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Reaction pathways and selectivity in the chemo-catalytic conversion of cellulose and its derivatives to ethylene glycol:A review

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Chinese Journal of Chemical engineering 2024年第2期66卷 310-331页

作者： Yao Li Yuchun Zhang Zhiyu Li Huiyan Zhang Peng Fu College of Agricultural Engineering and Food Science Shandong University of TechnologyZibo 255000China Key Laboratory of Energy Thermal Conversion and Control Ministry of EducationSchool of Energy and EnvironmentSoutheast UniversityNanjing 210096China

Biomass-to-ethylene glycol is an effective means to achieve high-value utilisation of cellulose but is hindered by low conversion efficiency and poor catalyst activity and *** and cellobiose are derivatives of cellulose conversion to ethylene glycol,and it is found that studying the reaction process of both can help to understand the reaction mechanism of *** is desirable to develop a reusable,highly active catalyst to convert cellulose into ethylene *** ideal catalyst might have one or more active sites described the conversion steps ***,we discuss the catalyst development of celluloseto-ethylene glycol,including tungsten,tin,lanthanide,and other transition metal catalysts,and special attention is given to the reaction mechanism and kinetics for preparing ethylene glycol from cellulose,and the economic advantages of biomass-to-ethylene glycol are briefly *** insights given in this review will facilitate further development of efficient catalysts,for addressing the global energy crisis and climate change related to the use of fossil fuels.

关键词： Ethylene glycol Cellulose Catalyst Retro-aldol condensation Hydrolysis Kinetics

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Fluorescence sensor based on IFE between AEP@UCNPs and oxTMB for the determination of Cd^(2+)in paddy rice combined with HRP enzyme inhibition mechanism

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Food science and Human Wellness 2025年第1期14卷 154-160页

作者： Haizhen Ding Shuai Hou Siqi Zhao Liping Guo Ao Sun Qiuhui Hu Leiqing Pan Qiang Liu Chao Ding Collaborative Innovation Center for Modern Grain Circulation and Safety Key Laboratory of Grains and Oils Quality Control and ProcessingCollege of Food Science and EngineeringNanjing University of Finance and EconomicsNanjing 210023China College of Food Science and Technology Nanjing Agricultural UniversityNanjing 210095China

Cadmium ion(Cd^(2+))detection technology plays a prominent role in food safety and human ***,we designed and constructed an 2-aminoethyl dihydrogen phosphate(AEP)@upconversion nanoparticles(UCNPs)fluorescence sensor for quantitative detection of Cd^(2+)in paddy rice based on inner filter effect(IFE)combined with enzyme inhibition *** AEP modification UCNPs can offer a stable fluorescence donor at 658 nm and be quenched by the oxidized tetramethylbenzidine(oxTMB)catalyzed by horseradish peroxidase(HRP)*** addition of Cd^(2+),the fluorescence of AEP@UCNPs fluorescence sensor was weaken due to the IFE between AEP@UCNPs and *** addition of Cd^(2+),HRP enzyme activity was inhibited by Cd^(2+),leading to the decreased oxTMB,resulting in the enhance upconversion fluorescence *** a result,the fluorescence intensity signal at 658 nm of the IFE-based AEP@UCNPs fluorescence sensor increased linearly with the increase in Cd^(2+)in a wide range from 0.5μmol/L to 6μmol/L and the limit of detection(LOD)was 24.6 n mol/*** addition,our proposed IFE-based AEP@UCNPs fluorescence sensor can achieve Cd^(2+)detection in paddy rice in 30 min.

