a broad temperature range up to 200℃.Compared with BaTiO_(3),80%BaTiO_(3)–20%PEI has superior performance,with a relative permittivity of 163 and a low dielectric loss of 0.014,and the electrical breakdown strength is increased by 80.65%compared with BaTiO_(3).Overall,the cold sintering process provides a potential way to develop dielectric nanocomposites with excellent comprehensive performance.

关键词： cold sintering process(CSP) dielectrics BaTiO_(3) ceramic-polymer composites

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Polyolefin vitrimers bearing acetoacetate functionality

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science China Chemistry 2024年第11期67卷 3861-3867页

作者： Zihao Wang Yue Liu Wenmin Pang Ao Chen Min Chen Chinese Academy of Sciences(CAS)Key Laboratory of Soft Matter Chemistry Department of Polymer Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China Institutes of Physical Science and Information Technology Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of EducationAnhui UniversityHefei 230601China

Polyolefin vitrimers are polymer networks bearing reversible covalent crosslinking points, enabling them to be reprocessed and recycled. In this contribution, a series of polyolefin vitrimers were designed based on the acetoacetate-functionalized polyolefin copolymers, which were produced through the direct copolymerization of ethylene with polar comonomers using a phosphinesulfonate palladium catalyst. The pendant acetoacetate group could mediate several characteristic reactions, such as the Michael addition reaction, ketone-amine condensation and metal coordination reaction. As such, structurally adjustable polyolefin vitrimers can be accessed by introducing various dynamic crosslinking bonds, including disulfide exchange, transamination of vinylogous urethane and labile metal coordination bond. The utilization of different crosslinking reactions and the mole ratio of crosslinkers significantly impact the material properties of the resultant polymers. Specifically, the generated polyolefin vitrimers demonstrated excellent reprocessability and closed-loop recycling properties. The study in this work provides an efficient strategy to access various polyolefin vitrimers.

关键词： polyolefin vitrimers acetoacetate group polar monomer olefin copolymerization

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Cascade equilibrium stage relaxation method by introducing equilibrium efficiency parameter

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Chinese Journal of Chemical engineering 2024年第2期66卷 145-156页

作者： Xuepu Cao Shengkun Jia Xing Qian Yiqing Luo Xigang Yuan College of Chemical and Pharmaceutical Hebei University of Science&TechnologyShijiazhuang 050018China School of Chemical Engineering and Technology State Key Laboratory of Chemical EngineeringTianjin UniversityTianjin 300072China College of Information Science and Technology Beijing University of Chemical TechnologyBeijing 100029China

Optimizing multistage processes,such as distillation or absorption,is a complex mixed-integer nonlinear programming(MINLP)*** integer into continuous variables and solving the easier nonlinear programming(NLP)problem is an optimization idea for the multistage *** this article,we propose a relaxation method based on the efficiency *** the efficiency parameter is 1or 0,the proposed model is equivalent to the complete existence or inexistence of the equilibrium *** non-integer efficiency represents partial existence.A multi-component absorption case shows a natural penalty for non-integer efficiency,which can assist the efficiency parameter converging to 0 or ***,its penalty is weaker than the existing relaxation models,such as the bypass efficiency *** a simple distillation case,we show that this property can weaken the nonconvexity of the optimization problem and increase the probability of obtaining better optimization results.

关键词： Mathematical modeling Absorption Distillation Optimization

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A Review of Intelligent Configuration and Its Security for Complex Networks

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Chinese Journal of Electronics 2024年第4期33卷 920-947页

作者： Yue ZHAO Bin YANG Fei TENG Xianhua NIU Ning HU Bo TIAN Science and Technology on Communication Security Laboratory School of Computer and Information Engineering Chuzhou University School of Computing and Artificial Intelligence Southwest Jiaotong University School of Computer and Software Engineering Xihua University Cyberspace Institute of Advanced Technology Guangzhou University

Complex networks are becoming more complex because of the use of many components with diverse technologies. In fact, manual configuration that makes each component interoperable has breed latent danger to system security. There is still no comprehensive review of these studies and prospects for further research. According to the complexity of component configuration and difficulty of security assurance in typical complex networks, this paper systematically reviews the abstract models and formal analysis methods required for intelligent configuration of complex networks, specifically analyzes, and compares the current key technologies such as configuration semantic awareness, automatic generation of security configuration, dynamic deployment, and verification evaluation. These technologies can effectively improve the security of complex networks intelligent configuration and reduce the complexity of operation and maintenance. This paper also summarizes the mainstream construction methods of complex networks configuration and its security test environment and detection index system, which lays a theoretical foundation for the formation of the comprehensive effectiveness verification capability of configuration security. The whole lifecycle management system of configuration security process proposed in this paper provides an important technical reference for reducing the complexity of network operation and maintenance and improving network security.

关键词： Complex networks Intelligent configuration Configuration security Software defined network Lifecycle management

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