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Transactions of Nonferrous Metals Society of China 2022年第3期32卷 750-764页

作者： Ming-ye DONG Yue ZHAO Quan LI Fu-de WANG Ai-ping WU Department of Mechanical Engineering Tsinghua UniversityBeijing 100084China Key Laboratory for Advanced Materials Processing Technology Ministry of EducationTsinghua UniversityBeijing 100084China Capital Aerospace Machinery Corporation Limited Beijing 100076China State Key Laboratory of Tribology Tsinghua UniversityBeijing 100084China

Wall structures were made by cold metal transfer-based wire and arc additive manufacturing using two kinds of ER2319 welding wires with and without Cd elements. T6 heat treatment was used to improve mechanical properties of these wall structures. Due to the higher vacancy binding energy of Cd, Cd-vacancy clusters are formed in the aging process and provide a large number of nucleation locations for θ′ phases. The higher diffusion coefficient of the Cd-vacancy cluster and the lower interfacial energy of θ′ phase lead to the formation of dense θ′ phases in the heat-treated α(Al). According to the strengthening model, after adding Cd in ER2319 welding wires, the yield strength increases by 43 MPa in the building direction of the heat-treated wall structures.

关键词： Cd welding wire wire and arc additive manufacturing Al-Cu alloy

Prediction of Primary Dendrite Arm Spacing in Pulsed Laser Surface Melted Single Crystal Superalloy

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Acta Metallurgica Sinica(English Letters) 2021年第4期34卷 485-494页

作者： Shiwei Ci Jingjing Liang Jinguo Li Haiwei Wang Yizhou Zhou Xiaofeng Sun Hongwei Zhang Yutian Ding Xin Zhou Shi-Changxu Innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang110016China School of Materials Science and Engineering University of Science and Technology of ChinaShenyang110016China Space Manufacturing Technology(CAS Key Lab) Beijing100094China Taizhou Xinma Technology Industry Develepment Co.Ltd Taizhou318000China State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metal Lanzhou University of Technology287 Langongping RoadLanzhou730000China Science and Technology On Plasma Dynamics Laboratory Air Force Engineering UniversityXi’an710000China

Primary dendritic arm spacing(PDAS)is an important microstructure feature of the nickel-base single crystal *** this paper,a numerical model predicting the PDAS evolution with additive manufacturing parameters using pulsed laser is established,which combines the theoretical PDAS models with the temperature field calculation model during pulsed laser *** on this model,processing maps that related process parameters to the evolution of PDAS are *** obtain more accurate prediction model,the parameters of different solidification conditions,G^(-0.5)V^(-0.25) and G^(-0.5)V^(-0.25),are selected to calculate *** simulation results show that the PDAS increases as the arise of P and *** processmgPDAS map can accurately predict the evolution of PDAS with pulsed laser process parameters,which is well in accordance with the experimental ***,the PDAS values calculated by the G^(-0.5)V^(-0.25) are more in line with the experimental results than those calculated by the G^(-0.5)V^(-0.25).

关键词： Additive manufacturing Nickel-base superalloy Single crystal Pulsed laser Primary dendritic arm spacing

Solid-state Transformation Composite Filler: A New Strategy to Strengthen Ceramic/Metal Joint

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SSRN 2024年

作者： Nai, Xin Zhao, Shuai Wang, Peng Chen, Haiyan Wang, Pengcheng Song, Xiaoguo Vairis, Achilles Li, Wenya Shaanxi Key Laboratory of Friction Welding Technologies State Key Laboratory of Solidification Processing Northwestern Polytechnical University Xi’an710072 China State Key Laboratory of Advanced Welding and Joining Harbin Institute of Technology Harbin150001 China Mechanical Engineering Department University of West Attica Athens12243 Greece School of Materials Science and Engineering Singapore

Residual stress is the main hindrance to achieve a robust ceramic/metal brazed joint. In this study, yttria stabilized zirconia (YSZ) particles was fabricated into solid-state transformation composite filler, which was proposed as a new strategy to strengthen Ti3SiC2/Cu brazed joint. After detailed characterization conducted on YSZ particles and brazed joint, the abnormal expansion properties of YSZ and its strengthening brazed joint mechanism were clarified. The content of Y2O3 in YSZ had significant effects on the phase transformation of ZrO2 from tetragonal to monoclinic. When 3 mol.% Y2O3 was added, the maximum phase transformation occurred at about 500 ◦C, half of brazing temperature, during the cooling process. The phase transformation of ZrO2 effectively released residual stress in the joint, which was induced by both temperature changes and residual stress. The abnormal volume expansion during phase transformation decreased the thermal mismatch of brazed joint further to strengthen brazed joint. © 2024, The Authors. All rights reserved.

