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Cobalt doping amount determines dominant reactive species in peroxymonosulfate activation via porous carbon catalysts co-doped by cobalt and nitrogen

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Journal of Environmental sciences 2024年第4期138卷 212-226页

作者： Xiang Li Limeng Wu Aiqin Zhang Shaohua Wu Yan Lin Chunping Yang Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Nanchang Hangkong UniversityNanchang 330063China Academy of Environmental and Resource Sciences School of Environmental Science and EngineeringGuangdong University of Petrochemical TechnologyMaoming 525000China College of Environmental Science and Engineering Hunan University and Key Laboratory of Environmental Biology and Pollution Control(Hunan University)Ministry of EducationChangsha 410082China

Switching the reaction routes in peroxymonosulfate(PMS)-based advanced oxidation processes have attracted much attention but remain ***,a series of Co-N/C catalysts with different compositions and structures were prepared by using bimetallic zeolitic imidazolate frameworks based on ZIF-8 and ZIF-67(x Zn/Co-ZIFs).Results show that Co doping amount could mediate the transformation of the activation pathway of PMS over CoN/*** Co doping amount was less than 10%,the constructed x Co-N/C/PMS system(x≤10%)was singlet oxygen-dominated reaction;however further increasing Co doping amount would lead to the generation and coexistence of sulfate radicals and high-valent cobalt,besides singlet ***,the nitrogen-coordinated Co(Co-NX)sites could serve as main catalytically active sites to generate singlet *** excess Co doping amount caused the formation of Co nanoparticles from which leached Co ions were responsible for the generation of sulfate radicals and high-valent *** to undoped N/C,Co doping could significantly enhance the catalytic *** 0.5%Co-N/C could achieve the optimum degradation(0.488 min^(-1))and mineralization abilities(78.4%)of sulfamethoxazole among the investigated Co-N/C catalysts,which was superior to most of previously reported *** addition,the application prospects of the two systems in different environmental scenarios(pH,inorganic anions and natural organic matter)were assessed and showed different degradation *** study provides a strategy to regulate the reactive species in PMS-based advanced oxidation process.

关键词： Peroxymonosulfate Sulfate radical Singlet oxygen Cobalt Zeolitic imidazolate framework Advanced oxidation process

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Intake of tobacco nitrosamines of smokers in various provinces of China and their cancer risk:A meta-analysis

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Journal of Environmental sciences 2024年第7期141卷 249-260页

作者： Xiao Li Zhiwei Ye Jun Wang Pengfei Lin Xiaojin Zhang Shuguang Xie Chao Chen Research Institute for Environmental Innovation(Suzhou) TsinghuaSuzhouJiangsu 215163China State Key Joint Laboratory of Environmental Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing 100084China Shenzhen Key Laboratory of Organic Pollution Prevention and Control State Key Laboratory of Urban Water Resource and EnvironmentHarbin Institute of TechnologyShenzhen 518055China State Key Joint Laboratory of Environmental Simulation and Pollution Control College of Environmental Science and EngineeringPeking UniversityBeijing 100871China

Nitrosamines are a class of carcinogens which have been detected widely in food,water,some pharmaceuticals as well as *** objectives of this paper include reviewing the basic information on tobacco consumption and nitrosamine contents,and assessing the health risks of tobacco nitrosamines exposure to Chinese *** searched the publications in English from“Web of science”and those in Chinese from the“China National Knowledge Infrastructure”in 2022 and collected 151 literatures with valid *** content of main nitrosamines in tobacco,including 4-(methylnitrosoamino)-1-(3-pyridyl)-1-butanone(NNK),N-nitrosonornicotine(NNN),N-nitrosoanatabine(NAT),N-nitrosoanabasine(NAB),total tobacco-specific nitrosamines(TSNA),and N-nitrosodimethylamine(NDMA)were *** information of daily tobacco consumption of smokers in 30 provinces of China was also ***,the intakes of NNN,NNK,NAT,NAB,TSNAs,and NDMA via tobacco smoke were estimated as 1534ng/day,591 ng/day,685 ng/day,81 ng/day,2543 ng/day,and 484 ng/day by adult smokers in30 provinces,*** cancer risk(CR)values for NNN and NNK inhalation intake were further calculated as 1.44×10^(-5)and 1.95×10^(-4).The CR value for NDMA intake via tobacco smoke(inhalation:1.66×10^(-4))indicates that NDMA is similarly dangerous in tobacco smoke when compared with the *** China,the CR values caused by average nitrosamines intake via various exposures and their order can be estimated as the following:smoke(3.75×10^(-4))>food(1.74×10^(-4))>drinking water(1.38×10^(-5)).Smokers in China averagely suffer 200%of extra cancer risk caused by nitrosamines in tobacco when compared with non-smokers.

