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Controllab.e preparation of Eu3+-doped octacalcium phosphate and fluorescence study of its hydrolysis into hydroxyapatite

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CrystEngComm 2025年

作者： Zhou, Heng Chen, Jia Tan, Xinyu Wei, Xuanhe Han, Yingchao State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Biomedical Materials and Engineering Research Center of Hubei Province Wuhan University of Technology Wuhan430070 China

Octacalcium phosphate (OCP) is generally considered the intermediate of hydroxyapatite (HAP) during bone mineralization. Crystalline phase transformation of OCP to HAP is an important topic in the study of biomineralization processes. In this study, Eu3+-doped OCP (Eu-OCP) was synthesized controllab.y by an improved co-precipitation method. The results showed that Eu-OCP had different fluorescence properties (i.e. emission intensity and I614/I591 ratio) due to the varied crystal field environment compared with Eu3+-doped HAP. Furthermore, the relationship between the I614/I591 ratio and the mass ratio of HAP to OCP in a HAP/OCP mixture was revealed based on a Eu3+ fluorescent probe, which was verified by X-ray diffraction (XRD) analysis. The I614/I591 ratio was related to the content (x) of HAP in the HAP/OCP mixture according to I614/I591 = 2.0971 − 0.70246/(1 + exp(x − 0.68956)/0.11274) (R2 = 0.970). By this fluorescent probe method, the crystal phase transition from OCP to HAP was quantitatively analyzed during the hydrolysis of OCP, which was in accordance with the XRD analysis. Therefore, this fluorescent probe method has potential to monitor crystal phase transition in biomineralization in situ. © 2025 The Royal Society of Chemistry.

关键词： Hydrolysis

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Multi-functionalized sites in metalated COFs film for chemiresistive gas sensing at room temperature

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Chemical Engineering Journal 2025年 514卷

作者： Mei, Aohan Zhou, Min Zhang, Wenyuan Bao, Yunan Liu, Yueli Chen, Wen State Key Laboratory of Silicate Materials for Architectures School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China Wuhan Brilliant Tech Co. Ltd. Wuhan430205 China

Post-synthetic modification of covalent organic frameworks (COFs) has attracted much attention due to its simple introduction of metals and functional groups as active sites for diverse applications. However, the charge transport improvement and the functions of active sites in metalated COFs are so far ignored in gas sensors. Herein, Zn2+ is loaded on two kinds of sites on TpBpy COFs film by a simple photochemical synthesis. Zn2+ coordination improves the NH3 sensitivity by increasing the charge density and adsorption of ammonia molecules. DFT simulation and UPS result prove that the suitable adsorption configuration and work function of Zn@TpBpy COFs film play the key role for the gas sensing behavior. The as-fabricated Zn@TpBpy COFs gas sensors exhibit high sensitivity with linear response behavior and a low detection limit of 500 ppb. By comparing Zn@TpBpy with Cu@TpBpy COFs, the electron donating coordination structure from the fully occupied 3d orbital in Zn2+ boosts the response value and sensing speed, providing a novel insight into manipulating sensing behavior of metalated COFs films. © 2025 Elsevier B.V.

关键词： Chemical sensors

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Microstructure and tribological properties of -oriented 3C-SiC by chemical vapor deposition

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Ceramics International 2025年

作者： Yang, Wenxuan Huang, Wei Li, Cuicui Wang, Chongjie Zhang, Chitengfei Tu, Rong Zhang, Song Hubei Longzhong Laboratory No.101 Luming Road Xiangyang441000 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Hubei Technology Innovation Center for Advanced Composites Wuhan430070 China

Highly -oriented 3C-SiC coatings were fabricated by chemical vapor deposition method at different temperatures. As deposition temperature increased from 1473 K to 1773 K, the surface structure of -oriented 3C-SiC transitioned from hexagonal structure with sixfold symmetry to hill-like structure, and finally to conical porous surface composed of stacked short rods. Owing to alteration of surface structure, the hardness of 3C-SiC coatings presented a trend of initially increasing and subsequently decreasing. The 3C-SiC coating deposited at 1673 K possessed the highest hardness, with a value of 42.08 GPa. The average friction coefficient for 3C-SiC/Si3N4 pair ranged from 0.258 to 0.569. The wear rate and hardness exhibited opposite trends. Compared with 3C-SiC coatings prepared at the other three temperatures, the 3C-SiC coating deposited at 1573 K exhibited the lowest wear rate under loads of 5 N, 10 N, and 15 N. Furthermore, the lowest wear rate, recorded at 15 N, was 4.1 × 10−6 mm3/Nm, attributed to high hardness and uniform grain size. The wear mechanism of -oriented 3C-SiC coatings during dry sliding primarily involved fracture, leading to fatigue and third-body wear. © 2025 Elsevier Ltd and Techna Group S.r.l.