关键词： Brazing

Structure engineering for organic ammonium ion batteries: A controllable distribution of Cu atoms in Mn-based Prussian blue analogues

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Journal of Power Sources 2025年 653卷

作者： Haode Zhang Bingling Shang Xinlei Tang Zhiqing Wang Shan Hu Wen Chen State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology Wuhan 430070 China

Ammonium ion batteries (AIBs) attract extensive attention owing to the abundant resources, eco-friendly and high safety. Multivalent Prussian blue analogues (PBAs), characterized by multi-electron transfer and high operating voltage, are considered as promising cathodes for AIBs. However, their structural stability is compromised by irreversible structural evolution and metal ion dissolution. Herein, a structure engineering strategy is proposed to boost NH 4 + ion storage by regulating the distribution of Cu atoms in Mn-based PBAs. Cu atoms not only enrich on the surface to form a uniform layer but are doped inside the Mn-based PBAs. The resulting PBAs (noted as Cu x Mn 1-x HCF) with an optimal x value of 0.15, deliver a stable capacity of 110.1 mAh g −1 at 50 mA g −1 and an exceptional capacity retention of 91 % over 4000 cycles at 200 mA g −1 . Ex-situ characterizations and density functional theory (DFT) calculations reveal that the controllable distribution of Cu atoms significantly enhances the structural stability and suppresses the dissolution of Mn atoms. Notably, this strategy can be extended to other PBAs materials. We believe that this work advances the development of high-performance cathode materials for AIBs.

关键词：

synthesis of Cr_2AlC from Elemental Powders with Modified Pressureless Spark Plasma Sintering

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Journal of Wuhan University of technology(materials Science) 2019年第2期34卷 287-292页

作者：葛梦妮 WANG Xiaofan LI Gaiye LU Chen 张建峰 TU Rong College of Mechanics and Materials Hohai University State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology

We introduced a modified pressureless sintering strategy by SPS with a new T-shape die and tapered punches, which helps the evaporation of melted Al and reduces the sample sticking with the inner wall of the die. Thus, the die breaking risk in the sintering process or the de-molding process is avoided at all. At a low temperature and short holding time, a high purity of Cr_2 AlC was obtained in this SPS process from the optimization of different molar ratios of raw materials. Simultaneously, the high porosity of the as-obtained sample was also a distinguishing feature worth noticing. The reaction mechanism for this process was also discussed in detail. This study presented a new venue for future development of high purity "MAX" materials and others related materials by a modified pressureless sintering strategy.

关键词： pressureless spark plasma sintering Cr2AlC reaction mechanism

Operando Selenium Treatment Towards Enhanced Cyclic Stability for Single-Crystal Ni-Rich Cathode at Ultra-High Voltage of 4.7 V

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SSRN 2023年

作者： Zhang, Zhi Ding, Xiang He, Xinyou Gong, Yang Xiao, Biaobiao Shen, Jixue Ou, Xing Hunan Provincial Key Laboratory of Water Treatment Functional Materials Hunan Provincial Key Laboratory for Control Technology of Distributed Electric Propulsion Aircraf College of Chemistry and Materials Engineering Hunan University of Arts and Science Changde415000 China Engineering Research Center of the Ministry of Education for Advanced Battery Materials School of Metallurgy and Environment Central South University Changsha410083 China Institute of Advanced Battery Materials and Devices Faculty of Materials and Manufacturing Beijing University of Technology Beijing100124 China Tianmu Lake Institute of Advanced Energy Storage Technologies Co. Ltd Liyang213300 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China

