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Proton storage chemistry in aqueous zinc-organic batteries:A review

InfoMat 2023年第2期5卷 45-65页

作者： Xianming Deng James Kumankuma Sarpong Guobin Zhang Jing Hao Xu Zhao Linyuan Li Hongfei Li Cuiping Han Baohua Li Shenzhen Key Laboratory of Power Battery Safety and Shenzhen Geim Graphene Center Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhenPeople's Republic of China School of System Design and Intelligent Manufacturing Southern University of Science and TechnologyShenzhenGuangdongPeople's Republic of China Faculty of Materials Science and Energy Engineering Institute of Technology for Carbon NeutralityShenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhenPeople's Republic of China Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhenPeople's Republic of China

Benefiting from the advantageous features of structural diversity and resource renewability,organic electroactive compounds are considered as attractive cathode materials for aqueous Zn-ion batteries(ZIBs).In this review,we discuss the recent developments of organic electrode materials for aqueous *** the proton(H^(+))storage chemistry in aqueous Zn-organic batteries has triggered an overwhelming literature surge in recent years,this topic remains ***,our review focuses on this significant issue and summarizes the reported electrochemical mechanisms,including pure Zn^(2+)intercalation,pure H^(+)storage,and H^(+)/Zn^(2+)***,the impact of H^(+)storage on the electrochemical performance of aqueous ZIBs is discussed *** the significance of H^(+)storage,we also highlight the relevant characterization methods ***,perspectives and directions on further understanding the charge storage mechanisms of organic materials are *** hope that this review will stimulate more attention on the H^(+)storage chemistry of organic electrode materials to advance our understanding and further its application.

关键词： aqueous zinc-ion batteries H^(+)/Zn^(2+)co-storage organic electrode materials proton storage chemistry

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Identification Algorithm Framework and Structural model on Input Pattern of Metamorphic Relations 9

Identification Algorithm Framework and Structural model on I...

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9th International Conference on Dependable systems and Their Applications, DSA 2022

作者： Yan, Shiyu Yang, Xiaohua Lu, Zhongjian Li, Meng Gong, Helin Liu, Jie Computer School University of South China Hunan Hengyang China Intelligent Equipment Software Evaluation Engineering Technology Research Center of Hunan Hengyang China Cnnc Key Laboratory on High Trusted Computing Hunan Hengyang China Nuclear Power Institute of China Science and Technology on Reactor System Design Technology Laboratory Chengdu China

ISBN: (数字)9781665488778

ISBN: (纸本)9781665488778

Metamorphic Relation (MR) plays a crucial role in Metamorphic Testing (MT), which can be regarded as the implication relation from the input pattern to the output pattern. Based on MR's properties, the identification of Metamorphic Relations (MRs) can be from its input pattern and output pattern, respectively. However, the finding of the effective input pattern is very first and important. Especially for complicated mathematical function includes more than two input variables, we systematically analyze the structural model of input pattern in MR, propose the concept of the class of basic input pattern, as well as prove that any one input pattern can be expressed as a combination of basic input patterns in scientific computing programs. Moreover, the structural model of input pattern in MR is established based on previous proof. Finally, we put forward an identification algorithm framework and analysis its complexity. The core contribution of our method is to decompose the input pattern identification problem in multi-dimensional space into a single one-dimensional. For this reason, the examples show that the complexity of the algorithm is reduced significantly. © 2022 IEEE.

关键词： Computational complexity

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Study on the mechanism of microcrack propagation in bentonite under confining pressure conditions

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Quarterly Journal of Engineering Geology and Hydrogeology 2025年

作者： Guo, Jingna Liu, Jiangfeng Liu, Daoping Zhao, Yu Lei, Min Shi, Hao School of Applied Mathematics Chengdu University of Information Technology Sichuan Chengdu610225 China State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering China University of Mining and Technology Jiangsu Xuzhou221116 China Science and Technology on Reactor System Design Technology Laboratory Nuclear Power Institute of China Chendu610213 China School of Civil Engineering and Architecture Anhui University of Science and Technology Huainan232001 China