关键词： Paddy rice Cd^(2+) Enzyme inhibition Upconversion nanoparticles(UCNPs) Inner filter effect(IFE)

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Photoelectrocatalytic hydrogen evolution and synchronous degradation of organic pollutants by pg-C_(3)N_(4)/β-FeOOH S-scheme heterojunction

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science China(Technological sciences) 2024年第4期67卷 1238-1252页

作者： LI XiBao HAN Tao ZHOU YingTang XIE Yu LUO YiDan HUANG JunTong CHEN Zhi DENG Fang School of Materials Science and Engineering Nanchang Hangkong UniversityNanchang 330063China National-Local Joint Engineering Research Center of Heavy Metal Pollutants Control and Resource Utilization Nanchang Hangkong UniversityNanchang 330063China Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control National Engineering Research Center for Marine AquacultureMarine Science and Technology CollegeZhejiang Ocean UniversityZhoushan 316022China

Crafting photoelectrocatalytic materials with robust oxidation-reduction properties for simultaneous hydrogen evolution and pollutant degradation poses a formidable *** this study,a pg-C_(3)N_(4)/β-FeOOH S-scheme heterostructure with a special energy band structure was developed by anchoring porous pg-C_(3)N_(4)on needle shapedβ-*** as a hole extraction layer,needle-leaf-likeβ-FeOOH can facilitate efficient hole migration and enhance charge ***,the optimized 0.2-pg-C_(3)N_(4)/β-FeOOH could degrade 78%of ofloxacin(OFLO)in 90 *** organic pollutants could absorb a large number of holes,which prompted a greater proportion of photogenerated electrons to actively participate in the hydrogen evolution reaction at the ***,the hydrogen production of 0.2-pg-C_(3)N_(4)/β-FeOOH reached 1452.88μmol cm^(-2)h^(-1),exhibiting a notable increase of 61.81-165.12μmol cm^(-2)h^(-1)compared with that in the absence of *** and theoretical calculation results underscore that this investigation is grounded in a distinctive electron and hole dual channel transfer *** findings offer novel insights for the future development of S-scheme heterojunction photoelectrocatalytic materials capable of concurrently degrading pollutants and promoting hydrogen evolution.

关键词： photoelectrocatalysis hydrogen evolution degradation synchronous S-scheme heterojunction

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Unintentional emissions of polychlorinated naphthalenes in China:Sources,composition,and historical trends

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Journal of Environmental sciences 2025年第2期148卷 221-229页

作者： Ye Huang Lin Huang Ying Li Nazupar Sidikjan Yunshan Zhang Yan Chen Yangmin Chen Ye Li Wei Du Long Chen YanWu Shanshan Zhang Jing Yang Wenjun Meng Guofeng Shen Min Liu Shu Tao Key Laboratory of Geographic Information Science of the Ministry of Education School of Geographic SciencesEast China Normal UniversityShanghai 200241China Yunnan Provincial Key Laboratory of Soil Carbon Sequestration and Pollution Control Faculty of Environmental Science&EngineeringKunming University of Science&TechnologyKunming 650500China Laboratory of Earth Surface Processes College of Urban and Environmental SciencePeking UniversityBeijing 100871China

Polychlorinated naphthalenes(PCNs)are detrimental to human health and the *** the commercial production of PCNs banned,unintentional releases have emerged as a significant environmental ***,relevant information is still *** this study,provincial emissions for eight PCNs homologues from 37 sources in the Chinese mainland during the period of 1960-2019 were estimated based on a source-specific and time-varying emission factor *** results showed that the total PCNs emissions in 2019 reached 757.0 kg with Hebei ranked at the top among all the provinces and iron&steel industry as the biggest ***-chlorinated PCNs comprised 90%of emissions by mass,while highly chlorinated PCNs dominated in terms of toxicity,highlighting divergent priorities for mitigating emissions and safeguarding human *** emissions showed an overall upward trend from 1960 to 2019 driven by emission increase from iron&steel industry in terms of source,and from North China and East China in terms of geographic ***-capita emissions followed an inverted U-shaped environmental Kuznets curvewhile emission intensities decreased with increasing per-capita Gross Domestic Product(GDP)following a nearly linear pattern when log-transformed.

