The electronic structure of the titanium dioxide (TiO2)-fluorine-doped tin dioxide (SnO2:F) interface is investigated by soft x-ray absorption spectroscopy using synchrotron radiation. The measurements probe the site-...
The electronic structure of the titanium dioxide (TiO2)-fluorine-doped tin dioxide (SnO2:F) interface is investigated by soft x-ray absorption spectroscopy using synchrotron radiation. The measurements probe the site- and symmetry-selected unoccupied density of states and reflect the interaction between an early transition-metal-oxide (d0) semiconductor and a post-transition-metal-oxide (d10) degenerate semiconductor. The distinct interfacial electronic structure of TiO2-SnO2:F is established by contrasting spectra with those for anatase and rutile TiO2, SnO2:F, and ZnO-SnO2:F and CdO-SnO2:F interfaces. Oxygen 1s absorption spectra, which relate to the O 2p partial density of states of the conduction band, indicate that the interface is associated with a reduction in Ti d-O p orbital hybridization and an alteration of the TiO2 crystal field. These observations are consistent with measured titanium 2p absorption spectra, which in addition provide evidence for distortion of long-range order around the cation site in the interfacial TiO2. The TiO2-SnO2:F interface is a functional component of a number of optoelectronic devices, perhaps most notably within the anode structure of solar cell architectures. In nonequilibrium conditions, such as those found in operating solar cells, interfacial electronic structure directly influences performance by modifying, for instance, the quasi-Fermi level electrons and the potential distribution at the transparent electrode.
Nickel and antimony doped tin dioxide (NATO) coated titanium electrodes are prepared and tested for electrochemical treatment of pentachlorophenol (PCP).The effect of nickel content on the electrochemical activity is ...
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ISBN:
(纸本)9781612843377
Nickel and antimony doped tin dioxide (NATO) coated titanium electrodes are prepared and tested for electrochemical treatment of pentachlorophenol (PCP).The effect of nickel content on the electrochemical activity is studied using PCP as target organic *** nickel content has an optimized value for the *** NATO is characterized and the relationship between activity and oxygen to tin atomic ratio is discussed.
The Ni-doped (CuIn)0.2Zn1.6S2 photocatalysts were prepared via a two-step ultrasonic-hydrothermal method under an environmental-friendly condition. XRD pattern profiles suggested that Ni2+ successfully doped into (CuI...
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In this paper, a three-layer Back Propagation (BP) algorithm artificial neural network (ANN) for predicting critical heat flux (CHF) in saturated forced convective boiling on a heated surface with impinging jets was t...
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As the speed of high-speed train (HST) increases continuously, aerodynamic noise has become more important compared with the wheel/rail noise, which affects the inhabited environment around the railway and the comfort...
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Since the opacifier-loaded silica aerogel composites have strong ability to inhibit radiant heat transfer compared to the pure silica aerogel, they can improve effectively the insulation performance at high temperatur...
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Since the opacifier-loaded silica aerogel composites have strong ability to inhibit radiant heat transfer compared to the pure silica aerogel, they can improve effectively the insulation performance at high temperature conditions and have been used extensively as thermal insulation materials in a variety of industrial applications. This paper developed a theoretical model to predict the radiant performance of opacifiers by using the Mie scattering theory, Beer law and a radiant heat transfer equations. The model was used to calculate the radiant performance of carbon black opacifier with various particle diameters and the radiant performance of three opacifiers, carbon black, SiC and ZrO2. The results showed that the opacifier-loaded silica aerogel composites had much higher extinction coefficient than the pure silica aerogel in a range of 3-7.5 μm wave band or in medium and high temperature ranges, which significantly improved the insulation performance of composites. With a fixed opacifier mass fraction, the optimal particle diameter was 2-3 μm for carbon black opacifier. Among the three opacifiers, carbon black opacifier had better opaque property than that of SiC and ZrO2 opacifiers. Due to poor thermostability for carbon black opacifier at high temperature conditions, the optimal material design for opacifier-loaded silica aerogel composites should be as follows: SiC or ZrO2 are added on high temperature side of aerogel and carbon black is added on low temperature side.
The heat transfer enhancement of Longitudinal Vortex (LV) is a kind of technology with efficiency is high and resistance is low. The effective influence distance of LV is very important to extend this kind of technolo...
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The experiment of flow boiling heat transfer on micro-pin-finned chips in FC-72 with jet impingement was *** experimental conditions consisted of two different liquid subcooling degrees (25,35°C),three different ...
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The experiment of flow boiling heat transfer on micro-pin-finned chips in FC-72 with jet impingement was *** experimental conditions consisted of two different liquid subcooling degrees (25,35°C),three different cross flow velocities (Vc=0.5,1,1.5 m/s) and three different jet velocities (Vj=0,1,2 m/s).The dimensions of the silicon chips were 10 mm×10 mm×0.5 mm (length×width×thickness) on which two kinds of micro-pin-fins with the dimensions of 30 μm×120 μm,50 μm×120 μm (thickness×height) were fabricated by the dry etching technique. A smooth surface was also tested for comparison. The correlations for nucleate boiling curves and the maximum allowable heat flux curves were obtained. The results show that the heat transfer performance was improved with increasing liquid subcooling and flow velocity. All micro-pin-finned surfaces displayed a considerable heat transfer enhancement. The addition of jet impingement further enhanced the heat transfer at a high heat flux and increased the CHF. At a certain cross flow velocity, the enhancement was more significant as the jet velocity increased, especially for Vc=0.5 m/s, Vj=2 m/s. For the micro-pin-finned chips, the CHF increased by more than 93% while the subcooling was 35°C compared with Vc=0.5 m/s, Vj=0 m/s. As the cross velocity increased, the intensification degree of jet impingement decreased and the increase of CHF also decreased.
An effective way to boost natural gas production from low pressure gas field was introduced in the paper. The supersonic ejector used the energ off high pressure gas wells, which was generally wasted through the choke...
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