For underground nuclear disposal repositories, sealing performance is crucial to ensuring long-term operational safety. Bentonite, widely employed as a sealing material, effectively reduces leakage risks owing to its self-healing capacity. However, a comprehensive investigation of gas migration mechanisms in bentonite is imperative to elucidate the underlying leakage dynamics. This study not only offers theoretical insights for the safety assessment and design optimization of disposal repositories but also holds substantial practical significance in ensuring their secure performance. To accurately model gas migration in saturated bentonite, this study systematically investigates the effects of pore pressure on soil deformation and experimentally evaluates the impact of damage evolution on permeability and elastic modulus. Building on these experimental insights, we propose a coupled fluid-solid constitutive model. This model elucidates the progressive development of microcracks within bentonite under increasing gas pressure, providing a mechanistic understanding of fracture propagation in sealing systems. By integrating experimental data from bentonite hydration and gas breakthrough tests, the study verifies that gas migration under flexible boundary conditions is primarily governed by the dilatancy effect of bentonite. Furthermore, the model's validity and applicability are demonstrated. Subsequently, the model is employed to systematically investigate the influence of confining pressure on (1) the evolution of microcracks in bentonite, (2) permeability variations, and (3) gas breakthrough pressure thresholds. Based on these analyses, theoretical mitigation strategies to prevent gas breakthrough are established for specific confining pressure ranges. © 2025 The Author(s). Published by The Geological Society of London. All rights, including for text and data mining (TDM), artificial intelligence (AI) training, and similar technologies, are reserved. For permissions:

关键词： Microcracks

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Entangled chip removal utilizing mass-spring model with mobile manipulator

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CIRP Annals 2025年

作者： Takahashi, Ryuki Kimura, Hayato Kakinuma, Yasuhiro Department of System Design Engineering Faculty of Science & Technology Keio University 3-14-1 Hiyoshi Yokohama Kohoku-ku Japan

This study aims to automate the removal of entangled chips in manufacturing environments using a mobile manipulator. Despite advancements in factory automation technology, this task often necessitates manual intervention. Accordingly, this study proposes a deformable chip model (based on a reconfigurable mass-spring system per frame), incorporating visual chip tracking data and force reactions. Consequently, to evaluate the removal state, an efficient removal strategy is derived by defining the instantaneous stiffness and energy absorption rate. Validation of system performance through two removal tests demonstrates the feasibility of automating entangled chip removal, contributing to enhanced operational efficiency in fully automated production lines. © 2025 The Author(s)

关键词： Factory automation

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A Selection Method of Effective Metamorphic Relations 13

A Selection Method of Effective Metamorphic Relations

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13th International Conference on Reliability, Maintainability, and Safety, ICRMS 2022

作者： Zhang, Jie Hong, Jie Huang, Dafei Li, Meng Yan, Shiyu Gong, Helin School of Computing University of South China Hunan Hengyang China Engineering and Technology Research Center of Software Evaluation and Testing for Intellectual Hunan Hengyang China CNNC Key Laboratory on High Trusted Computing Hunan Hengyang China Nuclear Power Institute of China Science and Technology on Reactor System Design Technology Laboratory Chengdu China

ISBN: (数字)9781665486903

ISBN: (纸本)9781665486903

Metamorphic testing can effectively alleviate the test oracle problem. However, the program under test needs to be executed one more time;it is particularly significant to select the metamorphic relation with the highly fault-detecting ability and improve the test cost-effectiveness. Due to the limitations of existing evaluation methods in engineering applications, a validity evaluation method for metamorphic relation is presented based on single factor and multi-factor mutation scores. It can guide their priority ranking and selection. Experiments show that this method can significantly reduce test costs. © 2022 IEEE.

