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Mechanical properties and microstructure evolution of T2 copper in multimodal ultrasonic vibration assisted micro-compression

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材料科学技术（英文版） 2025年第5期208卷 152-163页

作者： Weiqiang Wan Zidong Yin Guangchao Han Ming Yang Jitao Hu Fuchu Liu Linhong Xu Wei Bai Hui Chen School of Mechanical Engineering and Electronic Information China University of GeosciencesWuhan 430074China Graduate School of System Design Tokyo Metropolitan UniversityTokyo 191-0065Japan Graduate School of System Design Tokyo Metropolitan UniversityTokyo 191-0065Japan School of Mechanical Engineering and Electronic Information China University of GeosciencesWuhan 430074China Shenzhen Research Institute China University of GeosciencesShenzhen 518057China State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi'an 710072China School of Mechanical Engineering and Electronic Information China University of GeosciencesWuhan 430074China School of Mechanical Engineering and Electronic Information China University of GeosciencesWuhan 430074China Shenzhen Research Institute China University of GeosciencesShenzhen 518057China School of Mechanical Engineering and Electronic Information China University of GeosciencesWuhan 430074China Shenzhen Research Institute China University of GeosciencesShenzhen 518057China Shenzhen Huazhong University of Science and Technology Research Institute Shenzhen 518000China State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi'an 710072China

Multimodal ultrasonic vibration(UV)assisted micro-forming has been widely investigated for its advan-tages of further reducing forming loads and improving forming ***,the influence mecha-nism of different UV modes on microstructure evolution and mechanical properties was still ***-timodal UV assisted micro-compression tests on T2 copper with different grains and sample sizes were conducted in this *** microstructure evolution for different UV modes was observed by *** results showed that the true stress reduction caused by UV was increased sequentially with tool ultrasonic vibration(TV),mold ultrasonic vibration(MV)and compound ultrasonic vibration(CV).The region of grain deformation was shifted along the direction of UV,and the MV promoted the uniform distribution of deformation *** grain refinement,fiber streamline density,grain deformation and rotation degree were further enhanced under CV,due to the synergistic effect of TV and ***,a coupled theoretical model considering both acoustic softening effect and size effect was proposed for describing the mechanical *** a physical model of dislocation motion in different UV modes was developed for describing the microstructure *** maximum error between the theoretical and experimental results was only 2.39％.This study provides a theoretical basis for the optimization of UV assisted micro-forming process.

关键词： Multimodal ultrasonic vibration Microstructure evolution Acoustic softening Size effect Coupling mechanism

A compact fluorescence/circular dichroism dual-modality probe for detection, differentiation, and detoxification of multiple heavy metal ions via bond-cleavage cascade reactions

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Chinese Chemical Letters 2021年第12期32卷 3876-3881页

作者： Junwei Chen Na Wang Hongjuan Tong Chao Song Huijuan Ma Yajun Zhang Feng Gao Huan Xu Wei Wang Kaiyan Lou State Key Laboratory of Bioengineering Reactor.Shanghai Key Laboratory of New Drug Design and Shanghai Key Laboratory of Chemical BiologySchool of PharmacyEast China University of Science & TechnologyShanghai 200237China School of Pharmacy Collaborative Innovation Center of Green Manufacturing Technology for Traditional Chinese Medicine in Shaanxi ProvinceShaanxi Institute of International Trade&CommerceXi'an 712046China Department of Pharmacology and Toxicology and BIO5 Institute University of ArizonaTucson AZ 85721-0207United States

Selective detection of multiple analytes in a compact design with dual-modality and theranostic features presents great challenges. Herein, we wish to report a coumarin-thiazolidine masked D-penicillamine based dual-modality fluorescent probe COU-DPA-1 for selective detection, differentiation, and detoxification of multiple heavy metal ions(Ag^(+), Hg^(2+), Cu^(2+)). The probe shows divergent fluorescence(FL)/circular dichroism(CD) responses via divergent bond-cleavage cascade reactions(metal ion promoted C-S cleavage and hydrolysis at two distinctive cleavage sites): FL “turn-off” and CD “turn-on” for Ag+(no hydrolysis), FL “turn-on” and CD “turn-off” for Hg^(+)(imine hydrolysis), and FL “self-threshold ratiometric” and CD “turn-off” for excess Cu^(2+)(lactone and imine hydrolysis), providing the first example of a fluorescence/CD dual-modality probe for multiple species with complimentary responses. Moreover, the bond-cleavage cascade reactions also lead to the formation of D-penicillamine heavy metal ion complexes for potential detoxification treatments.

