Designing highly efficient and stable photocatalysts is of vital importance for solar-to-fuel conversion,as a potential strategy to address the concerns of global energy crisis and environmental *** development of nov...
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Designing highly efficient and stable photocatalysts is of vital importance for solar-to-fuel conversion,as a potential strategy to address the concerns of global energy crisis and environmental *** development of novel photocatalytic materials is desirable to overcome those shortcomings of traditional semiconductor photocatalysts.
In order to improve the wear resistance, a kind of alumina ceramic with good wear resistance was created in an Al_2O_3-CaC_O3-SiO_2-MgO-La_2O_3（ACSML） system. The effects of La_2O_3 content on sintering temperature,...
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In order to improve the wear resistance, a kind of alumina ceramic with good wear resistance was created in an Al_2O_3-CaC_O3-SiO_2-MgO-La_2O_3（ACSML） system. The effects of La_2O_3 content on sintering temperature, bulk density, and wear rate were investigated. The wear rate of sample was as low as 0.0393‰. The wear resistance of the sample containing La_2O_3 has improved 43% than that of the sample without La_2O_3. Appropriate La_2O_3 doping could inhibit grain growth, enhance density, and purify grain boundary. La_2O_3 could diffuse into Al_2O_3 to form a solid solution and react with Al_2O_3 to form high-aluminum low-lanthanum complex oxides. The combination among Al_2O_3, the solid solution layer, and the layer of high-aluminum low-lanthanum complex oxides combined closely, which could improve grain boundary cohesion. Besides, the homogeneous distributions of elements made uniform structure. Finally, the wear resistance of alumina ceramic was improved.
In this work,homogeneous Ni0.33Co0.67Se hollow nanoprisms were synthesized successfully in virtue of Kirkendall *** is the first time for bimetallic Ni-Co compounds Ni0.33Co0.67Se to be used in lithium-ion batteries (...
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In this work,homogeneous Ni0.33Co0.67Se hollow nanoprisms were synthesized successfully in virtue of Kirkendall *** is the first time for bimetallic Ni-Co compounds Ni0.33Co0.67Se to be used in lithium-ion batteries (LIBs).Impressively,the Ni0.33Co0.67Se hollow nanoprisms show superior specific capacity (1,575 mAh/g at the current density of 100 mA/g) and outstanding rate performance (850 mAh/g at 2,000 mA/g) as anode material for *** work proves the potential of bimetallic chalcogenide compounds as high performance anode materials for LIBs.
Carbon nanotubes（CNTs） decorated with palladium were synthesized and applied to hydrogen storage of gas phase. The results show that the amount of hydrogen storage of the decorated CNTs is up to 3.9%（mass fraction...
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Carbon nanotubes（CNTs） decorated with palladium were synthesized and applied to hydrogen storage of gas phase. The results show that the amount of hydrogen storage of the decorated CNTs is up to 3.9%（mass fraction）, of which, almost 85% H2 can be desorbed at ambient temperature and pressure, while the non-decorated CNTs has a poor performance of hydrogen storage（only about 0.5%H2, mass fraction）. These indicate that it is feasible to enhance the performance of hydrogen storage of CNTs by further decoration with hydrogen-storing metals or alloys.
Electroless CoNiWP magnetic films were prepared by varying the bath pH and then characterized by energy dispersive X-ray analysis, X-ray diffraction and magnetic force microscopy, it has been found that the microstruc...
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Electroless CoNiWP magnetic films were prepared by varying the bath pH and then characterized by energy dispersive X-ray analysis, X-ray diffraction and magnetic force microscopy, it has been found that the microstructure and the magnetic properties of films were influenced greatly by the bath pH. At the bath pH 8.06, the grain size and coercivity of the films reach maximuml while the squareness （Mr/Ms） of MH curves reaches minimum. The Henkel plots indicates that the exchange-coupling interaction is very weak at this pH, which may be caused by phase-separation and large grain size, and then results in the lowest squareness. At pH above 8.5, obvious exchange-coupling interaction is observed because of the inexistence of phase-separation and the refinement of grain size.