关键词： Cost effectiveness

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Hot Compression Mechanical Behavior of Solution Heat‑Treated and Pre‑aged Mg–Zn–Gd–Er Alloys

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Acta Metallurgica Sinica(English Letters) 2023年第3期36卷 469-485页

作者： Bo Che Liwei Lu Longfei Liu Yan Yang Wei Kang Jun Luo Zhiqiang Wu Yongfeng Qiu School of Materials Science and Engineering Hunan University of Science and TechnologyXiangtan 411201China College of Materials Science and Engineering Chongqing UniversityChongqing 400044China Hunan Provincial Key Laboratory of Vehicle Power and Transmission System Hunan Institute of EngineeringXiangtan 411104China Guiyang Aluminum Magnesium Design&Research Institute Co. LtdGuiyang 550081China School of Automation Central South UniversityChangsha 410083China

The mechanical behavior of solution heat-treated and pre-aged Mg–6Zn–1Gd–1Er alloys during hot compression(from 180 to 330℃)has been *** results showed that the flow stress curves of the pre-aged sample(PAS)intersected with that of the solution heat-treated sample(SHTS)during hot *** 180℃,when the true strain is 0.27 and 0.47,the PAS showed larger and smaller stress(210.80 MPa vs.207.58 MPa and 205.67 MPa vs.207.93 MPa)than the SHTS,*** phenomena were due to the stronger interaction of W phase and dislocations/twins under the strain of 0.27,while dynamic recrystallization softening occurred under the strain of *** the temperature increased to 330℃,the flow stress of PAS and SHTS showed an opposite trend to that of 180℃.Continuous dynamic recrystallization and particle stimulated nucleation based on slip operations are the main deformation mechanisms under 330℃.At the true strain is 0.33 and 0.53,the PAS has smaller and larger stress(61.32 MPa vs.63.69 MPa and 58.75 MPa vs.57.09 MPa)than the SHTS,*** increasing deformation resistance of dynamic precipitation improved the flow stress under smaller strain and dynamic recrystallization decreased the flow stress under high strain,which resulted the opposite phenomena of SHTS.

关键词： Mg-6Zn-1Gd-1Er alloy Mechanical behavior Precipitates Twin Dynamic recrystallization

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Characterization of the Oxide Film and Deuterium Permeation Behavior of Cocrmnfeni High Entropy Alloy Oxidized at 550 °C for 24 Hours

SSRN

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SSRN 2023年

作者： Yin, Chunyu Li, Wenxuan Qiu, Xi Luo, Bin Huang, Hongtao Science and Technology on Reactor System Design Technology Laboratory Nuclear Power Institute of China Chengdu610213 China Sino-French Institute of Nuclear Energy and Technology Sun Yat-Sen University Zhuhai519082 China

High entropy alloys have become potential candidate materials for high temperature nuclear reactor due to its high strength, high hardness, excellent corrosion resistance and radiation resistance, therefore the compatibility of hydrogen isotopes with HEAs becomes a key issue that has attracted a lot of attentions. The deuterium permeation behavior of the CoCrMnFeNi high entropy alloy after oxidation at 550 °C for 24 h was investigated by gas-phase deuterium permeation testing, SEM, X-ray diffraction methods in this paper. The results show that a dense oxide film with a thickness of about 1μm was formed on the surface of the sample after oxidation. The outer layer of the oxide film is rich in Mn2O3 and the inner layer is rich in Cr2O3. The deuterium permeability of the CoCrMnFeNi sample after oxidation was reduced by an order of magnitude and was 1/7-1/17 times as high as that for the unoxidized one. © 2023, The Authors. All rights reserved.

关键词： Entropy

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Analysis of Age of Information in Non-terrestrial Networks

Analysis of Age of Information in Non-terrestrial Networks

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2023 IEEE Globecom Workshops, GC Wkshps 2023

作者： Lu, Yanwu Yang, Howard H. Pappas, Nikolaos Geraci, Giovanni Ma, Chuan Quek, Tony Q. S. ZJU-UIUC Institute Zhejiang University Haining China Linköping University Department of Computer and Information Science Linköping Sweden Telefonica Research Universitat Pompeu Fabra Barcelona Spain Zhejiang Lab Hangzhou China Information System and Technology Design Pillar Singapore University of Technology and Design Singapore

ISBN: (纸本)9798350370218

Non-terrestrial networks (NTN), particularly low Earth orbit (LEO) satellite networks, have emerged as a promising solution to overcome the limitations of traditional terrestrial networks in the context of next-generation (6G) wireless systems. In this paper, we focus on analyzing the timeliness of information delivery in NTN through the concept of Age of Information (AoI). We propose an on-off process to approximate the service process between LEO satellites and a source node located on the Earth's surface. By utilizing stochastic geometry, we derive a closed-form expression for the time-average AoI in an NTN. This expression also applies to on-off processes with one component following an exponential distribution while the other has its probability density function supported on a bounded interval. Numerical results validate the accuracy of our analysis and demonstrate the impact of source status update rate and satellite constellation density on the time-average AoI. Our work fills a gap in the literature by providing a comprehensive analysis of AoI in NTN and offers new insights into the performance of LEO satellite networks. © 2023 IEEE.

