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Stabilized Hf-doped Ti/Sb-SnO2 electrode for efficient degradation of tetracycline

environmental Science and Pollution Research 2024年第35期31卷 47960-47973页

作者： Li, Danni Guo, Xin Shao, Xiang Zhou, Anhui Zhu, Lin Zhang, Yuting Li, Binbin Du, Yan Cao, Limei Yang, Ji State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control On Chemical Processes School of Resources and Environmental Engineering East China University of Science and Technology 130 Meilong Road Shanghai200237 China Shanghai Institute of Pollution Control and Ecological Security Shanghai200092 China

The electrochemical advanced oxidation process (EAOP) has shown significant promise in the field of refractory organic wastewater treatment due to its high efficiency and environmentally friendly nature. In this study, Ti/Sb-SnO2 electrodes with varying proportions of Hf were prepared using the sol–gel method. The addition of Hf transformed the original collapsing and broken surface into a flat and regular surface. The results demonstrated that Ti/Sb-SnO2-Hf electrode doped with 6% Hf exhibited a higher oxygen evolution potential (OEP) and excellent stability. The OEP increased from 2.315 V without Hf-doping to 2.482 V, and the corresponding actual life was 321.05% higher than that without Hf. The current density (5–40 mA·cm−2), electrolyte concentration (0.02–0.2 mol·L−1), pH (3–11), and initial pollutant concentration (5–80 mg·L−1) were evaluated to confirm the tetracycline (TC) degradation characterization of Ti/Sb-SnO2-6%Hf electrodes. It was concluded that under the optimal degradation conditions, the removal rate of TC could reach 99.66% within 2 h. The degradation of TC follows first-order reaction kinetics. The oxidative degradation of TC was achieved through indirect oxidation, with ·OH playing a dominant role. TC’s electrochemical oxidation degradation pathway has been proposed: Based on LC–MS results, three main pathways are speculated. During the electrocatalytic oxidation process, decarboxylation, deamidation, and ring-opening reactions occur under ·OH attack, producing intermediate compounds with m/z values of 427, 433, 350, 246, 461, 424, 330, 352, 309, 263, and 233. These intermediates are further oxidized to intermediate compounds with an m/z value of 218. This work introduces a new efficient anode electrochemical catalyst for the degradation of TC, providing a strategy for industrial applications. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

关键词： Electrolytes

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Impact of climate change shocks on health risks attributed to urban residential PM2.5 in China

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Science Bulletin 2025年第8期70卷 1230-1234页

作者： Hui Dai John S.Ji Shuxiao Wang Bin Zhao Department of Building Science School of ArchitectureTsinghua UniversityBeijing 100084China Beijing Key Laboratory of Indoor Air Quality Evaluation and Control Tsinghua UniversityBeijing 100084China Vanke School of Public Health Tsinghua UniversityBeijing 100084China State Key Joint Laboratory of Environmental Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing 100084China State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex School of EnvironmentTsinghua UniversityBeijing 100084China

With the rapid global urbanization and increasing climate risks in urban environments,urban planning has emerged as a pivotal component of climate policy[1,2].Urban areas are significant contributors to greenhouse gas emissions and highly vulnerable to climate change *** planning crucially contributes to changing the behavior and dynamics of exposure to both indoor and outdoor air *** the 28th United Nations Climate Change Conference(COP28),a declaration on health was adopted globally.

关键词： greenhouse gas emissions declaration health PM health risks climate policy urban changing behavior dynamics urban planning climate change

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Electro-oxidation of ammonia nitrogen using W, Ti-doped IrO2 DSA as a treatment method for mariculture and livestock wastewater

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environmental Science and Pollution Research 2024年第31期31卷 44385-44400页

作者： Zhang, Yiheng Li, Binbin Zhang, Wenjing Guo, Xin Zhu, Lin Cao, Limei Yang, Ji State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control On Chemical Processes School of Resources and Environmental Engineering East China University of Science and Technology 130 Meilong Road Shanghai200237 China Shanghai Institute of Pollution Control and Ecological Security Shanghai200092 China

