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SSRN 2024年

作者： Liu, Xiaolin Zhou, Mengjun Liao, Xiaobin Zhao, Yan State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China State Key Laboratory of Silicate Materials for Architectures Wuhan University of Science and Technology China

The utilization of CO2 electrochemistry in energy storage has been considered as a promising power source due to its high theoretical energy density, high electrochemical potential, and ability to fix CO2. However, the low efficiency and poor reversibility of Li-CO2 evolution significantly impede the applications of Li-CO2 batteries. Herein, first-principles calculations were employed to investigate the 21 M1M2N4C active sites and explore the catalytic mechanism for the Li-CO2 evolution reaction. The adsorption and activation of CO2 on the thermodynamically stable DACs show that the TM atoms in M1M2N4C center sites with decreasing d-band center appeared to increase CO2 adsorption energy. Among the active sites, the MoMoN4C shows the most robust activation interaction with CO2 due to its high d-center and strong d-p orbital coupling. The implicit solvent CEP simulations verify the effects of dual-atom sites on the products' activities and selectivity by searching the possible reaction pathways toward the battery-discharging processes in the ether electrolyte. The decomposition of *Li2CO3 was simulated by the NEB calculations. The results prove that the MoMoN4C active site can boost the reaction dynamics and exhibit high reversibility for the Li-CO2 battery. © 2024, The Authors. All rights reserved.

关键词： Carbon dioxide

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Operando reconstruction towards stable CuI nanodots with favorable facets for selective CO_(2) electroreduction to C2H4

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Science China Chemistry 2023年第6期66卷 1834-1843页

作者： Wenjie Xue Hongxia Liu Xinqing Chen Xiaoju Yang Ruoou Yang Youwen Liu Minghao Li Xuan Yang Bao Yu Xia Bo You Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of EducationHubei Key Laboratory of Material Chemistry and Service FailureSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074China School of Chemistry and Chemical Engineering Wuhan Textile UniversityWuhan 430200China Shanghai Advanced Research Institute Chinese Academy of SciencesShanghai 201210China State Key Laboratory of Materials Processing and Die&Mold Technology and School of Materials Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China

Cu-based electrocatalysts with favorable facets and Cu^(+)can boost CO_(2) reduction to valuable multicarbon ***,the inevitable Cu^(+)reduction and the phase evolution usually result in poor ***,we fabricate CuI nanodots with favorable(220)facets and a stable Cu^(+)state,accomplished by operando reconstruction of Cu(OH)_(2) under CO_(2)-and I--containing electrolytes for enhanced CO_(2)-to-C_(2)H_(4) *** X-ray absorption spectroscopy(XAS),in-situ Raman spectroscopy and thermodynamic potential analysis reveal the preferred formation of *** gas electroresponse and density functional theory(DFT)calculations reveal that CO_(2)-related species induce the exposure of the(220)plane of Cu ***,the small size of nanodots enables the adequate contact with I^(-),which guarantees the rapid formation of Cu I instead of the electroreduction to Cu^(0).As a result,the resulting catalysts exhibit a high C2H4 Faradaic efficiency of 72.4%at a large current density of 800 m A cm^(-2) and robust stability for 12 h in a flow *** in-situ ATR-SEIRS spectroscopic characterizations and DFT calculations indicate that the(220)facets and stable Cu^(+) in CuI nanodots synergistically facilitate CO_(2)/*CO adsorption and*CO dimerization.