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High-Precision Point Cloud Data Acquisition for Robot Based on Multiple Constraints 16th

High-Precision Point Cloud Data Acquisition for Robot Based ...

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16th International Conference on Intelligent Robotics and Applications, ICIRA 2023

作者： Li, Bingbing Zhang, Teng Sun, Hao Deng, Runpeng Peng, Fangyu Yan, Rong Tang, Xiaowei The National NC System Engineering Research Center School of Mechanical Science and Engineering Huazhong University of Science and Technology Wuhan430074 China The Wuhan Digital Design and Manufacturing Innovation Center Co. Ltd. Wuhan430074 China The State Key Laboratory of Digital Manufacturing Equipment and Technology School of Mechanical Science and Engineering Huazhong University of Science and Technology Wuhan430074 China

ISBN: (纸本)9789819964796

The foundation of high-precision 3D reconstruction is the acquisition of high-precision point clouds. Through multi-view point cloud scanning and alignment, the point cloud of parts can be obtained. The great flexibility of the robot enables it to carry out scanning operations that require multi-view. However, the robots are limited in position error, and the accuracy of the camera varies depending on the range of vision. In addition, the point cloud density is influenced by the curvature of the workpiece, which seriously limits the accuracy of point cloud acquisition and registration. To solve these problems, a method of high-precision point cloud data acquisition for robots based on multiple constraints is proposed. The precision of the measuring system is increased by imposing constraints. So the high-performance field of vision of the camera and the high-performance motion space of the robot are obtained. The effect of workpiece curvature on point cloud scanning is thought to require increased camera viewpoints. After obtaining the camera viewpoints, the moving route planning of the robot is implemented using the ant colony voting method. In this paper, a curved blade experiment was carried out to prove the advantages of our method. It is not necessary for the point cloud overlap rate or the parts with many features. The accuracy of scanned point clouds is 0.249 mm, which is less than the results of using intelligent algorithms and marked points. © The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2023.

关键词： Cameras

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Position-and-Force-Sensorless Control Considering Equivalent Mass Matrix and Cross-Coupling Factors 49

Position-and-Force-Sensorless Control Considering Equivalent...

引用

49th Annual Conference of the IEEE Industrial Electronics Society, IECON 2023

作者： Shimamoto, Keita Murakami, Toshiyuki Yaskawa Electric Corporation Tsukuba Research Laboratory Ibaraki Japan Graduate School of Science and Technology Keio University Yokohama Japan Keio University Department of System Design Engineering Yokohama Japan

ISBN: (纸本)9798350331820

This paper presents a hybrid position/force control with equivalent mass matrices for position-and-force-sensorless manipulators and the evaluation of the control system. Position and force estimation methods in the controller are cascaded to estimate the position and force according to the respective characteristics of the electrical and mechanical systems. The proposed controller is designed to reduce vibration of the force control axes' motion from the cross-coupling factors of the dq-axis inductance, which cause position estimation error, and the cross-coupling effects among control axes from equivalent mass matrices, which expresses the relationship between the workspace force and acceleration. The position estimation based on the voltage equation, including the cross-coupling factors, derives compensation terms of the estimation error. The cross-coupling effects between position and force control axes in the equivalent mass matrices are designed to suppress the undesired force response vibrations. The experimental results show that the proposed system kept contact with an object during the rubbing motion by a 4-degree-of-freedom manipulator without position and force sensors. The utilized equivalent mass matrix reduced the force vibration caused by the vibration of the position estimation. © 2023 IEEE.

关键词： Force control

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