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Advancements in heterojunction,cocatalyst,defect and morphology engineering of semiconductor oxide photocatalysts

Journal of Materiomics 2024年第2期10卷 315-338页

作者： Guojing Wang Shasha Lv Yuanhua Shen Wei Li Linhan Lin Zhengcao Li State Key Laboratory of New Ceramics and Fine Processing Key Laboratory of Advanced Materials(MOE)School of Materials Science and EngineeringTsinghua UniversityBeijing100084China Key Laboratory of Beam Technology and Material Modification Ministry of EducationCollege of Nuclear Science and TechnologyBeijing Normal UniversityBeijing100875China School of Physical Science and Technology Lanzhou UniversityLanzhou730000China Department of Engineering Physics Tsinghua UniversityBeijing100084China State Key Laboratory of Precision Measurement Technology and Instruments Department of Precision InstrumentTsinghua UniversityBeijing100084China

Photocatalytic technology has emerged as a crucial avenue for harnessing solar energy,presenting itself as a viable solution to address the current energy crisis and environmental *** past 50 years have witnessed significant progress and breakthroughs in scientific research on photocatalytic *** paper provides a comprehensive review of the mechanism of photocatalytic technology and methods to improve the photocatalytic efficiency of semiconductor photocatalysts,such as TiO_(2) and *** this paper,common modification methods are divided into four categories:heterojunction con-struction,cocatalysts,defects,and morphological *** origin and development of photo-catalysts in each category are briefly summarized;moreover,the latest progress in each type of modification is discussed.S-scheme heterojunctions retain the high reduction and oxidation capacity of photogenerated electrons and holes by sacrificing half of the photogenerated carriers,showing excellent performance in photocatalysis and great application *** challenges associated with current modification schemes are *** is growing interest in quantitative and atomic-level modu-lation as attractive approaches to tackling these *** the electronic spin state and internal field is important for minimizing photogenerated carrier recombination in *** review will inspire researchers and promote the application of photocatalytic technology.

关键词： Photocatalytic activity Modification Heterostructure Thermal annealing Ion irradiation

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Emerging natural clay-based materials for stable and dendrite-free lithium metal anodes:A review

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Chinese Chemical Letters 2025年第2期36卷 133-144页

作者： Haobo Wang Fei Wang Yong Liu Zhongxiu Liu Yingjie Miao Wanhong Zhang Guangxin Wang Jiangtao Ji Qiaobao Zhang School of Materials Science and Engineering Provincial and Ministerial Co-construction of Collaborative Innovation Center for Non-ferrous Metal new Materials and Advanced Processing TechnologyHenan University of Science and TechnologyLuoyang 471023China Faculty of Engineering Huanghe Science and Technology UniversityZhengzhou 450063China Henan Key Laboratory of Non-Ferrous Materials Science&Processing Technology Henan University of Science and TechnologyLuoyang 471023China College of Agricultural Equipment Engineering Henan University of Science and TechnologyLuoyang 471023China State Key Laboratory of Physical Chemistry of Solid Surfaces College of MaterialsXiamen UniversityXiamen 361005China

Lithium metal is one of the most promising anodes for lithium batteries because of their high theoretical specific capacity and the low electrochemical ***,the commercialization of lithium metal anodes(LMAs)is facing significant obstacles,such as uncontrolled lithium dendrite growth and unstable solid electrolyte interface,leading to inferior Coulombic efficiency,unsatisfactory cycling stability and even serious safety *** low-cost natural clay-based materials(NCBMs)in LMAs is deemed as one of the most effective methods to solve aforementioned *** NCBMs have received considerable attention for stabilizing LMAs due to their unique structure,large specific surface areas,abundant surface groups,high mechanical strength,excellent thermal stability,and environmental *** the rapidly growing research enthusiasm for this topic in the last several years,here,we review the recent progress on the application of NCBMs in stable and dendrite-free *** different structures and modification methods of natural clays are first *** addition,the relationship between their modification methods and nano/microstructures,as well as their impact on the electrochemical properties of LMAs are systematically ***,the current challenges and opportunities for application of NCBMs in stable LMAs are also proposed to facilitate their further development.

