Y2O3, Er2O3 and Nd2O3 doped polycrystalline silicon nitride ceramics were prepared by hot press sintering method at 1850°C and 30 MPa pressure. 1 wt.% of each rare earth oxides (REO) were sintered with 3 wt.% MgO...
Y2O3, Er2O3 and Nd2O3 doped polycrystalline silicon nitride ceramics were prepared by hot press sintering method at 1850°C and 30 MPa pressure. 1 wt.% of each rare earth oxides (REO) were sintered with 3 wt.% MgO, 9 wt.% AlN and 87 wt.% α-*** optical, mechanical and tribological properties of REO doped polycrystalline silicon nitride ceramics were investigated. Optical transmittance was measured in visible and near infrared region and found to be 54% transmittance for Y2O3 doped Si3N4 ceramics. β- phase transformation was suppressed with REO addition. High hardness and high fracture toughness were achieved by addition of REO. Adding REO shows good mechanical properties as high strength and toughness. Coefficient of friction of the REO doped silicon nitride ceramics was lower than that of without REO doped silicon nitride ceramics.
Optical transparency was achieved at infrared region and overall translucent silicon nitride was fabricated using hot press sintering (HPS). The increase in h-BN content decreased the optical transparency. Microstruct...
Optical transparency was achieved at infrared region and overall translucent silicon nitride was fabricated using hot press sintering (HPS). The increase in h-BN content decreased the optical transparency. Microstructral observations shows that the optical, mechanical and tribological properties of BN dispersed polycrystalline Si3N4 ceramics were affected by the density, α:β-phase ratio and content of h-BN in sintered ceramics. The hot pressed samples were prepared from the mixture of α-Si3N4, AlN, MgO and h-BN at 1850°C. The composite contained from 0.25 to 2 mass % BN powder with sintering aids (9% AlN + 3% MgO). Maximum transmittance of 57% was achieved for 0.25 mass % BN doped Si3N4 ceramics. Fracture toughness was increased and wear volume and friction coefficient were decreased with increase in BN content.
A compact and uniform (Ti, Si, O, N)/Ti composite coating was fabricated on the surface of a NiTi shape memory alloy (SMA) (containing 50.8 at.% Ni) using plasma immersion ion implantation and deposition (PIIID) with ...
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A novel method based on radio frequency magnetron sputtering tailored to the deposition of low residual stress and adherent c-BN thin films on silicon substrates was developed. In this study, the effect of noble gas (...
A novel method based on radio frequency magnetron sputtering tailored to the deposition of low residual stress and adherent c-BN thin films on silicon substrates was developed. In this study, the effect of noble gas (Kr, Ar, Ne and He) added in Ar gas during sputtering on the residual stress and the c-BN content has been investigated. As a result, it was found that the residual stress of c-BN thin film decreased with increasing the helium gas flow rate within argon gas.
Silver nanoparticles were prepared by pulsed wire discharge (PWD) using silver wire in deionized water at various relative energy (K) from 10 to 98, which is ratio of the charged energy of the capacitor in the electri...
Silver nanoparticles were prepared by pulsed wire discharge (PWD) using silver wire in deionized water at various relative energy (K) from 10 to 98, which is ratio of the charged energy of the capacitor in the electrical circuit to the vaporization energy of the wire. From energy deposition calculated by the measured voltage and current waveforms, deposited energy of the wire was increased with increasing K. From X-ray diffraction (XRD) analysis, prepared nanoparticles were phase identified as silver. From transmission electron microscopy observations, the shape of prepared silver nanoparticles were spherical and the median particle diameter (D50) and the geometric standard deviation (σg) were calculated from the particle distribution. D50 was decreased from 34 to 19 nm with increasing K. The particle size in prepared by PWD in liquid media can be controlled by K.
The maximum principal stress, von Mises equivalent stress and equivalent creep strain in the welding joint of martensitic heat-resistant steel (9CrlMoVNb) are simulated by finite-element method (FEM) under the conditi...
