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Biomimetic brain-like nanostructures for solid polymer electrolytes with fast ion transport

Science China materials 2022年第6期65卷 1476-1484页

作者： Ahmed Eissa Abdelmaoula Lulu Du Lin Xu Yu Cheng Amir AMahdy Muhammad Tahir Ziang Liu Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200China Mining and Metallurgical Department Faculty of EngineeringAl-Azhar UniversityCairo 11884Egypt

The intrinsic drawbacks of electrolytes and the growth of lithium dendrites limit the development of commercial lithium *** address the aforementioned challenges,a novel biomimetic brain-like nanostructure(BBLN)solid polymer electrolyte was created by manipulating the shape of the incorporated *** designed BBLN solid polymer electrolyte was created by incorporating spherical core-shell(UIO-66@67)fillers into polymer electrolyte,which is significantly different from traditional polymer-based composite ***-66@67 spherical nanoparticles are highly favorable to eliminating polymer electrolyte stress and deformation during solidification,indicating a great potential for fabricating highly uniform BBLN solid polymer electrolytes with a substantial number of continuous ***,spherical nanoparticles can significantly reduce the crystalline structure of polymer electrolytes,improving polymer chain segmental movement and providing continuous pathways for rapid ion *** a result,BBLN solid polymer electrolyte shows excellent ionic conductivity(9.2×10^(−4)S cm^(−1)),a high lithium transference number(0.74),and outstanding cycle stability against lithium electrodes over 6500 h at room *** concept of biomimetic brain-like nanostructures in this work demonstrates a novel strategy to enhance ion transport in polymerbased electrolytes for solid-state batteries.

关键词： brain structure spherical nanoparticles continuous interphase nanophase separation MOF-in-MOF

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S-scheme photocatalyst Bi2O3/TiO2 nanofiber with improved photocatalytic performance

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Journal of materials Science & technology 2020年第17期52卷 145-151页

作者： Rongan He Haijuan Liu Huimin Liu Difa Xu Liuyang Zhang Hunan Province Key Laboratory of Applied Environmental Photocatalysis Changsha UniversityChangsha 410022China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

In this study,a hierarchical Bi2O3/TiO2 fibrous composite was in-situ fabricated on an electrospun TiO2 nanofiber at ambient *** the Bi2O3/TiO2 composite,S-scheme electron migration occurred between Bi2O3 and *** the photocatalytic degradation of phenol under simulated sunlight,the asprepared Bi2O3/TiO2 nanofibers considerably outperformed Bi2O3 nanoparticles and TiO2 *** improvement is contributed by maintaining and effectively utilizing the useful carriers and consuming the useless holes and electrons,realized by the S-scheme heterojunction and hierarchical *** study also provides an alternative design fashion for photocatalysts.

关键词： Electrospinning Bismuth Fiber In-situ synthesis

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Predictive Damage Evolution and Fracture Behavior in High-Carbon Steel Via Multiscale Simulation and Experiments

SSRN

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SSRN 2024年

作者： Wang, Huiling Wang, Feng Qian, Dongsheng Dong, Zhaohua Tian, Han Hua, Lin Chen, Jiancheng School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Hubei Engineering Research Center for Green Precision Material Forming Wuhan430070 China Hubei Key Laboratory of Advanced Technology for Automotive Components Wuhan430070 China

High-carbon steel consisting of soft ferrite and hard cementite is susceptible to micro-defects owing to the mismatched deformation between the ferrite and cementite during cold forming, which seriously deteriorates the fatigue life. However, the investigation of the damage and failure behavior in high-carbon steel during cold deformation remains largely undisclosed, which hinders further control of the microstructure and forming process. The current work investigates the damage evolution and fracture behavior related to the microstructural characteristics of spheroidized ferrite-cementite steel. A multiscale modeling framework is presented by coupling macroscale finite element (FE) simulation, mesoscale representative volume element (RVE) modeling, and nanoscale molecular dynamics (MD) simulation to analyze largescale plastic deformation and damage characteristics. In particular, the Gurson-Tvergaard-Needleman (GTN) damage model is used to predict the fracture behavior of the macroscale FE model. The uncoupled Rice-Tracy law and the maximum principal stress criterion are utilized to simulate the mesoscale damage behavior. The cohesive zone model (CZM) in the form of B-K constitutive law is utilized to simulate the interfacial decohesion. The GTN model parameters are evaluated by the response surface method (RSM). The nanoscale molecular dynamics simulations are conducted to obtain matrix-particle interface strength properties under the mixed loading. The mechanical property of ferrite phase was calibrated by the inverse analysis method based on genetic algorithm (GA). The failure model parameters of two phases are identified by DIC test results. The macroscale simulations accurately predict damage and fracture behavior of high-carbon steel. The results show that the voids preferentially initiate at the two-phase interface with the smallest spacing between particles. Subsequently, voids grow along the boundary of the cementite particles and then coalesce to form a c

