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Investigation of suitable precursors for manganese oxide catalysts in ethyl acetate oxidation

Journal of environmental Sciences 2021年第6期33卷 17-26页

作者： Yan Zhang Meng Wang Shunyu Kang Tingting Pan Hua Deng Wenpo Shan Hong He Center for Excellence in Regional Atmospheric Environment and Key Laboratory of Urban Pollutant Conversion Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Zhejiang Key Laboratory of Urban Environmental Processes and Pollution Control Ningbo Urban Environment Observation and Research StationChinese Academy of SciencesNingbo 315800China State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China

The control of ethyl acetate emissions from fermentation and extraction processes in the pharmaceutical industry is of great importance to the *** have developed three Mn_(2)O_(3)catalysts by using different Mn precursors(MnCl_(2),Mn(CH_(3)COO)_(2),MnSO_(4)),named as Mn_(2)O_(3)-Cl,-Ac,-SO_(4).The tested catalytic activity results showed a sequence with Mn precursors as:Mn_(2)O_(3)-Cl>Mn_(2)O_(3)-Ac>Mn_(2)O_(3)-SO_(4).The Mn_(2)O_(3)-Cl catalyst reached a complete ethyl acetate conversion at 212℃(75℃lower than that of Mn_(2)O_(3)-SO_(4)),and this high activity 100%could be maintained high at 212℃for at least 100 *** characterization data about the physical properties of catalysts did not show an obvious correlation between the structure and morphology of Mn_(2)O_(3)catalysts and catalytic performance,neither was the surface area the determining factor for catalytic activity in the ethyl acetate *** we firstly found there is a close linear relationship between the catalytic activity and the amount of lattice oxygen species in the ethyl acetate oxidation,indicating that lattice oxygen species were essential for excellent catalytic *** H_(2)temperature-programmed reduction(H_(2)-TPR)results,we found that the lowest initial reduction temperature over the Mn_(2)O_(3)-Cl had stronger oxygen mobility,thus more oxygen species participated in the oxidation reaction,resulting in the highest catalytic *** convenient preparation,high efficiency,and stability,Mn_(2)O_(3)prepared with MnCl_(2)will be a promising catalyst for removing ethyl acetate in practical application.

关键词： Ethyl acetate Catalytic oxidation Manganese Precursor Lattice oxygen species

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Targeting Ultra-Emitters for Effective Methane Mitigation in China’s Coal Sector

ACS ES&T Air

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ACS ES&T Air 2024年第7期1卷 734-742页

作者： Helan Wang Bo Zheng Hui Li Qiang Zhang Kebin He Shenzhen Key Laboratory of Ecological Remediation and Carbon Sequestration Institute of Environment and Ecology Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen 518055 China State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex Beijing 100084 China Department of Earth System Science Ministry of Education Key Laboratory for Earth System Modeling Institute for Global Change Studies Tsinghua University Beijing 100084 China State Key Joint Laboratory of Environment Simulation and Pollution Control School of Environment Tsinghua University Beijing 100084 China

The energy system fuels climate change as the largest emitter of global greenhouse gases, while a lack of transparent, infrastructure-level information undermines efforts to cut emissions. Coal mining has been the largest emitter of methane (CH4) in China over the past 10 years, which is not tracked at the mine level, and effective mitigation pathways have yet to be established. Herein, we develop a state-of-the-art CH4emission database, comprising 3343 active coal mines in China, by harmonizing multisource information. The results suggest that China’s coal mines emitted 15.8 ± 5.1 million metric tons CH4yr–1in 2019. Those with CH4emission intensities >2 standard deviations above the national mean accounted for 4% of China’s coal production, yet they generated 23% of China’s coal CH4emissions. We project a steady decline in China’s coal CH4emissions by >75% in 2100 compared to 2019 levels under three different scenarios, due to reduced coal demand during energy transition. Targeting ultra-emitters for mine closure will accelerate emission reductions in the midterm and achieve deep CH4emission cuts by >92% in 2100, which buys us time to control global warming. Our idealized mine closure strategy serves as a cost-effective CH4mitigation strategy to enable swift climate action.