关键词： CO_(2)reduction reaction cuprous iodide favorable facets halogen electrolyte reconstruction

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High‑Speed Sirospun Conductive Yarn for Stretchable Embedded Knitted Circuit and Self‑Powered Wearable Device

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advanced Fiber materials 2023年第1期5卷 154-167页

作者： Li Niu Jin Wang Kai Wang Heng Pan Gaoming Jiang Chaoyu Chen Pibo Ma Engineering Research Center of Knitting Technology Ministry of EducationCollege of Textile Science and EngineeringJiangnan UniversityWuxi 214122China State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200China

In the intelligent era,the textile technique is a high efficiency,mature and simple manufacturing solution capable of fabricat-ing fully flexible wearable ***,the external circuit with its integration and comfort limitations cannot satisfy the requirements of intelligent wearable and portable *** study presents an industrialized production method to fabricate core–shell structure conductive yarn for direct textile use,prepared by the high-speed sirospun *** integration and flexibility are significantly improved over previous *** sirospun conductive yarn(SSCY)and the intarsia technique can provide the SSCY seamless and convenient embedded knitted circuit(SSCY-EKC)to form a full textile electrical element as the channel of power and signals transmission,allowing for a stable resistance change and wide strain range for meeting practical *** based on the triboelectric nanogenerator(SSCY-TENG)can be designed as a caution carpet with attractive design and good washability for a self-powered sensor that recognizes human ***,intrinsic textile properties such as washability,softness,and comfort *** benefits such as excellent extension,fitting,and stretchability,the SSCY-EKC used herein can realize a fully flexible electrical textile with a high potential for physical detection,body gesture recognition,apparel fashion,and decoration.

关键词： Sirospun technique Embedded knitted circuit Intarsia technique Stretchable Wearable devices

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Carrier recombination suppression and transport enhancement enable high-performance self-powered broadband Sb_(2)Se_(3) photodetectors

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InfoMat 2023年第4期5卷 60-76页

作者： Shuo Chen Yi Fu Muhammad Ishaq Chuanhao Li Donglou Ren Zhenghua Su Xvsheng Qiao Ping Fan Guangxing Liang Jiang Tang Shenzhen Key Laboratory of Advanced Thin Films and Applications Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong ProvinceCollege of Physics and Optoelectronic EngineeringShenzhen UniversityShenzhenGuangdongthe People's Republic of China MOE Key Laboratory of New Processing Technology for Non-ferrous Metals and Materials Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured MaterialsGuangxi UniversityNanningGuangxithe People's Republic of China State Key Laboratory of Silicon Materials&School of Materials Science and Engineering Zhejiang UniversityHangzhouZhejiangthe People's Republic of China Wuhan National Laboratory for Optoelectronics(WNLO) School of Optical and Electronic InformationHuazhong University of Science and TechnologyWuhanHubeithe People's Republic of China

Antimony selenide(Sb_(2)Se_(3))is a promising candidate for photodetector applications boasting unique material benefits and remarkable optoelectronic *** high-performance self-powered Sb_(2)Se_(3)photodetector through a synergistic regulation of absorber layer and heterojunction interface demonstrates great potential and needs essential *** this study,an effective two-step thermodynamic/kinetic deposition technique containing sputtered and selenized Sb precursor is implemented to induce self-assembled growth of Sb_(2)Se_(3)light absorbing thin film with large crystal grains and desirable[hk1]orientation,presenting considerable thin-film photodetector ***,aluminum(Al^(3+))cation dopant is introduced to modify the optoelectronic properties of CdS buffer layer,and further optimize the Sb_(2)Se_(3)/CdS(Al)heterojunction interface *** to the suppressed carrier recombination and enhanced carrier transport kinetics,the champion Mo/Sb_(2)Se_(3)/CdS(Al)/ITO/Ag photodetector exhibits self-powered and broadband characteristics,accompanied by simultaneously high responsivity of 0.9 A W^(-1)(at 11 nW cm^(-2)),linear dynamic range of 120 dB,impressive ON/OFF switching ratio over 10^(6)and signal-to-noise ratio of 10^(9),record total noise determined realistic detectivity of 4.78×10^(12)Jones,and ultra-fast response speed with rise/decay time of 24/75 ns,representing the top level for Sb_(2)Se_(3)-based *** intriguing work opens up an avenue for its selfpowered broadband photodetector applications.