Developing high-voltage (≥4.3 V vs Li/Li+) single-crystal Ni-rich LiNixCoyMn1-x-yO2 offers an enticing strategy to achieve high energy density for lithium-ion batteries. However, at high-voltage operation, the cathode will be vulnerable to induce the intrinsic Oα- (α 0.6Co0.1Mn0.3O2 (SC-NCM) cathode materials by introducing the surface Se element, exhibiting an "anti-aging" effect of inhibiting the escape of oxygen on SC-NCM particles during the ultra-high voltage (4.7 V) cycling. Both theoretical calculation and experimental results confirm that the outside-in nanostructure would substitute some mobile Oα- at the surface of highly charged SC-NCM particle, stabilizing the oxygen lattice and suppressing O2 release during long-term cycling. Meanwhile, the surface modification of thin Se layer will alleviate the parasitic reactions and improve the electronic conductivity. Under the synergistic strategy of surface modification and interface doping, the obtained SC-NCM exhibits boosted cyclic stability in coin half-cell and pouch full-cell simultaneously. Therefore, the reversible capacity of LiNi0.6Co0.1Mn0.3O2 at high voltage is competitive with comercial LiNixCoyMn1-x-yO2 (x ≥ 0.8), demonstrating more superior safety ability and cyclic property. It provides an effective approach for improving the long-term performance of Ni-rich cathode materials for practical application under ultra-high working voltage. © 2023, The Authors. All rights reserved.

关键词： Single crystals

In Situ Programming Acid-Base Pair Proton-Conductive Channels of Perfluorosulfonic Acid Membrane for Fuel Cells

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SSRN 2022年

作者： Zhang, Wenxing Zhao, Shengqiu Wang, Rui Zhang, Aojie Huang, Yi Tang, Haolin State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen Valley Foshan528200 China State Key Laboratory of Automotive Safety and Energy School of vehicle and Mobility Tsinghua University Beijing100084 China

The development of rapid and dependable proton transport channels is crucial for proton exchange membrane fuel cells (PEMFCs) operating in low humidity conditions. Herein, an NH-Zr framework rich in basic sites was constructed in situ in a perfluorosulfonic acid solution, and PFSA-NH-Zr hybrid proton exchange membranes were prepared. The introduced NH-Zr framework successfully induced proton conducting groups (-SO3H) reorganization along the NH-Zr framework, resulting in the formation of fast ion transport channels. Meanwhile, under low humidity, the acid-base pairs between N-H (N-H-Zr framework) and -SO3H (PFSA) promoted the protonation/deprotonation and the subsequent proton leap via the Grotthuss processes. Especially, the hybrid membrane PFSA-NH-Zr-1 with suitable NH-Zr content had a promising proton conductivity of 0.031 S/cm at 80°C, 40% RH, and 0.292 S/cm at 80°C, 100% RH, which were approximately 33% and 40% higher than the pristine PFSA membrane (0.023 S/cm and 0.209 S/cm), respectively. In addition, the maximum power density of the hybrid PEM was 0.726 W/cm2, which was nearly 20% higher than the pristine PFSA membrane (0.604 W/cm2) under 80°C, 40% RH. This work established a referable strategy for developing high-performance proton exchange membranes under low RH conditions. © 2022, The Authors. All rights reserved.

关键词： Proton conductivity

Improved nitrogen reduction electroactivity by unique MoS_(2)‐SnS_(2) heterogeneous nanoplates supported on poly(zwitterionic liquids)functionalized polypyrrole/graphene oxide

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Chinese Journal of Catalysis 2022年第5期43卷 1341-1350页

作者： Hui Mao Haoran Yang Jinchi Liu Shuai Zhang Daliang Liu Qiong Wu Wenping Sun Xi‐Ming Song Tianyi Ma Institute of Clean Energy Chemistry Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced MaterialsCollege of ChemistryLiaoning UniversityShenyang 110036LiaoningChina Centre for Translational Atomaterials Swinburne University of TechnologyHawthornVIC 3122Australia School of Materials Science and Engineering State Key Laboratory of Clean Energy UtilizationZhejiang UniversityHangzhou 310027ZhejiangChina