关键词： Biological databases Climate Coal Energy Hydrocarbons

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Impacts of Comorbidity and Mental Shock on Organic Micropollutants in Surface Water During and After the First Wave of COVID-19 Pandemic in Wuhan (2019–2021), China

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Engineering 2024年第6期37卷 40-48页

作者： Jian Zhao Jin Kang Xiaofeng Cao Rui Bian Gang Liu Shengchao Hu Xinghua Wu Chong Li Dianchang Wang Weixiao Qi Cunrui Huang Huijuan Liu Jiuhui Qu Center for Water and Ecology State Key Joint Laboratory of Environment Simulation and Pollution ControlSchool of EnvironmentTsinghua UniversityBeijing 100084China Hubei Provincial Research Institute of Environmental Science Wuhan 430072China Key Laboratory of Drinking Water Science and Technology Research Centre for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Sanitary Engineering Department of Water ManagementFaculty of Civil Engineering and GeosciencesDelft University of TechnologyDelft 2600 GAThe Netherlands China Three Gorges Corporation Wuhan 430010China Vanke School of Public Health Tsinghua UniversityBeijing 100084China

The first pandemic wave of coronavirus disease 2019(COVID-19)induced a considerable increase in several antivirals and antibiotics in surface *** common symptoms of COVID-19 are viral and bacterial infections,while comorbidities(e.g.,hypertension and diabetes)and mental shock(e.g.,insomnia and anxiety)are ***,little is known about the long-term impacts of comorbidities and mental shock on organic micropollutants(OMPs)in surface ***,we monitored 114 OMPs in surface water and wastewater treatment plants(WWTPs)in Wuhan,China,between 2019 and *** pandemic-induced OMP pollution in surface water was confirmed by significant increases in 26 OMP *** increases in four antihypertensives and one diabetic drug suggest that the treatment of comorbidities may induce OMP ***,cotinine(a metabolite of nicotine)increased 155 times to 187 ngL1,which might be associated with increased ***,the increases in zolpidem and sulpiride might be the result of worsened insomnia and ***,it is reasonable to note that mental-health protecting drugs/behavior also contributed to OMP *** the observed OMPs,telmisartan,lopinavir,and ritonavir were associated with significantly higher ecological risks because of their limited WWTP-removal rate and high *** study provides new insights into the effects of comorbidities and mental shock on OMPs in surface water during a pandemic and highlights the need to monitor the fate of related pharmaceuticals in the aquatic environment and to improve their removal efficiencies in WWTPs。

关键词： Coronavirus disease 2019 Comorbidities Mental shock Micropollutant Surface water

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Aqueous-phase formation of N-containing secondary organic compounds affected by the ionic strength

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Journal of environmental Sciences 2024年第4期138卷 88-101页

作者： Yuqi Gan Xiaohui Lu Shaodong Chen Xinghua Jiang Shanye Yang Xiewen Ma Mei Li Fan Yang Yewen Shi Xiaofei Wang Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention Department of Environmental Science and EngineeringFudan UniversityShanghai 200433China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China Guangdong Provincial Observation and Research Station for Coastal Atmosphere and Climate of the Great Bay Area Southern University of Science and TechnologyShenzhen 518055China Institute of Mass Spectrometry and Atmospheric Environment Guangdong Provincial Engineering Research Center for On-line Source Apportionment System of Air PollutionJinan UniversityGuangzhouChina Environmental Monitoring Station of Pudong New District Shanghai 201200China Shanghai Municipal Center for Disease Control&Prevention Shanghai 200336China