关键词： Ferrite

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Prediction of Two-Dimensional Semiconductor Compounds Man3 (M = V, Nb, Ta;a = Si, Ge) from Ma2n4 Family

SSRN

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SSRN 2023年

作者： Zhu, Ying Li, Pei-Yue Yuan, Jun-Hui Zhang, Pan Wang, Jiafu School of Science Wuhan University of Technology Wuhan430070 China School of Integrated Circuits Peking University Beijing100871 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing

Two-dimensional (2D) materials, renowned for their excellent structural and electronic properties, are considered to be the best candidates in the post-Moore era. Herein, we successfully designed 22 stable 2D monolayers with built-in electric fields based on the design principle of valence charge balance and layer stacking. The predicted novel monolayers, i.e., 2D MAN3, originates from the MA2N4 (M = V, Nb, Ta;A = Si, Ge), which has been widely studied in recent years. All these monolayers exhibit semiconductor properties, covering a wide range band gaps from 1.23 to 3.14 eV, with half displaying a direct band feature. Based on the modified carrier mobility calculation method, we found that the MAN3 monolayer shows remarkable hole mobility, reaching up to 104 cm2V-1s-1. Owing to their wide range of band gaps, 2D MAN3 has excellent optical absorption in the infrared, visible, and ultraviolet regions. Additionally, due to their non-centrosymmetric structure, these monolayers possess intrinsic built-in electric fields that can effectively adjust the band edges, which not only facilitates the construction of different types of interface contacts, but also satisfies the requirements of photovoltaic water splitting. Our work not only significantly expands the MAN3 family, but also provides valuable insights for future research. © 2023, The Authors. All rights reserved.

关键词： Monolayers

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Effect of Ni content in Cu_(1-x)Ni_(x) coating on microstructure evolution and mechanical properties of W/Mo joint via low-temperature diffusion bonding

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Journal of materials Science & technology 2020年第19期54卷 171-180页

作者： Mei Rao Guoqiang Luo Jian Zhang Yiyu Wang Qiang Shen Lianmeng Zhang State Key Lab of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China Materials Science and Technology Division Oak Ridge National LaboratoryOak RidgeTN37831-6064USA

The 93 W and Mo1 refractory metals were bonded with different Cu_(1-x)Ni_(x) coating interlayers of various Ni content using plasma-activated sintering at 700℃.The effects of the Ni content in the Cu_(1-x)Ni_(x) coating interlayer on the interfacial microstructure evolution and mechanical properties of the W/Mo joints were *** maximum average shear strength of the W/Mo joint was 316.5 MPa when the Ni content of the Cu_(1-x)Ni_(x) coating interlayer was 25%.When the Ni content of the Cu_(1-x)Ni_(x) coating interlayer was below 50%,the atomic diffusion at the W/Mo joint interface was adequate without the formation of intermetallic compounds,as demonstrated by the High Resolution Transmission Electron Microscope analyses of the *** presence of Ni in Cu_(1-x)Ni_(x) promoted diffusion bonding at the interface,which contributed to the high mechanical properties of the W/Mo *** an increase in the Ni content of the Cu_(1-x)Ni_(x) coating interlayer,the Mo Ni intermetallic compound(IMC)nucleated and grew at the Cu1-xNix coating/Mo1 *** the Ni content of the Cu_(1-x)Ni_(x) coating interlayer was above 50%,the generation of a brittle Mo Ni IMC weakened the shear strength of the W/Mo joint dramatically.

