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Chiral effect on Aβ fibrillation from molecular-scale to nanoscale

Nano Research 2022年第7期15卷 6721-6729页

作者： Guanbin Gao Guowei Zhu Liangchong Yu Zijun Zhang Ting Zhang Xinglin Liu Cheng Zhang Lin Zhou Taolei Sun State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Chemistry Chemical Engineering and Life ScienceWuhan University of TechnologyWuhan 430070China

β-Amyloid(Aβ)peptide fibrillation,one of the characteristic hallmarks of Alzheimer’s disease,is determined by many interfacial physical-chemical factors,e.g.,charge,hydrophobicity,*** extensive research,chiral effect in different-scales on the fibrillation process of Aβremains ***,molecular-scale,sub-nanoscale,and nanoscale chiral-structures were constructed to investigate their chiral effect on the fibrillation of Aβ_(40) *** structures from molecular-scale to nanoscale were obtained from the different periods of the chemosynthesis process of chiral ZnS quantum-dots(QDs),confirmed by real-time monitoring of circular dichroism *** molecular-scale,both L-penicillamine(L-P)and D-P ligands accelerated the fibrillation of Aβ_(40),and the speed-up effect of D-P was slightly stronger than *** sub-nanoscale,both two chiral Zncomplexes(L-Zn and D-Zn)induced the agglomeration of Aβ_(40) without chirality *** nanoscale,both L-ZnS and DZnS QDs inhibited the fibrillation of Aβ_(40),and the inhibition effect of L-ZnS was notably better than that of ***-situ kinetics experiments of Aβ_(40) co-incubated with two chiral QDs demonstrated that L-ZnS completely prevents the misfolding of Aβ_(40) from unfolded toβ-sheet,while D-ZnS cannot achieve *** site-replacement experiments and simulation results revealed the underlying molecular mechanisms of the different inhibition efficiency of chiral ZnS QDs on Aβ_(40) fibrillation,which mainly attribute to the stereoselectivity interaction between the chiral ligands of ZnS QDs and electro-positive amino acid residues(R5,K16,and K28)of Aβ_(40).This work offers a microscopic insight of chiral effect on Aβfibrillation exerted by structures in different-scales,and provides a guidance in precise regulation of protein fibrillation via manipulating chiral structures in different-scales.

关键词： chirality molecular-scale sub-nanoscale nanoscale Aβ_(40) fibrillation

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Directly Unveiling the Photothermal Corrosion of BiVO4 via In-situ Transmission Electron Microscopy

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Chemical Research in Chinese Universities 2025年第2期41卷 351-357页

作者： WANG Lindong SUN Jingyi WANG Lang LI Yu HU Zhiyi SU Baolian State Key Laboratory of Advanced Technology for Materials Synthesis and Processing International School of Materials Science and Engineering(ISME)Wuhan University of TechnologyWuhan 430070P.R.China Nanostructure Research Centre(NRC) Wuhan University of TechnologyWuhan 430070P.R.China CMI(Laboratory of Inorganic Materials Chemistry) University of Namurrue deBruxelles 61B-5000NamurBelgium

BiVO4(BVO)is widely utilized in photothermal catalysis because of its favorable bandgap structure(2.4 eV),excellent photo response capabilities and high thermal ***,the mechanism of BVO photothermal corrosion still remains unclear due to the lack of visualized characterization on the degradation process in real ***,we directly unveil the photothermal-induced microstructural evolution of BVO through in-situ heating(scanning)transmission electron microscopy[(S)TEM].The results indicate that the electrons are the initiating condition(“switch”)for the photothermal corrosion of BVO,resulting in the precipitation of Bi and reduction of V5+to V3+in the substrate,while the thermal field facilitates the evaporation of Bi and the recrystallization of *** work sheds light on the mechanism of BVO photothermal corrosion in dynamics and provides significant insights into the photothermal synergistic effects.

