检索结果-内蒙古大学图书馆

Kinetic investigation of the energy storage process in graphene fiber supercapacitors:Unraveling mechanisms,fabrications,property manipulation,and wearable applications

引用

Carbon Energy 2025年第1期7卷 133-173页

作者： Juan Zhang Wenwen Liu Minzhi Du Qingli Xu Minren Hung Ruifang Xiang Meng Liao Xinhou Wang Bingjie Wang Aiping Yu Kun Zhang Key Laboratory of Textile Science and Technology(Donghua University) Ministry of EducationCollege of TextilesDonghua UniversityShanghaiChina Department of Chemical Engineering Waterloo Institute for NanotechnologyUniversity of WaterlooWaterlooONCanada Laboratory of Advanced Materials State Key Laboratory of Molecular Engineering of PolymersDepartment of Macromolecular ScienceFudan University2205 Songhu RdShanghai 200438China College of Mechanical Engineering Donghua UniversityShanghai 201620China

Graphene fiber supercapacitors(GFSCs)have garnered significant attention due to their exceptional features,including high power density,rapid charge/discharge rates,prolonged cycling durability,and versatile weaving ***,inherent challenges in graphene fibers(GFs),particularly the restricted ion-accessible specific surface area(SSA)and sluggish ion transport kinetics,hinder the achievement of optimal capacitance and rate *** existing reviews on GFSCs,a notable gap exists in thoroughly exploring the kinetics governing the energy storage process in *** review aims to address this gap by thoroughly analyzing the energy storage mechanism,fabrication methodologies,property manipulation,and wearable applications of *** theoretical analysis of the energy storage process,specific parameters in advanced GF fabrication methodologies are carefully summarized,which can be used to modulate nano/micro-structures,thereby enhancing energy storage *** particular,enhanced ion storage is realized by creating more ion-accessible SSA and introducing extra-capacitive components,while accelerated ion transport is achieved by shortening the transport channel length and improving the accessibility of electrolyte *** on the established structure-property relationship,several critical strategies for constructing optimal surface and structure profiles of GF electrodes are *** on the exceptional flexibility and wearability of GFSCs,the review further underscores their potential as foundational elements for constructing multifunctional e-textiles using conventional textile *** conclusion,this review provides insights into current challenges and suggests potential research directions for GFSCs.

关键词： fiber-shaped supercapacitor graphene ion storage ion transport wearable application

来源：评论

学校读者我要写书评

暂无评论

Angle-insensitive transmission and absorption with a PT phase transition via coupled interface states in hybrid one-dimensional photonic crystal heterostructures

引用

Physical Review A 2024年第5期109卷 053504-053504页

作者： Guochao Wei Beibei Wang Kang Du Bohan Zhang Cai Zhou Tingting Wang Weijia Han Wei Zhu Shengxiang Wang School of Mathematical and Physical Sciences Wuhan Textile University Wuhan 430200 China State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile University Wuhan 430200 China

Non-Hermitian systems offer novel methods for manipulating electromagnetic waves, including applications in sensing and mode conversion, attracting significant research interest. In this work, we propose a hybrid photonic crystal comprised of two topologically distinct heterostructures with angle-insensitive band gaps. This hybrid photonic crystal can sustain two topological interface states (TISs), and is considered as an optical non-Hermitian system. By precisely tuning of the coupling between these TISs, we achieve perfect wave transmission, revealing a parity-time (PT) phase transition, as evidenced by the evolution of the transmission spectra. Remarkably, the perfect transmission of waves remains resilient against fluctuating incident angles, ensured by the angle-tolerant photonic band gaps of the heterostructures. Additionally, we explore another hybrid photonic crystal heterostructure featuring two interface channels supporting the TIS and the Tamm plasma polariton. As the coupling between these two modes strengthens, two distinct resonance peaks emerge. Gradually reducing this coupling results in the merging of these peaks into a single peak. As the PT phase transition case, perfect wave absorption can be realized. Notably, the frequency shifts of the transmission and absorption peaks remain minimal, demonstrating a remarkable stability with an angle variation from 0 ° to 90 ° (Δf=1.4THz). These results further expand and complement the ongoing exploration of non-Hermitian topological physics.

