Learning from the process of biominerals formation provides tremendous ideas for developing advancedsynthesis techniques. According to the structure formation of tooth enamel, a recombinant amelogenin his-Amel X was ...
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Learning from the process of biominerals formation provides tremendous ideas for developing advancedsynthesis techniques. According to the structure formation of tooth enamel, a recombinant amelogenin his-Amel X was designed and constructed. The protein was over-expressed and could be conveniently purified in one-step heat treatment. The mineralization process of hydroxyapatite was initiated by enzyme AP and regulated by the recombinant amelogenin. Effects of solution pH value and mineralization duration were studied. It was demonstrated that his-Amel X could induce the nucleation of apatite and quicken the growth rate at pH 7.0-7.4, while impeded hydroxyapatite growth at pH 6.8. Moreover, a much denser layer of hydroxyapatite was achieved with the addition of his-Amel X. The present study may not only provide insight into the formation of natural biomaterials but also open a new path to prepare materials under environmentally benign conditions.
The grain-boundary resistance of ZrO2 mainly consists of the contribution from the space-charge layers Rsc and that from the grain-boundary phase Rgbp The reduction of Rsc can be realized by the segregations of solute...
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The grain-boundary resistance of ZrO2 mainly consists of the contribution from the space-charge layers Rsc and that from the grain-boundary phase Rgbp The reduction of Rsc can be realized by the segregations of solutes with positive effective charge in the space-charge layers,while the reduction of Rgbp can be achieved by decreasing the amount of the grain-boundary phase,changing the morphology of the phase and forming grain-boundary phase with high *** best grain-boundary design effect can only be achieved by the joint design of the space-charge layers and the grain-boundary phase.
The rods that were shaped from nanocrystalline WC- 10.21 Co-0.42 VC/ Cr3 C2 （ wt% ） composite powders by using powder extrusion molding （PEM） were investigated. The nanocrystalline WC- 10.21 Co- 0. 42 VC/ Cr3 C2 ...
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The rods that were shaped from nanocrystalline WC- 10.21 Co-0.42 VC/ Cr3 C2 （ wt% ） composite powders by using powder extrusion molding （PEM） were investigated. The nanocrystalline WC- 10.21 Co- 0. 42 VC/ Cr3 C2 （ wt% ） composite powders were prepared by the spray thermal decomposition-continuous reduction and carburization technology. In order to improve the properties of rods shaped by using powder extrusion molding, the cold isostatic pressing （CIP） technology was used before or after debinding. Specimens were siutered by vacuum siutering and hot isostatic pressing （HIP）. The density, Rockwell A hardness, magnetic coercivity , and magnetic saturation induction of siutered specimen were measured. The microstructure of the green bodies and the siutered specimens was studied by scanning electron microscopy （SEM）. Results show that the rod formed by using powder extrusion molding after debinding and followed by cold isostatic pressing can be siutered to 99.5% density of composite cemented carbide rods with an average grain size of about 200- 300 nm, magnetic coercivity of 30.4 KA / m, Rockwell A hardness of 92.6 and magnetic saturation induction of 85% . Superfine WC- 10 Co cemented carbide rods with excellent properties were obtained.
Polymer-protected monodisperse nickel nanoparticles were synthesized by a modified polyol reduction method in the presence of poly（N-vinyl-2-Pyrrolidone）.These nanoparticles were characterized by transmission electr...
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Polymer-protected monodisperse nickel nanoparticles were synthesized by a modified polyol reduction method in the presence of poly（N-vinyl-2-Pyrrolidone）.These nanoparticles were characterized by transmission electron microscopy（TEM）,X-ray diffraction（XRD）,selected area electron diffraction（SAED）,as well as vibrating sample magnetometer（VSM）.The experimental results show that the addition of PVP and the concentration of NaOh have strong influences on the *** and uniformity of *** the presence of PVP and NaoH with low *** nickel nanoparticles with average diameters about 42 nm were obtained and characterized to the pure nickel crystalline with foc *** structures such as *** strings resulted from magnetic interactions between particles were *** chemical interaction between the PVP and nickel nanoparticles was found by *** saturation magnetization（Ms）.remanent magnetization（Mr）and coercivity（Hc）of these nickel nanoparticles are lower than those of bulk nickel.
A theoretical model based on BCT lattice structure was developed. Resultant force in the BCT lattice structure was deduced, following the interaction force of two kinds of magnetic particles. According to empirical Fr...
