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Microstructure modification and corrosion resistance enhancement of die-cast Mg-Al-Re alloy by Sr alloying

Journal of Magnesium and Alloys 2021年第3期9卷 950-963页

作者： Matthew S.Dargusch Zhiming Shi Hanliang Zhu Andrej Atrens Guang-Ling Song The University of Queensland Centre for Advanced Materials Processing and Manufacturing(AMPAM)School of Mechanical and Mining EngineeringBrisbaneQLD 4072Australia Australian Nuclear Science&Technology Organisation Locked Bag 2001Kirrawee DCSydneyNSW 2232Australia The University of Queensland Materials EngineeringSchool of Mechanical and Mining EngineeringBrisbaneQld 4072Australia State Key Lab for Physical Chemistry of Solid State Surfaces Center for Marine Materials Corrosion and ProtectionCollege of MaterialsXiamen UniversityXiamenFujian 361005China

The effects of Sr additions on the microstructure and corrosion performance of a Mg-Al-RE alloy in 3.5 wt.%Na Cl saturated with Mg(OH)_(2) have been *** examination reveals that the Sr addition introduces additional intermetallic phases,refines intermetallic networks and dendritic grains,and improves the network *** Al and rare earth elements can be identified in the intermetallics and grain boundaries or inter-dendrite regions under a transmission electron microscope and secondary electron microscope,*** the Sr-containing intermetallic phases and the refined microstructure,the oxide films become more protective,resulting in more corrosion resistant boundary areas and thus dendrite grain ***,the presence of large amounts of intermetallics and boundaries can enhance the corrosion performance of the Mg-Al-RE alloy containing Sr.

关键词： A.magnesium B.TEM B.SEM C.segregation C.Alkaline corrosion

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The issues on the commercialization of perovskite solar cells

Materials Futures

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materials Futures 2024年第2期3卷 1-35页

作者： Lixiu Zhang Yousheng Wang Xiangchuan Meng Jia Zhang Pengfei Wu Min Wang Fengren Cao Chunhao Chen Zhaokui Wang Fu Yang Xiaodong Li Yu Zou Xi Jin Yan Jiang Hengyue Li Yucheng Liu Tongle Bu Buyi Yan Yaowen Li Junfeng Fang Lixin Xiao Junliang Yang Fuzhi Huang Shengzhong Liu Jizhong Yao Liangsheng Liao Liang Li Fei Zhang Yiqiang Zhan Yiwang Chen Yaohua Mai Liming Ding Center for Excellence in Nanoscience(CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication(CAS)National Center for Nanoscience and TechnologyBeijing 100190People’s Republic of China Institute of New Energy Technology College of Information Science and TechnologyJinan UniversityGuangzhou 510632People’s Republic of China Institute of Polymers and Energy Chemistry(IPEC) Nanchang UniversityNanchang 330031People’s Republic of China School of Information Science and Technology Fudan UniversityShanghai 200433People’s Republic of China School of Chemical Engineering and Technology Tianjin UniversityTianjin 300072People’s Republic of China School of Physical Science and Technology Soochow UniversitySuzhou 215006People’s Republic of China Institute of Functional Nano&Soft Materials(FUNSOM) Soochow UniversitySuzhou 215123People’s Republic of China Institute of optoelectronics Fudan UniversityShanghai 200433People’s Republic of China College of Chemistry Chemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123People’s Republic of China School of Physics and Electronic Science East China Normal UniversityShanghai 200241People’s Republic of China State Key Laboratory for Artificial Microstructure and Mesoscopic Physics Department of PhysicsPeking UniversityBeijing 100871People’s Republic of China College of Biophotonics South China Normal UniversityGuangzhou 510631People’s Republic of China School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081People’s Republic of China School of Physics and Electronics Central South UniversityChangsha 410083People’s Republic of China School of Materials Science and Engineering Shaanxi Normal UniversityXi’an 710119People’s Republic of China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070People’s Republic of China Microquanta semiconductor Hangzhou 311121People’s Republic of China