The reaction of carbonyl-to-imine/hemiaminal conversion in the atmospheric aqueous phase is a critical pathway to produce the light-absorbing N-containing secondary organic compounds(SOC).The formation mechanism of these compounds has been wildly investigated in bulk solutions with a low ionic ***,the ionic strength in the aqueous phase of the polluted atmosphere may be *** is still unclear whether and to what extent the inorganic ions can affect the SOC *** we prepared the bulk solution with certain ionic strength,in which glyoxal and ammonium were mixed to mimic the aqueous-phase *** characterization by High-resolution Mass Spectrometry was performed to identify the N-containing products,and the light absorption of the mixtures was measured by ultraviolet-visible ***-nine N-containing compounds were identified and divided into four categories(N-heterocyclic chromophores,high-molecular-weight compounds with N-heterocycle,aliphatic imines/hemiaminals,and the unclassified).It was observed that the longer reaction time and higher ionic strength led to the formation of more N-heterocyclic chromophores and the increasing of the lightabsorbance of the *** added inorganic ions were proposed to make the aqueous phase somewhat viscous so that the molecules were prone to undergo consecutive and intramolecular reactions to form the *** general,this study revealed that the enhanced ionic strength and prolonged reaction time had the promotion effect on the lightabsorbing SOC *** implies that the aldehyde-derived aqueous-phase SOC would contribute more light-absorbing particulate matter in the industrial or populated area where inorganic ions are abundant.

关键词： Ionic strength Carbonyl-to-imine/hemiaminal Heterocyclic Brown carbon Mass spectrometry Aqueous-phase reaction

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Microbial responses to the use of NaClO in sediment treatment

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Frontiers of environmental Science & Engineering 2022年第2期16卷 25-38页

作者： Kun Li Tingming Ye Wang Zhang Jianfeng Peng Yaohui Bai Weixiao Qi Huijuan Liu Key Laboratory of Drinking Water Science and Technology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Center for Water and Ecology State Key Joint Laboratory of Environment Simulation and Pollution ControlSchool of EnvironmentTsinghua UniversityBeijing 100084China University of Chinese Academy of Sciences Beijing 100049China China University of Mining&Technology Beijing 100083China

Chlorine is often used in algal removal and deodorization of landscape waters,and occasionally used as an emergency treatment of heavily polluted ***,the ecological impact of this practice has not been fully studied and *** this study,NaClO at 0.1 mmol/g based on dry weight sediment was evenly mixed into the polluted sediment,and then the sediment was incubated for 150 days to evaluate its microbial *** showed that NaClO addition enhanced the release of TOC,TN,Cr and Cu from the *** microbial richness in the examined sediment decreased continuously,and the Chao1 index declined from 4241 to 2731,in 150 *** microbial community composition was also *** abundance of Proteobacteria and Bacteroidetes increased to 54.8%and 4.2%within 7 days compared to the control,and linear discriminant analysis(LDA)showed gram-negative bacteria and aerobic bacteria enriched after *** functional prediction with PICRUSt2 showed the functions of the microbial community underwent major adjustments,and the metabolic-related functions such as carbon metabolism,including pyruvate and methane metabolisms were significantly inhibited;besides,15 out of 22 analyzed key enzymes involved in C cycling and 6 out of 12 key enzymes or genes involved in N cycling were strongly impacted,and the enzymes and genes involved in carbon degradation and denitrification showed remarkable *** can be concluded that chlorination posed a seriously adverse effect on microbial community structure and *** study deepens the understanding of the ecological effects of applying chlorine for environmental remediation.

关键词： Sediment chlorination Substance mobility Microbial response Community composition Function

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Microbial Electrosynthesis for Producing Medium Chain Fatty Acids

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Engineering 2022年第9期16卷 141-153页

作者： Na Chu Wen Hao Qinglian Wu Qinjun Liang Yong Jiang Peng Liang Zhiyong Jason Ren Raymond Jianxiong Zeng Fujian Provincial Key Laboratory of Soil Environmental Health and Regulation College of Resources and EnvironmentFujian Agriculture and Forestry UniversityFuzhou 350002China State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing 100084China College of Architecture and Environment Sichuan UniversityChengdu 610065China Department of Civil and Environmental Engineering&Andlinger Center for Energy and the Environment Princeton UniversityPrincetonNJ 08544USA