关键词： Natural clay-based materials Aolid-state electrolyte Surface modification Li metal anodes Rechargeable batteries

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Synthesis of a novel Al foam with a periodic architecture by introducing hollow Al tubes and Al/Mg powders

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Journal of materials Science & technology 2023年第17期148卷 105-115页

作者： Zhigang Xu Dayong Shen Kai Wang Peng He Jian Zhang Hao Zhang Peng Cao Shangyu Huang Jian Peng Qiang Shen Chuanbin Wang Lianmeng Zhang Hubei Key Laboratory of Advanced Technology for Automotive Components Wuhan University of TechnologyWuhan 430070China State Key Lab of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China Wuhan Second Ship Design and Research Institute Wuhan 430205China Department of Chemical and Materials Engineering University of AucklandPrivate Bag 92019Auckland 1142New Zealand

In this work,we synthesized a brand-new Al foam with a periodic structure via a simple powder metallurgical *** periodic architecture consists of both hierarchical porous and bi-directional composition-graded *** results show that the hierarchical porous material includes large pores on millimeter scale inheriting from the hollow structure of the Al tubes,and small pores on mi-crometer scale produced by the sintering of Al/Mg *** bi-directional Mg concentration-graded structure is formed in the tube walls due to the condensation of Mg vapor in the inner tube *** addition of Mg powders achieves excellent metallurgical bonding between the Al powders and the hollow tubes at 550℃.The plateau stress and energy absorption capacity of the Al foam in y-axis compression are significantly higher than that in the x-axis due to their anisotropic *** general,the Al foam with Mg addition presents the most superior compression performance,and we believe that our find-ings could open up a unique strategy for developing high-performance metallic foams with the periodic architecture involving both hierarchical porous and bi-directional graded structure.

关键词： Al foam Hollow Al tube Mg evaporation Bi-directional composition-graded structure Compression properties Energy absorbing performance

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Efficient Construction of Chiral Binaphthalene-Core Phosphepine Compounds Using Palladium-Catalyzed C—P Coupling Reactions

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有机化学 2024年第12期44卷 3771-3783页

作者： Wang Cuiying Zhang Ying Zheng Jia-Lian Yuan Ji Meng Sixuan Chen Jian Yu Guang-Ao State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200 International Joint Research Center for Intelligent Biosensor Technology and Health National Key Laboratory of Green PesticidesCollege of ChemistryCentral China Normal UniversityWuhan 430079

Binaphthalene-core phosphepine compounds with axial chirality belong to an important class of organocatalysts and ligands used in catalytic asymmetric ***,the number and application of these compounds have been limited due to the lack of efficient synthetic methods currently available to ***,a simple and efficient palladium-catalyzed C—P cross-coupling reaction of enantiopure(R)-1 with a variety of aryl and heteroaryl halides is *** reaction provides access to a series of chiral binaphthalene-core phosphepine compounds using Pd(OAc)2/dippf as a catalyst,which allows most products to be formed in moderate to high yields(40%~92%)with excellent ee values(90%~99%ee).

关键词： Pd catalysis chiral axially binaphthalene C-P coupling reactions

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Internal magnetic-field-enhanced photogenerated charge separation in ferromagnetic TiO_(2)surface heterojunctions

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Journal of materials Science & technology 2023年第29期160卷 240-247页

作者： Guojing Wang Shirong Xiong Yonghui Chen Chunchang Wang Shasha Lv Ke Jia Yunjie Xiang Jianbo Liu Chong Liu Zhengcao Li School of Materials and Energy Lanzhou UniversityLanzhou 730000China State Key Laboratory of New Ceramics and Fine Processing Key Laboratory of Advanced Materials(MOE)School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Laboratory of Dielectric Functional Materials School of Physics and Material ScienceAnhui UniversityHefei 230601China Key Laboratory of Beam Technology Ministry of EducationCollege of Nuclear Science and TechnologyBeijing Normal UniversityBeijing 100875China School of Materials and Energy Southwest UniversityChongqing 404100China