关键词： Fluorescent probe Circular dichroism Heavy metal ions Dual-modality Detoxification Cascade reaction Divergent responses

Effect of the Graphene Oxide Incorporation on the Morphology, Corrosion Resistance And Fatigue Performance Of Micro-Arc Oxidation Coating on Mg Alloy

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SSRN 2024年

作者： Tan, Yansong Liu, Xin Sun, Xiaohao Gao, Lilan Liu, Debao Zhang, Chunqiu Tianjin Key Laboratory for Advanced Mechatronic System Design and Intelligent Cont rol School of Mechanical Engineering Tianjin University of Technology Tianjin300384 China National Demonstration Center for Experimental Mechanical and Electrical Engineerin g Education Tianjin University of Technology Tianjin300384 China School of Materials Science and Engineering Tianjin University of Technology Tianjin300384 China

Mg alloy has great potential in biomedical applications, but the rapid corrosion rate which mismatches with bone reconstruction rate limits its clinical use. A protective oxide coating layer can be generated on the surface of Mg alloy by micro-arc oxidation (MAO) technique, aiming to improve the corrosion performance and long-term structural integrity of Mg alloy. In this study, the MAO coating layer of Mg alloy was improved by adding appropriate content of graphene oxide (GO) into electrolyte solution. GO has excellent adsorption property and plays a role in the MAO process, reducing the intermolecular gap, thereby improving the densification and obturation of the coating surface. With the increase of GO content, the surface morphology of the MAO coating initially has improved, then later deteriorated, and the best surface morphology has achieved at a GO content of 0.4 g/L. When the GO content increases from 0 g/L to 0.4 g/L, the corrosion current density reduces to 5.226 μA/cm2, with a reduction two orders in magnitude;in addition, at a stress amplitude of 140 MPa and a frequency of 4 Hz, the fatigue life increases from 9261 cycles to 13887 cycles without corrosion, and from 2042 cycles to 2759 cycles after pre-corrosion. This study provided a promising approach to ameliorate the morphology, corrosion resistance and fatigue performance of MAO coating on Mg alloy by elaborately configuring the electrolyte solution and customizing the process parameters. © 2024, The Authors. All rights reserved.

关键词： Corrosion resistance

Effect of the Graphene Oxide Incorporation on the Morphology, Corrosion Resistance and Fatigue Performance of Micro-Arc Oxidation Coating on Magnesium Alloy

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SSRN 2024年

Magnesium (Mg) alloy has great potential in biomedical applications, but the rapid corrosion rate which mismatches with bone reconstruction rate limits its clinical use. In this study, the graphene oxides (GO) were added into alkaline electrolyte solution during micro-arc oxidation (MAO) process, aiming to form a corrosion resistant surface coating on Mg alloy. By changing the concentration of GO, the coatings' morphology, composition, corrosion resistance, and fatigue property were compared to reveal the strengthening mechanism and find out the optimal graphene concentration. The results show that the MAO coating is composed of MgO, Mg2SiO4, Mg3(PO4)2 and GO. The added GO exhibits excellent adsorption property in the MAO process, reducing the intermolecular gap, thereby improving densification and obturation of the MAO coating. The surface morphology of MAO coating initially improves with increasing GO content, but then deteriorates, reaching its best quality at 0.4 g/L. Compared to MAO samples without GO, the samples with 0.4g/L GO not only have lower corrosion current density of 5.226 μA/cm2, but also show higher fatigue lives both before and after pre-corrosion. This study offers a promising approach to enhance the corrosion resistance and fatigue performance of Mg alloy by applying a GO-strengthened MAO coating onto its surface. © 2024, The Authors. All rights reserved.

