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Enhancing energy density of poly(vinylidene fluoride) composite film via addition of N-doped carbon modified boron nitride and sandwich-structural engineering

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Applied Surface Science 2023年第1期640卷

作者： Huang, Huabo Mei, Wentao Wang, Yucong Huang, Juan Li, Liang Ji, Jiayou Xiong, Chuanxi Hubei Key Laboratory of Plasma Chemistry and Advanced Materials Key Laboratory for Green Chemical Process of Ministry of Education School of Materials Science and Engineering Wuhan Institute of Technology Wuhan430205 China Key Laboratory of Green Processing and Functional New Textile Materials of Ministry of Education School of Textile Science and Engineering Wuhan Textile University Wuhan430200 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China

It is a challenge to simultaneously enhance dielectric constant and breakdown strength of dielectrics and achieve a greatly elevated energy density. Herein, polyaniline was first coated onto the surface of boron nitride nanosheets (BN), and then nitrogen-doped carbon (NC) was formed through a carburization process, resulting in BN@NC composite, which was subsequently added to poly(vinylidene fluoride) (PVDF) to prepare a composite film with high dielectric performance. The characterization showed that BN@NC effectively preserved the nanosheet structure of BN and formed strong hydrogen bonding interactions with the PVDF matrix, promoting the β-PVDF formation. This not only improved the compatibility but also enhanced the interfacial polarization between conductive NC and the polymer, leading to a high dielectric constant. Moreover, the electrically insulating BN prevented the formation of leakage current, resulting in a high breakdown strength. Finally, a sandwich-structured film was constructed, and exhibited a dielectric constant of 10.2 (at 1 kHz), a breakdown strength of 380 MV m−1, and an energy density of 6.1 J cm−3, which were 20%, 36%, and 74% higher, respectively, than those of pure PVDF film (8.5, 280 MV m−1, and 3.5 J cm−3). This work highlights significant potential for applications in low-cost and high-energy density dielectric composites. © 2023 Elsevier B.V.

关键词： Boron nitride

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An aqueous Zn||Br2 battery by electrolyte activating the positive charge of cyanidin additive to resolve challenges of both anode and cathode

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Energy Storage materials 2025年 79卷

作者： Feng, Tao Zhang, Zishuai Guo, Yili Li, Shidong Han, Kang Wang, Yu Gong, Chuang Fan, Jun Liu, Gang Huang, Yan Hubei Key Laboratory of Plasma Chemistry and Advanced Materials School of Materials Science and Engineering Wuhan Institute of Technology Wuhan430205 China Xiangyang441000 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing International School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China Sauvage Laboratory for Smart Materials School of Materials Science and Engineering Harbin Institute of Technology Shenzhen518055 China Department of Materials Science and Engineering City University of Hong Kong 83 Tat Chee Avenue Kowloon999077 Hong Kong

Aqueous Zn||Br2 batteries are deemed as highly promising candidates for high-energy storage due to their low cost, inherent safety, and high theoretical energy density. However, their practical applications are hindered by the poor reversibility of the Zn anode and severe dissolution of the Br2 cathode. In this study, the cyanidin additive—characterized by a cationic property activated through the acidic nature of the ZnSO4 electrolyte—simultaneously addresses challenges at both electrodes without exogenous ions. The −OH groups of cyanidin can bond with free H2O molecules to suppress the hydrogen evolution reaction, and cyanidin can form an electrostatic protective layer on the Zn surface to promote the reversibility of the Zn anode. Simultaneously, cyanidin exhibits strong affinity for bromine species and accelerates their redox kinetics in the Br2 cathode. As a result, the Zn||Br2 coin cell achieves a discharge capacity of 225.5 mAh g–1 with 99.2 % Coulombic efficiency after 20,000 cycles at 5 A g–1, and retains 180 mAh g–1 even at 30 A g–1. Furthermore, the Zn||Br2 pouch cell demonstrates stable cycling over 1400 cycles at 5 A g–1. This work provides a new avenue for simultaneously addressing challenges at both electrodes in aqueous Zn||Br2 batteries and promotes the development of advanced high-performance metal||halogen or metal||chalcogen batteries. © 2025 Elsevier B.V.