关键词： Rockwell hardness

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Achieving enhanced thermoelectric and mechanical performance in p-type bismuth telluride through constrained hot deformation

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Ceramics International 2025年

作者： Chen, Quansheng Ji, Chen Yu, Jian Hua, Lin Zhao, Wenyu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China School of Automotive Engineering Wuhan University of Technology Wuhan430070 China School of Materials Science and Engineering Jiujiang University Jiujiang332005 China Hubei Key Laboratory of Advanced Technology for Automobile Components Wuhan University of Technology Wuhan430070 China

Bi2Te3-based alloys remain the only commercially availab.e thermoelectric (TE) materials. However, their practical applications are severely constrained by the inferior mechanical performance of the zone melting (ZM) ingot. Herein, a simple constrained hot deformation (CHD) technology was developed to prepare the p-type Bi0.5Sb1.5Te3 polycrystalline materials derived from ZM ingots. It was discovered that the deformation process has negligible impact on the phase composition, but can efficiently refine the grains to approximately 5 μm through the dynamic recrystallization and simultaneously introduce high-density dislocations. Although the donor-like effect induced by deformation would obviously deteriorate the electrical conductivity, the recovery effect triggered by high deformation temperature can effectively optimize the carrier concentration and thus alleviate the degradation of power factor. The material deformed at 773 K maintains a relatively high power factor ∼3.33 mW K−2 m−1 at 300 K, together with a significantly decreased lattice thermal conductivity ∼0.59 W m−1 K−1, and an improved zT ∼1.1 was obtained ultimately. More importantly, the deformed materials show a significant improvement in mechanical performance due to the grain refinement. A maximum average Vickers hardness of 0.67 GPa was achieved for the material deformed at 723 K, which is ∼40 % higher than that of the ZM ingot. Our work indicates the simple CHD is an efficient technology to synergistically enhance both TE and mechanical properties of Bi2Te3-based ZM ingot. © 2025 Elsevier Ltd and Techna Group S.r.l.

关键词： Polycrystalline materials

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Boosting oxygen evolution of LiCoO2 electrocatalysts via lithium defect

Materials Today Catalysis

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materials Today Catalysis 2025年 8卷

作者： Li, Huamei Li, Mengyuan Liao, Lingling Yang, Han Xiang, Kun Luo, Guoqiang Xie, Mingjiang School of Chemistry and Environmental Engineering Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education Wuhan Institute of Technology Wuhan430205 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Hubei Key Lab for Processing and Application of Catalytic Materials College of Chemical Engineering Huanggang Normal University Huanggang438000 China

The challenge of the complex oxygen evolution reaction (OER) currently impedes the efficient production of hydrogen via electrolytic water splitting. To address this issue, the development and improvement of effective electrocatalysts are required. LiCoO2, a key material in lithium-ion batteries, has shown promising potential as an electrocatalyst for electrochemical energy conversion. However, OER catalysts derived from LiCoO2 have faced obstacles such as high overpotential and a complicated preparation process. In this study, the preparation method is adjusted to optimize the synthesis of Li1-xCoO2 with a defective structure, resulting in an impressive overpotential of only 290 mV at a current density of 100 mA cm−2 and a remarkable Tafel slope of 15.2 mV dec−1. The exceptional catalytic activity of Li1-xCoO2 can be attributed to the absence of Li, which triggers oxidative alterations in the electronic structure of Co. Density functional theory (DFT) calculations reveal that Li defects can influence the d-band center of active Co sites, enhancing the adsorption capabilities of Co sites towards *OOH intermediates and increasing the conductivity of the electrocatalyst during the OER process. These alterations improve the velocity of the crucial step in the reaction, ultimately boosting the catalyst's overall performance and efficiency. © 2024 The Authors

关键词： Lithium-ion batteries

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Rodent enamel-inspired hydroxyapatite nanocomposites with Fe 3+ -rich amorphous intergranular phases

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Journal of materials Research and technology 2025年 36卷 7423-7432页