Animal farming wastewater is one of the most important sources of ammonia nitrogen (NH4+-N) emissions. Electro-oxidation can be a viable solution for removing NH4+-N in wastewater. Compared with other treatment methods, electro-oxidation has the advantages of i) high removal efficiency, ii) smaller size of treatment facilities, and iii) complete removal of contaminant. In this study, a previously prepared DSA (W, Ti-doped IrO2) was used for electro-oxidation of synthetic mariculture and livestock wastewater. The DSA was tested for chlorine evolution reaction (CER) activity, and the reaction kinetics was investigated. CER current efficiency reaches 60–80% in mariculture wastewater and less than 20% in livestock wastewater. In the absence of NH4+-N, the generation of active chlorine follows zero-order kinetics and its consumption follows first-order kinetics, with cathodic reduction being its main consumption pathway, rather than escape or conversion to ClO3−. Cyclic voltammetry experiments show that NH4+-N in the form of NH3 can be oxidized directly on the anode surface. In addition, the generated active chlorine combines with NH4+-N at a fast rate near the anode, rather than in the bulk solution. In electrolysis experiments, the NH4+-N removal rate in synthetic mariculture wastewater (30–40 mg/L NH4+-N) and livestock wastewater (~ 450 mg/L NH4+-N) is 112.9 g NH4+-N/(m2·d) and 186.5 g NH4+-N/(m2·d), respectively, which is much more efficient than biological treatment. The specific energy consumption (SEC) in synthetic mariculture wastewater is 31.5 kWh/kg NH4+-N, comparable to other modified electro-catalysts reported in the literature. However, in synthetic livestock wastewater, the SEC is as high as 260 kWh/kg NH4+-N, mainly due to the suppression of active chlorine generation by HCO3− and the generation of NO3− as a by-product. Therefore, we conclude that electro-oxidation is suitable for mariculture wastewater treatment, but is not recommended for livestock waste

关键词： Cyclic voltammetry

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Altitude-dependent gaseous emissions from freight trucks along the China-Pakistan Economic Corridor in Pakistan

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environmental Science and Ecotechnology 2023年第2期14卷 72-78页

作者： Asad Ali Shaikh Tingkun He Fanyuan Deng Zhenyu Luo Junchao Zhao Zhining Zhang Huan Liu State Key Joint Laboratory of ESPC State Environmental Protection Key Laboratory of Sources and Control of Air Pollution ComplexSchool of EnvironmentTsinghua UniversityBeijing100084China

Recent increases in emissions from freight transport have caused strong concerns about air quality in Pakistan,following the rapid development of projects related to the China-Pakistan Economic Corridor(CPEC).This study reported the first measurements of on-road truck emissions in Pakistan and investigated their dependence on altitude along CPEC *** from 70 trucks were measured on CPEC highways located in Islamabad(540 m above sea level),Sost(2800 m above sea level),and at the Khunjerab Pass(4693 m above sea level).Calculated emission factors for carbon monoxide,hydrocarbons,and nitrogen oxides from heavy-duty trucks in Islamabad were 12.94±1.46,15.21±1.67,and 10.69±1.34 g km^(-1)(95%confidence level),respectively,for pre-Pak-II trucks,and 12.75±2.80,14.24±3.53,and 10.24±2.34 g km^(-1)(95%confidence level),respectively,for Pak-II trucks,representing 2e20 times higher values than the emission standards in Pakistan and *** altitude increase of approximately 4000 m,with the associated changes in meteorology and fleet characteristics,induced an average increase of 103.6%,86.3%,124.5%,and 133.6%in the emission factors of carbon monoxide,hydrocarbons,nitrogen oxides,and carbon dioxide,***,on-road emissions along the CPEC were mainly influenced by truck *** study will support the budget evaluation of transport emissions from the CPEC trade fleet.