关键词： photoresponse recombination suppression Sb_(2)Se_(3) self-powered photodetector transport enhancement

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Green synthesis of luminescent La-MOF nanoparticle from waste poly(ethylene terephthalate) for high-performance in Fe(Ⅲ) detection

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Rare Metals 2024年第8期43卷 3833-3843页

作者： Zhi Gong Zhi-Kui Dai Zhi-Yue Dong Qiu-Xuan Liu Valentin A.Milichko Hua-Jian Liu Jie Liu Ran Niu Jiang Gong Key Laboratory of Material Chemistry for Energy Conversion and Storage Hubei Key Laboratory of Material Chemistry and Service FailureHubei Engineering Research Center for Biomaterials and Medical Protective MaterialsSemiconductor Chemistry CenterSchool of Chemistry and Chemical EngineeringMinistry of EducationHuazhong University of Science and TechnologyWuhan 430074China School of Chemical Engineering and Pharmacy Wuhan Institute of TechnologyWuhan 430073China Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical EngineeringHubei UniversityWuhan 430062China School of Physics and Engineering ITMO UniversitySt.Petersburg197101Russia School of Materials Science and Engineering Hubei UniversityWuhan430062China Guangdong Provincial Key Laboratory of Technique and Equipment for Macromolecular Advanced Manufacturing School of Mechanical and Automotive EngineeringKey Laboratory of Polymer Processing EngineeringMinistry of EducationSouth China University of TechnologyGuangzhou 510641China

Developing luminescent metal-organic frameworks(MOFs) capable of high-efficiency Fe^(3+)sensing has aroused great attraction in the fields of biology,chemistry,***,previous solvothermal methods are limited by organic solvent usage,time consuming,high pressure,and high-energy ***,we propose the waste-toMOF strategy towards the scale-up production of La-MOF nanoparticles through the ball milling of recycled poly(-ethylene terephthalate)(PET) bottles and La(NO_(3))_(3)·_(6)H_(2)*** goes on alkaline hydrolysis to form 1,4-benzenedicarboxylic acid sodium salt(Na_(2)BDC) and ethylene glycol by ball ***,BDC reacts with La^(3+)to form *** as-prepared La-MOF crystal nanoparticles possess a rod-like morphology with the size of few hundred ***,La-MOF nanoparticles display high selectivity and sensitivity for Fe^(3+)*** quenching constant and limit of detection are 5.29×10^(3)(mol·L^(-1))^(-1) and 0.147 μmol·L^(-1),respectively,thus surpassing many advanced Fe^(3+) *** to the result of density functional theory,the high Fe^(3+) detection performance of La-MOF is related to the complexing of Fe^(3+)with La-MOF,which leads to the gradual dissociation of the coordination bond between terephthalic acid and La^(3+).It is anticipated that the mechanochemistry milling-based wasteto-MOF strategy provides a new platform for the massive production of functional MOFs in a green manner.

关键词： Metal-organic framework Waste polyester Mechanochemistry milling Fluorescence sensor

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Bioinspired cellulose-integrated MXene-based hydrogels for multifunctional sensing and electromagnetic interference shielding

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Interdisciplinary materials 2022年第4期1卷 495-506页

作者： Jingjiang Wei Chenglong Zhu Zhihui Zeng Fei Pan Fuqiang Wan Liwen Lei Gustav Nyström Zhengyi Fu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanHubeiPR China Laboratory for Cellulose and Wood Materials Swiss Federal Laboratories for Materials Science and Technology(Empa)DübendorfSwitzerland Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials School of Material Science and EngineeringShandong UniversityJinanShandongPR China Laboratory for Biointerfaces Swiss Federal Laboratories for Materials Science and Technology(Empa)St.GallenSwitzerland Department of Health Science and Technology ETH ZürichZürichSwitzerland