关键词： Light propagation, transmission & absorption Phononic crystals Plasma waves Topological effects in photonic systems 1-dimensional systems Non-Hermitian systems

来源：评论

学校读者我要写书评

暂无评论

NASICONs-type solid-state electrolytes:The history,physicochemical properties,and challenges

引用

Interdisciplinary materials 2023年第1期2卷 91-110页

作者： Lixiao Zhang Yimeng Liu Ya You Ajayan Vinu Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina International School of Materials Science and Engineering Wuhan University of TechnologyWuhanChina Global Innovative Center for Advanced Nanomaterials(GICAN) School of EngineeringCollege of EngineeringScienceand the EnvironmentThe University of NewcastleCallaghanNew South Wales 2308Australia

Solid-state electrolytes are critical for the development of next-generation high-energy and high-safety rechargeable *** all the candidates,sodium(Na)superionic conductors(NASICONs)are highly promising because of their evident advantages in high ionic conductivity and high chemical/electrochemical *** concept of NASICONs was proposed by Hong and Goodenough et *** 1976 by reporting the synthesis and characterization of Na1+xZr2(SixP3−x)O12(0≤x≤3),which has attracted tremendous attention on the NASICONs-type solid-state *** this review,we are committed to describing the development history of NASICONs-type solid-state electrolytes and elucidating the contribution of Goodenough as a tribute to *** summarize the correlations and differences between lithium-based and sodium-based NASICONs electrolytes,such as their preparation methods,structures,ionic conductivities,and the mechanisms of ion *** challenges of NASICONs-structured electrolytes are discussed,and several research directions are proposed to tackle the obstacles toward practical applications.

关键词： electrode/electrolyte interface grain boundary resistance high ionic conductivity NASICONs solid-state electrolyte

来源：评论

学校读者我要写书评

暂无评论

Layer stacked SiO_(x) microparticle with disconnected interstices enables stable interphase and particle integrity for lithium-ion batteries

引用

Journal of Energy Chemistry 2023年第11期86卷 300-307,I0007页

作者： Yang Ren Xucai Yin Lizhi Xiang Rang Xiao Hua Huo Geping Yin Chunyu Du MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage and Institute of Advanced Chemical Power Sources School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001HeilongjiangChina Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology School of Chemistry and Chemical EngineeringGuangxi UniversityNanning 530004GuangxiChina

Severe mechanical fractu re and unstable interphase,associated with the large volumetric expansion/contraction,significantly hinder the application of high-capacity SiO_(x)materials in lithium-ion ***,we report the design and facile synthesis of a layer stacked SiO_(x)microparticle(LS-SiO_(x))material,which presents a stacking structure of SiO_(x)layers with abundant disconnected *** LS-SiO_(x)microparticle can effectively accommodate the volume expansion,while ensuring negligible particle *** importantly,the interstices within SiO_(x)microparticle are disconnected from each other,which efficiently prevent the electrolyte from infiltration into the interior,achieving stable electrode/-electrolyte ***,the LS-SiO_(x)material without any coating delivers ultrahigh average Coulombic efficiency,outstanding cycling stability,and full-cell *** 6 cycles can attain>99.92%Coulombic efficiency and the capacity retention at 0.05 A g^(-1)for 100 cycles exceeds99%.After 800 cycles at 1 A g^(-1),the thickness swelling of LS-SiO_(x)electrode is as low as 0.87%.Moreover,the full cell with pure LS-SiO_(x)anode exhibits capacity retention of 91.2%after 300 cycles at 0.2 *** work provides a novel concept and effective approach to rationally design silicon-based and other electrode materials with huge volume variation for electrochemical energy storage applications.

