The setting chemistry of glass ionomer cement was imestigated by using mechanical determination of compressive strength at predetermined intervals,and measurement of structure changes of correspondling fracture sample...
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The setting chemistry of glass ionomer cement was imestigated by using mechanical determination of compressive strength at predetermined intervals,and measurement of structure changes of correspondling fracture sample by means of IR spectra and differential scanning calorimetry（DSC）.Zinc polycarboxylate cement was used as a comparison *** compressive strength of glass ionomer cement（GIC） increases with *** spectra and DSC of corresponding fracture sample show the structure changes of the matrix and interface layer comprising of silica gel during the predetermined intervals ***,no significant changes occur in the zinc polycarxyolate *** the structure changes of the matrix and/or interface layer are responsible for compressive strength increasing with *** structure changes include the crosslink density,the ratio of complex form to ionic form,the content ratio of Al-PAA to Ca-PAA,the forming and maturing process of the interface layer comprising of silica gel.
Fe-6.5wt%Si composite compact was fabricated by spark plasma sintering(SPS).Mec hanical alloying(MA)was used to prepare Fe-Si composite *** composite p owders were sintered by SPS at elevsated temperature from 500℃ t...
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Fe-6.5wt%Si composite compact was fabricated by spark plasma sintering(SPS).Mec hanical alloying(MA)was used to prepare Fe-Si composite *** composite p owders were sintered by SPS at elevsated temperature from 500℃ to 700℃.The exp erimental results indicate that the non-equilibrium state of composite Fe-Si i s preserved in the *** density of the bulk rises with the increasing tem perature and there is no diffusion of silicon and iron in the interface.
Based on the single-chain structure model of magnetorheological fluids, a formu la for the calculation of shear stresses was established. The interaction force of two magnetic particles in an infinite single-chain wa...
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Based on the single-chain structure model of magnetorheological fluids, a formu la for the calculation of shear stresses was established. The interaction force of two magnetic particles in an infinite single-chain was deduced using a new theoretical model which is founded on Ampere' molecular curr ent hypothesis, dipole theory and Ampere' law. Furthermore, the resultant force on a particle was then deduced by taking into account of the action caused by al l the other particles in the single-chain. A predictive formula for shear stres ses was made corresponding to the case that MR fluids were sheared by a small an gle and the calculating results fit well on the order with the yield stresses of the commercial MR fluids.
The Ti2AlC-Ti3AlC2-Ti3SiC 2 composite was fabricated in Ti-Al-Si-C quaternary system by spark plasma sintering (SPS) method from elemental powders. IN the SPS process, the gas in the chamber is discharged out at a con...
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The Ti2AlC-Ti3AlC2-Ti3SiC 2 composite was fabricated in Ti-Al-Si-C quaternary system by spark plasma sintering (SPS) method from elemental powders. IN the SPS process, the gas in the chamber is discharged out at a constant rate. It was observed that pressure peaks appeared in both samples sintered at 1200 and 1300 °C. It was found that for the sample sintered at 1300 °C, pressure peak was more pronounced than that of sample sintered at 1200 °c, which indicates the evaporation of Al or Si is more serious in sample sintered at 1300 °C, leading to the formation of TiC and the disapperance of Ti2AlC.
With the preparation of organic-inorganic layered perovskite-type compounds (C4H9NH3)2MCl4 (M = Mn, Cu) in solutions, X-ray diffraction (XRD), scanning electron microscopy (SEM),thermal gravimetry (TG) and differentia...
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Polycrystalline samples of Sr4Nd2Ti 4Ta6O30 (SNTT) and Sr4Sm 2Ti4Ta6O30 (SSTT) were prepared using high temperature solid state reaction techniques. SNTT and SSTT showed room temperature dielectric constant of around ...
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Polycrystalline samples of Sr4Nd2Ti 4Ta6O30 (SNTT) and Sr4Sm 2Ti4Ta6O30 (SSTT) were prepared using high temperature solid state reaction techniques. SNTT and SSTT showed room temperature dielectric constant of around 225 and 220 at 1 MHz. SSTT belongs to ferroelectric phase of tungsten-bronze (TB) structure and underwent diffuse type of ferroelectric-paraelectric phase transition around 30°C. Low temperature dielectric constant observed in the ceramic sample indicates that it may have attractive benefits in electrooptic and infrared pyroelectric detector applications when grown in buck single crystal or thin film form.