关键词： Magnesium alloys

One-Pot Synthesis of Tetraarylpyrrolo[3,2-b]pyrrole Dopant-Free Hole-Transport Materials for Inverted Perovskite Solar Cells

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Chinese Journal of Chemical Physics 2021年第2期34卷 217-226,I0002页

作者： Liang-sheng Duan Quan-ping Wu Yuan-yuan Xu Hui Wang Zhe Sun Yu Chen Song Xue School of Materials Science and Engineering Tianjin Key Laboratory of the Design and Intelligent Control of the Advanced Mechanical SystemSchool of Mechanical EngineeringTianjin University of TechnologyTianjin 300384China

Four organic smallmolecule hole transport materials(D41, D42,D43 and D44) of tetraarylpyrrolo[3,2-b]pyrroles were prepared. They can be used without doping in the manufacture of the inverted planar perovskite solar cells. Tetraarylpyrrolo[3,2-b]pyrroles are accessible for one-pot synthesis.D42, D43 and D44 possess acceptor-π-donor-π-acceptor structure, on which the aryl bearing substitutes of cyan, fluorine and trifluoromethyl, respectively. Instead, the aryl moiety of D41 is in presence of methyl with a donor-π-donor-π-donor structure. The different substitutes significantly affected their molecular surface charge distribution and thin-film morphology, attributing to the electron-rich properties of fused pyrrole ring. The size of perovskite crystalline growth particles is affected by different molecular structures,and the electron-withdrawing cyan group of D42 is most conducive to the formation of large perovskite grains. The D42 fabricated devices with power conversion efficiency of17.3% and retained 55% of the initial photoelectric conversion efficiency after 22 days in dark condition. The pyrrolo[3,2-b]pyrrole is efficient electron-donating moiety for hole transporting materials to form good substrate in producing perovskite thin film.

关键词： Pyrrole[3,2-b]pyrrole Hole-transporting materials Organic small molecules Dopant-free Perovskite solar cells

Prediction of boiling crisis in a full-size rod bundle with spacer grids 14

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Prediction of boiling crisis in a full-size rod bundle with ...

14th International Nuclear Fuel Cycle Conference, GLOBAL 2019 and Light Water reactor Fuel Performance Conference, TOP FUEL 2019

作者： Li, Quan Li, Yuanming Avramova, M. Huang, Yongzhong Liu, Zhenhai Ma, Chao Qi, Feipeng Zhao, Bo Science and Technology on Reactor System Design Technology Laboratory Nuclear Power Institute of China Chengdu610213 China Department of Nuclear Engineering North Carolina State University NC27695 United States

In this paper, two-phase CFD approach is used to simulate the boiling crisis in PSBT rod bundle with spacer grids. The 5×5 rod bundle contains 17 spacer grids, which are finely modeled through UG code. Eulerian two-fluid model coupled with the extended wall boiling model is used to simulate the subcooled boiling flow. The used sub-models for nucleation site density and bubble departure diameter both take the effects of high pressure into consideration. The calculated surface averaged void fraction in the central four sub-channels shows good agreement with the experimental data at high void fraction conditions, while higher than the measured data at low void fraction conditions. Based on the two-phase simulations, the void fraction distribution in the plane section on which thermocouples are placed is used as the criteria for CHF prediction. The numerical simulation of boiling two-phase flow and prediction method of CHF provide new approach for the optimization of spacer grid and fuel assembly. Copyright © GLOBAL 2019 - International Nuclear Fuel Cycle Conference and TOP FUEL 2019 - Light Water reactor Fuel Performance *** rights reserved.

关键词： Forecasting

Research on Intelligent Temperature Control Method of Closed-Loop Cooling system Based on Deep Q-Network

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SSRN 2024年

作者： Liu, Yongchao Wang, Bo Zheng, Wei Wang, Zibo Li, Tong Cheng, Jiahao Niu, Zhenfeng Ke, Zhiwu Tan, Sichao Li, Jiangkuan Gao, Puzhen Tian, Ruifeng Zhu, Qidan Heilongjiang Provincial Key Laboratory of Nuclear Power System & Equipment Harbin Engineering University Harbin150001 China Key Laboratory of Nuclear Safety and Advanced Nuclear Energy Technology Ministry of Industry and Information Technology Harbin Engineering University Harbin150001 China Science and Technology Thermal Energy and Power Laboratory Wuhan430205 China Wuhan Second Ship Design and Research Institute Wuhan430205 China College of Intelligent Systems Science and Engineering Harbin Engineering University Harbin150001 China

As one of the most important subsystem types in the nuclear power system, the closed-loop cooling system is used for the heat transfer of the system. The control quality of its operating temperature is important for the safe operation of the entire nuclear power system. This paper proposes an intelligent temperature control method based on deep reinforcement learning (DRL). First, the closed-loop cooling system simulator is built and expanded to provide an experimental platform for the implementation of DRL. Secondly, a DRL interaction system is designed based on prior knowledge such as system thermal control characteristics and temperature control targets. Finally, the improved deep Q-network (DQN) algorithm is used to train the deep neural network agent, and the optimal temperature control strategy is approached and saved through self-learning interaction. The experimental results demonstrate that the DRL controller can realize automatic control operation and has good target tracking ability and robustness. © 2024, The Authors. All rights reserved.