关键词： Lithium-ion batteries Silicon oxide Layer stacked structure Disconnected interstices Coulombic efficiency

来源：评论

学校读者我要写书评

暂无评论

Effect of content and spin state of iron on electronic properties and floatability of iron-bearing sphalerite:A DFT+U study

引用

International Journal of Mining Science and technology 2023年第12期33卷 1563-1571页

作者： Yao Feng Zhuofan Li Jianhua Chen Ye Chen State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures School of Chemistry&Chemical EngineeringGuangxi UniversityNanning 530004China MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materials Guangxi UniversityNanning 530004China School of Resources Environment and MaterialsGuangxi Higher School Key Laboratory of Minerals EngineeringGuangxi UniversityNanning 530004China

Iron is an impurity widely occurred in sphalerite,and its effect on sphalerite flotation is *** this work,the effects of iron content and spin state on electronic properties and floatability of iron-bearing sphalerite are comprehensively studied using density functional theory Hubbard U(DFT+U)calculations combined with coordination chemistry *** band gap of ideal sphalerite is 3.723 eV,and thus electron transition is difficult to occur,resulting in poor *** results suggest the band gap of sphalerite decreases with increasing iron *** low iron content,the decreased band gap facilitates electron transition;at this case,Fe^(2+)in a high-spin state possesses oneπelectron pair,which can form a weakπ-backbonding with xanthate,causing increasing ***,for medium and high iron-bearing sphalerite,with the further decrease of band gap,Fe^(2+)is oxidized to Fe^(3+)due to electrochemical interaction,and henceπ-backbonding is eliminated,leading to lower floatability of iron-bearing sphalerite,which is consistent with the flotation experimental *** work could give a deeper understanding of how sphalerite flotation behaviors are affected by iron content.

关键词： Sphalerite Iron-bearing sphalerite Iron content Spin state Density functional theory

来源：评论

学校读者我要写书评

暂无评论

Recent Progress in the Auxiliary Phase Enhanced Flexible Piezocomposites

引用

Energy & Environmental materials 2025年第1期8卷 292-312页

作者： Xin Gao Mupeng Zheng Boyue Hou Junshu Wu Mankang Zhu Yunfan Zhang Ke Wang Bing Han College of Materials Science and Engineering Beijing University of TechnologyBeijing 100124China School of Basic Medical Sciences Capital Medical UniversityBeijing 100069China Department of Orthodontics Peking University School and Hospital of Stomatology&National Center of Stomatology&National Engineering Laboratory for Digital and Material Technology of Stomatology&NMPA Key Laboratory for Dental MaterialsBeijing 100089China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China

Piezocomposites with both flexibility and electromechanical conversion characteristics have been widely applied in various fields,including sensors,energy harvesting,catalysis,and biomedical *** the composition of piezocomposites or their preparation process,a category of materials is commonly employed that do not possess piezoelectric properties themselves but play a crucial role in performance *** this review,the concept of auxiliary phase is first proposed to define these materials,aiming to provide a new perspective for designing high-performance *** different categories of modulation forms of auxiliary phase in piezocomposites are systematically summarized,including the modification of piezo-matrix,the modification of piezo-fillers,and the construction of special *** category emphasizes the role of the auxiliary phase and systematically discusses the latest advancements and the physical mechanisms of the auxiliary phase enhanced flexible ***,a summary and future outlook of piezocomposites based on the auxiliary phase are provided.

关键词： auxiliary phase flexibility microstructure piezocomposites piezoelectricity

来源：评论

学校读者我要写书评

暂无评论

Robust architecture of 2D nano Mg-based borohydride on graphene with superior reversible hydrogen storage performance

引用

Journal of materials Science & technology 2023年第15期146卷 121-130页

作者： Xuancheng Wang Yuxiao Jia Xuezhang Xiao Panpan Zhou Jiapeng Bi Jiacheng Qi Ling Lv Fen Xu Lixian Sun Lixin Chen State Key Laboratory of Silicon Materials School of Materials Science and EngineeringZhejiang UniversityHangzhou 310027China Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials School of Material Science and EngineeringGuilin University of Electronic TechnologyGuilin 541004China Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province Hangzhou 310013China