Perovskite solar cells have aroused a worldwide research upsurge in recent years due to their soaring photovoltaic performance,ease of solution processing,and low *** power conversion efficiency record is constantly being broken and has recently reached 26.1%in the lab,which is comparable to the established photovoltaic technologies such as crystalline silicon,copper indium gallium selenide and cadmium telluride(CdTe)solar ***,perovskite solar cells are standing at the entrance of industrialization,where huge opportunities and risks ***,towards commercialization,challenges of up-scaling,stability and lead toxicity still remain,the proper handling of which could potentially lead to the widespread adoption of perovskite solar cells as a low-cost and efficient source of renewable *** review gives a holistic analysis of the path towards commercialization for perovskite solar cells.A comprehensive overview of the current state-of-the-art level for perovskite solar cells and modules will be introduced first,with respect to the module efficiency,stability and current status of *** will then discuss the challenges that get in the way of commercialization and the corresponding strategies to address them,involving the upscaling,the stability and the lead toxicity *** into the future direction of commercialization of perovskite photovoltaics was also provided,including the flexible perovskite cells and modules and perovskite indoor ***,the future perspectives towards commercialization are put forward.

关键词： commercializations perovskite solar cells state-of-the-art level challenges and perspectives indoor photovoltaics

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Sulfur-doped g-C3N4/TiO2 S-scheme heterojunction photocatalyst for Congo Red photodegradation

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Chinese Journal of Catalysis 2021年第1期42卷 56-68页

作者： Juan Wang Guohong Wang Bei Cheng Jiaguo Yu Jiajie Fan Hubei Key Laboratory of Pollutant Analysis and Reuse Technology College of Chemistry and Chemical EngineeringInstitute for Advanced MaterialsHubei Normal UniversityHuangshi 435002HubeiChina State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina Material Science and Engineering School Zhengzhou UniversityZhengzhou 450001HenanChina

Constructing step-scheme(S-scheme)heterojunctions has been confirmed as a promising strategy for enhancing the photocatalytic activity of composite *** this work,a series of sulfur-doped g-C3N4(SCN)/TiO2 S-scheme photocatalysts were synthesized using electrospinning and calcination *** as-prepared SCN/TiO2 composites showed superior photocatalytic performance than pure TiO2 and SCN in the photocatalytic degradation of Congo Red(CR)aqueous *** significant enhancement in photocatalytic activity benefited not only from the 1D well-distributed nanostructure,but also from the S-scheme ***,the XPS analyses and DFT calculations demonstrated that electrons were transferred from SCN to TiO2 across the interface of the SCN/TiO2 *** built-in electric field,band edge bending,and Coulomb interaction synergistically facilitated the recombination of relatively useless electrons and holes in hybrid when the interface was irradiated by simulated solar ***,the remaining electrons and holes with higher reducibility and oxidizability endowed the composite with supreme redox *** results were adequately verified by radical trapping experiments,ESR tests,and in situ XPS analyses,suggesting that the electron immigration in the photocatalyst followed the S-scheme heterojunction *** work can enrich our knowledge of the design and fabrication of novel S-scheme heterojunction photocatalysts and provide a promising strategy for solving environmental pollution in the future.

关键词： TiO2 nanofiber Sulfur-doped g-C3N4 Step-scheme heterojunction photocatalysis In situ XPS S-scheme mechanism

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Energetic Mof-Derived Hollow Carbon Tubes with Interconnected Channels and Encapsulated Nickel-Cobalt Alloy Sites as Bifunctional Catalysts for Zn–Air Batteries with Stable Cycling Over 600 Cycles

SSRN

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SSRN 2022年

作者： Duan, Xin-De Zhu, Jia-Wei Zheng, He-Gen State Key Laboratory of Coordination Chemistry School of Chemistry and Chemical Engineering Collaborative Innovation Center of Advanced Microstructures Nanjing University Jiangsu Nanjing210023 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Hubei Wuhan430070 China

