Monodispersed mesoporous silicon dioxide microspheres were prepared by polymerization-induced colloid aggregation (PICA) method and calcined at 850°C. The prepared samples were characterized with scanning electro...
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Monodispersed mesoporous silicon dioxide microspheres were prepared by polymerization-induced colloid aggregation (PICA) method and calcined at 850°C. The prepared samples were characterized with scanning electron microscopy (SEM), thermogravimetry (TG) and BET surface areas. The results showed that the obtained SiO2 microspheres had an average diameter of about 2.0 μm, a surface area of 253.3 m2g-1, an average pore volume of 0.62 mLg-1, and an average pore diameter of 7.9 nm. The formation mechanism of SiO2 spherical particles was discussed.
The functionally graded thermal barrier coating (TBC) serves in high temperature and/or high temperature gradient environment for a long time. According to the experimental and theoretical research, in the metal subst...
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ISBN:
(纸本)0878499709
The functionally graded thermal barrier coating (TBC) serves in high temperature and/or high temperature gradient environment for a long time. According to the experimental and theoretical research, in the metal substrate and the metal-rich interlayer creep deformation will appear under high temperature environment. In order to design and optimize the compositional distribution of FGM, it is necessary to analyze the stress and strain responses taking into account the creep phenomenon of the materials. In this article, the thermo-mechanical responses of ceramic/metal functionally graded TBC in work environment are analyzed by a finite element method. The creep phenomenon of the metal and the interlayers are taken into account. The numerical results indicate that the creep behavior of all interlayers, even for the ceramic-rich interlayer, cannot be neglected in analysis. It is suggested that the creep phenomenon of the material is important in the functionally graded TBC systems.
In the present study, Fe and Si powders (3:1 in atomic proportion) were mechanical alloyed and subsequently treated under different anneal conditions. The changes of phase composition and structure during the mechanic...
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In the present study, Fe and Si powders (3:1 in atomic proportion) were mechanical alloyed and subsequently treated under different anneal conditions. The changes of phase composition and structure during the mechanical alloying and following heat treatment processes were mainly studied. The results showed that the XRD peaks of Fe were gradually broadened and weakened with the increase of the milling time associated with the shifting from low angles to high angles, and the main phase changed into α-Fe (Si) solid solution after milling for 20h. When the product was heat treated below 400°C, the main phase remained α-Fe (Si). While it was treated above 400°C, ordered Fe3Si phase was found and the XRD peaks of Fe3Si became sharper with the further increase of the temperature.
The fracture of the functionally graded thermal barrier coating (TBC) under the thermal loads is a key for the engineering application of this kind of materials. In the previous studies, the functionally graded TBC is...
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ISBN:
(纸本)0878499709
The fracture of the functionally graded thermal barrier coating (TBC) under the thermal loads is a key for the engineering application of this kind of materials. In the previous studies, the functionally graded TBC is usually simplified into a laminate by homogenizing the material of each interlayer as an isotropic layer. Nevertheless, this method is a macro equivalent method, which neglected the microstructure characteristics of materials. In this paper, the computational micromechanics method (CMM) is employed to study the fracture problem of the functionally graded TBC with the interface crack. Essentially, CMM is a finite element analytical method based on the real microstructure of materials, which combines the digital image processing technique, the auto mesh generation technique with the finite element method. Firstly, the microstructure photos of the functionally graded TBC are required. Secondly, the digital image processing technique and the auto mesh generation technique are used to construct the finite element model. Finally, the finite element method is utilized for the fracture analysis of the functionally graded TBC under the thermal shock loads. Moreover, the problem is also analyzed using the macro equivalent method and the results from the two methods are compared. The temperature field obtained using CMM is basically consistent with the one obtained from the macro equivalent method and the influences of the interface crack on the temperature fields are limited in a local region. But results of the driving forces for the crack propagation, J-integrals, from the two methods are quite different. Comparing with the CMM results, J-integrals from the macro equivalent method are smaller. It means that the macro equivalent method tends to underestimate the driving force of the interface crack. On the other hand, the prediction of the critical location of the interface crack from the two methods is also different. Since the influence of the microstructure
作者：
王友法Biomedical Materials and Engineering Research Center
Wuhan University of TechnologyWuhan 430070ChinaState Key Lab of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 China
Inorganic nanoparticles were used to treat cancer cells us well as normal cells. Ca9Sr（ PO4）6（OH）2 nanopartides were prepared through homogeneous precipitation method. Strontium hydroxide, calcium hydroxide solat...