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A theoretical model based on BCT lattice structure was developed. Resultant force in the BCT lattice structure was deduced, following the interaction force of two kinds of magnetic particles. According to empirical FroHlich-Kermelly law, the relationship between the magnetic induction and the magnetic field was discussed, and a predictive formula of shear stresses of the BCT lattice structure model was established for the case of small shear deformation. Compared with the experimental data for different particle volume fractions, the theoretical results of the shear stress indicate the effects of the saturation magnetization and the external magnetic field on the shear stress.
Surface-attached micropattemed polyelectrolyte brushes on planar solid surfaces are generated using free radical polymerization photo-initiated by self-assembled initiator monolayers. It is shown that the formed patte...
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Surface-attached micropattemed polyelectrolyte brushes on planar solid surfaces are generated using free radical polymerization photo-initiated by self-assembled initiator monolayers. It is shown that the formed patterns can be either negative or positive with different patterning processes.
SiCp/ Al composites containing high volume fraction of SiC particles were fabricated by spark plasma sintering （SPS）. and their thermophysical properties, such as thermal conductivity （TC） and *** of thermal expan...
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SiCp/ Al composites containing high volume fraction of SiC particles were fabricated by spark plasma sintering （SPS）. and their thermophysical properties, such as thermal conductivity （TC） and *** of thermal expansion （CTE）, were characterized. The electric field in the vacuum column was calculated and the generation condition of the spark was analyzed. Spark can be generated by a low current if the cavity in the green body is large enough. A high relative density of the composites was successfully achieved through the optimization of sintering parameters. The measured TCs of the SiCp/ Al composites fabricated by SPS are higher than 195 W/m ·K.
Both silica and boron-silica glass materials doped with terbium organic complex were prepared by in situ sol-gel method respectively. XRD and SEM measurements were performed to verify the non-crystalline structure of ...
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Both silica and boron-silica glass materials doped with terbium organic complex were prepared by in situ sol-gel method respectively. XRD and SEM measurements were performed to verify the non-crystalline structure of the glass. The influence of the glass contents on the structure of the glass and the erwrgy level of the doped Tb （Ⅲ） ions was analyzed by the emission spectra and IR spectra. The effect of B2O3 on the photolumirwscence properties of rare earth organic complex in silica- based glass was investigated. The IR spectra indicate that the in situ sylthesized rare earth complex molecule was confined to the micropores of the bost and the vibration of the ligands was frozen. When B2O3 was added into the silica host gel, B2O3 had little influence on the noncrystallirw structure of the glass, and BO3 triangle, which had a layer structure different from the silica framework, could form. So the silica network became more inhomogenous, and the luminescence of terbium complexes was quenched with the increase of the B2O23 amount.
ZrB2 ceramics were prepared by self-propagating high-temperature synthesis（SHS） and were sintered by hot pressing（HP）.The effects of the granularities and doses of raw materials in Zr-B2O3-Mgon SHS process and pro...
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ZrB2 ceramics were prepared by self-propagating high-temperature synthesis（SHS） and were sintered by hot pressing（HP）.The effects of the granularities and doses of raw materials in Zr-B2O3-Mgon SHS process and product were *** and combustion temperature curves prove that the ideal SHS reactants of Zr-B2O3-Mg are 50μm Zr powder,75μm B2O3 powder and 400μm Mg powder with 45% *** particle sizes of SHS product,acid-leached product,sintered product are 2-5μm,0.5-2μm,2-10μm *** analysis indicates that the acid-leached product consists of ZrB2（94.59%）,ZrO2（3.87%）,and H3BO3（1.54%）,The sintered product has a relative density of 95.4%.
Both titanium and germanium were introduced into silicon dioxide system by sol-gel method to move its region of anomalous dispersion caused by IR resonance absorption towards the wavelength of CO 2 *** is indicated b...
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Both titanium and germanium were introduced into silicon dioxide system by sol-gel method to move its region of anomalous dispersion caused by IR resonance absorption towards the wavelength of CO 2 *** is indicated by IR absorption spectra that as the content of SiO 2 decreases in this glass system TiO 2 and GeO 2 tends to exist in their own *** for the gel glass with a composition of 40SiO 2·30TiO 2·30GeO 2,when the temperature is below 600℃,germanium atoms exist mainly in Ge-O-Ge *** the temperature increasing from 800℃ to 1000℃, titanium atoms in Si-O-Ti bonds almost transform into Ti-O-Ti ***,a large number of Si-O-Ti and Si-O-Ge bonds formed when the temperature approaches 800℃,which makes a notable IR absorption band round the wavelength of CO 2 ***, sol-gel based SiO 2-TiO 2-GeO 2 gel glass is a candidate material for CO 2 laser hollow waveguide.
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