Efficient technical strategies to synthesize hydrides with high capacity and favorable reversibility are significant for the development of novel energy ***,nano Mg-based borohydride,Mg(BH_(4))_(2),with robust architecture was designed and prepared by confining on graphene through a solution selfconfinement *** Mg(BH_(4))_(2) confined on graphene displays a wrinkled 2D nano layer morphology within 8.8 nm *** 2D nano Mg(BH_(4))_(2) can start dehydrogenation at 67.9℃ with a high capacity of 12.0 wt.%,which is 190.5℃ lower than pristine Mg(BH_(4))_(2).The isothermal dehydrogenation tests and kinetics fitting results indicate the 2D nano Mg(BH_(4))_(2) possesses much-enhanced dehydrogenation kinetics of 31.3 kJ/mol activation energy,which is only half of pristine Mg(BH_(4))_(2).The thermodynamics of the 2D nano Mg(BH_(4))_(2) is also verified by PCT tests,of which Gibbs free energy value for the confined 2D nano Mg(BH_(4))_(2) is estimated to be-18.01 kJ/mol H_(2),lower than-16.36 kJ/mol H_(2) of pristine Mg(BH_(4))_(2).Importantly,the reversibility of the confined 2D nano Mg(BH_(4))_(2) is significantly enhanced to over 90%capacity retention with relatively kinetics stability during 10 *** mechanism analyses manifest that Mg(BH_(4))_(2) exhibits stable 2D nano morphology during 10 cyclic tests,resulting in the greatly reduced H diffusion path and the improved de/rehydrogenation kinetics of the 2D nano Mg(BH_(4))_(2).Based on theoretical calculations of Mg(BH_(4))_(2) and the intermediate MgB12H12 confined on graphene,the charge transfer status of both samples is modified to facilitate de/rehydrogenation,thus leading to the significant thermodynamic improvements of the reversible hydrogen storage performances for 2D nano Mg(BH_(4))_(2).Such investigation of the Mg-based borohydride will illuminate prospective technical research of energy storage materials.

关键词： Mg(BH_(4))_(2) Nano-confinement Kinetics Thermodynamics Reversible hydrogen storage

来源：评论

学校读者我要写书评

暂无评论

Inhibiting Voltage Decay in Li-Rich Layered Oxide Cathode:From O3-Type to O2-Type Structural Design

引用

Nano-Micro Letters 2024年第12期16卷 81-102页

作者： Guohua Zhang Xiaohui Wen Yuheng Gao Renyuan Zhang Yunhui Huang Institute of New Energy for Vehicles Shanghai Key Laboratory for R&D and Application of Metallic Functional MaterialsSchool of Materials Science and EngineeringTongji UniversityShanghai 201804People’s Republic of China Contemporary Amperex Technology Co. LtdNingde 352100People’s Republic of China State Key Laboratory of Material Processing and Die and Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074HubeiPeople’s Republic of China

Li-rich layered oxide(LRLO)cathodes have been regarded as promising candidates for next-generation Li-ion batteries due to their exceptionally high energy density,which combines cationic and anionic redox ***,continuous voltage decay during cycling remains the primary obstacle for practical applications,which has yet to be fundamentally *** is widely acknowledged that voltage decay originates from the irreversible migration of transition metal ions,which usually further exacerbates structural evolution and aggravates the irreversible oxygen redox ***,constructing O2-type structure has been considered one of the most promising approaches for inhibiting voltage *** this review,the relationship between voltage decay and structural evolution is systematically *** to suppress voltage decay are systematically ***,the design of O2-type structure and the corresponding mechanism of suppressing voltage decay are comprehensively ***,the reported O2-type LRLO cathodes still exhibit partially disordered structure with extended ***,the factors that may cause the irreversible transition metal migrations in O2-type LRLO materials are also explored,while the perspectives and challenges for designing high-performance O2-type LRLO cathodes without voltage decay are proposed.