The use of the internal magnetic field of ferromagnets can effectively promote charge separation and transfer(CST)in photoelectrochemical energy ***,photoelectrochemical materials with a ferromagnetic field are scarce,and the internal magnetic field is negligible in nonferromagnetic *** address this issue,we propose a rational method for preparing ferromagnetic TiO_(2)powder using controllable oxygen vacancies in anatase TiO_(2)with co-exposed{001}and{101}***,an ex-cellent saturation magnetisation of 0.0014 emu/g in TiO_(2)is achieved owing to an asymmetric and uneven charge *** with that of nonferromagnetic TiO_(2),the efficiency of photocatalytic hydro-gen generation of ferromagnetic TiO_(2)is improved by 0.64 *** enhancement of photocatalytic hy-drogen generation is due to the different forces exerted on the electrons and holes in the magnetic field,which significantly improve the photogenerated CST efficiency of ferromagnetic TiO_(2).This result high-lights the significant role of the synergistic regulation of the crystal structure and defects in regulating the ferromagnetic characteristics of *** findings of this study provide guidance for leveraging point defects to promote CST for high-efficiency solar-energy conversion systems.

关键词： Photocatalysis TiO_(2){001}-{101}surface heterojunctions Oxygen vacancies Ferromagnetic

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Synthesis and luminescence properties of apatite-type red-emitting Ba_(2)La_(8)(GeO_(4))_(6)O_(2):Eu^(3+)phosphors

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Journal of Rare Earths 2021年第11期39卷 1320-1326,I0001页

作者： Kun Nie Xiaoxue Ma Panlong Lin Navnita Kumar Luoxin Wang Lefu Mei State Key Laboratory of New Textile Materials&Advanced Processing Technology and Key Laboratory of Textile Fiber and Products(Ministry of Education) School of Materials Science and EngineeringWuhan Textile UniversityWuhan 430200China Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes National Laboratory of Mineral MaterialsSchool of Materials Science and TechnologyChinaUniversity of Geosciences(Beijing)Beijing 100083China Department of Chemistry and Biochemistry University of CaliforniaLos AngelesCA 90095USA

A new kind of apatite-type red-emitting Ba_(2)La_(8)(GeO_(4))_(6)O_(2):Eu^(3+)phosphor was prepared by high temperature solid-state *** Rietveld analysis based on the powder diffraction data shows that Ba_(2)La_(8)(GeO_(4))_(6)O_(2):Eu^(3+)phosphors possess a pure apatite phase without any *** emission spectrum of Ba_(2)La_(8)(GeO_(4))_(6)O_(2):Eu^(3+)phosphor consists of two bands,an orange emission band from 500 to 600 nm and a red emission band from 600 to 680 *** varying the amount of the doped europium ions from 0.02 to 0.14 mol,it is found that the luminescent properties of this rare earth phosphor are the best when the concentration of europium ion is 0.08 *** optimum concentration is eventually proved to be 0.08 *** Eu^(3+)doping dependent luminescence quenching can be further ascribed to dipole-quadrupole *** quantum yield of Ba_(2)La_(7.92)(GeO_(4))_(6)O_(2):0.08 Eu^(3+)is 37.23%.The CIE analysis confirms a reddish emission in the near ultraviolet(n-UV)*** these above properties of the phosphor can help in contribution of promoting white light-emitting diode.