关键词： BiVO4 Photothermal corrosion In-situ transmission electron microscopy(TEM) Photothermal catalysis Structural evolution

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Hybrid ionic/electronic interphase enabling uniform nucleation and fast diffusion kinetics for stable lithium metal anode

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Chinese Chemical Letters 2024年第2期35卷 626-633页

作者： Lun Li Pengxia Ji Meng Huang Zixin Zhang Hong Wang Francis Verpoort Jinlong Yang Daping He State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Guangdong Research Center for Interfacial Engineering of Functional Materials College of Materials Science and EngineeringShenzhen UniversityShenzhen 518060China Sanya Science and Education Innovation Park of Wuhan University of Technology Sanya 572000China Hubei Engineering Research Center of RF-Microwave Technology and Application Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430070China

Lithium(Li)dendrite issue,which is usually caused by inhomogeneous Li nucleation and fragile solid electrolyte interphase(SEI),impedes the further development of high-energy Li metal ***,the integrated construction of a high-stable SEI layer that can regulate uniform nucleation and facilitate fast Li-ion diffusion kinetics for Li metal anode still falls ***,we designed an artificial SEI with hybrid ionic/electronic interphase to regulate Li deposition by in-situ constructing metal Co clusters embedded in LiF *** generated Co and LiF both enable fast Li-ion diffusion kinetics,meanwhile,the lithiophilic properties of Co clusters can serve as Li-ion nucleation sites,thereby contributing to uniform Li nucleation and non-dendritic *** a result,a dendrite-free Li deposition with a low overpotential(16.1 mV)is achieved,which enables an extended lifespan over 750 h under strict *** full cells with high-mass-loading LiFePO_(4)(11.5 mg/cm^(2))as cathodes exhibit a remarkable rate capacity of 84.1 mAh/g at 5 C and an improved cycling performance with a capacity retention of 96.4%after undergoing 180 cycles.

关键词： Lithium metal anode Hybrid ionic/electronic interphase Solid electrolyte interphase Fast diffusion kinetics Dendritic growth of lithium

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Mitigating the dissolution of V_(2)O_(5) in aqueous ZnSO_(4) electrolyte through Ti-doping for zinc storage

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Chinese Chemical Letters 2024年第1期35卷 558-562页

作者： Zihe Wei Xuehua Wang Ting Zhu Ping Hu Liqiang Mai Liang Zhou Hubei Longzhong Laboratory Wuhan University of Technology(Xiangyang Demonstration Zone)Xiangyang 441000China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Materials Science and Engineering Wuhan Institute of TechnologyWuhan 430205China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200China

Aqueous zinc-ion batteries(AZIBs)have become a hotspot for electrochemical energy storage owing to the high safety,low cost,environmental friendliness,and favorable rate ***,the serious dissolution of cathode materials in aqueous electrolytes would lead to poor cyclability,which should be addressed before ***,we designed a Ti-doped V_(2)O_(5) with yolk-shell microspherical structure for *** Ti doping stabilizes the crystal structure and relieves the dissolution of V_(2)O_(5) in aqueous ZnSO_(4) *** optimized sample,Ti_(0.2)V_(1.8)O_(4.9),delivers a high capacity(355 mAh/g at 0.05 A/g)as well as good capacity retention(89%after 2500 cycles at 1.0 A/g).This work provides an effective strategy to mitigate the dissolution of cathode material in aqueous ZnSO_(4) electrolyte for cyclability enhancement.

关键词： Aqueous zinc-ion batteries V_(2)O_(5)cathode materials Aqueous ZnSO_(4)electrolyte Yolk-shell structure Ti doping

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In Situ-Constructed Li_(x)MoS_(2)with Highly Exposed Interface Boosting High-Loading and Long-Life Cathode for All-Solid-state Li-S Batteries

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Energy & Environmental materials 2024年第4期7卷 163-174页

作者： Hao Li Rui Wang Jiangping Song Dan Liu Hongyang Gao Yimin Chao Haolin Tang A State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Department of Chemistry Chemical Engineeringand Life ScienceWuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200China School of Chemistry University of East AngliaNorwich NR47TJUK