关键词： Halon

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Boosting in-plane anisotropy by periodic phase engineering in two-dimensional VO_(2) single crystals

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Fundamental Research 2022年第3期2卷 456-461页

作者： Meng Ran Chao Zhao Xiang Xu Xiao Kong Younghee Lee Wenjun Cui Zhi-Yi Hu Alexander Roxas Zhengtang Luo Huiqiao Li Feng Ding Lin Gan Tianyou Zhai State Key Laboratory of Materials Processing and Die and Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China Centre for Multidimensional Carbon Materials Institute for Basic ScienceSchool of Materials Science and EngineeringUlsan National Institute of Science and TechnologyUlsanSouth Korea Center for Integrated Nanostructure Physics Institute for Basic ScienceSungkyunkwan UniversitySuwonSouth Korea State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Nanostructure Research CentreWuhan University of TechnologyWuhan 430074China Department of Chemical and Biological Engineering The Hong Kong University of Science and TechnologyClear Water BayKowloonHong KongChina

In-plane anisotropy(IPA)due to asymmetry in lattice structures provides an additional parameter for the precise tuning of characteristic polarization-dependent properties in two-dimensional(2D)materials,but the narrow range within which such method can modulate properties hinders significant development of related *** we present a novel periodic phase engineering strategy that can remarkably enhance the intrinsic IPA obtainable from minor variations in asymmetric *** introducing alternant monoclinic and rutile phases in 2D VO_(2)single crystals through the regulation of interfacial thermal strain,the IPA in electrical conductivity can be reversibly modulated in a range spanning two orders of magnitude,reaching an unprecedented IPA of *** an intriguing local phase engineering in 2D materials can be well depicted and predicted by a theoretical model consisting of phase transformation,thermal expansion,and friction force at the interface,creating a frame-work applicable to other 2D ***,the considerable adjustability and reversibility of the presented strategy provide opportunities for future polarization-dependent photoelectric and optoelectronic devices.

关键词： Periodic phase engineering Two-dimensional VO_(2) Interfacial strain In-plane anisotropy Electrical anisotropy Chemical vapor deposition

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A numerical method for predicting bursting strength of composite rocket motor case considering filament winding process-induced stress

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Chinese Journal of Aeronautics 2025年第2期 509-522页

作者： Jiqiu LIANG Fei ZHAO Dan WU Anxin DING Hubei Key Laboratory of Advanced Aerospace Propulsion Technology System Design Institute of Hubei Aerospace Technology Academy School of Materials Science and Engineering Wuhan University of Technology State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology

A numerical method to predict the bursting strength of filament wound composite rocket motor case is proposed here. This method can evaluate the longitudinal stress evolution of each composite layer as impregnated filaments with fiber tension are wound layer by layer, and consider the effects of accumulated stress and deformation during filament winding on the bursting strength of composite case. Taking ?520 mm composite cases as a case study, the filament-winding-processinduced stress and deformation as well as progressive damage behavior are numerically predicted,followed by a comparison with experimental results. The numerical results show that the predicted bursting pressures for composite cases manufactured on the mandrels with and without a flexible component are 14.20 MPa and 21.40 MPa, respectively. These values exhibit slight deviation from the measured pressures of 13.50 MPa and 21.57 MPa. Moreover, the predicted damage locations,situated respectively in the dome and cylinder, agree well with the experimental observation. These observations indicate that use of flexible component reduces the load-bearing capacity of the ***, it validates the reliability and accuracy of the proposed numerical method in predicting the bursting strength of composite cases.

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Spherical Fe3o4 Morphology Modulation for Enhancing Infrared Emissivity and Radiant Heat Dissipation

SSRN

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SSRN 2024年

作者： Qi, Xiaoting Liu, Mingrui Zhu, Wanting Wei, Zhijie Liang, Yu Sun, Chuanqing Bao, Chenxi Zhao, Wenyu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China National energy key laboratory for new hydrogen-ammonia energy technologies Foshan Xian hu Laboratory Guangdong Foshan528200 China

Radiant heat dissipation has emerged as a critical technique for effective thermal management, offering energy efficiency, cost-effectiveness, and adaptability to various shapes while promoting environmental sustainability. However, the intricate relationship between material structures and emissivity remains inadequately understood. This study primarily utilizes a straightforward and economical solvothermal method to regulate the synthesis of Fe3O4 ferrite, exploring its structural relationship with infrared radiation performance. By adjusting the solvent ratio of ethylene glycol and diethylene glycol in the solvothermal system, we successfully synthesized uniformly dispersed Fe3O4 nanospheres ranging from 10 to 800 nm. Notably, our research revealed a positive correlation between infrared emissivity and the particle size. Submicron hollow spheres with a size of 800 nm exhibit an exceptionally high emissivity of 0.992 within the 8~13 μm wavelength range. Morphological and size variations induced alterations in lattice strain, oxygen vacancies, and phonon lifetimes, which consequently influencing the lattice vibration absorption and infrared emissivity. Moreover, the device surface with a composite coating formed by combining 15wt% Fe3O4 particles with organic matter, achieves a temperature difference of 17.6 °C under a 4 W input power condition compared to blank device. This finding contributes to further revealing the process of material radiative heat dissipation, driving the application of high-emissivity materials for heat dissipation in high-power electronic devices. © 2024, The Authors. All rights reserved.