作者： Shenye Chen Zhengjian Su Bingyu Xue Benxi Xu Yafei Cheng Kun Wang Yidi Li Zhengyi Fu Hubei Longzhong Laboratory Xiangyang 441000 PR China School of Materials Science and Engineering Wuhan University of Technology Wuhan 430070 PR China State Key Laboratory of Precision Blasting Jianghan University Wuhan 430056 PR China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 PR China

Rodent enamel is primarily composed of hydroxyapatite (HAP) nanowires and Fe 3+ -rich amorphous intergranular phases (AIP). Inspired by rodent tooth enamel, this study successfully formed a layer of Fe 3+ -rich AIP on the outer layer of HAP nanowires by ion exchange between Fe 3+ and Ca 2+ within the HAP lattice. The thermal stability of Fe-HAP nanowires with Fe 3+ -rich AIP was enhanced. By bi-directional freezing of Fe-HAP nanowires with polyvinyl alcohol (PVA), rodent enamel-like nanocomposites (Fe-HEN) were obtained. Owing to the reinforcing and toughening effect of Fe 3+ -rich AIP, Fe-HEN exhibited a hardness of 1.66 ± 0.23 GPa, a Young's modulus of 48.8 ± 6.7 GPa in the longitudinal direction, as well as a hardness of 1.38 ± 0.16 GPa and a Young's modulus of 40.2 ± 3.0 GPa in the transversal direction. The flexural strength of the sample reached 153.5 ± 5.0 MPa, which is 2.9 times higher than that of samples without AIP, surpassing the performance of natural rodent enamel. The compressive strength reached 205 ± 4.3 MPa, representing a 1.5-fold increase over the sample without AIP and comparable to that of natural enamel. Compared to samples without AIP, Fe-HEN exhibits superior fracture toughness and crack deflection, better corrosion resistance, owing to the reinforcing effect of Fe 3+ -rich AIP at nanowire interfaces. This study demonstrates the incorporation of amorphous reinforced structures into the tooth enamel-like materials via ion exchange, offering a promising strategy for the development of high-performance multiscale composites.

关键词： Hydroxyapatite nanowires Amorphous intergranular phases Enamel-like nanocomposites Ion exchange Rodent enamel-inspired

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Ag-Induced Synergistic Enhancement of mechanical and shape memory characteristics in Cu-Al-Ni alloys

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materials Letters 2025年 395卷

作者： Zhang, Jinjin Zhang, Chi Jia, Mingyong Yin, Guanchao Chen, Fei Hubei Longzhong Laboratory Xiangyang441106 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Hubei Technology Innovation Center for Advanced Composites Wuhan University of Technology Wuhan430070 China International School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China

This study investigates the microstructure, mechanical properties, and shape memory behavior of a series of (84-x) Cu-12Al-4Ni-xAg (x = 0, 4, 8, 12 wt%) alloys with varying Ag contents. The alloys predominantly exhibited martensitic phases: 18R and 2H, with the 18R phase becoming more prevalent as Ag was introduced. The formation of the Ag2Al phase and microstructural refinement contributed to significant improvements in mechanical properties. Notably, the alloy with 8 wt% Ag (x = 8) exhibited peak compressive strength of 947.1 MPa, the compressive strain of 14.1 %. Additionally, the inclusion of Ag enhanced the shape memory effect of the alloys, with the x = 8 alloy demonstrating a reversible strain of 4.7 % upon heating after an 8 % pre-strain. © 2025 Elsevier B.V.

关键词： Microhardness

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Crystallization Modulation and Holistic Passivation Enables Efficient Two‑Terminal Perovskite/CuIn(Ga)Se_(2)Tandem Solar Cells

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Nano-Micro Letters 2025年第1期17卷 205-215页

作者： Cong Geng Kuanxiang Zhang Changhua Wang Chung Hsien Wu Jiwen Jiang Fei Long Liyuan Han Qifeng Han Yi‑Bing Cheng Yong Peng State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070People’s Republic of China Triumph Photovoltaic Materials Co. Ltd.No.1001 Yannan AvenueHigh‑Tech Development DistrictBengbuAnhui 233000People’s Republic of China College of Materials Science and Engineering Guilin University of TechnologyGuilin 541004People’s Republic of China State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China