As the persistent concerns regarding sluggish reaction kinetics and insufficient conductivities of sulfur cathodes in all-solid-state Li-S batteries(ASSLSBs),numerous carbon additives and solid-state electrolytes(SSEs)have been incorporated into the cathode to facilitate ion/electron pathways around ***,this has resulted in a reduced capacity and decomposition of ***,it is worth exploring neotype sulfur hosts with electronic/ionic conductivity in the ***,we present a hybrid cathode composed of few-layered S/MoS_(2)/C nanosheets(<5 layers)that exhibits high-loading and long-life performance without the need of additional carbon additives in advanced *** multifunctional MoS_(2)/C host exposes the abundant surface for intimate contacting sites,in situ-formed LixMoS_(2)during discharging as mixed ion/electron conductive network improves the S/Li2S conversion,and contributes extra capacity for the part of active *** a high active material content(S+MoS_(2)/C)of 60 wt%in the S/MoS_(2)/C/Li_(6)PS_(5)Cl cathode composite(the carbon content is only~3.97 wt%),the S/MoS_(2)/C electrode delivers excellent electrochemical performance,with a high reversible discharge capacity of 980.3 mAh g^(-1)(588.2 mAh g^(-1)based on the whole cathode weight)after 100 cycles at 100 mA g^(-1).The stable cycling performance is observed over 3500 cycles with a Coulombic efficiency of 98.5%at 600 mA g^(-1),while a high areal capacity of 10.4 mAh cm^(-2)is achieved with active material loading of 12.8 mg cm^(-2).

关键词： all-solid-state lithium-sulfur batteries conversion/intercalation high-loading and long-life low carbon content mixed ionic/electronic conductivities

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Scalable graphene foam with ultrahigh conductivity for stabilizing Pt towards efficient hydrogen evolution

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Nano Research 2024年第8期17卷 6968-6976页

作者： Ming Zhao Meng Huang Huihui Jin Dayin He Wei Qian Zixin Zhang Daping He State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Engineering Research Center of RF-Microwave Technology and Application Wuhan University of TechnologyWuhan 430070China School of Information Engineering Wuhan University of TechnologyWuhan 430070China School of Chemistry and Materials Science University of Science and Technology of ChinaHefei 230026China Sanya Science and Education Innovation Park of Wuhan University of Technology Sanya 572000China

For the carbon-based catalyst to be active and stable,especially in harsh electrochemical environments,the key is to decrease the concentration of defects and raise the degree of graphitization of the carbon ***,we develop a highly graphitized graphene foam with multiplicated structure to fabricate self-supporting Pt-based catalysts for efficient and stable hydrogen evolution reaction(HER)*** foam(GO-2850)is obtained through an ultra-high temperature treatment at 2850℃,with perfect graphene structure and extremely low defect,ensuring high electrical conductivity and corrosion ***,its multiplicated structure provides an inherently favorable environment for the dispersion of Pt nanoparticles(Pt NPs)and offers abundant channels for electrolyte infiltration during the catalytic *** a result,the as-prepared Pt/GO-2850 is far active and stable than the Pt NPs supported on commercial carbon paper(Pt/CP)counterpart toward catalyzing HER,exhibiting an outstanding activity and long-term durability(300 h@10 mA·cm^(−2))in acidic/alkaline/seawater *** can be attributed to the stronger interaction between the lower-defect GO-2850 substrate and Pt,as evidenced by characterization and theoretical *** work extends further insight into the design self-supporting catalysts of high activity and stability with promising prominent application toward green energy devices.