关键词： Magnetite

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Surface Roughening of Sio2 Filler to Enhance the High-Frequency Dielectric and Thermal Properties of Sio2/Ptfe Composites

SSRN

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SSRN 2022年

作者： Li, Xin Zhou, Jing Shen, Jie He, Wenhao Yu, Yuanying Li, Qiangzhi Chen, Wen State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China

Low dielectric constant (Εr), low dielectric loss (tan δ), and low coefficient of thermal expansion (CTE) are necessary for polytetrafluoroethylene (PTFE)-based composites in high-frequency applications. In this paper, we construct the rough structure on the SiO2 filler surface to enhance the performance of SiO2/PTFE composites through a physical interaction way without coupling agents. The microstructure, interfacial combination, dielectric, and thermal properties of SiO2/PTFE composites were systematically investigated using the rough surface SiO2 (rSiO2). The results show that rSiO2 has a superior interfacial combination with PTFE than the smooth surface SiO2 (sSiO2), and the rSiO2 is more uniformly dispersed in the PTFE matrix, these result in a decrease in tan δ and CTE of the rSiO2/PTFE composites from 2.07–4.89 × 10-3, 80 ppm/°C for sSiO2/PTFE to 1.41–3.38 × 10-3, 67 ppm/°C (10–38 GHz). Meanwhile, the rSiO2/PTFE composites are kept in the low Εr (about 2.40, at 38 GHz). The rSiO2/PTFE composites possess excellent dielectric and thermal properties, making it promising for higher frequency applications. © 2022, The Authors. All rights reserved.

关键词： Silica

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Magnetic Units-Ordered Architectonics Triggering Excellent Electric-Thermal Conversion Performance of Thick Films

SSRN

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SSRN 2024年

作者： Zhang, Haojun Ke, Shaoqiu Kuang, Ziyao Li, Haotian Chen, Tiantian Nie, Xiaolei Zhu, Wanting Wei, Ping He, Danqi Liu, Mingrui Zhao, Wenyu Zhang, Qingjie State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Nanostructure research center Wuhan University of Technology Wuhan430070 China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu 528000 China

The low electrical transport performance of flexible thermoelectric (TE) films is the bottleneck that restricts the development of in-plane heat dissipation technology based on Peltier effect. The architectonics of magnetic materials into TE materials has been proven to be an effective method to improve the efficiency of TE conversion. In this study, a series of Bi0.5Sb1.5Te3 (BST)/Fe-NPs/BST thermo-electromagnetic (TEM) films were successfully prepared by orderly embedding ferromagnetic Fe nanoparticles (Fe-NPs) with different distribution shapes in BST matrix through screen-printing combined with hot-press curing. The study focuses on the influence of the ferromagnetism of Fe-NPs and Fe3O4-NPs -induced thermo-electromagnetic coupling on the microstructure and electro-thermal transport properties of BST. The results reveal a 36.5% enhancement in the maximum power factor (PF) of TEM films structured with Fe-NPs in a rhombic dot matrix sequence, while the applied Fe-NPs has no impact on the thermal conductivity, which remains at 0.94 Wm-1K-1 at room temperature, and the calculated zT value is 0.87 under the room temperature. The single-arm device prepared based on TEM thick films can achieve a cooling effect at 1.8 K, and the design of the in-plane heat dissipation device can realize a cooling efficiency in the cooling region reaching 2.8 K. In this paper, the effect of magnetic order on the electrical transport properties of BST thick films is explained from the point of view of the physical model for the first time. © 2024, The Authors. All rights reserved.