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Inorganic nanoparticles were used to treat cancer cells us well as normal cells. Ca9Sr（ PO4）6（OH）2 nanopartides were prepared through homogeneous precipitation method. Strontium hydroxide, calcium hydroxide solation and monocalcium phosphate were used as initial materials. The strontium-doped hydroxyapatite nanoparticles were characterized by XRD, PCS and AFM. The nanoparticles were applied to interact with human bepatocellular carcinoma cells Bel-7402 and nornud liver cells L-02. Experimental results revealed that nano strontium-strontium apatiw has different bioeffects on proliferation of these two kinds of cells.
The HAP nanoparticles were synthesized with a chemical co-precipitation method. It was monodispersed in needle shape, Its average diameter was 30 nm and length was 70 nm. Human liver cancer cells and normal hepatic ce...
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The HAP nanoparticles were synthesized with a chemical co-precipitation method. It was monodispersed in needle shape, Its average diameter was 30 nm and length was 70 nm. Human liver cancer cells and normal hepatic cells were treated by hydroxyapatite nanopartides. SR-XRF analysis was used to detect the content variation of calcium and phosphor elements in cancer cells when the cells were treated by hydroxyapatite nanoparticles. It was introduced to reveal the anti-cancer mechanism of HAP nanoparticles. Experiments verified that the contents of calcium and phosphor elements in hepatocelltdar carcinoma had been obviously increased after the cells were treated by hydroxyapatite nanoparticles. And the contents increased with hydroxyapatite concentration and treatment time increasing. The Ca/P molar ratio in treated cell was different from both that in hydroxyapatite and that in untreated cancer cell. Apatite nanoparticles evidently altered the calcium and phosphor environmeats in treated hepatocellalar carcinoma cells. That finally halted the proliferation of carcinoma cells.
Two types of electromagnetic edge dams were analyzed by using finite element method in present paper. The magnetic vector potential method and edge element method were used. The distributions of the magnetic field, th...
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Two types of electromagnetic edge dams were analyzed by using finite element method in present paper. The magnetic vector potential method and edge element method were used. The distributions of the magnetic field, the eddy current intensity and the magnetic force were obtained from the computing. The differences in these fields were explained according to the two types of electromagnetic dam, and characters of their application in twin roll casting were also discussed.
This paper studies the optimization problem of composition distribution of functionally graded material (FGM) coating subjected to steady heat flux loading. The investigation object of the paper is an infinite plate s...
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ISBN:
(纸本)0878499709
This paper studies the optimization problem of composition distribution of functionally graded material (FGM) coating subjected to steady heat flux loading. The investigation object of the paper is an infinite plate substrate with FGM coating in the surface. The materials are heated at the ceramic surface (upside) with a steady high-intensity heat flux input, and cooled at the metal surface (underside) with flowing liquid nitrogen. The thermal stress distribution and the temperature distribution are obtained by formulation. For optimization, the design variables are the thickness of each interlayer and the volume fraction distribution of the coating. The objective function is the danger coefficient and the restricted condition is the total thickness of FGM plate and heat insulation coefficient. In the paper, three different optimization schemes are considered and compared. The μGA and related parameters are discussed in detail. Optimizing the thermal stress distribution and minimizing the danger coefficient are carried out by μGA. The optimization results of composition distribution are gained, and the results show the optimum composition distribution can distinctly reduce the danger coefficient.
A new approach to produce superfine WC-Co powder by direct reduction and carbonization is proposed. Water-soluble salts containing W and Co were used as raw materials. Tungsten and cobalt oxide powder （CoWO4/WO3） wa...
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A new approach to produce superfine WC-Co powder by direct reduction and carbonization is proposed. Water-soluble salts containing W and Co were used as raw materials. Tungsten and cobalt oxide powder （CoWO4/WO3） was first formed by a spray-pyrolysis technique, which was then mixed with carbon black and converted to WC-Co composite powder at 950℃ for 4 h in N2 atmosphere. The resulting powder has a particle size of 100-300 nm.
Ti/Al 2O 3 composite with improved mechanical properties was synthesized by th e spark plasma sintering. The effect of Nb on the microstructure of the composit e was analyzed by TEM, SEM and so on. The experimental ...
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Ti/Al 2O 3 composite with improved mechanical properties was synthesized by th e spark plasma sintering. The effect of Nb on the microstructure of the composit e was analyzed by TEM, SEM and so on. The experimental results indicate that the bending strength, fracture toughness, micro-hardness and relative density of t he composite are 897.29MPa, 17.38MPa·m 1/2, 17.13GPa and 99.24% respec tively when adding 1.5vol%Nb. The bending strength is improved by reason of form ing dislocation ring and transfering fracture mode from intergranular to mixture fracture of intergranular and transgranular. The crack propagating is mainly th e deflection bridging. It indicates a reduction of crack driving force and an in crease in crack growth resistance,which results in toughness enhanced.
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