Microbial electrosynthesis(MES)employs microbial catalysts and electrochemistry to enhance CO_(2)bioconversion to organics with concurrent waste biorefining *** aim of this review is to comprehensively discuss the current state of the art and prospects of medium chain fatty acids(MCFAs)production in MES from CO_(2)and organic *** mechanisms and development of MCFAs production via conventional fermentation are introduced as *** on MCFAs production in MES are summarized,highlighting the strategy of multiple-electron donors(EDs).Challenges for MCFAs production in MES from CO_(2)are presented,and the primary discussions included methanogenesis inhibition,adenosine triphosphate(ATP)limitations of acetogens,and production of limited EDs via *** applications of electrochemical approaches to promote the bioconversion of actual waste materials with MCFAs production are ***,future directions are explored,including multi-stage reactions,substrate supply,product extraction,and microbial pathways.

关键词： Electro-fermentation Microbial electrochemistry Acetogen Chain elongation Electroactive microorganism

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Identification of resistant pharmaceuticals in ozonation using QSAR modeling and their fate in electro-peroxone process

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Frontiers of environmental Science & Engineering 2021年第5期15卷 325-338页

作者： Majid Mustafa Huijiao Wang Richard H.Lindberg Jerker Fick Yujue Wang Mats Tysklind Department of Chemistry UmeåUniversityUmeåS-90187Sweden School of Environment Beijing Key Laboratory for Emerging Organic Contaminants ControlState Key Joint Laboratory of Environmental Simulation and Pollution Control(Ministry of Education)Tsinghua UniversityBeijing100084China

The abatements of 89 pharmaceuticals in secondary effluent by ozonation and the electro-peroxone(E-peroxone)process were *** on the results,a quantitative structure-activity relationship(QSAR)model was developed to explore relationship between chemical structure of pharmaceuticals and their oxidation rates by *** orthogonal projection to latent structure(OPLS)method was used to identify relevant chemical descriptors of the pharmaceuticals,from large number of descriptors,for model *** resulting QSAR model,based on 44 molecular descriptors related to the ozone reactivity of the pharmaceuticals,showed high goodness of fit(R^(2)=0.963)and predictive power(Q^(2)=0.84).After validation,the model was used to predict second-order rate constants of 491 pharmaceuticals of special concern(k_(O_(3)))including the 89 studied *** predicted k_(O_(3))values and experimentally determined pseudo-first order rate constants of the pharmaceuticals’abatement during ozonation(k_(OZ))and the E-peroxone process(k_(EP))were then used to assess effects of switching from ozonation to the E-peroxone process on removal of these *** results indicate that the E-peroxone process could accelerate the abatement of pharmaceuticals with relatively low ozone reactivity(k_(O_(3))<∼10^(2)M^(−1)⋅s^(−1))than ozonation(3–10 min versus 5–20 min).The validated QSAR model predicted 66 pharmaceuticals to be highly O_(3)-*** developed QSAR model may be used to estimate the ozone reactivity of pharmaceuticals of diverse chemistry and thus predict their fate in ozone-based processes.

关键词： Ozone Electro-peroxone Wastewater Quantitative structure activity relationship Advanced oxidation processes

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Kinetic study of ultrasonic-assisted vanadium(V) adsorption by supported bifunctionalizedized ionic liquid

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Transactions of Nonferrous Metals Society of China 2025年第3期35卷 1000-1016页

作者： Jia-hao ZHOU Shen-xu BAO Yi-min ZHANG Bo CHEN Yu LIANG Xiao-chuan HOU Si-yuan YANG Yang PING Key Laboratory of Green Utilization of Critical Non-metallic Mineral Resources Ministry of EducationWuhan University of TechnologyWuhan 430070China School of Resources and Environmental Engineering Wuhan University of TechnologyWuhan 430070China Hubei Key Laboratory of Mineral Resources Processing and Environment Wuhan 430070China State Environmental Protection Key Laboratory of Mineral Metallurgical Resources Utilization and Pollution Control Wuhan University of Science and TechnologyWuhan 430081China Zhejiang New Era Zhongneng Recycling Technology Co. Ltd.Shaoxing 312000China Powerchina Eco-environmental Group Co. Ltd.Shenzhen 518102China