In order to compare the spark plasma sintedng （SPS） process plus hot isostatic press （HIP） with vacuum sintedng plus HIP, an investigation was carried out on the topography, microstructure and gain size distributi...
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In order to compare the spark plasma sintedng （SPS） process plus hot isostatic press （HIP） with vacuum sintedng plus HIP, an investigation was carried out on the topography, microstructure and gain size distribution of nanocrystalline WC-10Co composite powder and the sintered specimens prepared by SPS plus HIP and by vacuum sintering plus HIP by means of atomic force microscopy （AFM）. The mechanical properties of the sintered specimens were also investigated. It is very easy to find cobalt lakes in the specimen prepared by vacuum sintering plus HIP process. But the microstructure of the specimen prepared by SPS plus HIP is more homogeneous, and the grain size is smaller than that prepared by vacuum sintering plus HIP. The WC-10Co ultrafine cemented carbide consolidated by SPS plus HIP can reach a relative density of 99.4%, and the transverse rupture strength （TRS） is higher than 3540 MPa, the Rockwell A hardness （HRA） is higher than 92.8, the average grain size is smaller than 300 nm, and the WC-10Co ultrafine cemented carbide with excellent properties is achieved. The specimen prepared by SPS with HIP has better properties and microstructure than that prepared by vacuum sintering with HIP.
Mass production of ZnO nanobelts and hexagonal nanorods has been successfully synthesized on CuO catalyzed porous silicon （PS） using a simple vapour-solid （VS） growth method. A comparison of their morphologies is ...
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Mass production of ZnO nanobelts and hexagonal nanorods has been successfully synthesized on CuO catalyzed porous silicon （PS） using a simple vapour-solid （VS） growth method. A comparison of their morphologies is investigated by scanning electron microscopy （SEM）. The transmission electron microscopy （TEM） confirms that ZnO nanobelts and nanorods are single crystalline with the growth direction of （0110） and （0001）, respectively. Field emission tests indicate that the ZnO nanostructures on porous silicon have low turn-on field of about 3.6 V/μm （at 1.0μA/cm^2） and the threshold field of about 8.3 V/μm （at 1.0mA/cm^2）, high emission site density （ESD） of approximately 104 cm^-2.
In this paper, a new micromechanical method, the Weighted Residual Self-consistent Scheme (WRSCS), is developed for the prediction of the effective thermal conductivity of particulate composites with arbitrary configu...
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In this paper, a new micromechanical method, the Weighted Residual Self-consistent Scheme (WRSCS), is developed for the prediction of the effective thermal conductivity of particulate composites with arbitrary configurations. The method is based on the concept of the traditional Self-consistent Scheme (SCS). For some special configurations of inclusions, such as spherical or ellipsoidal, the effective conductivity of the composite can be solved without much difficulty using SCS. But for the composite with inclusion of arbitrary geometry, such as polygon or other irregular configurations, it is difficult to get an analytic solution. In the WRSCS, the arbitrary inclusion configuration is modeled by applying collocation points at interface. Based on SCS micromechanical model, the local fields inside the inclusion can be evaluated by using the solution of a single inclusion in an infinite matrix and inclusion interaction is taken into account through the yet unknown average equivalent medium. The solution for calculating the potential field inside the inclusion is obtained by means of Weighted Residual Method (WRM). Using the WRSCS, the effective thermal conductivities for composites with different inclusion's geometry are calculated. For the case of spherical inclusion, the results from the WRSCS show good agreements with the one from traditional SCS [7, 8]. Examining results corresponding to different inclusion's geometry, it shows that the effective thermal conductivity depends not only on the volume fractions and the properties of components, but also on the inclusion's configuration.
Monodispersed mesoporous silicon dioxide microspheres were prepared by polymerization-induced colloid aggregation (PICA) method and calcined at 850°C. The prepared samples were characterized with scanning electro...
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Monodispersed mesoporous silicon dioxide microspheres were prepared by polymerization-induced colloid aggregation (PICA) method and calcined at 850°C. The prepared samples were characterized with scanning electron microscopy (SEM), thermogravimetry (TG) and BET surface areas. The results showed that the obtained SiO2 microspheres had an average diameter of about 2.0 μm, a surface area of 253.3 m2g-1, an average pore volume of 0.62 mLg-1, and an average pore diameter of 7.9 nm. The formation mechanism of SiO2 spherical particles was discussed.
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