关键词： Reinforcement learning

Photocatalytic Degradation of Tetracycline Over Bimetallic Layered Double Hydroxides-Mxenes Heterostructures Under Visible Light

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SSRN 2024年

作者： Yao, Jixin Liu, Yong Tong, Xiaowei Lu, Shibin Meng, Ying Li, Guang Anhui Province Key Laboratory of Simulation and Design for Electronic Information System Universities Joint Key Laboratory of Photoelectric Detection Science and Technology in Anhui Province Hefei Normal University Hefei230601 China School of Materials Science and Engineering Anhui Key Laboratory of Information Materials and Devices Key Laboratory of Structure and Functional Regulation of Hybrid Materials Ministry of Education Institute of Physical Science and Information Technology Anhui University Hefei230601 China School of Electronic Engineering Huainan Normal University Huainan232038 China

Layered double hydroxides (LDHs) are widely used in photocatalytic degradation of antibiotic pollutants under ultraviolet (UV)-light, but their efficiency under visible light is hampered by large band gaps and layer agglomeration. To address these challenges, we have successfully developed innovative bimetallic NiCo LDHs-MXenes heterostructures (LDHs-MXenes) for enhanced degradation of tetracycline (TC) pollutants under visible light conditions. As-prepared LDHs-MXenes photocatalysts (20 mg) show exceptional performance, achieving ~97.4% TC degradation efficiency (20 mg L-1, 100 mL) within just 50 minutes under a 300 W Xe lamp. This significant enhancement underscores the synergistic effects derived from the combination of LDHs and MXenes nanosheets. © 2024, The Authors. All rights reserved.

关键词： Heterojunctions

Non-Stoichiometric Protic Ionic Liquids for Efficient Carbon Dioxide Capture and Subsequent Conversion Under Mild Conditions

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SSRN 2024年

作者： Wang, Litian Chen, Jie Wang, Shuai Zhou, Tongyao Li, Dan Li, Cuiping Qian, Lirong Xiong, Yang Miao, Lin Xie, Zhiyong Tianjin Key Laboratory of Film Electronic and Communication Devices School of Integrated Circuit Science and Engineering Tianjin University of Technology Tianjin300384 China School of Integrated Circuit Science and Engineering Tianjin University of Technology Tianjin300384 China Tianjin Key Laboratory for Advanced Mechatronic System Design and Intelligent Control School of Mechanical Engineering Tianjin University of Technology Tianjin300384 China China Tianjin Bohua Yongli Chemical Industry CO. Ltd Tianjin30045 China

Protic ionic liquids (PILs) have emerged as innovative solvents with significant potential for CO2 capture and transformation, presenting a sustainable alternative to conventional methods which often involve energy-intensive processes or environmentally detrimental chemicals. Herein, a novel strategy for CO2 capture and conversion at mild conditions using non-stoichiometric protic ionic liquids (NPILs) was demonstrated for the first time. These NPILs, employed as sorbents, solvents, and catalysts, were composed of imidazole (Im) and 1,8-diazabicyclo [5.4.0] undec-7-ene (DBU) in various ratios. Correlations between the mole ratio of DBU/Im and physicochemical properties such as viscosity, conductivity, thermal stability, and the distribution of neutral and ionic species were systematically investigated. Effects of the absorption temperature and CO2 partial pressure on the absorption capacity were also studied. Different absorption mechanisms, including carbonate and carbamate pathways, were analyzed using FT-IR and NMR spectroscopy. Moreover, the fixed CO2 could be catalytically converted to quinazoline-2,4(1H,3H)-diones under exceptionally mild reaction conditions (1atm, 50 °C, metal-free process). A plausible reaction mechanism involving simultaneous CO2 activation and substrate activation for the transformation of CO2 into quinazoline-2,4(1H,3H)-diones was verified through NMR spectra. It is believed that the new insights into the CO2 mechanism will facilitate the rationaldesign of functional ionic liquids for CO2 capture, utilization, and storage in the future. © 2024, The Authors. All rights reserved.

关键词： Carbon dioxide