关键词： Refractory metal Cu_(1-x)Ni_(x)coating interlayer Solid solution MoNi IMC Microstructure Shear strength

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A review of CoSb_(3)-based skutterudite thermoelectric materials

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Journal of advanced Ceramics 2020年第6期9卷 647-673页

作者： Zhi-Yuan LIU Jiang-Long ZHU Xin TONG Shuo NIU Wen-Yu ZHAO School of Materials Science and Engineering Anhui University of TechnologyMaanshan 243002China Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials Ministry of EducationAnhui University of TechnologyMaanshan 243002China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

The binary skutterudite CoSb_(3) is a narrow bandgap semiconductor thermoelectric(TE)material with a relatively flat band structure and excellent electrical ***,thermal conductivity is very high because of the covalent bond between Co and Sb,resulting in a very low ZT ***,researchers have been trying to reduce its thermal conductivity by the different optimization *** addition,the synergistic optimization of the electrical and thermal transport parameters is also a key to improve the ZT value of CoSb_(3) material because the electrical and thermal transport parameters of TE materials are closely related to each other by the band structure and scattering *** review summarizes the main research progress in recent years to reduce the thermal conductivity of CoSb_(3)-based materials at atomic-molecular scale and nano-mesoscopic *** also provide a simple summary of achievements made in recent studies on the non-equilibrium preparation technologies of CoSb_(3)-based materials and synergistic optimization of the electrical and thermal transport *** addition,the research progress of CoSb_(3)-based TE devices in recent years is also briefly discussed.

关键词： skutterudite CoSb_(3)-based materials lattice thermal conductivity synergistic optimization thermoelectric properties thermoelectric devices

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Atomic defects,functional groups and properties in MXenes

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Chinese Chemical Letters 2021年第1期32卷 339-344页

作者： Wenjun Cui Zhi-Yi Hu Raymond RUnocic Gustaaf Van Tendeloo Xiahan Sang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China NRC(Nanostructure Research Centre) Wuhan University of TechnologyWuhan 430070China Center for Nanophase Materials Sciences Oak Ridge National LaboratoryOak RidgeTN 37831United States EMAT(Electron Microscopy for Materials Science) University of AntwerpAntwerpB-2020Belgium

MXenes,a new family of functional two-dimensional(2 D) materials,have shown great potential for an extensive variety of applications within the last *** defects and functional groups in MXenes are known to have a tremendous influence on the functional *** this review,we focus on recent progress in the characterization of atomic defects and functional group chemistry in MXenes,and how to control them to directly influence various properties(e.g.,electron transport,Li^(+) adsorption,hydrogen evolution reaction(HER) activity,and magnetism) of 2 D MXenes *** structural transformations such as oxidation and growth induced by atomic defects in MXenes are also *** review thus provides perspectives on property optimization through atomic defect engineering,and bottom-up synthesis methods based on defect-assisted homoepitaxial growth of MXenes.

关键词： MXenes Atomic defects Surface functional groups Electron microscopy Functional properties

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Simpler and Greener Preparation of An In-Situ Polymerized Polyimide Anode for Lithium Ion Batteries

SSRN

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SSRN 2023年

作者： Zhang, Qiuyitong Xu, Yuexin Lv, Ning Li, Hanyang Wei, Zijie Tiana, Tian Wang, Yadong Tang, Haolin State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen Valley Foshan528200 China

A simplified and greener procedure for in-situ obtaining polyimide anode materials for lithium-ion battery electrodes is developed. The combined polyimide material synthesis and electrode preparation reduces the number of processing steps and treatment duration and decreases the energy required for heat treatment, solvent evaporation, and organic solvent use. More importantly, polymerization in situ on the electrode surface render the polyimide particles a sea urchin-like structure, leading to fast electrochemical kinetics, and significant improvement in discharge capacity and cycling performance compared with materials obtained using traditional procedures. Specific capacities of 1870 mAh g-1 and 2277 mAh g-1 at 30℃ and 60℃, respectively, are obtained. A capacity of 1774 mAh g-1 is retained after 500 cycles at high current density of 1000 mA g-1 at 60℃. This new preparation process not only simplifies the preparation process and makes it greener, but also significantly improves the battery performance, providing new possibilities for the preparation of high-performance low-cost lithium-ion battery electrodes. © 2023, The Authors. All rights reserved.