关键词： PCNs Emission inventory Emission factor Composition profile Emission intensity Chinese mainland

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Topography Modeling of Surface Grinding Based on Random Abrasives and Performance Evaluation

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Chinese Journal of Mechanical engineering 2024年第5期37卷 126-148页

作者： Yanbin Zhang Peng Gong Lizhi Tang Xin Cui Dongzhou Jia Teng Gao Yusuf Suleiman Dambatta Changhe Li Key Lab of Industrial Fluid Energy Conservation and Pollution Control Qingdao University of TechnologyMinistry of EducationQingdao 266520China School of Materials Science and Engineering Xi’an University of TechnologyXi’an 710048China College of Mechanical Engineering and Automation Liaoning University of TechnologyJinzhou 121001China Mechanical Engineering Department Ahmadu Bello UniversityZaria 810106Nigeria

The surface morphology and roughness of a workpiece are crucial parameters in grinding *** prediction of these parameters is essential for maintaining the workpiece’s surface ***,the randomness of abrasive grain shapes and workpiece surface formation behaviors poses significant challenges,and accuracy in current physical mechanism-based predictive models is *** address this problem,by using the random plane method and accounting for the random morphology and distribution of abrasive grains,this paper proposes a novel method to model CBN grinding wheels and predict workpiece surface ***,a kinematic model of a single abrasive grain is developed to accurately capture the three-dimensional morphology of the grinding ***,by formulating an elastic deformation and formation model of the workpiece surface based on Hertz theory,the variation in grinding arc length at different grinding depths is ***,a predictive model for the surface morphology of the workpiece ground by a single abrasive grain is *** model integrates the normal distribution model of abrasive grain size and the spatial distribution model of abrasive grain positions,to elucidate how the circumferential and axial distribution of abrasive grains influences workpiece surface ***,by integrating the dynamic effective abrasive grain model,a predictive model for the surface morphology and roughness of the grinding wheel is *** examine the impact of changing the grit size of the grinding wheel and grinding depth on workpiece surface roughness,and to validate the accuracy of the model,experiments are *** indicate that the predicted three-dimensional morphology of the grinding wheel and workpiece surfaces closely matches the actual grinding wheel and ground workpiece surfaces,with surface roughness prediction deviations as small as 2.3%.

关键词： Surface topography prediction Grinding Grinding wheel model Random plane method

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Co-pyrolysis of oil sludge with hydrogen-rich plastics in a vertical stirring reactor:Kinetic analysis,emissions,and products

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Frontiers of Environmental science & engineering 2022年第10期16卷 131-143页

作者： Lujun Zhao Jiaming Shao Li Xiang Yiping Feng Zhihua Wang Fawei Lin State Key Laboratory of Industrial Control Technology College of Control Science and EngineeringZhejiang UniversityHangzhou 310027China State Key Laboratory of Clean Energy Utilization Zhejiang UniversityHangzhou 310027China Zhejiang SUPCON Technology Co. Ltd.Hangzhou 310053China School of Environmental Science and Engineering Tianjin University/Tianjin Key Laboratory ofBBiomass/Wastes UtilizationTianjin 300072China

Pyrolysis is an effective method to treat oily sludge(OS)due to its balance between oil recovery and nonhazardous ***,tank bottom OS contains a high content of heavy fractions,which creates obstacles for pyrolysis due to the high activation *** incomplete cracking of macromolecules and secondary polymerization decreases the oil quality and causes coking during the operation *** study introduced polyethylene(PE)into OS to deploy the H/Ceff ratio of feedstocks for pyrolysis A strong interaction between OS and PE during copyrolysis could be observed from the TG/DTG *** tightly participated in OS degradation,while OS also promoted PE degradation at high *** pits were generated in solid residues from copyrolysis,which was attributed to the uniform and violent gas *** addition to HCN,other nitrogenous and sulphurous pollutants were ***,more gas products were attained after PE addition with more value-added compositions of alkanes and *** the oil yield decreased after PE addition,the oil products from copyrolysis possessed higher heating values and higher contents of light fractions with short chains as well as ***,copyrolysis of OS and PE significantly improved the pyrolysis process and resulted in high oil quality.