关键词： graphene foam high graphitization Pt nanoparticles hydrogen evolution reaction long-term stability

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Microemulsion synthesis of Mesoporous β-tricalcium Phosphate Powder with a Novel System

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Journal of Wuhan University of technology(materials Science) 2022年第4期37卷 773-778页

作者： BIELEC Monikaq HUANG An XIA Yuhao DAI Honglian State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyShenzhen 5180ooChina Shenzhen Institute of Wuhan University of Technology Wuhan 430070China

The synthesis of mesoporous β-tricalcium phosphate(β-TCP)powder was performed by using the microemulsion approach,with hexadecyltrimethyl ammonium bromide(CTAB)/cyclohexane/n-octyl alcohol microemulsion *** influences of different pH values and calcination temperatures on the phase composition of the β-TCP powder were *** in vitro proliferation of bone marrow mesenchymal stem cells(BMSCs)in the suspensions of β-TCP powders with meso-structure was *** phase composition,mesoporous structure,powder morphology,cell morphology and the optical density(OD)were characterized through X-ray diffraction(XRD),field emission scanning electron microscopy(FESEM),Fourier transform infrared(FTIR)spectroscopy,Nadsorption-desorption isotherms,inverted phase contrast microscopy and Multiskan spectrum,*** mesoporous β-TCP powder with specific surface area of 12.85 m^(2)/g and the average pore size 7.11 nm was obtained through the microemulsion approach(100 g/L CTAB/250 mL/L cyclohexane/250 mL/L n-octyl alcohol)with a controlled pH of 7.0,after calcinating the powder at 800℃.It was confirmed that mesoporous β-TCP powder benefits the activity of BMSCs more than the non-mesoporous β-TCP powder.

关键词： β-tricalcium phosphate mesoporous microemulsion bone marrow mesenchymal stem cells

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Rational design and synthesis of Cr_(1-x)Te/Ag_(2)Te composites for solid-state thermoelectromagnetic cooling near room temperature

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Chinese Physics B 2024年第5期33卷 580-586页

作者：孙笑晨谢承昊陈思汗万京伟谭刚健唐新峰 State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China International School of Materials Science & Engineering Wuhan University of TechnologyWuhan 430070China

materials with both large magnetocaloric response and high thermoelectric performance are of vital importance for all-solid-state thermoelectromagnetic *** two properties,however,hardly coexist in single phase materials except previously reported hexagonal Cr_(1-x)Te half metal where a relatively high magnetic entropy change(-△S_(M))of~2.4 J·kg^(-1)·K^(-1)@5 T and a moderate thermoelectric figure of merit(ZT)of~1.2×10^(-2)@300 K are simultaneously *** we aim to increase the thermoelectric performance of Cr_(1-x)Te by compositing with semiconducting Ag_(2)*** is discovered that the in-situ synthesis of Cr_(1-x)Te/Ag_(2)Te composites by reacting their constitute elements above melting temperatures is unsuccessful because of strong phase ***,at elevated temperatures(T>800 K),Cr_(1-x)Te has a much lower deformation energy than Ag_(2)Te and tends to become more Cr-deficient by capturing Te from Ag_(2)***,Ag is insufficiently reacted and as a metal it deteriorates *** then rationalize the synthesis of Cr_(1-x)Te/Ag_(2)Te composites by ex-situ mix of the pre-prepared Cr_(1-x)Te and Ag_(2)Te binary compounds followed by densification at a low sintering temperature of 573 K under a pressure of 3.5 *** show that by compositing with 7 mol%Ag_(2)Te,the Seebeck coefficient of Cr_(1-x)Te is largely increased while the lattice thermal conductivity is considerably reduced,leading to 72%improvement of *** comparison,-△S_(M)is only slightly reduced by 10%in the *** work demonstrates the potential of Cr_(1-x)Te/Ag_(2)Te composites for thermoelectromagnetic cooling.