关键词： Solvents

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Tellurium intervened Fe-N codoped carbon for improved oxygen reduction reaction and high-performance Zn-air batteries

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Journal of materials Science & technology 2023年第6期137卷 215-222页

作者： Rui Wang Zihan Meng Xuemin Yan Tian Tian Ming Lei Rami Adel Pashameah Hala MAbo-Dief Hassan Algadi Nina Huang Zhanhu Guo Haolin Tang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200China College of Chemistry and Environmental Engineering Yangtze UniversityJingzhou 434023China State Key Laboratory of Information Photonics and Optical Communications Beijing University of Posts and TelecommunicationsBeijing 100876China Department of Chemistry Faculty of Applied ScienceUmm Al-Qura UniversityMakkah 24230Saudi Arabia Department of Science and Technology University College-RanyahTaif UniversityP.O.Box 11099Taif 21944Saudi Arabia Department of Electrical Engineering Faculty of EngineeringNajran UniversityP.O.Box 1988Najran 11001Saudi Arabia College of Materials Science and Engineering Taiyuan University of Science and TechnologyTaiyuan 030024China Department of Chemical and Bimolecular Engineering Integrated Composites Laboratory(ICL)University of TennesseeKnoxvilleTN 37996USA Guangdong Hydrogen Energy Institute of WHUT Xianhu Hydrogen ValleyFoshan 528200China

Pyrolysis-acquired iron and nitrogen codoped carbon(Fe-N-C)has been comprehensively investigated for its promising oxygen reduction reaction(ORR)catalytic performance and structural *** modification of non-metal elements with larger atomic radius and the corresponding intrinsic microstructure-property relations are rarely *** this study,tellurium(Te)intervened Fe-N-C was prepared by micelles-induced polymerization with Te nanowires as an in-situ intervening *** out-plane bonding of Te with Fe induced the increase of both N content and proportion of pyridinic N on the material surface,thus improving the ORR catalytic *** assembled Zn-air battery demonstrated a maximum power density of 250 mW/cm^(2)and excellent rate capability under various discharge current densities,which was much better than the Pt/***,the current work demonstrates a novel Te/Fe-N-C material and reveals an original Te intervened Fe-N-C strategy and N reconfiguration mechanism,which is of great significance for the design of key materials in energy-related fields.

关键词： Te/Fe-N-C Assembly ORR Electrocatalysis Zn-air battery

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Carbon quantum dots modified TiO_(2) composites for hydrogen production and selective glucose photoreforming

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Journal of Energy Chemistry 2022年第1期31卷 201-208,I0006页

作者： Heng Zhao Xinti Yu Chao-Fan Li Wenbei Yu Aiguo Wang Zhi-Yi Hu Steve Larter Yu Li Md Golam Kibria Jinguang Hu Department of Chemical and Petroleum Engineering University of Calgary2500 University DriveNWCalgaryAlberta T2N 1N4Canada State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina Nanostructure Research Centre Wuhan University of Technology.Wuhan 430070Hubei.China Department of Geosciences University of Calgary2500 University DriveNWCalgaryAlberta T2N 1N4Canada

Lignocellulosic biomass photoreforming is a promising and alternative strategy for both sustainable H_(2) production and biomass valorization with infinite solar ***,harsh reaction conditions(high alkalinity or toxic organic solvents),with low biomass conversion and selectivity are often reported in *** this work,we report glucose photoreforming for coproduction of H_(2) and arabinose with improved selectivity under neutral condition using carbon quantum dots(CQDs)modified TiO_(2) *** show that the conventional CQDs fabricated by a facile one-step hydrothermal process could be endowed with novel color changing property,due to the particle aggregation under the regulation of incident *** as-fabricated CQDs/TiO_(2) composites with certain colored CQDs could greatly improve glucose to arabinose conversion selectivity(-75%)together with efficient hydrogen evolution(up to 2.43 mmolh^(-1)g^(-1))in *** arabinose is produced via the direct C1-C2 α-scissions mechanism with reactive oxygen species of·O_(2)^(-) and·OH,as evidenced by ^(13)C labeled glucose and the electron spin-resonance(ESR)studies,*** work not only sheds new lights on CQDs assisted photobiorefinery for biomass valorization and H_(2) coproduction,but also opens the door for rationale design of different colored CQDs and their potential applications for solar energy utilization in the noble-metal-free system.

关键词： CQDs Size regulation Hydrogen production Glucose photoreforming Arabinose

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