关键词： Apatite Calcination Phosphor Optical property Luminescence Rare earths

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Dealloyed TiCuMn efficiently catalyze the NO reduction and Zn-NO batteries

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Frontiers of Chemical Science and Engineering 2024年第9期18卷 51-59页

作者： Lang Zhang Tong Hou Weijia Liu Yeyu Wu Tianran Wei Junyang Ding Qian Liu Jun Luo Xijun Liu State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures MOE Key Laboratory of New Processing Technology for Nonferrous Metals and MaterialsSchool of ResourcesEnvironment and MaterialsGuangxi UniversityNanning 530004China Education Department of Guangxi Zhuang Autonomous Region Key Laboratory of Applied Analytical ChemistryGuangxi Collaborative Innovation Center for Chemistry and Engineering of Forest ProductsGuangxi Key Laboratory of Chemistry and Engineering of Forest ProductsKey Laboratory of Chemistry and Engineering of Forest ProductsState Ethnic Affairs CommissionSchool of Chemistry and Chemical EngineeringGuangxi Minzu UniversityNanning 530006China Institute for New Energy Materials&Low-Carbon Technologies School of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China Institute for Advanced Study Chengdu UniversityChengdu 610106China ShenSi Lab Shenzhen Institute for Advanced StudyUniversity of Electronic Science and Technology of ChinaShenzhen 518110China

Electrocatalytic NO reduction reaction offers a sustainable route to achieving environmental protection and NH3 production targets as *** this work,a class of dealloyed Ti_(60)Cu_(33)Mn_(7)ribbons with enough nanoparticles for the high-efficient NO reduction reaction to NH_(3)is fabricated,reaching an excellent Faradaic efficiency of 93.2%at–0.5 V vs reversible hydrogen electrode and a high NH_(3) synthesis rate of 717.4μmol·h^(-1)·mg_(cat).^(-1) at–0.6 V vs reversible hydrogen *** formed nanoparticles on the surface of the catalyst could facilitate the exposure of active sites and the transportation of various reactive ions and ***,the Mn content in the TiCuMn ribbons modulates the chemical and physical properties of its surface,such as modifying the electronic structure of the Cu species,optimizing the adsorption energy of N^(*)atoms,decreasing the strength of the NO adsorption,and eliminating the thermodynamic energy barrier,thus improving the NO reduction reaction catalytic ***,a Zn-NO battery was fabricated using the catalyst and Zn plates,generating an NH_(3) yield of 129.1µmol·h^(-1)·cm^(-2)while offering a peak power density of 1.45 mW·cm^(-2).

关键词： nitric oxide reduction NH_(3)electrosynthesis TiCuMn alloy Mn modulation Zn-NO battery

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Reducing Cyclic Prefix Overhead Based on Symbol Repetition in NB-IoT-Based Maritime Communication

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China Communications 2022年第9期19卷 1-9页

作者： Tian Xiang Daiming Qu Faquan Zhang Dejin Kong School of Electronic and Electrical Engineering Wuhan Textile UniversityWuhan 430200China Sthe State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200China School of Electronic Information and Communication Huazhong University of Science and TechnologyWuhan 430074China

With the increasing maritime activities,a great demand of wide-area maritime digital data services is ***,Narrowband Internet of Things(NB-IoT)that can provide wide coverage has been expected as an application for maritime communication networks(MCNS).In this paper,we aim to enhance the spectral efficiency in NB-IoT by reducing the cyclic prefix(CP)overhead in random access signal without causing *** key point of the proposed scheme is the symbols transmitted for multiple times repeatedly in ***,all CP are removed and multi-path fading effect is eliminated by using a repeated symbol to cover the disturbed symbol to construct a circular convolution structure of the channel with the same effect as adding *** addition,a single-tap equalization is still *** validate the effectiveness of the proposed scheme,simulation results are carried out with respect to the bit error ratio(BER).