Bioinspired hydrogels are complex materials with distinctive properties comparable to biological *** exceptional sensitivity to various external stimuli leads to substantial application potential in wearable smart ***,these multifaceted hydrogels are often challenging to be combined with pattern customization,stimulus responsiveness,self-healing,and ***,inspired by mussel secretions,a printable,self-healing,and biocompatible MXene-based composite hydrogel was designed and prepared by incorporating Ti3C2Tx MXene nanosheets into the hydrogel framework through the chelation of calcium ions(Ca2+)with polyacrylic acid and cellulose nanofibers at alkaline *** biocompatible conductive hydrogel exhibited sensitivity(gauge factor of 2.16),self-healing(within 1 s),recognition,and adhesion,distinguishing it as an ideal candidate for wearable multifunctional sensors toward strain sensing,vocal sensing,signature detection,and Morse code ***,the multifunctional hydrogel manifested efficient electromagnetic interference shielding properties(reaching more than 30 dB at a thickness of 2.0 mm),protecting electronics and humans from electromagnetic radiation and ***,the presented work represents a versatile strategy for developing environmentally friendly conductive hydrogels,demonstrating the perspectives of intelligent hydrogels for multifunctional applications.

关键词： cellulose nanofiber electromagnetic interference shielding hydrogel MXene sensor

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Stretchable wireless optoelectronic synergistic patches for effective wound healing

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npj Flexible Electronics 2024年第1期8卷 233-242页

作者： Qian Wang Siyuan Cai Guang Yao Liyuan Zhang Wenhao Lou Youxin Chen Qingqing Li Maowen Xie Xingyi Gan Chenzheng Zhou Taisong Pan Min Gao Kangning Zhao Zhen Cai Yuan Lin School of Materials and Energy University of Electronic Science and Technology of ChinaChengduSichuanChina Department of Plastic Surgery Sichuan Provincial People’s HospitalUniversity of Electronic Science and Technology of ChinaChengduSichuanChina Department of Plastic and Cosmetic Surgery Xinqiao HospitalArmy Medical UniversityChongqingChina State Key Laboratory of Electronic Thin Films and Integrated Devices University of Electronic Science and Technology of ChinaChengduSichuanChina Shenzhen Institute for Advanced Study University of Electronic Science and Technology of ChinaShenzhenGuangdongChina State Key Laboratory of Advanced Technology for Materials Synthesis and Processing International School of Materials Science and EngineeringWuhan University of TechnologyWuhanHubeiChina Medico-Engineering Cooperation on Applied Medicine Research Center University of Electronic Science and Technology of ChinaChengduSichuanChina

Physiotherapies play a crucial role in noninvasive tissue engineering for wound ***,challenges such as the implementation of complex interventions and unsatisfactory treatment outcomes impede widespread ***,we proposed a stretchable and wirelessly-powered optoelectronic synergistic patch with a dual-layer serpentine wireless receiver circuit to drive the optoelectronic modulation *** structure and impedance matching enable the patch to seamlessly attach to irregular skin surfaces and operate robustly over a 30%tensile strain *** on Sprague-Dawley rat wound *** wound closure rate of the optoelectronic synergistic group significantly outperformed both monointervention and blank control ***,optoelectronic synergistic intervention enhances the secretion of vascular endothelial marker proteins and growth factors,and stabilizes mitochondrial function during oxidative ***,the scalable amalgamation of flexible electronics,wireless transmission,and synergistic interventions promise to improve wound care.

关键词： optoelectronic synergistic healing

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Pancake-Like MOF Solid-state Electrolytes with Fast Ion Migration for High-Performance Sodium Battery

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Nano-Micro Letters 2021年第7期13卷 74-85页

作者： Gang Zhang Jun Shu Lin Xu Xinyin Cai Wenyuan Zou Lulu Du Song Hu Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070People’s Republic of China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200People’s Republic of China

Solid-state electrolyte(SSE)of the sodium-ion battery have attracted tremendous attention in the next generation energy storage materials on account of their wide electrochemical window and thermal ***,the high interfacial impedance,low ion transference number and complex preparation process restrict the application of ***,inspired by the excellent sieving function and high specific surface area of red blood cells,we obtained a solid-like electrolyte(SLE)based on the combination of the pancake-like metal-organic framework(MOF)with liquid electrolyte,possessing a high ionic conductivity of 6.60×10^(-4) S cm^(−1),and excellent sodium metal *** addition,we investigated the ion restriction effect of MOF’s apertures size and special functional groups,and the ion transference number increased from 0.16 to ***,the assembled Na_(0.44)MnO_(2)//SLE//Na full batteries showed no obvious capacity decrease after 160 *** material design of SLE in our work is an important key to obtain fast ion migration SLE for high-performance sodium-ion batteries.