关键词： Oily sludge Pyrolysis Polyethylene H/Ceff ratio Oil quality

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Diminishing ether-oxygen content of electrolytes enables temperature-immune lithium metal batteries

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science China Chemistry 2023年第9期66卷 2700-2710页

作者： Tao Liu Jingnan Feng Zhe Shi Huajun Li Weina Zhao Minglei Mao Xiangzhen Zhu Yong-Sheng Hu Hong Li Xuejie Huang Liquan Chen Liumin Suo Beijing National Laboratory for Condensed Matter Physics Institute of PhysicsChinese Academy of SciencesBeijing 100190China Qingdao Industrial Energy Storage Research Institute Qingdao Institute of Bioenergy and Bioprocess TechnologyChinese Academy of SciencesQingdao 266101China Department of Nuclear Science and Engineering and Department of Materials Science and Engineering Massachusetts Institute of TechnologyCambridgeMA 02139USA Guangzhou Key Laboratory of Environmental Catalysis and Pollution Control Guangdong Key Laboratory of Environmental Catalysis and Health Risk ControlSchool of Environmental Science and EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China

The reversibility of lithium(Li) metal anodes is highly susceptible to temperature,owing to the aggravated side reactions at high temperatures and serious Li dendrite growth at low *** it is extremely challenging to simultaneously realize the high Li reversibility in both low and high temperature ***,an oxygen-free solvent(n-hexane,HEX) assisted with the hexyl methyl ether and 1 mol L^(-1)lithium bis(fluorosulfonyl)imide is proposed to constitute an electrolyte for temperatureimmune lithium metal *** demonstrates that the HEX not only greatly suppresses the solvent reduction even at high temperatures but also weaken the Li~+-solvent interaction for the facile Li-ion desolvation,leading to high Li Coulombic efficiencies(99.59% at 25℃,99.30%at 60℃ and 98.75% at -30℃) and the dendrite-free Li plating from -30℃ to 60℃.Benefitting from the low density and temperature-immune properties of our electrolyte,the sulfurized polyacrylonitrile(3.8mAh cm^(-2))||Li(60 μm) pouch-cells deliver 278 Wh kg^(-1)energy density and maintain the stable performance over 50 cycles,and retain 248 and 320 Wh kg^(-1) energy density at -30℃ and 60℃,*** work provides a new perspective on the electrolyte design for wide-temperature Li metal batteries.

关键词： wide temperature range oxygen-free solvent dendrite-free Li plating high Coulombic efficiencies lithium metal batteries

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GO/MgO/Mg interface mediated strengthening and electromagnetic interference shielding in AZ31 composite

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Journal of Magnesium and Alloys 2023年第10期11卷 3800-3814页

作者： Z.Y.Xu C.F.Fang C.J.Li R.Wang X.P.Zhang J.Tan Y.M.Wang Key Laboratory of Solidification Control and Digital Preparation Technology(Liaoning Province) School of Materials Science and EngineeringDalian University of TechnologyDalian 116024China Faculty of Materials Science and Engineering Kunming University of Science and TechnologyKunming 650093China College of Materials Science and Engineering Chongqing UniversityChongqing 400045China Key Laboratory of Materials Modification by Laser Ion and Electron Beams(Ministry of Education)School of Materials Science and EngineeringDalian University of TechnologyDalian 116023China

More requirements of electromagnetic interference(EMI) shielding performance are put forward for lightweight structural materials due to the development of aerospace and 5G communications. Herein, graphene oxide(GO) decorated with SnO_(2) coating is introduced as reinforcement into AZ31 Mg alloy. During the smelting process, the MgO layer is in situ gernerated at interface between GO and the molten Mg alloy matrix by consuming SnO_(2). In the solid state, such kind of interface structure can improve the GO-Mg interface bonding intensity,also significantly generate stacking faults. The AZ31 composite reinfoced by trace modified GO(0.1 wt%) exhibits high ultimate strength and almost the same elongation with AZ31 alloy. Compared with AZ31 alloy, the yield strength and ultimate tensile strength of composite are increased by 33.5% and 23.7%, respectively. Meanwhile, the multi-level electromagnetic reflection from the multi-layer structure of GO and the interface polarization caused by the MgO mid-layer can significantly improve EMI shielding performance. The appropriate interface design strategy achieves the effect of “two birds with one stone”.