关键词： NB-IoT narrowband physical random access channel cyclic prefix spectral efficiency

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Aligne d nanofib ers incorporate d composite solid electrolyte for high-sensitivity oxygen sensing at medium temperatures

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Journal of materials Science & technology 2024年第14期181卷 189-197页

作者： Mengfei Zhang Lei Yao Yan Xing Jing Cheng Tianrang Yang Jianguo Liu Wei Pan Institute of Energy Power Innovation North China Electric Power UniversityBeijing 102206China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Shenzhen Key Laboratory of Special Functional Materials Shenzhen Engineering Laboratory for Advanced Technology of CeramicsGuangdong Research Center for Interfacial Engineering of Functional MaterialsCollege of Materials Science and EngineeringShenzhen UniversityShenzhen 518060China New Energy Technology Engineering Lab of Jiangsu Province School of ScienceNanjing University of Posts&Telecommunications(NUPT)Nanjing 210003China

otentiometric oxygen sensors have been widely used in internal combustion engines,industrial boilers,and metallurgical heat treatment ***,traditional oxygen sensors based on yttria-stabilized zirconia(YSZ)electrolyte can only be operated at elevated temperatures(>750℃)due to their rela-tively low ionic *** this study,we present a highly efficient micro-oxygen sensor that can be operated at a temperature as low as 300℃.This micro-oxygen sensor incorporates a composite solid electrolyte,i.e.,well-aligned gadolinium-doped cerium oxide(CGO)nanofibers embedded within a YSZ matrix(YSZ/CGO_(f)).The arrays of CGO nanofibers in the YSZ matrix are parallel to the conduction direc-tion,providing rapid conducting channels for oxygen *** from this design,the composite electrolyte leads to a conductivity of four times higher than that of traditional YSZ solid electrolytes at low *** enhancement in conductivity is attributed to the presence of a defective interfacial region between CGO_(f)and YSZ,which promotes the mobility of oxygen *** strategy of constructing fast ionic conduction in the composite electrolyte by using well-aligned nanofibers may be considered for the design and optimization of other micro/nano-devices including sensors,batteries,and fuel cells.

关键词： Oxygen sensor Nanofibers Composite electrolyte Ionic conduction

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用于电热转换、电磁屏蔽的导电陶瓷的简易大规模制备

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Engineering 2023年第2期21卷 143-151,M0006页

作者：李岱祺唐彬程德山吴静唐文杨赵仲李建强蔡光明王金凤王训该 State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200China Institute for Frontier Materials Deakin UniversityMelbourne/GeelongVIC 3216Australia

通过传统瓷砖制备工艺的干压法,制备了一种碳化酚醛树脂基导电陶瓷复合材料(CCC)。首先,将导电前驱体溶液(酚醛树脂)与陶瓷前驱体均匀混合,随后在单次热处理中同时实现了碳化和陶瓷化。碳化后的材料赋予复合材料出色的电导率和可靠的循... 详细信息

通过传统瓷砖制备工艺的干压法,制备了一种碳化酚醛树脂基导电陶瓷复合材料(CCC)。首先,将导电前驱体溶液(酚醛树脂)与陶瓷前驱体均匀混合,随后在单次热处理中同时实现了碳化和陶瓷化。碳化后的材料赋予复合材料出色的电导率和可靠的循环加热特性。在12 V电压下通电10 min后材料表面温度可达386℃,在20 V电压下达到400℃仅需48 s。红外热像图表明,热量在复合材料表明分布均匀,并且可以通过更改电路布置(串联或并联)来调节电热转换性能。此外,与普通陶瓷相比,导电陶瓷复合材料在8.2 GHz下表现出了26.2 dB的优异电磁屏蔽性能,并提升了光热转换性能。更重要的是,这种单次热处理加热生产导电陶瓷复合材料的方法成本较低,可在原有瓷砖生产线的基础上进行大规模生产。出色的电学性能促进了该陶瓷复合材料在焦耳加热中的应用(如除冰、烧水和烹饪)及电磁屏蔽领域的应用。

关键词：陶瓷复合材料电学性能电磁屏蔽红外热像图导电陶瓷陶瓷前驱体大规模制备焦耳加热

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