Energetic metal–organic frameworks (EMOFs) and EMOF-derived materials are currently a hot spot to replace precious-metal electrocatalysts. Here, the reasonable strategy and synthesis of an inventive class of alloy@C materials from EMOFs via one-step pyrolysis is reported as the first example. The freshly progressive NiCo@C with a individual hierarchical structure, being composed of uniformly distributive metal alloy nanoparticles (MANPs) decorated by N-doped porous hollow carbon nanotubes (HCNTs), displays extraordinary bifunctional catalytic activities for oxygen reduction and oxygen evolution reactions (ORR and OER) than that of commercial precious-metal catalysts. Experimental characterizations and theoretical calculations reveal the vital role of Ni-Co alloy doping in adjusting both performances. Moreover, as an air electrode in Zn–air batteries, NiCo@C demonstrates a large peak power density of 170 mW cm−2 and superior long-term stability over 600 cycles. In consideration of the expansive category of EMOFs and the governable fixation of single/multiple metal particles, this strategy gives evidence of a capacious scientific range. © 2022, The Authors. All rights reserved.

关键词： Nickel alloys

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Effects on the thermal expansion coefficient and dielectric properties of CLST/PTFE filled with modified glass fiber as microwave material

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Chinese Chemical Letters 2019年第5期30卷 1111-1114页

作者： Liu Zheng Jing Zhou Jie Shen Yanyuan Qi Wen Chen State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology

Ceramic and polytetrafluoroethylene composites as dielectric materials have a low dielectric loss at high frequency and play an important role in the modern communication ***,room temperature phase transformation of PTFE resins,which is accompanied by a large volume change(>400 ppm/℃),seriously affects the dimensional stability and performance stability of *** LD125 modified glass fiber(GF)was introduced to the CaO-Li2 O-Sm2O3-TiO2(CLST)/PTFE composite,to reduce the thermal expansion coefficient(CTE)of the *** tri-phase composites(CLST/PTFE/GF)show the low dielectric loss and excellent *** effect of GF content on the dielectric properties and CTE was also *** CLST/PTFE filled with 5%GF exhibits the best overall performance,which is a promising microwave dielectric material for microwave communication.

关键词： Microwave communication Thermal expansion coefficient CLST PTFE Dielectric loss Dielectric constant

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Novel layered K0.7Mn0.7Ni0.3O2 cathode material with enlarged diffusion channels for high energy density sodium-ion batteries

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Science China materials 2020年第7期63卷 1163-1170页

作者： Jinghui Chen Zhitong Xiao Jiashen Meng Jinzhi Sheng Yanan Xu Junjun Wang Chunhua Han Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing International School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China

As promising,low-cost alternatives of lithiumion batteries for large-scale electric energy storage,sodiumion batteries(SIBs)have been studied by many ***,the relatively large size of Na+leads to sluggish diffusion kinetics and poor cycling stability in most cathode materials,restricting their further *** this work,we demonstrated a novel K+-intercalated Mn/Ni-based layered oxide material(K0.7Mn0.7Ni0.3O2,denoted as KMNO)with stabilized and enlarged diffusion channels for high energy density SIBs.A spontaneous ion exchange behavior in forming K0.1Na0.7Mn0.7Ni0.3O2between the KMNO electrode and the sodium ion electrolyte was clearly revealed by in situ X-ray diffraction and ex situ inductively coupled plasma *** interlayer space varied from 6.90 to 5.76?,larger than that of Na0.7Mn0.7Ni0.3O2(5.63?).The enlarged ionic diffusion channels can effectively increase the ionic diffusion coefficient and simultaneously provide more K+storage sites in the product *** a proof-of-concept application,the SIBs with the as-prepared KMNO as a cathode display a high reversible discharge capacity(161.8 mA h g-1at0.1 A g-1),high energy density(459 W h kg-1)and superior rate capability of 71.1 mA h g-1at 5 A *** work demonstrates that the K+pre-intercalation strategy endows the layered metal oxides with excellent sodium storage performance,which provides new directions for the design of cathode materials for various batteries.