关键词： Truck emissions High altitude China-Pakistan Economic corridor Emission factors

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Deciphering decadal urban ozone trends from historical records since 1980

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National Science Review 2024年第11期11卷 117-129页

作者： Haolin Wang Xiao Lu Paul I.Palmer Lin Zhang Keding Lu Ke Li Tatsuya Nagashima Ja-Ho Koo Hiroshi Tanimoto Haichao Wang Meng Gao Cheng He Kai Wu Shaojia Fan Yuanhang Zhang School of Atmospheric Sciences Sun Yat-sen University and Key Laboratory of Tropical Atmosphere-Ocean System Ministry of Education Guangdong Provincial Observation and Research Station for Climate Environment and Air Quality Change in the Pearl River Estuary Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai) School of Geo Sciences University of Edinburgh National Centre for Earth Observation University of Edinburgh Laboratory for Climate and Ocean-Atmosphere Studies Department of Atmospheric and Oceanic SciencesSchool of PhysicsPeking University State Key Joint Laboratory of Environmental Simulation and Pollution Control The State Environmental Protection Key Laboratory of Atmospheric Ozone Pollution ControlCollege of Environmental Sciences and Engineering Peking University Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Collaborative Innovation Center of Atmospheric Environment and Equipment Technology School of Environmental Science and Engineering Nanjing University of Information Science &Technology National Institute for Environmental Studies Department of Atmospheric Sciences Yonsei University Department of Geography Hong Kong Baptist University Department of Civil and Environmental Engineering University of California

Ozone pollution is a major environmental threat to human health. Timely assessment of ozone trends is crucial for informing environmental policy. Here we show that for the most recent decade（2013–2022） in the northern hemisphere, warm-season（April–September） mean daily 8-h average maximum ozone increases much faster in urban regions with top ozone levels(mainly in the North China Plain, 1.2 ± 1.3 ppbv year-1) than in other, low-ozone regions(0.2 ± 0.9 ppbv year-1). These trends widen the ozone differences across urban regions, and increase extreme pollution levels and health threats from a global perspective. Comparison of historical trends in different urban regions reveals that ozone increases in China during 2013–2022 differ in magnitude and mechanisms to historical periods in other regions since *** reflects a unique chemical environment characterized by exceptionally high nitrogen oxides and aerosol concentrations, where reducing ozone precursor emissions leads to substantial ozone *** increase in China has slowed down in 2018–2022 compared to 2013–2017, driven by ongoing emission reductions, but with ozone-favorable weather conditions. Historical ozone evolution in Japan and South Korea indicates that ozone increases should be suppressed with continuous emission *** temperature and associated wildfires have also reversed ozone decreases in the USA and Europe,with anthropogenic ozone control slowing down in recent decades.

关键词： air quality surface ozone trends

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Enhanced degradation and methane production of food waste anaerobic digestate using an integrated system of anaerobic digestion and microbial electrolysis cells for long-term operation

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environmental Science and Pollution Research 2024年第27期31卷 39637-39649页

作者： Zhu, Yusen Guo, Meixin Qi, Xuejiao Li, Mingxiao Guo, Meng Jia, Xuan State Environmental Protection Key Laboratory of Food Chain Pollution Control Beijing Technology and Business University Beijing100048 China State Key Laboratory of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental Sciences Beijing100012 China Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences Qingdao266101 China

The integrated system of anaerobic digestion and microbial electrolysis cells (AD-MEC) was a novel approach to enhance the degradation of food waste anaerobic digestate and recover methane. Through long-term operation, the start-up method, organic loading, and methane production mechanism of the digestate have been investigated. At an organic loading rate of 4000 mg/L, AD-MEC increased methane production by 3–4 times and soluble chemical oxygen demand (SCOD) removal by 20.3% compared with anaerobic digestion (AD). The abundance of bacteria Fastidiosipila and Geobacter, which participated in the acid degradation and direct electron transfer in the AD-MEC, increased dramatically compared to that in the AD. The dominant methanogenic archaea in the AD-MEC and AD were Methanobacterium (44.4–56.3%) and Methanocalculus (70.05%), respectively. Geobacter and Methanobacterium were dominant in the AD-MEC by direct electron transfer of organic matter into synthetic methane intermediates. AD-MEC showed a perfect SCOD removal efficiency of the digestate, while methane as clean energy was obtained. Therefore, AD-MEC was a promising technology for deep energy transformation from digestate. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

