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Exploring Geometric Chirality in Nanocrystals for Boosting Solar-to-Hydrogen Conversion

Angewandte Chemie 2024年第45期136卷

作者： Wenlong Fu Qi Gao Chunyang Zhang Lili Tan Biao Jiang Chengyu Xiao Prof. Maochang Liu Prof. Peng-peng Wang State Key Laboratory for Mechanical Behavior of Materials Shaanxi International Research Center for Soft Matter School of Materials Science and Engineering Xi'an Jiaotong University Xi'an Shaanxi 710049 PR China International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an Shaanxi 710049 PR China

Advancing catalyst design is pivotal for the enhancement of photocatalytic processes in renewable energy conversion. The incorporation of structural chirality into conventional inorganic solar hydrogen nanocatalysts promises a significant transformation in catalysis, a feature absent in this field. Here we unveil the unexplored potential of geometric chirality by creating a chiral composite that integrates geometric chiral Au nanoparticles (NPs) with two-dimensional C 3 N 4 nanosheets, significantly boosting photocatalytic H 2 evolution beyond the achiral counterparts. The superior performance is driven by the geometric chirality of Au NPs, which facilitates efficient charge carrier separation through the favorable C 3 N 4 -chiral Au NP interface and chiral induced spin polarization, and exploits high-activity facets within the concave surfaces of chiral Au NPs. The resulting synergistic effect leads to a remarkable increase in photocatalytic H 2 evolution, with an apparent quantum yield of 44.64 % at 400 nm. Furthermore, we explore the selective polarized photo-induced carrier separation behavior, revealing a distinct chiral-dependent photocatalytic HER performance. Our work advances the design and utilization of chiral inorganic nanostructures for superior performance in energy conversion processes.

关键词： Geometric chirality Nanoparticles Photocatalytic hydrogen evolution reaction Chiral effect

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Lithium–Sulfur Batteries: Flexible and High‐Loading Lithium–Sulfur Batteries Enabled by Integrated Three‐In‐One Fibrous Membranes (Adv. Energy Mater. 38/2019)

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Advanced Energy Materials 2019年第38期9卷

作者： Jianan Wang Guorui Yang Jie Chen Yunpeng Liu Yuankun Wang Cheng‐Yen Lao Kai Xi Duowen Yang Christopher J. Harris Wei Yan Shujiang Ding Ramachandran Vasant Kumar Department of Applied Chemistry School of Science MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter State Key Laboratory for Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 China Department of Environmental Science and Engineering State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Department of Materials Science and Metallurgy University of Cambridge Cambridge CB3 0FS UK

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Energy Storage: In Situ Fabrication of Hierarchically Branched TiO2Nanostructures: Enhanced Performance in Photocatalytic H2Evolution and Li–Ion Batteries (Small 47/2017)

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Small 2017年第47期13卷

作者： Guorui Yang Ling Wang Shengjie Peng Jianan Wang Dongxiao Ji Wei Yan Seeram Ramakrishna Department of Environmental Science & Engineering State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Department of Mechanical Engineering National University of Singapore Singapore 117574 Singapore Jiangsu Key Laboratory of Materials and Technology for Energy Conversion College of Materials Science and Technology Nanjing University of Aeronautics and Astronautics Nanjing 210016 China

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Single-atom cobalt-incorporating carbon nitride for photocatalytic solar hydrogen conversion: An X-ray spectromicroscopy study

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Journal of Electron Spectroscopy and Related Phenomena 2023年 264卷

作者： Huang, Yu-Cheng Chen, Jie Lu, Ying-Rui Arul, K. Thanigai Ohigashi, Takuji Chen, Jeng-Lung Chen, Chi-Liang Shen, Shaohua Chou, Wu-Ching Pong, Way-Faung Dong, Chung-Li National Synchrotron Radiation Research Center Hsinchu30010 Taiwan School of Chemical Engineering and Technology Xi'an Jiaotong University Xi'an710049 China Research Center for X-ray Science & Department of Physics Tamkang University New Taipei City25137 Taiwan Photon Factory Institute of Materials Structure Science High Energy Accelerator Research Organization Tsukabu Japan UVSOR Synchrotron Facility Institute for Molecular Science Okazaki Japan International Research Center for Renewable Energy State Key laboratory of Multiphase Flow in Power Engineering Xi`an Jiaotong University Shaanxi Xi`an710049 China Department of Electrophysics National Yang Ming Chiao Tung University Hsinchu30010 Taiwan