关键词： Lithium-ion batteries Li-rich layered oxide Voltage decay Migration of transition metal ions O2-type structural design

来源：评论

学校读者我要写书评

暂无评论

Hierarchical cobalt-molybdenum layered double hydroxide arrays power efficient oxygen evolution reaction

引用

Nano Research 2024年第6期17卷 5080-5086页

作者： Xinyi Zhu Jiahui Lyu Shanshan Wang Xingchuan Li Xiaoyu Wei Cheng Chen Wanida Kooamornpattana Francis Verpoort Jinsong Wu Zongkui Kou State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Sanya Science and Education Innovation Park of Wuhan University of Technology Sanya 572000China Nanostructure Research Center Wuhan University of TechnologyWuhan 430070China Department of Chemical Engineering Faculty of EngineeringMahidol UniversityNakhon Pathom 73170Thailand

Transition metal-based layered double hydroxides(LDHs)have been capable of working efficiently as catalysts in the basic oxygen evolution reaction(OER)for sustaining hydrogen production of alkaline water ***,exploring new LDH-based electrocatalysts featuring both remarkable activity and good stability is still in high demand,which is pivotal for comprehensive understanding and impressive improvement of the sluggish OER ***,a series of bimetallic(Co and Mo)LDH arrays were designed and fabricated via a facile and controlled strategy by incorporating a Mo source into presynthesized Co-based metal-organic framework(MOF)arrays on carbon cloth(CC),named as ZIF-67/CC *** found that tuning the Mo content resulted in gradual differences in the structural properties,surface morphology,and chemical states of the resulting catalysts,namely CoMox-LDH/CC(x representing the added weight of the Mo source).Gratifyingly,the best-performing CoMo_(0.20)-LDH/CC electrocatalyst demonstrates a low overpotential of only 226 mV and high stability at a current density of 10 mA·cm^(−2),which is superior to most LDH-based OER catalysts reported ***,it only required 1.611 V voltage to drive the overall water splitting device at the current density of 10 mA·cm^(−2).The present study represents a significant advancement in the development and applications of new OER catalysts.

关键词： layered double hydroxides(LDHs) metal-organic frameworks(MOFs) array catalysts Mo modification electrocatalytic oxygen evolution reaction(OER)

来源：评论

学校读者我要写书评

暂无评论

Synthesis and mechanical and elevated temperature tribological properties of a novel high-entropy(TiVNbMoW)C_(4.375) with carbon stoichiometry deviation

引用

Journal of advanced Ceramics 2023年第2期12卷 242-257页

作者： Jicheng LI Yanchun ZHOU Yunfeng SU Shuna CHEN Qiuan SUN Hengzhong FAN Junjie SONG Litian HU Yongsheng ZHANG State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Science and Technology on Advanced Functional Composite Laboratory Aerospace Research Institute of Materials&Processing TechnologyBeijing 100076China

High-entropy carbides are a nascent group of ceramics that are promising for high-temperature applications due to the combination of good stability,high hardness(H),high strength,and superior creep resistance that they *** to high melting points and low lattice diffusion coefficients,however,the high-entropy carbides are usually difficult to consolidate to a nearly full *** cope with this challenge,herein,binary carbides including TiC,V_(8)C_(7),NbC,Mo_(2)C,and WC with different carbon stoichiometry were used to prepare dense high-entropy(TiVNbMoW)C_(4.375),and the influence of carbon vacancy on formation ability and mechanical properties of carbon-deficient high-entropy(TiVNbMoW)C_(4.375) were ***,although the starting binary carbides have different crystal structures and carbon stoichiometry,the as-prepared high-entropy material showed a rock-salt structure with a relatively high density(98.1%)and good mechanical properties with hardness of 19.4±0.4 GPa and fracture toughness(KIC)of 4.02 MPa·m^(1/2).More importantly,the high-entropy(TiVNbMoW)C_(4.375) exhibited low coefficient of friction(COF)at room temperature(RT)and 800℃.Wear rate(W)gradually increased with the temperature rising,which were attributed to the formation of low-hardness oxidation films at high temperatures to aggravate *** 800℃,lubricating films formed from sufficient oxidation products of V_(2)O_(5) and MoO_(3) effectively improved tribological behavior of the high-entropy(TiVNbMoW)C_(4.375).Wear mechanisms were mainly abrasive wear resulting from grain pullout and brittle fracture as well as oxidation wear generated from high-temperature *** results are useful as valuable guidance and reference to the synthesis of high-entropy ceramics(HECs)for sliding parts under high-temperature serving conditions.

关键词： high-entropy ceramics(HECs) transition metal(TM)carbides carbon stoichiometry deviation tribological performances wear

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：