关键词： K0.7Mn0.7Ni0.3O2 K^+pre-intercalation enlarged layered structure high energy density sodium-ion batteries

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sp^(3)-like defect structure of hetero graphene-carbon nanotubes for promoting carrier transfer and stability

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Journal of Energy Chemistry 2021年第6期30卷 189-197,I0005页

作者： Shan-Shan Fan Ling Shen Yuan Dong Ge Tian Si-Ming Wu Gang-Gang Chang Christoph Janiak Ping Wei Jin-Song Wu Xiao-Yu Yang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing and School of Materials Science&EngineeringWuhan University of TechnologyWuhan 430070HubeiChina School of Chemistry Chemical Engineering and Life ScienceWuhan University of TechnologyWuhan 430070HubeiChina Institut für Anorganische Chemie und Strukturchemie Heinrich-Heine-Universität Düsseldorf40204 DüsseldorfGermany NRC(Nanostructure Research Centre) Wuhan University of TechnologyWuhan 430070HubeiChina Department of Engineering and Applied Sciences Harvard University CambridgeMA 02138United States

Three-dimensional(3 D) hybrid of nanocarbons is a very promising way to the high-performance design of electrocatalysis ***,sp^(3)-like defect structure,a combination of high strength and conduction of graphene and carbon nanotubes(CNTs) is rarely ***,3 D neural-like hybrids of graphene(from reduced graphene oxide) and carbon nanotubes(CNTs) have been integrated via sp^(3)-like defect structure by a hydrothermal *** sp^(3)-like defect structure endows 3 D nanocarbon hybrids with an enhanced carrier transfer,high structural stability,and electrocatalytic *** neural-like structure is shown to demonstrate a cascade effect of charges and significant performances regarding bio-electrocatalysis and lithium-sulfur energy *** concept and mechanism of "sp^(3)-like defect structure" are proposed at an atomic/nanoscale to clarify the generation of rational structure as well as the cascade electron transfer.

关键词： Graphene Carbon nanotubes sp^(3)-like defect structure Bio-electrocatalysis Lithium-sulfur batteries

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Low Anisotropy and Excellent Energy Absorption of Additively Manufactured Porous Ti-6al-4v Alloy Consisting of Disordered Trapezo-Rhombic Dodecahedron Cell Structures

SSRN

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SSRN 2024年

作者： Zhao, Rusheng Guo, Shiyue Zhang, Fan Zhang, Wen Yang, Dongsheng Yue, Xuezheng Guo, Xiangyu Tang, Huiling Liu, Yang Hubei Longzhong Laboratory Xiangyang441000 China Graduate School of Systems Design Tokyo Metropolitan University Tokyo1910065 Japan The State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China School of Mechanical Engineering Hunan University of Science and Technology Xiangtan411201 China School of Materials Science and Engineering University of Shanghai for Science and Technology Shanghai200082 China Wuhan University of Technology China

Additive manufacturing (AM) can fabricate porous metals with exceptional characteristics for lightweight structural applications and energy absorption. The mechanical properties of porous metals are determined by porosity, cell shape, cell size, and loading direction. In this study, porous Ti-6Al-4V samples with ordered and disordered cellular structures were manufactured using the laser powder bed fusion (L-PBF) process, and the anisotropic compression behavior under different regularities was systematically investigated. The results show that samples with ordered cellular structures exhibited higher compressive strength under z-axis compression but were prone to shear band formation under x- and y-axis compression, leading to a significant reduction in strength. As regularity decreased, shear bands gradually disappeared, and the samples exhibited more uniform plastic deformation. Notably, when the regularity coefficient R = 0.8, the samples showed the best overall mechanical performance in all directions, including the highest plastic collapse strength and energy absorption capacity. With decreasing regularity, the anisotropy of the porous structures also decreased. Additionally, when R = 0.4, the anisotropy of mechanical performance parameters was minimized;however, when R = 0.8, the overall performance of the mechanical parameters was optimal. These results indicate that effectively adjusting the regularity of the pore structure is key to achieving isotropy and optimizing overall mechanical performance. Compared to simply choosing ordered cells, adjusting the regularity of the cell structure can achieve excellent mechanical properties and reduce anisotropy, which is of significant value for lightweight structures and energy absorption applications. © 2024, The Authors. All rights reserved.