The use of carbon nitride-based materials and light to drive catalytic water splitting has enormous potential for the production of hydrogen. Revealing the processes of molecular conjugation, nucleation, and crystallization in crystalline carbon nitride is expected to enhance the photocatalytic activity through the creation of isotype heterojunctions and active sites. In this work, the addition of cobalt salts in ionothermal synthesis was found to promote the phase transition of heptazine-based crystalline carbon nitride (CCN) to triazine-based poly (triazine imide) (PTI), resulting in the formation of a single-atom cobalt-doped coordinated isotype CCN/PTI heterojunction. The new hybrid orbital modulates the atomic/electronic structure and the band gap of the CCN/PTI heterojunction, and synergistically increases the absorption of visible light, accelerating the separation and transfer of photoexcited electrons and holes. Synchrotron-based X-ray spectroscopy and microscopy are used to identify the origin of the improved performance of the single-atom cobalt-doped CCN/PTI heterojunction in the photocatalytic hydrogen evolution reaction. This work demonstrates that synchrotron X-ray spectroscopy is a promising tool for designing materials aimed at enhancing photocatalytic activity in solar energy conversion applications. © 2023 Elsevier B.V.

关键词： Carbon nitride

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Experimental study on pressure and temperature distribution characteristics of subcritical and supercritical water in vertical flow channel

International Journal of Fluid Engineering

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International Journal of Fluid engineering 2024年第4期1卷 56-64页

作者： Hui Jin Huibo Wang Yi Li Petr A.Nikrityuk State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityShaanxi 710049China Mechanical Engineering Department Eindhoven University of TechnologyEindhovenNetherlands Chemical and Materials Engineering Department University of AlbertaEdmontonAlberta T6G 2R3Canada

To enhance knowledge about efficiency improvement and reactor optimization in supercritical water gasification,an experimental system was designed to study the pressure and temperature distribution of subcritical and supercritical water in a channel,representing a simplified continuous *** pressure drop and temperature distribution along and perpendicular to the forced flow are studied by the measure points inserted inside the test *** results show that the pressure drop in the test section is linearly negatively correlated with the average enthalpy of the inlet and outlet,eventually reaching negative values(-0.177 MPa)at high average enthalpy(2300 kJ kg^(-1)).Temperature and specific enthalpy along the flow direction match theoretical estimates,except near the pseudocritical *** subcritical cases,horizontal temperature differences are positively correlated with enthalpy differences and mass flow rates but remain nearly constant in supercritical ***,with fluid temperature rising from the pseudocritical point,the horizontal temperature difference first increases,then decreases,and reaching a peak of 4.29 K at a fluid temperature of 664 *** of the obtained data reveals that the negative correlation and values of the pressure drop are caused by fluid volume ***,fluid volume expansion,near-wall natural convection,and turbulent forced flow fluctuations contribute to horizontal temperature non-uniformity.

关键词： flow distribution channel

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Investigation of exergy efficiency of organic Rankine cycle

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IOP Conference Series: Earth and Environmental Science 2019年第1期354卷

作者： G L Liu J L Xu S Cao Beijing Key Laboratory of Multiphase Flow and Heat Transfer for Low Grade Energy Utilization North China Electric Power University Beijing 102206 Beijing China School of Energy and Power Engineering Zhengzhou University of Light Industry Zhengzhou 450002 Henan Province China

Organic Rankine cycle (ORC) which recovers waste heat in the temperature range of 80°C-140°C was investigated. Exergy efficiencies of various components and ORC system were paid great attention. The working fluids of R245fa and R600a are used. It is found that, for saturated ORCs, the expander inlet temperature has the optimum value, so the system exergy efficiency is maximum. With the increase of heat source temperature, the optimal inlet temperature of the expander is also increased. And also for saturated ORCs, the exergy efficiencies of evaporator and expander are highest efficiency, when evaporator exergy efficiency is increased with increase of heat source temperatures, the expander exergy efficiency is unchanged. The condenser decreased exergy efficiencies by increasing the heat source temperatures.