关键词： Anaerobic digestion

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Heterogeneous reaction of NO_(2) with feldspar, three clay minerals and Arizona Test Dust

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Journal of environmental Sciences 2023年第8期130卷 65-74页

作者： Mingjin Tang Xiaohong Jia Lanxiadi Chen Wenjun Gu Chengpeng Huang FuWang Lan Luo Hongli Wang Xinming Wang Chao Peng State Key Laboratory of Organic Geochemistry Guangdong Key Laboratory of Environmental Protection and Resources Utilizationand Guangdong-Hong Kong-Macao Joint Laboratory for Environmental Pollution and ControlGuangzhou Institute of GeochemistryChinese Academy of SciencesGuangzhou 510640China CAS Center for Excellence in Deep Earth Science Guangzhou 510640China University of Chinese Academy of Sciences Beijing 100049China Longhua Center for Disease Control and Prevention of Shenzhen Shenzhen 518109China State Environmental Protection Key Laboratory of Formation and Prevention of Urban Air Pollution Complex Shanghai Academy of Environmental SciencesShanghai 200233China

Heterogeneous reaction of NO_(2) with mineral dust aerosol may play important roles in troposphere chemistry,and has been investigated by a number of laboratory ***,the influence of mineralogy on this reaction has not been well understood,and its impact on aerosol hygroscopicity is not yet *** work investigated heterogeneous reactions of NO_(2)(∼10 ppmv)with K-feldspar,illite,kaolinite,montmorillonite and Arizona Test Dust(ATD)at room temperature as a function of relative humidity(<1%to 80%)and reaction time(up to 24 hr).Heterogeneous reactivity towards NO_(2) was low for illite,kaolinite,montmorillonite and ATD,and uptake coefficients of NO_(2),γ(NO_(2)),were determined to be around or smaller than 1×10^(−8);K-feldspar exhibited higher reactivity towards NO_(2),and CaCO_(3) is most reactive among the nine mineral dust samples considered in this and previous *** heterogeneous reaction with NO_(2) for 24 hr,increase in hygroscopicity was nearly insignificant for illite,kaolinite and montmorillonite,and small but significant for K-feldspar;in addition,large increase in hygroscopicity was observed for ATD,although the increase in hygroscopicity was still smaller than CaCO_(3).

关键词： Mineral dust Heterogeneous reaction Hygroscopicity Mineralogy Nitrogen oxides Nitrate

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Ni-Cu bimetallic alloy anchored on nitrogen-doped carbon nanotubes for CO_(2)-to-CH_(4) electrochemical conversion

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Nano Research 2024年第8期17卷 6922-6930页

作者： Jing Li Chuanyong Jing Jin Wang School of Environment Beijing Key Laboratory of Aqueous Typical Pollutants Control and Water Quality SafeguardBeijing Jiaotong UniversityBeijing 100044China State Key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Tangshan Research Institute Beijing Jiaotong UniversityTangshan 063000China

Electrocatalytic CO_(2) reduction to CH_(4) remains challenging due to multi-electron transfer and intermediates ***,we synthesized electrocatalysts by growing Ni-Cu alloy structure on nitrogen-doped carbon nanotubes(NixCuy-NCNT)for electrocatalytic CO_(2) reduction reaction(CO_(2)RR)via hydrothermal method followed by *** optimized Ni_(1)Cu_(1)-NCNT demonstrated a superior CO_(2)RR performance,achieving 99.7%FECH_(4)(FE=Faradaic efficiency)and 11.54 mA·cm^(−2) current density at−1.2 V *** hydrogen electrode(RHE),which outperformed single metal *** outstanding performance was due to the electrons transferred from Cu to Ni and Ni-Cu alloy shifted the d-band center toward the Fermi level,which was more conducive to the intermediate *** situ electrochemical attenuated total reflection(EC-ATR)and density functional theory(DFT)calculations revealed the appearance of *CHO intermediate and the pathway during the CO_(2)RR *** design of the bimetallic electrocatalyst in this study provides a new perspective for the highly selective reduction of CO_(2).