关键词： N-nitrosamine Tobacco Cancer risk Tobacco specific nitrosamines(TSNAs) N-nitrosodimethylamine(NDMA)

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Adaptive Task Allocation for Multi-UAV Systems Using a Novel Dynamic Distributed Algorithm

Adaptive Task Allocation for Multi-UAV Systems Using a Novel...

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2024 China Automation Congress, CAC 2024

作者： Zhou, Cheng Li, Nuo Yang, Shuqi Yu, Lianbo Lian, Lei Wang, Dong Wang, Wei Key Laboratory of Intelligent Control and Optimization for Industrial Equipment Ministry of Education School of Control Science and Engineering Dalian University of Technology Dalian China

ISBN: (纸本)9798350368604

This paper introduces the Dynamic Efficient Distributed Performance Impact (DEDPI) algorithm for optimizing task allocation in multi-UAV systems operating in dynamic environments. The algorithm overcomes the limitations of existing approaches, specifically the suboptimal solutions of dynamic task algorithms and the computational inefficiencies of extending static algorithms to dynamic contexts, by dynamically adjusting task queues and employing a novel objective function to enhance resource allocation and responsiveness. Experimental results demonstrate that DEDPI significantly increases the number of completed tasks while reducing the average task execution cost, providing an effective solution for real-time, mission-critical UAV operations. © 2024 IEEE.

关键词： Resource allocation

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Yolo-S: Texture-Less Object Pose Estimation with Shape Prior 13

Yolo-S: Texture-Less Object Pose Estimation with Shape Prior

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13th IEEE Data Driven control and Learning Systems Conference, DDCLS 2024

作者： Wang, Danzhu Liu, Shan Polytechnic Institute Zhejiang University Hangzhou310015 China College of Control Science and Engineering Zhejiang University State Key Laboratory of Industrial Control Technology Hangzhou310027 China

ISBN: (纸本)9798350361674

This paper aims to address the challenge of pose estimation for texture-less objects under conditions of stacking, occlusion, and complex backgrounds. The proposed method, called Yolo-S, consists of two parts: a pre-estimation network based on Yolov8 backbone and a key point post-refinement network based on Graph Neural Network. The first part uses off-the-shelf detectors result as inputs (e.g. MaskRCNN) and outputs the pre-estimate keypoints at the pixel coordinates. The second part encodes the roughly estimated keypoints and the priori knowledge of the object's CAD model, uses a graph neural network to intergrate feature and predict the final keypoints. PNP method is used to obtain the object's pose. The main advantage of Yolo-S is that is has a prior knowledge embedded GNN model for estimating the pose of texture-less objects, which greatly improves prediction quality and accuracy and achieves zero-shot sim-to-real model transfer. Experimental results on the LINEMOD dataset demonstrate the effectiveness of the proposed method and its significant competitiveness with other state-of-the-art methods. © 2024 IEEE.

关键词： Graph neural networks

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Time-Varying Formation Tracking control of Heterogeneous Multi-Agent Systems With Intermittent Communications and Directed Switching Networks

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IEEE/CAA Journal of Automatica Sinica 2025年第1期12卷 294-296页

作者： Yuhan Wang Zhuping Wang Hao Zhang Huaicheng Yan the Shanghai Research Institute for Intelligent Autonomous Systems Tongji University the National Key Laboratory of Autonomous Intelligent Unmanned Systems the Frontiers Science Center for Intelligent Autonomous System of Ministry of Education the College of Electronic and Information Engineering the Department of Control Science and Engineering Tongji University the Key Laboratory of Advanced Control and Optimization for Chemical Processes of Ministry of Education the School of Information Science and Engineering East China University of Science and Technology

Dear Editor,This letter is concerned with the problem of time-varying formation tracking for heterogeneous multi-agent systems(MASs) under directed switching networks. For this purpose, our first step is to present so... 详细信息

关键词： Switches Topology Observers Formation control Event detection Switched systems Multi-agent systems control theory Autonomous systems Stability