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Preparation and Properties of Rice Hull Ash as the catalysis supporter in the fluidized-bed reactor

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IOP Conference Series: Earth and Environmental Science 2021年第1期766卷

作者： Zhaohui Teng Shan Huang Heng Xu Na Li Qulan Zhou College of energy Chengdu University of Tecnoogy Chengdu 610059 China National Key Laboratory of Nuclear Reactor System Design Technology Nuclear Power Institute of China Chengdu 610200 China shenzhen ILNG energy technology CO. LTD Shenzhen 518061 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

This research focuses on the preparation and properties of rice hull ash(RHA). We prepared RHA from combustion of rice husk in the fluidized-bed reactor. The temperature field of the furnace was steady and bellow 850°C to keep SiO2 amorphous. XRD, BET and SEM were applied in the characterization tests to investigate the effect of flow rate(u), the higher primary-secondary wind ratio(i) and relative height of bed material. The optimal combustion condition for preparing RHA was discussed. RHA obtained from rice hull contains abundant amorphous SiO2 (>90%) and the characterization results of RHA show its potential to be a good catalyst supporter.

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Aqueous Synthesis of Ultrathin Platinum/Non‐Noble Metal Alloy Nanowires for Enhanced Hydrogen Evolution Activity

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Angewandte Chemie 2018年第36期130卷

作者： Zhaojun Liu Jing Qi Moxuan Liu Shumeng Zhang Qikui Fan Hongpo Liu Kai Liu Haoquan Zheng Yadong Yin Chuanbo Gao Frontier Institute of Science and Technology and State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an Shaanxi 710054 China School of Chemistry and Chemical Engineering Shaanxi Normal University Xi'an Shaanxi 710119 China Department of Chemistry University of California Riverside CA 92521 USA

Although aqueous synthesis of nanocrystals is advantageous in terms of the cost, convenience, environmental friendliness, and surface cleanness of the product, nanocrystals of Pt and non‐noble metal alloys are difficult to obtain with controlled morphology and composition from this synthesis owing to a huge gap between the reduction potentials of respective metal salts. This huge gap could now be remedied by introducing a sulfite into the aqueous synthesis, which is believed to resemble an electroless plating mechanism, giving rise to a colloid of Pt‐M (M=Ni, Co, Fe) alloy nanowires with an ultrasmall thickness (ca. 2.6 nm) in a high yield. The sulfite also leads to the formation of surface M−S bonds and thus atomic‐level Pt/M–S(OH) interfaces for greatly boosted hydrogen evolution kinetics under alkaline conditions. An activity of 75.3 mA cm −2 has been achieved with 3 μg of Pt in 1 m KOH at an overpotential of 70 mV, which is superior to previously reported catalysts.

关键词： Dimetall-Legierungen Nanodrähte Platin Wasserstoffentwicklung Wässrige Synthesen

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Corrigendum to ‘Performance analysis of sCO 2 tube with high non-uniform heat flux: Thermal-fluid-structural evaluation and optimization’ [Volume 231, August 2023, 120849]

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Applied Thermal engineering 2023年 235卷

作者： Shuo Gao Yanjuan Wang Yi Li Qibin Liu Jinliang Xu The Beijing Key Laboratory of Multiphase Flow and Heat Transfer North China Electric Power University Beijing 102206 China Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing 100190 China University of Chinese Academy of Sciences Beijing 10049 China

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Anchoring group regulation in semiconductor/molecular complex hybrid photoelectrode for photoelectrochemical water splitting

Smart Molecules

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Smart Molecules 2024年

作者： Xiangyan Chen Fujun Niu Tongxiang Ma Qingyu Li Shaopeng Wang Shaohua Shen Northwest Institute for Non-ferrous Metal Research Xi'an Shaanxi China School of Advanced Energy Shenzhen Campus of Sun Yat-sen University Shenzhen China State Key Laboratory of Multiphase Flow in Power Engineering International Research Center for Renewable Energy Xi'an Jiaotong University Xi'an Shaanxi China

Rational interface engineering via regulating the anchoring groups between molecular catalysts and light-absorbing semiconductors is essential and emergent to stabilize the semiconductor/molecular complex interaction and facilitate the photocarriers transport, thus realizing highly active and stable photoelectrochemical (PEC) water splitting. In this mini review, following a showcasing of the fundamental details of hybrid PEC systems containing semiconductor photoelectrodes and molecular catalysts for water splitting, the state-of-the-art progress of anchoring group regulation at semiconductor/molecular complex interface for efficient and stable PEC water splitting, as well as its effect on charge transfer kinetics, are comprehensively reviewed. Finally, potential research directions aimed at building high-efficiency hybrid PEC water splitting systems are summarized.

关键词： anchoring groups hybrid systems molecular catalysts photoelectrochemical water splitting semiconductor photoelectrodes

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