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The maximum principal stress, von Mises equivalent stress and equivalent creep strain in the welding joint of martensitic heat-resistant steel (9CrlMoVNb) are simulated by finite-element method (FEM) under the condition of 600℃ and applied stress of 80MPa. The results show that the maximum principal stress and von Mises equivalent stress are high on the curved points of two sides of the groove face near the fine-grain heataffected zone (HAZ). The creep strain mainly concentrates in the fine-grain HAZ; the maximum creep strain locates in the bottom of fine-grain HAZ of specimen. The stress triaxiality in the fine-grain HAZ is maximum, and creep cracking occurs because of the intensive constrain of base metal and weld. The simulation result is good in agreement with those of crack initiation site and propagation path by using the stress triaxiality as the mechanical controlling parameter of weld joint of martensite heat-resistant steel. Therefore, it is reasonable that the stress triaxiality is used for analysis initiation and propagation of Type IV cracking in the fine-grain HAZ.
A compact and uniform (Ti, Si, O, N)/Ti composite coating was fabricated on the surface of a NiTi shape memory alloy (SMA) (containing 50.8 at.% Ni) using plasma immersion ion implantation and deposition (PIIID) with ...
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A compact and uniform (Ti, Si, O, N)/Ti composite coating was fabricated on the surface of a NiTi shape memory alloy (SMA) (containing 50.8 at.% Ni) using plasma immersion ion implantation and deposition (PIIID) with radio-frequency (RF) magnetron sputtering. The coating and coated NiTi SMA were studied using various techniques. Analysis showed that the Ni content was drastically reduced on the surface of coated samples due to coating formation. This could greatly improve the biocompatibility of NiTi SMA. There was no TiO2 or TiN formation in the coating. The shape memory ability of NiTi SMA samples was no deteriorated by the coating process. The coating significantly improved the corrosion resistance and wear resistance of NiTi SMA and also rendered the material bioactive.
In the present work, silica aerogel saturated with erythritol as phase change materials (PCMs) was prepared by melt infiltration. In the novel composite, erythritol with high latent heat of fusion was used as PCM for ...
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ISBN:
(纸本)9781439834015
In the present work, silica aerogel saturated with erythritol as phase change materials (PCMs) was prepared by melt infiltration. In the novel composite, erythritol with high latent heat of fusion was used as PCM for thermal control, whereas nanoporous silica aerogel was prepared as the phase change matrix to provide structural strength and prevent leakage of melted erythritol. Nitrogen gas adsorption curves and SEM analysis indicate that the pore structure of silica aerogel was porous and connected with each other. FTIR analysis showed that the composite formation of silica aerogel and erythritol were physical, whereas DSC analysis showed that the melting point and heat storage capacity of the composite were 123.8°C and 289.92 kJ/kg, respectively. The thermal protection properties of phase change composites were designed under laboratory conditions using a thermal measurement setup of a simulated thermal environment of an aircraft. Compared with the paraffin-silica aerogel composite, the erythritol-silica aerogel composite could rapidly control the rising temperature by absorbing heat under high thermal environments.
Cr(N,O) thin films were deposited by radio frequency reactive unbalanced magnetron sputtering on Si(100) or glassy carbon substrates. In this paper, the influence of oxygen content on hardness of Cr(N,O) thin films wa...
Cr(N,O) thin films were deposited by radio frequency reactive unbalanced magnetron sputtering on Si(100) or glassy carbon substrates. In this paper, the influence of oxygen content on hardness of Cr(N,O) thin films was investigated. The compositional analysis was carried out by Rutherford backscattering spectroscopy. It was found that these thin films contained up to 44at.% of oxygen. Phases in the samples were determined by X-ray diffraction. Cr(N,O) thin films show only peaks based on CrN. The microstructure was observed by utilizing a transmission electron microscope. At <1at.% of oxygen, crystallite size was approximately 100nm. Then, in accordance with increasing of oxygen content, crystallite size was decreased. The hardness of thin films was measured by using a nanoindenter. The micro hardness was changed with varying the oxygen content and the microstructure such as crystallite size. Thus, it was thought that the hardening on Cr(N,O) thin films was caused by solution hardening and/or Hall-Petch relationship.
A novel Nth-order microstrip filter with N+2 transmission zeros using two dual-mode resonators is presented in this paper. Two different coupling schemes are obtained by changing couplings between dual-mode resonators...
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