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Tailor-made overstable 3D carbon superstructures towards efficient zinc-ion storage

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Chinese Chemical Letters 2025年第4期36卷 439-445页

作者： Chengmin Hu Pingxuan Liu Ziyang Song Yaokang Lv Hui Duan Li Xie Ling Miao Mingxian Liu Lihua Gan Shanghai Key Lab of Chemical Assessment and Sustainability School of Chemical Science and Engineering Tongji University College of Chemical Engineering Zhejiang University of Technology Key Laboratory of Yangtze River Water Environment Ministry of Education College of Environmental Science and Engineering Tongji University Shanghai Institute of Pollution Control and Ecological Security

Designing carbon materials with ideal stable hierarchical porous structures and fiexible functional properties for efficient and sustainable Zn2+ion storage still faces great challenges. Herein, the threedimensional carbon superstructures with spherical nanofiower-like structures were tailor-made by the self-assembly strategy. Specifically, organic polymer units（i.e., organic motifs） were formed by tetrachloro-p-benzoquinone（TBQ） and 2,6-diamino anthraquinone（DAQ） via a noble-metal-free catalyzed coupling reaction. Subsequently, the organic motifs assemble into spherical nanofiower-like superstructures induced by intermolecular hydrogen bonding and aromatic π-π stacking interactions. Welldesigned carbon superstructures can provide a stable backbone that effectively blocks structural stacking and collapse. Meanwhile, the hierarchical porous structures in 3D carbon superstructures provide continuous charge transport pathways to greatly shorten the ion diffusion distance, and as a result, the carbon superstructures-based zinc-ion hybrid capacitors（ZIHCs） provide a capacity of 245 m Ah/g at 0.5 A/g, a high energy density of 152 Wh/kg and an ultra-long life of 300,000 cycles at 20 A/g. The excellent electrochemical performance is also attributed to the corresponding charge storage mechanism, i.e., the alternate binding of Zn2+/CF3SO3-ions. Besides, the high-level N/O motifs improve the surface properties of the carbon superstructures and reduce the ion migration barriers for more efficient charge storage. This paper provides insights into the design of advanced carbon-based cathodes and presents a fundamental understanding of their charge storage mechanisms.

关键词： Carbon superstructures High serformance Overstable Tailor-made Zinc-ion storage

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In-situ forming ultra-mechanically sensitive materials for high-sensitivity stretchable fiber strain sensors

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National science Review 2024年第6期11卷 254-263页

作者： Rouhui Yu Changxian Wang Xiangheng Du Xiaowen Bai Yongzhong Tong Huifang Chen Xuemei Sun Jing Yang Naoji Matsuhisa Huisheng Peng Meifang Zhu Shaowu Pan State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and Engineering Donghua University MOE Key Lab of Disaster Forecast and Control in Engineering School of Mechanics and Construction Engineering Jinan University State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science and Institute of Fiber Materials and Devices Fudan University Department of Cardiology Shanghai Xuhui Central HospitalZhongshan-Xuhui Hospital Fudan University Research Center for Advanced Science and Technology and Institute of Industrial Science The University of Tokyo

Fiber electronics with flexible and weavable features can be easily integrated into textiles for wearable applications. However, due to small sizes and curved surfaces of fiber materials, it remains challenging to load robust active layers, thus hindering production of high-sensitivity fiber strain sensors. Herein, functional sensing materials are firmly anchored on the fiber surface in-situ through a hydrolytic condensation *** anchoring sensing layer with robust interfacial adhesion is ultra-mechanically sensitive, which significantly improves the sensitivity of strain sensors due to the easy generation of microcracks during stretching. The resulting stretchable fiber sensors simultaneously possess an ultra-low strain detection limit of 0.05%, a high stretchability of 100%, and a high gauge factor of 433.6, giving 254-folds enhancement in sensitivity. Additionally, these fiber sensors are soft and lightweight, enabling them to be attached onto skin or woven into clothes for recording physiological signals, e.g. pulse wave velocity has been effectively obtained by them. As a demonstration, a fiber sensor-based wearable smart healthcare system is designed to monitor and transmit health status for timely intervention. This work presents an effective strategy for developing high-performance fiber strain sensors as well as other stretchable electronic devices.