Unique MoS_(2)‐SnS_(2)heterogeneous nanoplates have successfully in‐situ grown on poly(3‐(1‐vinylimidazolium‐3‐yl)propane‐1‐sulfonate)functionalized polypyrrole/graphene oxide(PVIPS/PPy/GO).PVIPS can attract heptamolybdate ion(Mo7O246−)and Sn^(4+)as the precursors by the ion‐exchange,resulting in the simultaneous growth of 1T’‐MoS2 and the berndtite‐2T‐type hexagonal SnS_(2)by the interfacial induced effect of *** obtained MoS_(2)‐SnS_(2)/PVIPS/PPy/GO can serve as electrocatalysts,exhibiting good NRR performance by the synergistic *** semi‐conducting SnS_(2)would limit the surface electron accessibility for suppressing HER process of 1T’‐MoS_(2),while metallic 1T’‐MoS_(2)might efficiently improve the NRR electroactivity of SnS_(2)by the creation of Mo‐Sn‐Sn trimer catalytic ***,the irreversible crystal phase transition has taken place during the NRR *** 1T’‐MoS_(2)and SnS_(2)have electrochemically reacted with N_(2),and irreversibly converted into Mo^(2)N and SnxNz due to the formation of Mo−N and Sn−N bonding,meanwhile,partial SnS_(2) has been irreversibly evolved into SnS due to the reduction by the power source in the electrochemical *** would put forward a new design idea for optimizing the preparation method and electrocatalytic activity of transition metal dichalcogenides.

关键词： MoS_(2) SnS_(2) Poly(3‐(1‐vinylimidazolium‐3‐yl)propane‐1‐sulfonate)functionalized polypyrrole/graphene oxide Nitrogen reduction reaction Irreversible crystal phase transition

Operando Selenium Treatment Towards Enhanced Cyclic Stability for Single-Crystal Ni-Rich Cathode at Ultra-High Voltage of 4.7 V

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SSRN 2023年

作者： Zhang, Zhi Ding, Xiang He, Xinyou Gong, Yang Xiao, Biaobiao Shen, Jixue Ou, Xing Engineering Research Center The Ministry of Education for Advanced Battery Materials School of Metallurgy and Environment Central South University Changsha410083 China Hunan Provincial Key Laboratory of Water Treatment Functional Materials Hunan Provincial Key Laboratory for Control Technology of Distributed Electric Propulsion Aircraf College of Chemistry and Materials Engineering Hunan University of Arts and Science Changde415000 China Institute of Advanced Battery Materials and Devices Faculty of Materials and Manufacturing Beijing University of Technology Beijing100124 China Tianmu Lake Institute of Advanced Energy Storage Technologies Co. Ltd Liyang213300 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China

关键词： Single crystals

Tunable Interlayer Spacings Ti3c2tx Mxene@Ni for Enhanced Electromagnetic Microwave Absorption

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SSRN 2024年

作者： Song, Jingyu Shen, Yongqian Zhang, Guibin Sun, Mingxuan Han, Mengyao Du, Xueyan School of Materials Science & Engineering State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Lanzhou University of Technology Lanzhou730050 China Shouhang Hi-TechEnergy Technology Co. Ltd. Lanzhou730000 China

While two-dimensional lamellar materials, specifically Ti3C2Tx MXenes, have shown great promise as wave-absorbing materials, the precise design of interlayer spacing poses a persistent challenge. In this study, Ti3C2 layers with adjustable interlayer spacings were crafted using a straightforward molecular welding technique. Through the incorporation of Ni nanoparticles onto the Ti3C2 layers using a combination of simple mechanical stirring and carbonation reactions, we successfully developed MXene@Ni composites featuring a distinct lamellar structure. A uniform dispersion of Ni nanoparticles on the surface of the Ti3C2 nanosheets was found with some of the nanoparticles intercalated into the layers. The MXene@Ni composites exhibited a maximum reflection loss (RL) value of −42.3 dB at 12.3 GHz, accompanied by an impressive effective absorption bandwidth (EAB) of 5.6 GHz. This outstanding absorption performance could be attributed to various factors, including the dielectric loss of the Ti3C2 lamellae, reflections and scattering of multiphase heterostructures, the magnetic loss of the Ni nanoparticles, and their synergistic attenuation. Furthermore, Ni nanoparticles with high electrical conductivity induced vortex currents under the alternating influence of electromagnetic waves (EMWs), resulting in a substantial depletion. This study introduces an innovative approach for synthesizing MXene@Ni composites with tunable interlayer spacing, showing their potential for applications in microwave absorption (MA). © 2024, The Authors. All rights reserved.

关键词： Welding