关键词： Metal-organic Frameworks Sodium-ion Battery Solid-like Electrolyte Interface Contact

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In-situ surface self-reconstruction in ternary transition metal dichalcogenide nanorod arrays enables efficient electrocatalytic oxygen evolution

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Journal of Energy Chemistry 2021年第4期30卷 10-16页

作者： Qiang Chen Yulu Fu Jialun Jin Wenjie Zang Xiong Liu Xiangyong Zhang Wenzhong Huang Zongkui Kou John Wang Liang Zhou Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina Department of Materials Science and Engineering National University of SingaporeSingapore 117574Singapore Foshan Xianhu Laboratory Foshan 528216GuangdongChina

Water splitting has received more and more attention because of its huge potential to generate clean and renewable *** highly active and durable oxygen evolution reaction(OER)catalysts play a decisive factor in achieving efficient water *** identification of authentic active origin under the service conditions can prompt a more reasonable design of catalysts together with well-confined micro-/nano-structures to boost the efficiency of water ***,Fe,Co,and Ni ternary transition metal dichalcogenide(FCND)nanorod arrays on Ni foam are purposely designed as an active and stable low-cost OER pre-catalyst for the electrolysis of water in alkaline *** optimized FCND catalyst demonstrated a lower overpotential than the binary and unary counterparts,and a 27-fold rise in kinetic current density at the overpotential of 300 m V compared to the nickel dichalcogenide *** spectra and other structural characterizations at different potentials reveal that the in-situ surface self-reconstruction from FCND to ternary transition metal oxyhydroxides(FCNOH)on catalyst surfaces initiated at about 1.5 V,which is identified as the origin of OER *** surface selfreconstruction towards FCNOH also enables excellent stability,without fading upon the test for 50 h.

关键词： Surface self-reconstruction Transition metal dichalcogenide Transition metal oxyhydroxide Oxygen evolution reaction Water splitting

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Co/Zn-metal organic frameworks derived functional matrix for highly active amorphous Se stabilization and advanced lithium storage

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Rare Metals 2023年第1期42卷 76-84页

作者： Hong Yu Jin-Zhao Kang Long-Sheng Huang Jin-Jin Wang Xiao-Mei Wang Xiang-Yuan Zhao Cheng-Feng Du State Key Laboratory of Solidification Processing Center of Advanced Lubrication and Seal MaterialsNorthwestern Polytechnical UniversityXi’an710072China Northwestern Polytechnical University Chongqing Technology Innovation Center Chongqing400000China College of Chemistry and Chemical Engineering Hubei UniversityWuhan430062China

Lithium-selenium batteries,as an advanced rechargeable battery system,have attracted wide ***,its application is hurdled by the ambiguous underlying mechanism such as the unclear active phase and the key role of the host ***,a three-dimensional(3D) functional matrix derived from the Co/Znmetal organic framework is synthesized to unravel the questions *** reveals that the strong interaction and voids in the 3D matrix serve to anchor the amorphous Se with high electrochemical *** obtained 3DC/Se exhibits 544.2 and 273.2 mAh·g^(-1) t current densities of 0.1C and 2.0C,respectively,with a diffusion-controlled *** excessive amount of Se beyond the loading capacity of the matrix leads to the formation of trigonal phase Se,which shows an unsatisfying electrochemical property.

关键词： Metal-organic frameworks(MOFs) Amorphous Se Functional matrix Li-Se batteries

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