关键词： fiber strain sensor stretchable wearable healthcare

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Strategies of selective electroreduction of aqueous nitrate to N_(2) in chloride-free system:A critical review

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Green Energy & Environment 2024年第2期9卷 198-216页

作者： Fukuan Li Weizhe Zhang Peng Zhang Ao Gong Kexun Li College of Environmental Science and Engineering Nankai UniversityTianjin300350China MOE Key Laboratory of Pollution Processes and Environmental Criteria Tianjin Key Laboratory of Environmental Remediation and Pollution ControlTianjin Key Laboratory of Environmental Technology for Complex Trans-Media PollutionNankai UniversityTianjin300350China

Electroreduction of nitrate has been gaining wide attention in recent years owing to it's beneficial for converting nitrate into benign N_(2) from the perspective of electrocatalytic denitrification or into value-added ammonia from the perspective of electrocatalytic NH_(3) *** reason of the undesired formation of ammonia is dominant during electroreduction of nitrate-containing wastewater,chloride has been widely used to improve N_(2) ***,selective electroreduction of nitrate to N2 gas in chloride-containing system poses several *** this review,we focus on the key strategies for efficiently enhancing N_(2) selectivity of electroreduction of nitrate in chloride-free system,including optimal selection of elements,combining an active metal catalyst with another metal,manipulating the crystalline morphology and facet orientation,constructing core–shell structure catalysts,*** summarizing the strategies,four possible reaction pathways of electro-reduction of nitrate to N_(2) are ***,this review attempts to provide practical strategies for enhancing N2 selectivity without the aid of electrochlorination and highlight directions for future research for designing appropriate electrocatalyst for final electrocatalytic denitrifi-cation.

关键词： Nitrate Chloride Electroreduction Selectivity Nitrogen

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Construction of Pd-doped RuO_(2) nanosheets for efficient and stable acidic water oxidation

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Green Energy & Environment 2024年第6期9卷 937-948页

作者： Yibo Liu Xing Hu Chenxi Liu Shan Zhu Kezhu Jiang Feng Liu Shijian Zheng Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology College of Materials Science and EngineeringHebei University of TechnologyTianjin300401China Yunnan Precious Metals Lab Co. LTDKunming650100China

RuO_(2) has been considered a potential alternative to commercial IrO_(2) for the oxygen evolution reaction(OER)due to its superior intrinsic ***,its inherent structure dissolution in acidic environments restricts its commercial *** this study,we report a novel Pd-doped ruthenium oxide(Pd–RuO_(2))nanosheet catalyst that exhibits improved activity and stability through a synergistic effect of Pd modulation of Ru electronic structure and the two-dimensional *** catalyst exhibits excellent performance,achieving an overpotential of only 204 mVat a current density of 10 mA cm^(-2).Impressively,after undergoing 8000 cycles of cyclic voltammetry testing,the overpotential merely decreased by 5 *** PEM electrolyzer with Pd0.08Ru0.92O_(2) as an anode catalyst survived an almost 130 h operation at 200 mA cm^(-2).To elucidate the underlying mechanisms responsible for the enhanced stability,we conducted an X-ray photoelectron spectroscopy(XPS)analysis,which reveals that the electron transfer from Pd to Ru effectively circumvents the over-oxidation of Ru,thus playing a crucial role in enhancing the catalyst's ***,density functional theory(DFT)calculations provide compelling evidence that the introduction of Pd into RuO_(2) effectively modulates electron correlations and facilitates the electron transfer from Pd to Ru,thereby preventing the overoxidation of ***,the application of the two-dimensional structure effectively inhibited the aggregation and growth of nanoparticles,further bolstering the structural integrity of the catalyst.

关键词： Oxygen evolution reaction Pd-doped ruthenium oxide Two-dimensional structure Electron transfer Stability

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Impact Analysis of MTD on the Frequency Stability in Smart Grid

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IEEE/CAA Journal of Automatica Sinica 2023年第1期10卷 275-277页

作者： Zhenyong Zhang Ruilong Deng the State Key Laboratory of Public Big Data and the College of Computer Science and Technology Guizhou UniversityGuiyang 550025China IEEE the State Key Laboratory of Industrial Control Technology Zhejiang UniversityHangzhou 310027China

Dear Editor, In order to accommodate the effects of false data injection attacks(FDIAs), the moving target defense(MTD) strategy is recently proposed to enhance the security of the smart grid by perturbing branch susceptances. However, most pioneer work only focus on the defending performance of MTD in terms of detecting FDIAs and the impact of MTD on the static factors such as the power and economic losses.

关键词： Smart MTD Impact

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