关键词： thermoelectromagnetic cooling thermoelectric magnetocaloric composite chromium telluride

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Mixed ion-electron conducting Li_(3)P for efficient cathode prelithiation of all-solid-state Li-ion batteries

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SmartMat 2023年第5期4卷 119-130页

作者： Jing Li Dan Liu Han Sun Deyu Qu Zhizhong Xie Haolin Tang Jinping Liu Department of Chemistry School of ChemistryChemical Engineering and Life ScienceWuhan University of TechnologyWuhanChina Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory FoshanChina State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina

All-solid-state batteries(ASSBs)using sulfide electrolytes hold promise for next-generation battery *** using a pure Li metal anode is believed to maximize battery energy density,numerous recent studies have implicated that Li-ion anodes(e.g.,graphite and Si)are more realistic candidates due to their interfacial compatibility with sulfide ***,those Li-ion ASSBs suffer from an issue similar to liquid Li-ion batteries,which is a loss of active Li inventory owing to interfacial side reactions between electrode components,resulting in reduced available capacities and shortened cycle ***,for the first time,we explore the potential of Li_(3)P for cathode prelithiation of Li-ion *** identify that the crystallized Li_(3)P(c-Li_(3)P)has room-temperature ionic and electronic conductivities of both over 1o-4 s/*** a mixed ion-electron conduct-ing feature ensures that the neat c-LisP affords a high Li+-releasing capacity of 983 mAh/g in ASSBs during the first ***,the electro-chemical delithiation of c-LisP takes place below 2 V versus Li+/Li,while its lithiation dominates below 1 V versus Lit/*** used as a cathode prelithiation regent for ASSBs,c-Li_(3)P only functions as a Li+donor without lithiation activity and can adequately compensate for the Li loss with minimal dosage *** mitigating first-cycle Li loss,c-LisP prelithiation can also improve the battery cyclability by sustained release of low-dosage Li+ions in subsequent cycles,which have been embodied in several full ASSBs by coupling a LiCoO2 cathode with various types of anodes(including graphite,in foil,Sb,and Si anode).Our work provides a universal cathode prelithiation strategy for high-efficiency Li-ion AsSBs.

关键词： all-solid-state batteries cathode prelithiation Li_(3)P lithium-ion batteries mixed ion-electron conductor

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Achieving asymmetric redox chemistry for oxygen evolution reaction through strong metal-support interactions

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Journal of Energy Chemistry 2024年第9期96卷 526-535页

作者： Shihao Wang Meiling Fan Hongfei Pan Jiahui Lyu Jinsong Wu Haolin Tang Haining Zhang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina National Energy Key Laboratory for New Hydrogen-Ammonia Energy Technologies Foshan Xianhu LaboratoryFoshan 528200GuangdongChina International School of Materials Science and Engineering(School of Materials and Microelectronics) Wuhan University of TechnologyWuhan 430070HubeiChina Nanostructure Research Centre Wuhan University of TechnologyWuhan 430070HubeiChina Hubei Key Laboratory of Fuel Cell Wuhan University of TechnologyWuhan 430070HubeiChina

Water electrolysis poses a significant challenge for balancing catalytic activity and stability of oxygen evolution reaction(OER)*** this study,we address this challenge by constructing asymmetric redox chemistry through elaborate surface OO–Ru–OH and bulk Ru–O–Ni/Fe coordination moieties within single-atom Ru-decorated defective NiFe LDH nanosheets(Ru@d-NiFe LDH)in conjunction with strong metal-support interactions(SMSI).Rigorous spectroscopic characterization and theoretical calculations indicate that single-atom Ru can delocalize the O 2p electrons on the surface and optimize d-electron configurations of metal atoms in bulk through ***^(18)O isotope labeling experiment based on operando differential electrochemical mass spectrometry(DEMS),chemical probe experiments,and theoretical calculations confirm the encouraged surface lattice oxygen,stabilized bulk lattice oxygen,and enhanced adsorption of oxygen-containing intermediates for bulk metals in Ru@d-NiFe LDH,leading to asymmetric redox chemistry for *** Ru@d-NiFe LDH electrocatalyst exhibits exceptional performance with an overpotential of 230 mV to achieve 10 mA cm^(−2)and maintains high robustness under industrial current *** approach for achieving asymmetric redox chemistry through SMSI presents a new avenue for developing high-performance electrocatalysts and instills confidence in its industrial applicability.

关键词： Reaction redox chemistry Strong metal-support interactions Layered double hydroxides Electrocatalysts Water electrolysis

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