关键词： electrocatalytic CO_(2) reduction Ni-Cu alloy nitrogen-doped carbon nanotube(NCNT) electrochemical attenuated total reflection(EC-ATR) density functional theory(DFT)calculations

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Degradation of chloroxylenol by CoS_x activated peroxomonosulfate:Role of cobalt-sulfur ratio

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Chinese Chemical Letters 2025年第4期36卷 379-383页

作者： Jiayi Guo Liangxiong Ling Qinwei Lu Yi Zhou Xubiao Luo Yanbo Zhou State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process East China University of Science and TechnologyShanghai 200237China School of Life Sciences Key Laboratory of Jiangxi Province for Functional Biology and Pollution Control in Red Soil RegionsJinggangshan UniversityJi'an 343009China State Key Laboratory of Coal Liquification Gasification and Utilization with High Efficiency and Low Carbon TechnologyShanghai 200237China

Cobalt sulfide has received widespread attention in the advanced oxidation treatment of wastewater,and its catalytic activity is infiuenced by crystal structure and exposed active *** work successfully constructed three types of cobalt sulfides,namely Co_(9)S_(8),Co_(3)S_(4)and CoS_(2),by changing the molar ratio of cobalt to *** results showed that the degradation efficiency of Co_(9)S_(8),Co_(3)S_(4)and CoS_(2) on chloroxylenol by activated peroxomonosulfate(PMS)were 100%,88.70%and 67.73%,*** with density functional theory(DFT),the structural properties and reaction energy barriers of different cobaltsulfur ratios were *** the ratio of cobalt to sulfur increases,the sulfur vacancies realized a fuller exposure of active sites(Co_(surf.)^(2+))on the surface of the catalysts,with a highly linear relationship with the reaction rate constant(R^(2)=0.945).This work explores the structure-activity relationship between cobalt sulfur ratio and degradation efficiency,which can guide new catalyst synthesis.

关键词： Peroxymonosulfate Fenton-like reaction Cobalt sulfides Chloroxylenol degradation Morphology control

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Screening of indicator pharmaceuticals and personal care products in landfill leachates: a case study in Shanghai, China

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Frontiers of environmental Science & Engineering 2023年第9期17卷 245-256页

作者： Xiping Kan Xia Yu Wentao Zhao Shuguang Lyu Shuying Sun Gang Yu Qian Sui State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process School of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai 200237China State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Advanced Interdisciplinary Institute of Environment and Ecology Beijing Normal University at ZhuhaiZhuhai 519087China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China

Identifying potential sources of pharmaceuticals and personal care products(PPCPs)in the environment is critical for the effective control of PPCP *** leachate is an important source of PPCPs in water;however,it has barely been involved in source apportionment due to the lack of indicator-PPCPs(i-PPCPs)in landfill *** study provides the first systematic framework for identifying i-PPCPs for landfill leachates based on the wide-scope target monitoring of *** number of target PPCPs increased from<20 in previous studies to 68 in the present ***-nine PPCPs were detected,with median concentrations in leachate samples ranging from below the method quantification limit(MQL)to 41μg/L,and 19 of them were rarely reported previously.A total of 29 target compounds were determined to be PPCPs of high concern by principal component analysis according to multiple criteria,including occurrence,exposure potential,and ecological *** with source-specificity and representativeness analysis,erythromycin,gemfibrozil,and albendazole showed a significant difference in their occurrence in leachate compared to other potential sources(untreated and treated municipal wastewater and livestock wastewater)and correlated with total PPCP concentrations;these were recommended as i-PPCPs for *** screening procedure can be used to develop a sophisticated source apportionment method to identify sources of PPCPs from adjacent landfills.

关键词： Landfill leachates PPCPs Indicator Screening criteria Source-specificity

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