The adsorption kinetics of polystyrene[1-butyl-3-methylimidazolium][bis(2,4,4-trimethylpentyl)phosphinate](PS[C_(4)mim][C272])towards V(V)in acidic leachate was explored under *** effects of ultrasonic power and V(V)concentration on the adsorption performance of PS[C_(4)mim][C272]were *** results showed that ultrasonic radiation significantly shortened the adsorption equilibrium time and improved the adsorption performance of PS[C_(4)mim][C272]compared with the conventional *** an ultrasonic power of 200 W,the equilibrium adsorption capacity of PS[C_(4)mim][C272]reached its maximum of 311.58 mg/*** kinetic model fitting results showed that the adsorption process of PS[C_(4)mim][C272]strictly followed the pseudo-second-order kinetic model under *** using the shrinking core model and the Weber−Morris model showed that the adsorption process of PS[C_(4)mim][C272]was primarily controlled by intra-particle diffusion *** adsorption isotherm model study showed that the Langmuir isotherm model could effectively fit the adsorption process of PS[C_(4)mim][C272]under ultrasound.

关键词： kinetics ultrasound vanadium polystyrene[1-butyl-3-methylimidazolium][bis(2,4,4-trimethylpentyl)-phosphinate] conventional oscillation adsorption

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Perspectives on the impacts of climate change and their adaptation

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National Science Open 2024年第1期3卷 4-5页

作者： Guohe Huang Jiapei Chen State Key Joint Laboratory of Environmental Simulation and Pollution Control China-Canada Center for EnergyEnvironment and Ecology ResearchUR-BNUSchool of EnvironmentBeijing Normal UniversityBeijing 100875China Environmental Systems Engineering Program University of ReginaReginaSaskatchewan S4S 0A2Canada

The pressing impacts of climate change and the imperative for adaptation strategies emphasize the immediate necessity for proactive global *** challenges encompass the enhancement of climate modeling,the development of sector-tailored strategies,and the implementation of adaptation *** these issues necessitates worldwide collaborations,sustainable practices,technological innovations.

关键词： climate adaptation collaboration

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Transformation of dissolved organic matter during groundwater arsenite removal using air cathode iron electrocoagulation

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Chemosphere 2024年 358卷 142083页

作者： Yuan, Ying Chen, Jiabao Zhang, Hao Wu, Yue Xiao, Yu Huang, Wan Wang, Yang Tang, Jun Zhang, Fang State Environmental Protection Key Laboratory of Simulation and Control of Groundwater Pollution Chinese Research Academy of Environmental Sciences Beijing100012 China School of Environment and State Key Joint Laboratory of Environment Simulation and Pollution Control Tsinghua University Beijing100084 China College of Environmental Science and Engineering Guilin University of Technology Guilin541004 China

Dissolve organic matters (DOM) usually showed negative effect on the removal of inorganic arsenic (As) in groundwater by electrochemical approaches, yet which parts of sub-component within DOM played the role was lack of evidence. Herein, we investigated the effects of land-source humic-like acid (HA) on groundwater As(III) removal using air cathode iron electrocoagulation, based on the parallel factor analysis of three-dimensional excitation–emission matrix and statistical methods. Our results showed that the land-source HA contained five kinds of components and all components presented significantly negative correlations with the removal of both As(III) and As(V). However, the high aromatic fulvic-like acid and low aromatic humic-like acid components of land-source HA presented the opposite correlations with the concentration of As(III) during the reaction. The high aromaticity fulvic-like components of land-source HA (Sigma-Aldrich HA, SAHA) produced during the reaction facilitated the oxidation of As(III) due to its high electron transfer capacities and good solubility in wide pH range, but the low aromaticity humic-like ones worked against the oxidation of As(III). Our findings offered the novel insights for the flexible activities of DOM in electron Fenton system. © 2024 Elsevier Ltd

关键词： Groundwater

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