Two-terminal(2-T)perovskite(PVK)/CuIn(Ga)Se_(2)(CIGS)tandem solar cells(TSCs)have been considered as an ideal tandem cell because of their best bandgap matching regarding to Shockley–Queisser(S–Q)***,the nature of the irregular rough morphology of commercial CIGS prevents people from improving tandem device *** this paper,D-homoserine lactone hydrochloride is proven to improve coverage of PVK materials on irregular rough CIGS surfaces and also passivate bulk defects by modulating the growth of PVK *** addition,the minority carriers near the PVK/C60 interface and the incompletely passivated trap states caused interface recombination.A surface reconstruction with 2-thiopheneethylammonium iodide and N,N-dimethylformamide assisted passivates the defect sites located at the surface and grain ***,LiF is used to create this field effect,repelling hole carriers away from the PVK and C60 interface and thus reducing *** a result,a 2-T PVK/CIGS tandem yielded a power conversion efficiency of 24.6%(0.16 cm^(2)),one of the highest results for 2-T PVK/CIGS TSCs to our *** validation underscores the potential of our methodology in achieving superior performance in PVK/CIGS tandem solar cells.

关键词： PVK/CIGS TSCs Irregular rough surfaces Modulating the growth PVK/C60 interface recombination

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Spall Strength and the Study of Damage Mechanism of Pure-Al in Different Wave Systems

SSRN

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SSRN 2025年

作者： Zhang, Yang Sun, Yi Li, Peibo Zhang, Kaichang Zhao, GuiNan Luo, Guoqiang Shen, Qiang Hubei Longzhong Laboratory Hubei Xiangyang441000 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Qingdao University of Science and Technology China

To study the structural damage behavior of pure-Al under various shock wave profiles, this paper investigates the target using a light gas gun-driven density gradient material and a homogeneous material. It also conducts structural characterization and failure analysis of the postmortem target. The results indicate that spall strength increases with peak stress. At a strain rate of 103 s−1, the spall strength of the gradient material (approximately 0.502 GPa) is significantly higher than that of the homogeneous material (about 0.157 GPa). This difference is attributed to the temperature softening effect in the homogeneous material. The peak stress of the gradient material impacting pure Al is higher, leading to an increase in small-angle grain boundaries and a phenomenon of grain refinement. Here, the structural damage is primarily influenced by stress effects, resulting in higher spall strength. In contrast, the homogeneous material impacting pure Al exhibits a notable temperature rise, which significantly affects structural damage, making it more susceptible to the formation of pores and cracks, thus resulting in lower spall strength. Furthermore, there are differences in pore morphology under various wave regimes: the pores in the gradient material are elliptical, with the long axis perpendicular to the impact direction, while the pores in the homogeneous material are irregularly shaped. Additionally, the gradient material exhibits multiple spallation surfaces, whereas the homogeneous material shows only one spallation surface. By explaining the damage mechanisms of pure Al under different wave systems, this study aims to provide insights and guidance on the spallation behavior of aluminum matrix composites under complex conditions. © 2025, The Authors. All rights reserved.

关键词： Grain refinement

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A machine learning approach to predict coefficient of friction of laser cladding high-entropy alloy coatings

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Journal of materials Research and technology 2025年 36卷 8240-8253页

作者： Yawen Pan Bingquan Xu Junjun Wang Jian Peng Zhigang Xu Qiang Shen Chuanbin Wang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology 122 Luoshi Road Wuhan 430070 PR China Hubei Key Laboratory of Plasma Chemistry and Advanced Materials Engineering Research Center of Environmental Materials and Membrane Technology of Hubei Province Wuhan Institute of Technology Wuhan 430074 PR China Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory Chaozhou Guangdong 521000 PR China

Traditional method for evaluating the coefficient of friction (COF) of laser cladding high-entropy alloy (HEA) coatings, relying on extensive experiments, is costly and inefficient. To address these limitations, this study proposed an efficient machine learning (ML) approach. Random Forest, Gradient Boosting Decision Tree, and XGBoost models were developed as base models to predict the COF of HEA coatings. Feature engineering and a voting strategy were employed to enhance model accuracy and generalization ability, yielding substantial improvements in performance. The optimal model achieved a testing R 2 of 0.97. A satisfactory agreement was achieved between the predicted COFs and the experimental measurements as well as their trend. Additionally, the impact of each feature on the COF was clarified using SHAP (Shapley Additive Explanations). The results indicate that this ML approach is a promising tool for predicting the COF of HEA coatings and can serve as a valuable aid in the design and optimization of coatings.

关键词： High-entropy alloy coating Laser cladding Machine learning Tribology Wear Coefficient of friction

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