关键词： Anisotropy

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In-Situ Transformation and Synergistic Electrocatalysis of Asymmetric Threefold Hollow Sites in Rosebud-Like Ternary Metal Diselenide

SSRN

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SSRN 2024年

作者： Wang, Shihao Liao, Lin Wu, Jinsong Tang, Haolin Zhang, Haining State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Hubei Wuhan430070 China National Energy Key Laboratory for New Hydrogen-Ammonia Energy Technologies Foshan Xianhu Laboratory Guangdong Foshan528200 China International School of Materials Science and Engineering School of Materials and Microelectronics Wuhan University of Technology Hubei Wuhan430070 China Nanostructure Research Centre Wuhan University of Technology Hubei Wuhan430070 China Hubei Key Laboratory of Fuel Cell Wuhan University of Technology Hubei Wuhan430070 China

Electrochemical dynamic reconstruction substantially optimizes the catalytic properties of transition-metal-based precatalysts for the multi-electron oxygen evolution reaction (OER) by altering the surface structure, exposing more active sites, improving electron/ion transport, and enhancing stability. This research provides a comprehensive understanding of the in-situ transformation manner of a rosebud-like ternary metal diselenide precatalyst (Ni0.8Fe0.2Co0.1Se2) and the synergistic electrocatalytic mechanism of catalytic active centers through in-situ and ex-situ characterization along with DFT calculations. Benefiting from the unique morphology and abundant nanoscale planar defects within the conductive Ni0.8Fe0.2Co0.1Se2 core and the in-situ formed catalytically active (Fe, Co)-doped γ-NiOOH shell, the reconstructed catalyst achieves rapid electron/ion transport and copious active site exposure. Accordingly, the Ni0.8Fe0.2Co0.1Se2 catalyst only requires overpotentials of 101 mV and 233 mV to achieve current densities of 10 mA cm−2 and 100 mA cm−2, respectively. The overall water-splitting cell using Ni0.8Fe0.2Co0.1Se2 anode delivers current densities of 10 and 100 mA cm−2 at low cell voltages of 1.41 and 1.56 V, respectively. Furthermore, the cell demonstrates exceptional durability of 400 h at an industrial-level current density. This work sheds light on the development of efficient transition-metal-based precatalysts for OER. © 2024, The Authors. All rights reserved.

关键词： Iron compounds

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Intraparticle ripening to create hierarchically porous Ti-MOF single crystals for deep oxidative desulfurization

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Dalton transactions (Cambridge, England : 2003) 2023年第35期52卷 12244-12252页

作者： Shen Yu Zhan Liu Jia-Min Lyu Chun-Mu Guo Yi-Long Wang Zhi-Yi Hu Yu Li Ming-Hui Sun Li-Hua Chen Bao-Lian Su Laboratory of Living Materials at the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology 122 Luoshi Road Wuhan 430070 Hubei China. chenlihua@***. Nanostructure Research Center Wuhan University of Technology Wuhan 430070 Hubei China. School of Chemistry Chemical Engineering and Life Science Wuhan University of Technology Wuhan 430070 Hubei China. Laboratory of Inorganic Materials Chemistry University of Namur 61 rue de Bruxelles B-5000 Namur Belgium.

The catalytic oxidative desulfurization (ODS) technique is able to remove sulfur compounds from fuels, conducive to achieving deep desulfurization for the good of the ecological environment. Ti-based metal-organic frameworks (Ti-MOFs) possessing good affinity to organic reactants and considerable numbers of Ti active sites are promising catalysts for ODS. However, current Ti-MOFs suffer from severe diffusion limitations caused by the size mismatch between sole micropores and bulky sulfur compounds, leading to poor ODS performance. Here, a facile method of intraparticle ripening without any additive is developed to obtain hierarchically meso-microporous Ti-MIL-125 single crystals (Meso-Ti-MIL-125) for the first time. Such Meso-Ti-MIL-125 shows a BET surface area of 1401 m g and a mesoporous volume that is 1.7 times as high as that of the conventional Ti-MIL-125. Our novel Meso-Ti-MIL-125 exhibits excellent catalytic performance in the ODS of a series of bulky thiophenic sulfur compounds, completely removing benzothiophene (BT), dibenzothiophene (DBT), and 4,6-dimethyldibenzothiophene (DMDBT) from model fuels, which is, respectively, 2.4 times, 1.5 times, and 6.7 times higher than the removal achieved with conventional Ti-MIL-125. Such a facile synthetic strategy is envisioned to be applied in many kinds of crystalline materials, such as zeolites, for industrial production.

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