关键词： Metal-matrix composites Mechanical properties EMI shielding Microstructures

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Adaptive dynamic surface control for quadrotor-slung load transportation system with uncertainties

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science China(Technological sciences) 2023年第10期66卷 2917-2929页

作者： DING Feng HUANG Jian SUN Chong AI Yong XU WenXia YANG ChenGuang School of Computer Science South-Central Minzu UniversityWuhan 430074China Key Laboratory of Ministryof EducationforImage Processing and Intelligent ControlHubei Key Laboratoryof Brain-inspired Intelligent Systems School of Artificial Intelligence and Automation Huazhong University of Science and TechnologyWuhan 430074China School of Computer Science and Engineering Wuhan Institute of TechnologyWuhan 430205China Key Laboratory of Ministry of Education for Autonomous Systems and Networked Control Guangdong Engineering Technology Research Center of Control of Intelligent SystemsCollege of Automation Science and EngineeringSouth China University of TechnologyGuangzhou 510640China

Quadrotors play a significant role in our lives and are transforming our *** cable-suspended loads is an unavoidable quadrotor application trend and a hot research topic in the control ***,the load swing and unpredictability pose significant challenges to the quadrotor's *** this paper,an anti-swing controller with an inner-outer control strategy for the quadrotor-slung load transportation system is *** facilitate the controller design,the outer position dynamics are restructured in the form of ***,a virtual controller is created to force the underactuated states to the dynamic surface to ensure the position subsystem's *** improve robustness,an adaptive law is used to eliminate the effects of uncertain cable ***,a dynamic surface controller for the inner attitude subsystem is presented to drive the actual force to the virtual *** is demonstrated that the control strategy can stabilize the quadrotor despite mass and cable length *** results are provided to demonstrate the efficacy and durability of the proposed method.

关键词： quadrotor-slung load transportation system dynamic surface control adaptive law cascade system model uncertainties

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Covalency triggers high catalytic activity of amorphous molybdenum oxides for oxidative desulfurization

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science China Chemistry 2023年第4期66卷 1211-1220页

作者： Juncong Zou Yan Lin Chunping Yang College of Environmental Science and Engineering Hunan University and Key Laboratory of Environmental Biology and Pollution Control(Hunan University)Ministry of EducationHunan UniversityChangsha 410082China Guangdong Provincial Key Laboratory of Petrochemcial Pollution Processes and Control and School of Environmental Science and EngineeringGuangdong University of Petrochemical TechnologyNaoming 525000China School of Environmental and Chemical Engineering Nanchang Hangkong UniversityNanchang 330063China

Oxidative desulfurization(ODS)is a promising technology to produce clean fuel with requiring superior catalysts to lower kinetic *** most ODS catalysts are based on crystalline transition-metal oxides(TMOs),extraordinary activity also can be achieved with amorphous ***,the origin of the remarkable catalytic activity of the amorphous TMOs remains greatly ***,we found the crucial role of Mo–O covalency in ruling the intrinsic catalytic activity of amorphous molybdenum oxides(MoO_(x)).Experimental and theoretical analysis indicated that the nonequivalent connectivity in the amorphous structure strongly enhanced Mo–O covalency,thereby increasing the content of electrophilic oxygen and nucleophilic molybdenum to favor the MoO_(x)–H_(2)O_(2) *** the boosted Mo–O covalency to improve the flexibility of the charge state,the amorphous MoO_(x)-based composite catalyst(PE-MoO_(x)/S-0.05)exhibited outstanding catalytic activity for ODS of fuel *** turnover frequency(TOF)value of the catalyst(18.63 h^(-1))was almost an order of magnitude higher than that of most reported crystalline MoO_(x)/molecular sieve composite *** in-depth understanding of the origin of the amorphous TMOs activity for ODS provides a valuable reference for developing ODS catalysts.

关键词： amorphous molybdenum oxide oxidative desulfurization covalency

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