关键词： Thermal conductivity

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Simultaneous optimization of lattice and spin configurations in atomic scale simulation of magnetic materials

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Physical Review B 2025年第13期111卷 134412-134412页

作者： Zhengtao Huang Teng Yang Hanxing Liu Ben Xu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Center for Smart Materials and Device Integration School of Material Science and Engineering Wuhan University of Technology Wuhan 430070 People's Republic of China Graduate School of China Academy of Engineering Physics Beijing 100088 People's Republic of China School of Materials Science and Engineering Tsinghua University Beijing 100084 People's Republic of China

Large scale atomistic simulations involving spin-lattice coupling are at the forefront of research in condensed matter physics and materials science. A key challenge lies in determining the ground state configurations of spins and lattices given this strong coupling, complicated by their evolution adherence to distinct governing equations. Unlike first-principles calculations, where the magnetic configuration is naturally determined by minimizing the electronic energy, no existing algorithm can simultaneously optimize both lattice and spin degrees of freedom at the atomic scale. This paper introduces a synergistic optimization framework for lattice and spin optimization in magnetic materials, overcoming the conventional separation approach. Employing a “pseudoatomic” method, the simultaneous optimization of atomic and spin configurations enhances accuracy and speed, enabling both atomic scale precision and large scale calculations. Applied to face-centered-cubic iron and BiFeO3, this approach demonstrates effective convergence, offering a robust tool for complex spin-lattice coupling problems, which paves a path for addressing high-dimensional optimization problems.

关键词： Atoms

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Change in elastic properties during room-temperature aging in body-centered cubic Mg-Li and Mg-Li-Al single crystals

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Journal of materials Science & technology 2022年第14期109卷 49-53页

作者： Ruxia Liu Shota Higashino Koji Hagihara Lianmeng Zhang Tohru Sekino Masakazu Tane SANKEN(The Institute of Scientific and Industrial Research) Osaka University8-1 MihogaokaIbarakiOsaka 567-0047Japan State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China Graduate School of Engineering Osaka City University3-3-138 SugimotoOsaka558-8585Japan Department of Physical Science and Engineering Nagoya Institute of TechnologyNagoya 466-8555Japan

Biodegradable materials,with many advantages over conventionally used non-biodegradable materials,have received much attention owing to the elimination of the need for a secondary surgery for the removal of implants after *** with other biodegradable ceramics and/or polymers,Mg alloys are considered to be the most promising biodegradable orthopedic materials because they feature not only high specific strength and compressive yield strength but also a low Young’s modulus,which is comparable to that of human bones(10-30 GPa)[1,2].

关键词： strength aging alloys

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Screen and discovery of 10-component high-entropy borides composed of IV-VI group transition metals and rare earth elements

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Journal of materials Science & technology 2026年 242卷 226-237页

作者： Zifan Zou Liang Xu Ji Zou Shuaihang Qiu Jingjing Liu Wei Ji Wenwen Wu Zhenhao Han Weimin Wang Zhengyi Fu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 China Hubei Longzhong Laboratory Wuhan University of Technology Xiangyang Demonstration Zone Xiangyang 441000 China School of Materials Science and Engineering Wuhan University of Technology Wuhan 430070 China School of Physics and Information Technology Shaanxi Normal University Xi’an 710062 China

High-entropy borides (HEBs) are emerging as promising candidates for extreme environmental applications due to their exceptional thermal stability, mechanical properties, and tunable electromagnetic properties. This study presents the first systematic investigation of rare-earth-doped deca-component high-entropy borides, (TM 0.9 RE 0.1 )B 2 , (TM = Zr, Hf, Nb, Ta, Ti, W, Cr, V, Mo and RE = Sc, Y, Gd, Dy, Ho, Er, Lu, Sm, Eu, Tm, Tb, Pr, Yb). Evaluations of multiple descriptors, including electron work function and mixing enthalpy, revealed that Sc-containing decaboride (HEB10-Sc) exhibits superior single-phase formation capability. In contrast, the widely used valence electron concentration parameter proved inapplicable due to identical outer-electron counts across rare-earth elements. Boro/carbothermal reduction (BCTR) experiments at 1650 °C, employing transition metal oxides, rare-earth oxides, and B 4 C as precursors, demonstrated that Sc uniquely enables the formation of a single-phase diboride with nine Group IVB-VIB transition metals, unlike other rare-earth dopants. The phase evolution mechanism during the BCTR process was elucidated: ScBO 3 , formed in situ during BCTR, exhibits greater reducibility resistance than the most refractory HfO 2 , thereby suppressing polyboride formation (common in other rare-earth systems) and facilitating single-phase HEB10 formation. The resulting HEB10-Sc displays outstanding electromagnetic wave absorption performance, achieving a reflection loss (RL) of −35.3 dB at 10.6 GHz (3 mm thickness) and an effective absorption bandwidth of 4.7 GHz in the X and Ku bands. These findings underscore the critical role of rare-earth doping in tailoring the structural and functional properties of high-entropy borides, offering a pathway to design advanced multifunctional materials for extreme environments such as thermal protection and high-temperature electromagnetic absorption in aerospace and electronic applications.

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