A kind of W/W-Mo/Mo system layered flier-plate material (LFP) was fabricated in this study by the methods of powder metallurgy and bonding together. Such LFP had high parallelism,planeness and densification and its de...
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A kind of W/W-Mo/Mo system layered flier-plate material (LFP) was fabricated in this study by the methods of powder metallurgy and bonding together. Such LFP had high parallelism,planeness and densification and its density varied from 17.25x103 kg/m3 to 10.22x103 kg/m3 through a total thickness of 3.0 mm. The W-Mo interlayer of this LFP was obtained by hot-press sintering and its densification at 1573 K was studied. Then by using additives 4Ni-3Cu (in wt pct), the LFP was fabricated under 1573 K-30 MPa-60 min. The mechanism of the interfacial bonding of the W/W-Mo/Mo system LFP was also mainly investigated.
Nanocomposites offer a promising approach to the incorporation of nanostructured constituents into bulk thermo- electric materials. The 0.7-at% Bi-doped Mg2Si nanocomposites are prepared by spark plasma sintering of t...
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Nanocomposites offer a promising approach to the incorporation of nanostructured constituents into bulk thermo- electric materials. The 0.7-at% Bi-doped Mg2Si nanocomposites are prepared by spark plasma sintering of the mixture of nanoscale and microsized 0.7-at% Bi-doped Mg2Si powders. Microstructure analysis shows that the bulk material is composed of nano- and micrograins. Although the nanograin hinders electrical conduction, the nanocomposite struc- ture is more helpful to reduce thermal conductivity and increase the Seebeck coefficient, hence improving thermoelectric performance. A dimensionless figure of merit of 0.8 is obtained for the 0.7-at% Bi-doped Mg2Si nanocomposite with 50-wt % nanopowder, which is about twice larger than that of the sample without nanopowder.
Two-dimensional(2D)titanium carbide(Ti_(3)C_(2)T_(x))MXene nanosheets show promising mechanical and electrical properties,indicating great potential applications in aerospace and electronic devices,etc.[1,2].There are...
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Two-dimensional(2D)titanium carbide(Ti_(3)C_(2)T_(x))MXene nanosheets show promising mechanical and electrical properties,indicating great potential applications in aerospace and electronic devices,etc.[1,2].There are many assembling approaches including vacuum filtration,blade coating and layer-by-layer[3–5].However,it still remains a great challenge to realize the intrinsic performance of MXene nanosheets into macroscopic film due to low stress transfer efficiency,which usually is indued by the voids and misalignment during the assembling process[6].Thus,it remains a great challenge to assemble MXene nanosheets into high-performance macroscopic MXene films.
A series of new microwave dielectric ceramics Ba3-nLa1+nTinNb3-nO12 (n=0,1,2) were prepared in the BaO-La2O3-TiO2-Nb2O5 system by high temperature solid-state reaction route. The phase and structure of the ceramics we...
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A series of new microwave dielectric ceramics Ba3-nLa1+nTinNb3-nO12 (n=0,1,2) were prepared in the BaO-La2O3-TiO2-Nb2O5 system by high temperature solid-state reaction route. The phase and structure of the ceramics were characterized by X-ray diffraction, scanning electron microscope, and microwave dielectric properties measurements. These samples were identified as single phase and adopted A4B3O12-type cation-deficient hexagonal perovskite structure, which can be described as consisting of identical perovskite-like blocks, three corner-sharing BO6 octahedra thick, separated by layers of vacant octahedral. These ceramics have high dielectric constants in the range of 48-42, high quality factors (Q×f) up to 38 000 GHz, and low temperature coefficient of resonant frequencies (τf) in the range of (-40-+6)×10-6℃-1. With increasing content of La and Ti, the dielectric constants slightly decrease butτf gradually increases.
The visualization experiments were carried out to investigate the permeability of the high permeable medium (HPM) and the roles of the peel ply and the HPM in the mold *** influence of process parameters on mold fill...
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The visualization experiments were carried out to investigate the permeability of the high permeable medium (HPM) and the roles of the peel ply and the HPM in the mold *** influence of process parameters on mold filling is ***,the whole vacuum infusion molding process (VIMP) procedure is introduced in detail taking the manufacture of a model boat for example.
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